CN113993981A - 洗涤剂组合物 - Google Patents
洗涤剂组合物 Download PDFInfo
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- CN113993981A CN113993981A CN202080045586.7A CN202080045586A CN113993981A CN 113993981 A CN113993981 A CN 113993981A CN 202080045586 A CN202080045586 A CN 202080045586A CN 113993981 A CN113993981 A CN 113993981A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
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Abstract
本发明涉及洗涤剂组合物,其包含:(a)2‑25重量%的式R1‑(OCH2CH2)mOSO3H的醇醚硫酸盐,其中R1是饱和或单不饱和的,优选饱和的直链C12和/或C14烷基链并且其中m为1‑4;和(b)2‑25重量%的式R2‑(OCH2CH2)nOSO3H的醇醚硫酸盐,其中R2是饱和或单不饱和的直链C16和/或C18烷基链,并且其中n为5‑20;其中(a)与(b)的重量比为5:1至1:8。本发明还涉及一种用0.5‑20g/L的所述洗涤剂组合物的水溶液处理纺织品的家用方法。
Description
技术领域
本发明涉及洗涤剂组合物。更具体地涉及包含C16和/或C18醚硫酸盐表面活性剂的洗涤剂组合物。
背景技术
醇醚硫酸盐广泛地用于清洁应用例如洗衣以溶解脂肪。使用具有C10-C14,特别是C12(月桂基)烷基链的醇作为起始材料合成醇醚硫酸盐表面活性剂(例如月桂基醚硫酸钠),用于洗衣洗涤剂中。
这种类型的醇醚硫酸盐的关键问题是泡沫控制。对于月桂基(C12)和肉豆蔻基(C14)醚硫酸盐,泡沫水平可能极高并且导致在洗衣机中过度起泡以及在漂洗水中使用过多的水以除去泡沫。
问题是如何降低包含这些有用材料的组合物的泡沫水平。
令人惊奇的是,该问题可以通过包含C16和/或C18醚硫酸盐解决。
发明内容
本发明涉及一种洗涤剂组合物,其包含:
(a)2-25重量%,优选3-20重量%,最优选4-15重量%的式R1-(OCH2CH2)mOSO3H的醇醚硫酸盐,其中R1是饱和或单不饱和的直链C12和/或C14烷基链并且其中m为1-4,优选1.5-3.5;和
(b)2-25重量%,优选3-20重量%,最优选4-15重量%的式R2-(OCH2CH2)nOSO3H的醇醚硫酸盐,其中R2是饱和或单不饱和的直链C16和C18烷基链,并且n为5-20,优选6-14,更优选7-13,最优选7-12;
其中(a)与(b)的重量比为5:1至1:8,优选4:1至1:4,更优选2:1至1:2,甚至更优选1.5:1至1:1.5。
优选地,所述组合物包含0.2-50重量%,优选1-40重量%,更优选1.5-30重量%,甚至更优选2-25重量%,最优选4-15重量%的表面活性剂(a)和(b)之外的另外的表面活性剂,其中所述表面活性剂选自:阴离子、非离子或两性表面活性剂及其混合物。更优选地,所述表面活性剂包含阴离子和/或非离子表面活性剂。
优选地,所述非离子表面活性剂是饱和和单不饱和的脂肪族醇乙氧基化物,优选地选自具有平均5-30个乙氧基化物基团的C12-C20直链伯醇乙氧基化物,更优选地具有平均5-25个乙氧基化物基团的C16-C18直链伯醇乙氧基化物。优选地,本发明组合物中的非离子表面活性剂的总量为0.5-10重量%,更优选1-8重量%,甚至更优选1.5-6重量%,最优选2-5重量%。
