CN114085698A - 一种环保润滑油及其制备方法 - Google Patents
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 20
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- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000012964 benzotriazole Substances 0.000 claims abstract description 15
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 14
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- 238000003756 stirring Methods 0.000 claims description 3
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- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 2
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- 125000000217 alkyl group Chemical group 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
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- 238000004364 calculation method Methods 0.000 description 1
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- 229910052802 copper Inorganic materials 0.000 description 1
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- 230000007812 deficiency Effects 0.000 description 1
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
- C10M2207/2835—Esters of polyhydroxy compounds used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/043—Ammonium or amine salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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Abstract
本发明涉及润滑油技术，特别是涉及一种环保润滑油及其制备方法。本发明提供了一种环保润滑油为：在新戊基多元醇酯中加入占新戊基多元醇酯重量百分比的下述物质：含氮硼酸酯：0.24～0.96％、二烃基五硫化物：0.24～0.42％、磷之星：0.10～0.30％，硫化异丁烯0.1～0.3％，苯三唑脂肪胺盐：0.09～0.63％。本发明具有较高的承载能力和较好的润滑减磨性能。
Description
本申请是申请日为2016年06月24日、申请号为201610471729.6、发明名称为《新戊基多元醇酯中添加含氮硼酸酯等多种添加剂的环保润滑油》的分案申请。
技术领域
本发明涉及润滑油技术，特别是涉及一种环保润滑油及其制备方法。
背景技术
润滑油是用在各种类型机械上以减少摩擦，保护机械及加工件的液体润滑剂，主要起润滑、冷却、防锈、清洁、密封和缓冲等作用。润滑油一般是由基础油和功能性添加剂组成。基础油是润滑油的主要成分，决定着润滑油的基本性质，添加剂则可弥补和改善基础油性能方面的不足，赋予某些新的性能，是润滑油的重要组成部分。
目前，公开号为CN107384549A的中国专利公开了一种压铸机用耐低温润滑油及其制备方法，其中，润滑油的原料按重量份数配比如下：基础油、十二烷基酸性亚磷酸酯、石墨、乙醚、硬脂酸、甲基硅油、聚氧乙烯、沸石、抗磨剂、纳米二氧化钛、乙丙共聚物、二甲基亚砜、分散剂、消泡剂和抗氧化剂，但是其高低温的高承载性能和抗磨性能不佳。
