CN114032130A - 一种用于高速轧机的专用工艺油及其制备工艺 - Google Patents
一种用于高速轧机的专用工艺油及其制备工艺 Download PDFInfo
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- 239000010734 process oil Substances 0.000 title claims abstract description 27
- 238000005096 rolling process Methods 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims description 5
- 239000000203 mixture Substances 0.000 claims abstract description 24
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002562 thickening agent Substances 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 10
- IWLBIFVMPLUHLK-UHFFFAOYSA-N azane;formaldehyde Chemical compound N.O=C IWLBIFVMPLUHLK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002199 base oil Substances 0.000 claims abstract description 8
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- KMYDSFJEYTVXKR-UHFFFAOYSA-B molybdenum(4+) tetrathiophosphate Chemical compound P(=S)([O-])([O-])[O-].[Mo+4].P(=S)([O-])([O-])[O-].P(=S)([O-])([O-])[O-].P(=S)([O-])([O-])[O-].[Mo+4].[Mo+4] KMYDSFJEYTVXKR-UHFFFAOYSA-B 0.000 claims abstract description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 7
- 239000010452 phosphate Substances 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims abstract description 7
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- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 7
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 5
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000012964 benzotriazole Substances 0.000 claims abstract description 5
- ONKUXPIBXRRIDU-UHFFFAOYSA-N Diethyl decanedioate Chemical compound CCOC(=O)CCCCCCCCC(=O)OCC ONKUXPIBXRRIDU-UHFFFAOYSA-N 0.000 claims abstract description 3
- JZTPOMIFAFKKSK-UHFFFAOYSA-N O-phosphonohydroxylamine Chemical compound NOP(O)(O)=O JZTPOMIFAFKKSK-UHFFFAOYSA-N 0.000 claims abstract description 3
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- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 3
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- DMBHHRLKUKUOEG-UHFFFAOYSA-N N-phenyl aniline Natural products C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 4
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- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 claims description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 150000003463 sulfur Chemical class 0.000 claims description 2