优选地,阴离子表面活性剂(a)和(b)之外的另外的阴离子表面活性剂选自C12-C18烷基醚羧酸盐;C16-C18甘油单酯的柠檬酸酯(citrem)、C16-C18甘油单酯的酒石酸酯(tatem)和C16-C18甘油单酯的二乙酰基酒石酸酯(datem);和具有包含约8至约22个碳原子的烷基基团的有机硫酸和磺酸的水溶性碱金属盐。最优选地,另外的阴离子表面活性剂包含C16-C18烷基醚羧酸盐;C16-C18甘油单酯的柠檬酸酯(citrem)、C16-C18甘油单酯的酒石酸酯(tatem)和C16-C18甘油单酯的二乙酰基酒石酸酯(datem)和磺酸盐,例如直链烷基苯磺酸盐。
优选地,本发明组合物中阴离子表面活性剂(a)和(b)之外的另外的阴离子表面活性剂的总量为0.5-20重量%,更优选1-16重量%,甚至更优选1.5-14重量%,最优选2-12重量%。
优选地,所述组合物包含0.5-15重量%,优选0.75-15重量%,甚至更优选1-12重量%,最优选1.5-10重量%的清洁增效剂(booster),其选自抗再沉积聚合物、去污聚合物、烷氧基化多羧酸酯及其混合物。
优选地,所述抗再沉积聚合物是烷氧基化聚胺;和/或所述去污聚合物是聚酯去污聚合物。
优选地,所述洗涤剂组合物是洗衣洗涤剂组合物,优选液体洗衣洗涤剂组合物。
优选地,所述组合物包含选自以下的一种或多种酶:脂肪酶、蛋白酶、α-淀粉酶、纤维素酶、过氧化物酶/氧化酶、果胶酸裂解酶和甘露聚糖酶或其混合物,更优选脂肪酶、蛋白酶、α-淀粉酶、纤维素酶及其混合物,其中本发明的组合物中每种酶的含量为0.0001重量%-0.1重量%。
在第二方面,本发明提供一种处理纺织品的家用方法,所述方法包括以下步骤:用0.5-20g/L的第一方面的洗涤剂组合物,优选液体洗衣洗涤剂组合物的水溶液处理纺织品。
具体实施方式
除非另有说明,本文所用的不定冠词“一个”或“一种”及其相应的定冠词“所述”表示至少一个或者一个或多个。
所有酶含量均指纯蛋白质。
重量%涉及基于组合物总重量按成分重量计的量。对于带电荷的表面活性剂(例如阴离子表面活性剂和C16和/或C18醚硫酸盐(b)),重量%是基于表面活性剂的质子化形式计算的。
整数m和n是摩尔平均值。
制剂可以是任何形式,例如液体、固体、粉末、液体单位剂量。优选地,所述组合物是液体组合物。
当在20℃下溶解在脱矿质水中时,所述制剂的pH值优选为4-8,更优选为6.5-7.5,最优选为7。
月桂基和肉豆蔻基醚硫酸盐
所述组合物包含2-25重量%,优选3-20重量%,最优选4-15重量%的式R1-(OCH2CH2)mOSO3H的醇醚硫酸盐,其中R1是饱和或单不饱和的,优选饱和的直链C12和/或C14烷基链,并且其中m为1-4,优选1.5-3.5。优选地,R1是饱和的。
所述饱和的材料也可以描述为月桂基(C12)和/或肉豆蔻基(C14)醚硫酸盐,其具有摩尔平均1-4个,优选1.5-3.5个乙氧基化基团。
C16和/或C18醚硫酸盐
醇醚硫酸盐在H.W Stache编辑的Anionic Surfactants:Organic Chemistry(Marcel Dekker,New York 1996)中讨论。
所述组合物包含2-25重量%,优选3-20重量%,最优选4-15重量%的C16和/或C18醚硫酸盐。
C16和/或C18醚硫酸盐是R2-(OCH2CH2)nOSO3H形式的醚硫酸盐,其中R2是饱和或单不饱和的直链C16和C18烷基,并且其中n为5-20,优选6-14,更优选7-13,最优选7-12。所述单不饱和优选在链的9位,并且双键可以是顺式或反式构型(油基或反油基)。所述顺式或反式醚硫酸盐CH3(CH2)7-CH=CH-(CH2)8O-(OCH2CH2)nOSO3H描述为C18:1(Δ9)醚硫酸盐。18是链中的碳原子的数量,1是双键的数量,并且Δ9是双键在链上的位置。最优选地,R2选自直链C16烷基、直链C18烷基、直链C18:1(Δ9)烷基及其混合物。