发明内容
本发明要解决的技术问题是，提供一种具有优良的高低温的高承载和抗磨性能，满足各种齿轮润滑的含硼和氮添加新戊基多元醇酯(NPE-3)环保润滑油。
采用的技术方案是：
本发明提供了一种环保润滑油，在新戊基多元醇酯(NPE-3)中加入占新戊基多元醇酯重量百分比的下述物质：含氮硼酸酯：0.24～0.96％、二烃基五硫化物：0.24～0.42％、磷之星：0.10～0.30％，硫化异丁烯0.1～0.3％，苯三唑脂肪胺盐：0.09～0.63％。
优选地，所述含氮硼酸酯为含氮硼酸酯BN。
优选地，所述新戊基多元醇酯为NPE-3。
优选地，所述二烃基五硫化物为Rc2540。
优选地，所述硫化异丁烯为T321。
优选地，所述苯三唑脂肪胺盐为T406E。
本发明还提供了上述所述环保润滑油的制备方法，包括以下步骤：
在新戊基多元醇酯加入含氮硼酸酯、二烃基五硫化物、磷之星、硫化异丁烯、苯三唑脂肪胺盐搅拌后加热，得到所述环保润滑油；
所述加热的温度为80℃，时间为40min。
本发明在合成油新戊基多元醇酯(NPE-3)中添加硼系添加剂含氮硼酸酯、二烃基五硫化物(RC2540)、磷之星(P120)、硫化异丁烯(T321)、苯三唑脂肪胺盐(T-406E)5种添加剂中进行试验，使用人工神经网络方法优化计算，并进行了复证。同时，利用添加剂含量范围为：硼系添加剂含氮硼酸酯0～0.96％、二烃基五硫化物0～0.48％、磷之星P120：0～0.40％，硫化异丁烯(T321)0～0.40％，作5因素9水平均匀分配，设计出新戊基多元醇酯(NPE-3)加入五种添加剂含量配比的九个组合，得到5种添加剂的含量配比优化设计，最大无卡咬负荷为Pb＝1970N，
研究采用5因素9水平测试。考察目标为Y1＝Pb,Y2＝D,Y3＝D,使用均匀设计表安排试验，试验结果，研究应用于合成油中添加剂在可生物降解基础油中的摩擦学研究。本发明提供的环保润滑油润滑性能好、承载能力高的特点。
具体实施方式
实施例一
以新戊基多元醇酯(NPE-3)为基础油，加入占NPE-3以下含量的添加剂：含氮硼酸酯BN：0.96％、二烃基五硫化物：Rc2540：0.36％、磷之星0.10％，硫化异丁烯(T321)0.20％，苯三唑脂肪胺盐T406E：0.45％，搅拌均匀后80℃加热40分钟，即得。
实施例二
以新戊基多元醇酯(NPE-3)基础油加入占新戊基多元醇酯重量百分比：含氮硼酸酯BN:0.6％、二烃基五硫化物:Rc2540：0.42％、磷之星0.15％，硫化异丁烯(T321)0.10％，苯三唑脂肪胺盐T406E：0.09％，混合搅拌均匀后80℃加热40分钟，即得。
实施例三
以新戊基多元醇酯(NPE-3)基础油加入占新戊基多元醇酯重量百分比：含氮硼酸酯BN 0.72％、二烃基五硫化物:Rc2540：0.24％、磷之星0.30％，硫化异丁烯(T321)0.30％，苯三唑脂肪胺盐T406E：0.63％，混合搅拌均匀后80℃加热40分钟，即得。
实施例四
是以新戊基多元醇酯(NPE-3)含氮硼酸酯BN：0.72％、二烃基五硫化物:Rc2540：0.24％、磷之星0.30％，硫化异丁烯T3210.30％，苯三唑脂肪胺盐T406E：0.63％。经加热混合均匀制成。
所述新戊基多元醇酯(NPE-3)基邻位为季碳原子的一类合成酯，比双酯具有更优异的热和水解稳定性，主要包括新戊二醇酯、三羟甲基丙烷酯和季戊四醇酯。
本发明具有较高的承载能力和较好的润滑减磨性能。
所述氮硼酸酯BN是含硼的硼酸盐类添加剂。硼系列添加剂无毒无味且具有良好的极压、抗磨、减摩、热氧化稳定、防腐蚀、密封适应等性能。硼系列添加剂的生物降解率能达到95％以上。在齿轮润滑油领域表现出了巨大的环保潜力。硼酸酯具有很好的减摩、抗磨性能。含氮硼酸酯，十八烷氧基氮代硼酸钙由摩擦改进剂、抗金属腐蚀剂、抗氧化剂等剂复配而成，油溶性佳，颜色浅且持久存放不变颜色，具有突出的极压抗磨性、热氧化稳定性能，是新型环保极压抗磨剂。
基础油新戊基多元醇酯(Neopentyl Polyol Ester)NPE-3，新戊基多元醇酯具有优良的高、低温性能，闪点高，倾点低，它的粘度较低，一般常用作Ⅱ型航空发动机油，高温链条油，合成空气压缩机油与之环保制冷剂相容的冷冻机油的基础油，其理化性能见表1。
表1新戊基多元醇酯(NPE-3)的理化性能