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Substances SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
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- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
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- 239000003085 diluting agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
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Abstract
本发明公开了一种用于高速轧机的专用工艺油，包括基础油50‑90份、增稠剂20‑25份、极压抗磨剂12‑20份、抗氧化剂0.1‑0.5份、高分子添加剂0.1‑0.5份、金属钝化剂0.1‑0.3份；所述的基础油为葵二酸二‑2‑乙基乙酯、有机磷酸酯、有机硼酸酯中的任一种；所述的高分子添加剂为聚四氟乙烯、聚异丁烯中的一种或混合物；所述的增稠剂为硫代磷酸钼盐、硫代硼酸钼盐、二氧化硅、改性纳米金刚石、二氧化钛、氨基磷酸螯合树脂、磷酸环氧树脂中的一种或混合物；所述的金属钝化剂为苯三唑胺甲醛缩合物、噻二唑胺甲醛缩合物中的一种或混合物。通过增加增稠剂，可以保持工艺油的黏性，从而保证轧机的压辊表面可以覆盖一层均匀的油膜，并保证油膜不会出现断裂的情况。
Description
技术领域
本发明涉及金属成型加工油领域，尤其涉及一种用于高速轧机的专用工艺油及其制备工艺。
背景技术
高速轧机一般是用于薄板类金属的轧制，高速轧机的专用工艺油既要保证较好的润滑性，也要保证一定的成膜能力。
且由于环保的要求，含硫、磷等元素的工艺油逐渐退出了市场，水性高速轧机专用工艺油的市场需求越来越强烈，但是水性润滑油的成膜能力较劣，所以在配制用于高速轧机的专用工艺油时，需要格外关注工艺油的成膜能力，以及成膜后的防破裂能力。
发明内容
发明目的：为了解决现有技术中所存在的问题，本发明提出了一种用于高速轧机的专用工艺油。
技术方案：为达以上目的，本发明采取以下技术方案：一种用于高速轧机的专用工艺油，包括以下组分：
基础油50-90份、增稠剂20-25份、极压抗磨剂12-20份、抗氧化剂0.1-0.5份、高分子添加剂0.1-0.5份、金属钝化剂0.1-0.3份；
所述的基础油为葵二酸二-2-乙基乙酯、有机磷酸酯、有机硼酸酯中的任一种；
所述的高分子添加剂为聚四氟乙烯、聚异丁烯中的一种或混合物；
所述的增稠剂为硫代磷酸钼盐、硫代硼酸钼盐、二氧化硅、改性纳米金刚石、二氧化钛、氨基磷酸螯合树脂、磷酸环氧树脂中的一种或混合物；
所述的金属钝化剂为苯三唑胺甲醛缩合物、噻二唑胺甲醛缩合物中的一种或混合物。
优选的，所述抗氧剂为2，6-二叔丁基对甲酚、4,4'-硫代双苯硫酚、2，6-二叔丁基酚、烷基二苯胺、3，5-二叔丁基-4-羟基苯基丙烯酸甲酯中的一种或多种的混合物。
优选的，包括水基润滑剂，所述的水基润滑剂为石油硫磺盐、石油酸、有机硅中的一种或几种的混合物。
一种用于高速轧机的专用工艺油的制备方法，包括如下步骤：
S1、将基础油与增稠剂进行混合，并添加极压耐磨剂与金属钝化剂，搅拌均匀后，放入球磨机内混匀；
S2、加入高分子添加剂，置于超声波机中进行均匀分散处理；
S3、将经过分散处理的浆液放入在反应釜中，并通过水浴加热至100-150℃；
S4、加入助剂，控制降解温度在80℃左右，进行均匀反应；
S5、制得符合要求的专用工艺油。
优选的，S4中加入热稳定剂，所述的热稳定剂为硬质酸钙。
有益效果：
本工艺油具有优异的抗磨性、摩擦特性、可以长时间保持润滑稳定性，并具有很好的防腐防锈特性。
通过增加增稠剂，可以保持工艺油的黏性，从而保证轧机的压辊表面可以覆盖一层均匀的油膜，并保证油膜不会出现断裂的情况。
具体实施方式
实施例一：
一种用于高速轧机的专用工艺油，包括以下组分：
有机硼酸酯与有机磷酸酯的混合物75份；
硫代磷酸钼盐和二氧化硅的混合物23份；
极压抗磨剂纳米WS212份；
苯三唑胺甲醛缩合物0.2份；
烷基二苯胺、3，5-二叔丁基-4-羟基苯基丙烯酸甲酯的混合物0.4份；
聚四氟乙烯0.4份；
不可避免的杂质。
将75份有机硼酸酯与有机磷酸酯的混合物与23份硫代磷酸钼盐和二氧化硅的混合物进行混合，并添加12份纳米WS2，在球磨机内混匀；
加入聚四氟乙烯，置于超声波机中进行均匀的分散处理；
将经过分散处理的浆液放入在反应釜中，并通过水浴加热至100-150℃；
加入助剂，控制降解温度在80℃左右，进行均匀反应；
制得符合要求的专用工艺油。
实施例二：
一种用于高速轧机的专用工艺油，包括以下组分：
有机硼酸酯与有机磷酸酯的混合物70份；
硫代磷酸钼盐和二氧化硅的混合物25份；
极压抗磨剂纳米WS215份；
苯三唑胺甲醛缩合物0.3份；