优选的示例是烷基链选自鲸蜡基(直链C16)和硬脂基(直链C18)的混合物的C16和/或C18醚硫酸盐;油基醚硫酸盐和反油基醚硫酸盐;及其混合物。
油基醚硫酸盐具有单不饱和C18链,其在链的9位具有顺式双键。反油基醚硫酸盐具有单不饱和的C18链,其在链的9位具有反式双键。
醇醚硫酸盐可通过将烷基醇乙氧基化以形成醇乙氧基化物,然后磺化和用合适的碱中和而合成。
醇乙氧基化物的产生涉及乙氧基化反应:
R-OH+q个环氧乙烷→R-O-(CH2CH2O)q-H
这类乙氧基化反应在Non-Ionic Surfactant Organic Chemistry(N.M.van Osed),Surfactant Science Series Volume 72,CRC Press中描述。
优选地,使用NaOH、KOH或NaOCH3对反应进行碱催化。甚至更优选的是提供比NaOH、KOH或NaOCH3更窄的乙氧基分布的催化剂。优选地,这些较窄分布的催化剂涉及WO 2007/147866中描述的第II族碱,例如十二烷酸钡;第II族金属醇盐;第II族水滑石(hyrodrotalcite)。还可以使用镧系元素。这类较窄分布的醇乙氧基化物可获自Azo Nobel和Sasol。
乙氧基分布优选地具有大于70重量%,更优选大于80重量%的醇乙氧基化物R-O-(CH2CH2O)q-H,其范围为R-O-(CH2CH2O)x-H至R-O-(CH2CH2O)y-H,其中q为乙氧基化的摩尔平均水平,并且x和y是绝对数,其中x=q-q/2,并且y=q+q/2。
例如当q=10时,则大于70重量%的醇乙氧基化物应该由具有5、6、7、8、9、10、11、12、13、14和15个乙氧基化物基团的乙氧基化物组成。
醇醚硫酸盐中的烷基链优选从植物获得,优选从多种植物获得。在这种情况下,优选提取油部分,甘油三酯被水解以得到羧酸,所述羧酸被还原得到表面活性剂合成所需的烷基醇。优选地,所述油被氢化以除去多不饱和烷基链,例如亚油酸和亚麻酸。优选的油的植物来源为棕榈、油菜籽、向日葵、玉米(maze)、大豆、棉籽、橄榄油和树木。来自树木的油称为妥尔油。最优选的油来源是油菜籽油。可以使用棕榈油,但其不是优选的。
油的氢化在A Practical Guide to Vegetable Oil Processing(GuptaM.K.Academic Press 2017中描述。
所述烷基醚硫酸盐表面活性剂可以是盐形式或酸形式,通常是水溶性的钠、钾、铵、镁或单-、二-或三-C2-C3链烷醇铵盐的形式,通常选择的一种是钠阳离子。
饱和R2(C18醇醚硫酸盐)/(C16醇醚硫酸盐)的重量比率优选为2-400,更优选8-200,其中烷基醚硫酸盐的重量是对于质子化形式R2-(OCH2CH2)nOSO3H。
直链饱和或单不饱和C20和C22醇醚硫酸盐可以存在,优选地其中n(乙氧基化的平均摩尔数)为6-14,优选7-13。优选地,(C18醇醚硫酸盐)/(C20和C22醇醚硫酸盐)之和的比率大于10。
其它优选成分
另外的表面活性剂
所述组合物可包含表面活性剂(a)和(b)之外的另外的表面活性剂,使得比率[另外的表面活性剂重量%]/[(a)和(b)的总和重量%]为0-0.5,优选0-0.2,最优选0-0.1。
另外的阴离子表面活性剂
所述组合物可包含阴离子表面活性剂(a)和(b)之外的另外的阴离子表面活性剂。可以使用任何另外的阴离子表面活性剂。然而优选的表面活性剂如下所述。可以添加的阴离子表面活性剂是权利要求的(a)和(b)中指定的那些表面活性剂((a)的月桂基/肉豆蔻基醚硫酸盐和(b)的C16和/或C18醚硫酸盐)之外的另外的表面活性剂。