磷之星极压抗磨剂(P120)含磷类的极压剂主要有磷之星P120和亚磷之星P110。磷之星P120，具有极好的极压抗磨性能，主要用于重负荷工业齿轮油。磷之星P120是由低碳醇与三氯氧磷反应制的烷基磷酸盐，再与有机胺与磷酸酯反应生成。因有机胺的烷基基团小极压性能高。它属于磷系列添加剂，具有较好的润滑性能。磷之星极压抗磨剂，是有机磷酸胺盐，该剂有非常高的抗磨性和极压性，这一特性，是国内外任何添加剂都无法比拟的。用该剂复配的各种通用齿轮油复剂等。磷之星(P120)的理化性能见表2。
表2磷之星(P120)的理化性能
硫化异丁烯Sulphurizedisobutylene，T321可与硫磷氮剂复配，是硫磷型工业齿轮油和GL-4、GL-5车辆齿轮油的主剂，也可用于金属加工用油，润滑脂等产品中。硫含量高，相对于一般的硫烯产品而言，具有更优异的极压、抗磨性能。氯含量极低，铜腐蚀性能良好。在各类基础油中均具有很好的相溶性。与其它极压抗磨剂具有优秀的协同效果，T321是车辆及工业用油中首选的极压抗磨剂,但T321有强烈的异味，人们要解决环保车辆齿轮油就要寻找其替代品。硫化异丁烯的理化性能见表3。
表3硫化异丁烯(T321)的理化性能
T406E多功能添加剂产品性能苯三唑脂肪胺盐(T-406E)具有抗磨、抗腐、抗氧化、防锈等多种功能。长期以来，在国内生产的齿轮油、抗磨液压油、润滑脂等，二十余种润滑油、脂中得到成功应用。苯三唑脂肪胺盐(T-406E)的理化性能见表4。
表4苯三唑脂肪胺盐(T-406E)的理化性能
以上所述仅为本发明的优选实施例而已，并不用于限制本发明，对于本领域的技术人员来说，本发明可以有各种更改和变化。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (7)
1.一种环保润滑油，其特征在于，在新戊基多元醇酯中加入占新戊基多元醇酯重量百分比的下述物质：含氮硼酸酯：0.24～0.96％、二烃基五硫化物：0.24～0.42％、磷之星：0.10～0.30％，硫化异丁烯0.1～0.3％，苯三唑脂肪胺盐：0.09～0.63％。
2.根据权利要求1所述的环保润滑油，其特征在于，所述含氮硼酸酯为含氮硼酸酯BN。
3.根据权利要求1所述的环保润滑油，其特征在于，所述新戊基多元醇酯为NPE-3。
4.根据权利要求1所述的环保润滑油，其特征在于，所述二烃基五硫化物为Rc2540。
5.根据权利要求1所述的环保润滑油，其特征在于，所述硫化异丁烯为T321。
6.根据权利要求1所述的环保润滑油，其特征在于，所述苯三唑脂肪胺盐为T406E。
7.权利要求1～6任一项所述环保润滑油的制备方法，包括以下步骤：
在新戊基多元醇酯加入含氮硼酸酯、二烃基五硫化物、磷之星、硫化异丁烯、苯三唑脂肪胺盐搅拌后加热，得到所述环保润滑油；
所述加热的温度为80℃，时间为40min。
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| CN103614194A (zh) * | 2013-11-22 | 2014-03-05 | 沈阳理工大学 | 一种新戊基多元醇酯汽车齿轮润滑油组合物 |
| CN103756765A (zh) * | 2013-12-27 | 2014-04-30 | 沈阳理工大学 | 一种含有硫稀的新戊基多元醇酯汽车齿轮润滑油 |
| CN104388164A (zh) * | 2014-11-03 | 2015-03-04 | 沈阳理工大学 | 一种含有硼和氮化合物的齿轮润滑油 |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101298578A (zh) * | 2007-04-30 | 2008-11-05 | 中国石油天然气股份有限公司 | 小轿车手动变速箱齿轮润滑油组合物 |
| CN103614194A (zh) * | 2013-11-22 | 2014-03-05 | 沈阳理工大学 | 一种新戊基多元醇酯汽车齿轮润滑油组合物 |
| CN103756765A (zh) * | 2013-12-27 | 2014-04-30 | 沈阳理工大学 | 一种含有硫稀的新戊基多元醇酯汽车齿轮润滑油 |
| CN104388164A (zh) * | 2014-11-03 | 2015-03-04 | 沈阳理工大学 | 一种含有硼和氮化合物的齿轮润滑油 |
Non-Patent Citations (1)
| Title |
|---|
| 程丽华等: "《石油产品基础知识》", 31 January 2008, 中国石化出版社 * |
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