烷基二苯胺、3，5-二叔丁基-4-羟基苯基丙烯酸甲酯的混合物0.5份；
聚四氟乙烯0.5份；
不可避免的杂质。
将70份有机硼酸酯与有机磷酸酯的混合物与25份硫代磷酸钼盐和二氧化硅的混合物进行混合，并添加15份纳米WS2，在球磨机内混匀；
加入聚四氟乙烯，置于超声波机中进行均匀的分散处理；
将经过分散处理的浆液放入在反应釜中，并通过水浴加热至100-150℃；
加入助剂，控制降解温度在80℃左右，进行均匀反应；
制得符合要求的专用工艺油。
对比例一：
不添加增稠剂与高分子添加剂，其余与实施例一相同。
对比例二：
不添加增稠剂与高分子添加剂，其余与实施例二相同。
测试结果如表1所示：
表1实施例与对比例制备产品性能对比
从表1的数据可以看出，本发明实施例一、二制备的一种用于高速轧机的专用工艺油各理化指标与对比例一、二制备的传统成型油相比，其理化性能更为优越。
上文提到的各文献经此引用并入本文。对任何文献的提及不是承认此类文献有资格作为现有技术或有权构成技术人员常识。除了在实施例中或在另行明确指明之处外，本说明书中指定材料量、反应条件、分子量、碳原子数等的所有数值量应被理解为用词语“大约”修饰。除非另行指明，本文提到的各化学品或组合物应该被认为是商品级材料，其可能含有异构体、副产物、衍生物和通常被理解为存在于商品级中的其它这样的材料。
但是，除非另行指明，各化学组分的量排除商业材料中常规存在的任何溶剂或稀释油。要理解的是，本文所列的上限和下限量、范围和比率限额可以独立地组合。类似地，本发明的各要素的范围和量可以与任何其它要素的范围或量一起使用。本文所用的术语“基本由...构成”允许包括不会实质影响所述组合物的基本和新型特性的物质。
Claims (5)
1.一种用于高速轧机的专用工艺油，其特征在于，包括以下组分：
基础油50-90份、增稠剂20-25份、极压抗磨剂12-20份、抗氧化剂0.1-0.5份、高分子添加剂0.1-0.5份、金属钝化剂0.1-0.3份；
所述的基础油为葵二酸二-2-乙基乙酯、有机磷酸酯、有机硼酸酯中的任一种；
所述的高分子添加剂为聚四氟乙烯、聚异丁烯中的一种或混合物；
所述的增稠剂为硫代磷酸钼盐、硫代硼酸钼盐、二氧化硅、改性纳米金刚石、二氧化钛、氨基磷酸螯合树脂、磷酸环氧树脂中的一种或混合物；
所述的金属钝化剂为苯三唑胺甲醛缩合物、噻二唑胺甲醛缩合物中的一种或混合物。
2.根据权利要求1所述的一种用于高速轧机的专用工艺油，其特征在于，所述抗氧剂为2，6-二叔丁基对甲酚、4,4'-硫代双苯硫酚、2，6-二叔丁基酚、烷基二苯胺、3，5-二叔丁基-4-羟基苯基丙烯酸甲酯中的一种或多种的混合物。
3.根据权利要求1所述的一种用于高速轧机的专用工艺油，其特征在于，包括水基润滑剂，所述的水基润滑剂为石油硫磺盐、石油酸、有机硅中的一种或几种的混合物。
4.一种用于高速轧机的专用工艺油的制备方法，其特征在于，包括如下步骤：
S1、将基础油与增稠剂进行混合，并添加极压耐磨剂与金属钝化剂，搅拌均匀后，放入球磨机内混匀；
S2、加入高分子添加剂，置于超声波机中进行均匀分散处理；
S3、将经过分散处理的浆液放入在反应釜中，并通过水浴加热至100-150℃；
S4、加入助剂，控制降解温度在80℃左右，进行均匀反应；
S5、制得符合要求的专用工艺油。
5.根据权利要求1所述的一种用于高速轧机的专用工艺油的制备方法，其特征在于，S4中加入热稳定剂，所述的热稳定剂为硬质酸钙。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080026967A1 (en) * | 2004-03-31 | 2008-01-31 | Nippon Oil Corporation | Metal Working Fluid |
| CN101245282A (zh) * | 2008-03-25 | 2008-08-20 | 佛山市顺德区远茂化工实业有限公司 | 一种金属拉丝润滑剂 |
| CN108085097A (zh) * | 2018-01-24 | 2018-05-29 | 合肥铭佑高温技术有限公司 | 一种高温设备润滑油 |
| CN109370716A (zh) * | 2018-10-22 | 2019-02-22 | 上海加美实业有限公司 | 一种润滑油及其制备方法 |
-
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080026967A1 (en) * | 2004-03-31 | 2008-01-31 | Nippon Oil Corporation | Metal Working Fluid |
| CN101245282A (zh) * | 2008-03-25 | 2008-08-20 | 佛山市顺德区远茂化工实业有限公司 | 一种金属拉丝润滑剂 |
| CN108085097A (zh) * | 2018-01-24 | 2018-05-29 | 合肥铭佑高温技术有限公司 | 一种高温设备润滑油 |
| CN109370716A (zh) * | 2018-10-22 | 2019-02-22 | 上海加美实业有限公司 | 一种润滑油及其制备方法 |
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