合适的阴离子洗涤剂化合物的示例选自C12-C18烷基醚羧酸盐;C16-C18甘油单酯的柠檬酸酯(citrem)、C16-C18甘油单酯的酒石酸酯(tatem)和C16-C18甘油单酯的二乙酰基酒石酸酯(datem);和具有包含约8至约22个碳原子的烷基基团的有机硫酸和磺酸的水溶性碱金属盐;及其混合物。
Citrem、tatem和datem在Hasenhuettl,G.L和Hartel,R.W.(Eds)FoodEmulsifiers and Their Application.2008(Springer)以及在Whitehurst,R.J.(Ed)Emulsifiers in Food Technology 2008(Wiley-VCH)中描述。
最优选地,另外的阴离子表面活性剂包含C16-C18烷基醚羧酸盐;C16-C18甘油单酯的柠檬酸酯(citrem)、C16-C18甘油单酯的酒石酸酯(tatem)和C16-C18甘油单酯的二乙酰基酒石酸酯(datem)和磺酸盐,例如直链烷基苯磺酸盐。
优选地,另外的阴离子表面活性剂的总量为所述另外的表面活性剂的0-100重量%,优选30-90重量%。
优选地,本发明组合物中阴离子表面活性剂(a)和(b)之外的另外的阴离子表面活性剂的总量为0.5-20重量%,更优选1-16重量%,甚至更优选1.5-14重量%,最优选2-12重量%。
优选地,所用的表面活性剂是饱和或单不饱和的。优选地,所述烷基链源自天然来源。
非离子表面活性剂
所述组合物可包含非离子表面活性剂。可以使用任何非离子表面活性剂,然而,优选的非离子表面活性剂如下所述。
非离子表面活性剂优选选自饱和的和单不饱和的脂肪族醇乙氧基化物。
用于本发明的脂肪族醇乙氧基化物可合适地选自C8-C18直链或支链伯或仲醇乙氧基化物,每摩尔醇具有平均2-40摩尔的环氧乙烷。
优选地,所述非离子表面活性剂是饱和和单不饱和脂肪族醇乙氧基化物,优选选自具有平均5-30个乙氧基化物的C12-C20直链伯醇乙氧基化物,更优选具有平均5-25个乙氧基化物的C16-C18。优选地,所述烷基链是单不饱和的。
还可以使用任何上述材料的混合物。
优选地,本发明组合物中非离子表面活性剂的总量为所述另外的表面活性剂的0-100重量%,优选另外的表面活性剂的10-70重量%。
优选地,本发明组合物中的非离子表面活性剂的总量为0.5-10重量%,更优选1-8重量%,甚至更优选1.5-6重量%,最优选2-5重量%。
清洁增效剂
所述组合物优选包含0.5-15重量%,更优选0.75-15重量%,甚至更优选1-12重量%,最优选1.5-10重量%的清洁增效剂,其选自抗再沉积聚合物;去污聚合物;WO/2019/008036和WO/2019/007636中所述的烷氧基化多羧酸酯;及其混合物。
抗再沉积聚合物
优选的抗再沉积聚合物包含烷氧基化聚胺。
优选的烷氧基化聚胺包含烷氧基化聚乙烯亚胺,和/或烷氧基化聚丙烯亚胺。所述聚胺可以是直链或支链的。它可以支化达到它是树枝状聚合物的程度。烷氧基化通常可以是乙氧基化或丙氧基化,或两者的混合。当氮原子被烷氧基化时,优选的平均烷氧基化度为10-30,优选15-25。优选的材料是乙氧基化聚乙烯亚胺,平均乙氧基化度为10-30,优选15-25,其中氮原子被乙氧基化。
去污聚合物
优选地,所述去污聚合物是聚酯去污聚合物。
优选的去污聚合物包含在WO 2014/029479和WO 2016/005338中描述的那些。
优选地,所述基于聚酯的去污聚合物是根据下式(I)的聚酯:
其中
R1和R2彼此独立地为X-(OC2H4)n-(OC3H6)m,其中X为C1-4烷基,并且优选为甲基,-(OC2H4)基团和-(OC3H6)基团呈嵌段排列并且由-(OC3H6)基团组成的嵌段与COO基团结合,或为HO(C3H6),并且优选地彼此独立地为X-(OC2H4)n-(OC3H6)m,
n是基于12-120的摩尔平均数,并且优选40-50,
m是基于1-10的摩尔平均数,并且优选1-7,并且
a是基于4-9的摩尔平均数。
优选地,作为活性共混物提供的聚酯包含:
A)45-55重量%的一种或多种根据下式(I)的聚酯的活性共混物:
其中
R1和R2彼此独立地为X-(OC2H4)n-(OC3H6)m,其中X为C1-4烷基,并且优选为甲基,-(OC2H4)基团和-(OC3H6)基团呈嵌段排列并且由-(OC3H6)基团组成的嵌段与COO基团结合,或为HO(C3H6),并且优选地彼此独立地为X-(OC2H4)n-(OC3H6)m,
n是基于12-120的摩尔平均数,并且优选40-50,
m是基于1-10的摩尔平均数,并且优选1-7,并且
a是基于4-9的摩尔平均数,和
B)10-30%重量的一种或多种醇的活性共混物,其选自乙二醇、1,2-丙二醇、1,3-丙二醇、1,2-丁二醇、1,3-丁二醇、1,4-丁二醇和丁二醇(butyl glycol),和
C)24-42重量%的水的活性共混物。
烷氧基化多羧酸酯
烷氧基化多羧酸酯可通过首先使包含至少三个羧酸单元的芳族聚羧酸或其衍生的酸酐、优选包含三个或四个羧酸单元的芳族聚羧酸或其衍生的酸酐、更优选包含三个羧酸单元的芳族聚羧酸或其衍生的酸酐、甚至更优选偏苯三酸或偏苯三酸酐、最优选偏苯三酸酐,与醇烷氧基化物反应并且在第二步骤中使所得产物与醇或醇的混合物(优选与C16/C18醇)反应获得。
酶
优选地酶,例如脂肪酶、蛋白酶、α-淀粉酶、纤维素酶、过氧化物酶/氧化酶、果胶酸裂解酶和甘露聚糖酶或其混合物可存在于制剂中。
如果酶存在,则它们优选选自:脂肪酶、蛋白酶、α-淀粉酶、纤维素酶及其混合物。
如果存在,则本发明的洗衣组合物中每种酶的含量为0.0001重量%至0.1重量%。
组合物中存在的酶含量优选与作为纯蛋白质的酶的含量相关。
合适的脂肪酶包括细菌或真菌来源的那些。化学修饰或蛋白质工程的突变体包括在内。有用的脂肪酶的示例包括来自腐质霉属(Humicola)(同义词嗜热真菌属(Thermomyces))的脂肪酶,例如来自EP258068和EP 305216中所述的柔毛腐质霉(H.lanuginosa)(疏棉状嗜热丝孢菌(T.lanuginosus))或来自WO 96/13580中所述的特异腐质霉(H.insolens)的脂肪酶;假单胞菌(Pseudomonas)脂肪酶,例如来自产碱假单胞菌(P.alcaligenes)或假产碱假单胞菌(P.pseudoalcaligenes)(EP 218272)、洋葱假单胞菌(P.cepacia)(EP 331376)、施氏假单胞菌(P.stutzeri)(GB 1,372,034)、焚光假单胞菌(P.fluorescens)、假单胞菌属菌株SD705(WO 95/06720和WO 96/27002),P.wisconsinensis(WO 96/12012)的脂肪酶;芽孢杆菌(Bacillus)脂肪酶,例如来自枯草芽孢杆菌(B.subtilis)(Dartois等(1993),Biochemica et Biophysica Acta,1131,253-360)、嗜热脂肪芽胞杆菌(B.stearothermophilus)(JP 64/744992)或短小芽孢杆菌(B.pumilus)(WO 91/16422)的脂肪酶。其它示例是脂肪酶变体,例如在WO 92/05249,WO94/01541,EP 407225,EP 260105,WO 95/35381,WO 96/00292,WO 95/30744,WO 94/25578,WO 95/14783,WO 95/22615,WO 97/04079和WO 97/07202,WO 00/60063中描述的那些。
优选地可商购脂肪酶包括LipolaseTM和Lipolase UltraTM,LipexTM和LipocleanTM(Novozymes A/S)。
本发明可以在分类为EC3.1.1.4和/或EC3.1.1.32的磷脂酶的存在下进行。如本文所用,术语磷脂酶是对磷脂具有活性的酶。
磷脂,例如卵磷脂或磷脂酰胆碱,由在外部(sn-1)和中间(sn-2)位置中被两个脂肪酸酯化并且第三个位置被磷酸酯化的甘油构成;所述磷酸进而可以被酯化为氨基醇。磷脂酶是参与磷脂水解的酶。可以区别几种类型的磷脂酶活性,包括水解一个脂酰基(分别在sn-1和sn-2位置)以形成溶血磷脂的磷脂酶A1和A2;和可以水解溶血磷脂中的剩余脂酰基的溶血磷脂酶(或磷脂酶B)。磷脂酶C和磷脂酶D(磷酸二脂酶)分别释放二酰基甘油或磷脂酸。
蛋白酶水解肽和蛋白质内的键,在洗衣情况中,这导致增强的含蛋白质或肽的污渍的去除。合适的蛋白酶家族的示例包括天冬氨酸蛋白酶;半胱氨酸蛋白酶;谷氨酸蛋白酶;天冬酰胺(aspargine)肽裂解酶;丝氨酸蛋白酶和苏氨酸蛋白酶。这类蛋白酶家族在MEROPS肽酶数据库(http://merops.sanger.ac.uk/)中描述。丝氨酸蛋白酶是优选的。枯草杆菌酶型丝氨酸蛋白酶是更优选的。术语“枯草杆菌酶”是指根据Siezen等,ProteinEngng.4(1991)719-737和Siezen等,Protein Science 6(1997)501-523所述的丝氨酸蛋白酶的亚组。丝氨酸蛋白酶是特征在于在活性位点具有丝氨酸的蛋白酶亚组,该丝氨酸与底物形成共价加合物。枯草杆菌酶可以分为6个亚分类,即枯草杆菌蛋白酶家族、嗜热蛋白酶(Thermitase)家族、蛋白酶K家族、羊毛硫抗生素(Lantibiotic)肽酶家族、Kexin家族和Pyrolysin家族。
枯草杆菌酶的示例是源自芽孢杆菌例如在US 7262042和WO 09/021867中描述的迟缓芽孢杆菌、嗜碱芽孢杆菌、枯草芽孢杆菌、解淀粉芽孢杆菌、短小芽孢杆菌和吉氏芽孢杆菌的那些,以及在WO 89/06279中描述的迟缓枯草杆菌蛋白酶(subtilisin lentus)、枯草杆菌蛋白酶Novo、枯草杆菌蛋白酶Carlsberg、地衣芽孢杆菌、枯草杆菌蛋白酶BPN’、枯草杆菌蛋白酶309、枯草杆菌蛋白酶147和枯草杆菌蛋白酶168,以及在WO 93/18140中描述的蛋白酶PD138。其它有用的蛋白酶可以是WO 92/175177、WO 01/016285、WO 02/026024和WO02/016547中描述的那些。胰蛋白酶样蛋白酶的示例是胰蛋白酶(例如猪或牛来源的)和WO89/06270、WO 94/25583和WO 05/040372中描述的镰刀菌蛋白酶,以及在WO 05/052161和WO05/052146中描述的源自纤维单胞菌属(Cellumonas)的糜蛋白酶。
最优选地,蛋白酶是枯草杆菌蛋白酶(EC 3.4.21.62)。
枯草杆菌酶的示例是源自芽孢杆菌例如在US 7262042和WO 09/021867中描述的迟缓芽孢杆菌、嗜碱芽孢杆菌、枯草芽孢杆菌、解淀粉芽孢杆菌、短小芽孢杆菌和吉氏芽孢杆菌的那些,以及在WO 89/06279中描述的迟缓枯草杆菌蛋白酶、枯草杆菌蛋白酶Novo、枯草杆菌蛋白酶Carlsberg、地衣芽孢杆菌、枯草杆菌蛋白酶BPN’、枯草杆菌蛋白酶309、枯草杆菌蛋白酶147和枯草杆菌蛋白酶168,以及在WO 93/18140中描述的蛋白酶PD138。优选地,枯草杆菌蛋白酶源自芽孢杆菌,优选迟缓芽孢杆菌、嗜碱芽孢杆菌、枯草芽孢杆菌、解淀粉芽孢杆菌、短小芽孢杆菌和吉氏芽孢杆菌,如US 6,312,936B1、US 5,679,630、US 4,760,025、US 7,262,042和WO 09/021867中所述。最优选地,枯草杆菌蛋白酶源自吉氏芽孢杆菌或迟缓芽孢杆菌。
本发明可以使用分类在EC 3.1.1.74中的角质酶。根据本发明使用的角质酶可以是任何来源。优选地,角质酶是微生物来源的,特别是细菌、真菌或酵母来源。
合适的淀粉酶(α和/或β)包括具有细菌或真菌来源的那些。包括化学修饰的或蛋白质工程化的突变体。淀粉酶包括例如获自芽孢杆菌,例如在GB 1,296,839中更详细描述的地衣芽孢杆菌的特殊菌株,或在WO 95/026397或WO 00/060060中公开的芽孢杆菌菌株的α-淀粉酶。可商购的淀粉酶是DuramylTM、TermamylTM、Termamyl UltraTM、NatalaseTM、StainzymeTM、FungamylTM和BANTM(Novozymes A/S)、RapidaseTM和PurastarTM(来自GenencorInternational Inc.)。
合适的纤维素酶包括细菌或真菌来源的那些。包括化学修饰的或蛋白质工程化的突变体。合适的纤维素酶包括来自以下属的纤维素酶:芽孢杆菌属、假单胞菌属、腐质霉属、镰刀菌属、梭孢壳属、支顶孢属,例如公开于US 4,435,307、US 5,648,263、US 5,691,178、US 5,776,757、WO 89/09259、WO 96/029397和WO 98/012307中的特异腐质霉、太瑞斯梭孢壳霉、嗜热毁丝霉和尖孢镰刀菌产生的真菌纤维素酶。可商购的纤维素酶包括CelluzymeTM、CarezymeTM、CellucleanTM、EndolaseTM、RenozymeTM(Novozymes A/S)、ClazinaseTM和Puradax HATM(Genencor International Inc.),及KAC-500(B)TM(Kao Corporation)。CellucleanTM是优选的。
合适的过氧化物酶/氧化酶包括植物、细菌或真菌来源的那些。包括化学修饰的或蛋白质工程化的突变体。有用的过氧化物酶的示例包括来自鬼伞属,例如来自灰盖鬼伞的过氧化物酶,及其变体,如在WO 93/24618、WO 95/10602和WO 98/15257中描述的那些。可商购的过氧化物酶包括GuardzymeTM和NovozymTM 51004(Novozymes A/S)。
其他适用的酶在WO 2009/087524、WO 2009/090576、WO 2009/107091、WO 2009/111258和WO 2009/148983中讨论。
酶稳定剂
存在于组合物中的任何酶可以使用常规稳定剂稳定化,例如多元醇(例如丙二醇或甘油)、糖或糖醇、乳酸、硼酸或硼酸衍生物(例如芳族硼酸酯,或苯基硼酸衍生物如4-甲酰基苯基硼酸),并且所述组合物可以如例如WO 92/19709和WO 92/19708中所述配制。
其他成分
制剂可包含其他成分。
助洗剂或络合剂
所述组合物可包含助洗剂或络合剂。
助洗剂材料可以选自1)钙螯合剂材料,2)沉淀材料,3)钙离子交换材料及4)其混合物。
钙螯合剂助洗剂材料的示例包括碱金属多磷酸盐,例如三聚磷酸钠,和有机螯合剂,例如乙二胺四乙酸。
所述组合物还可包含0-10重量%的助洗剂或络合剂,例如乙二胺四乙酸、二亚乙基三胺-五乙酸、柠檬酸、烷基-或烯基琥珀酸、次氮基三乙酸或下文提及的其他助洗剂。
更优选地,洗衣洗涤剂制剂是非磷酸盐助洗的洗衣洗涤剂制剂,即包含小于1重量%的磷酸盐。最优选地,洗衣洗涤剂制剂没有助洗,即包含小于1重量%的助洗剂。
如果洗涤剂组合物是水性液体洗衣洗涤剂,优选的是单丙二醇或甘油以1-30重量%,最优选2-18重量%的含量存在,以为制剂提供适宜的、可倾倒的粘度。
荧光剂
所述组合物优选包含荧光剂(光亮剂)。
荧光剂是众所周知的,并且许多这类荧光剂是可商购的。通常,这些荧光剂以其碱金属盐,例如钠盐的形式提供和使用。
组合物中使用的一种或多种荧光剂的总量通常为0.0001-0.5重量%,优选0.005-2重量%,更优选0.01-0.1重量%。荧光剂的优选类别是:二苯乙烯基联苯化合物,例如Tinopal(商标)CBS-X,二胺芪二磺酸化合物,例如Tinopal DMS pure Xtra和Blankophor(商标)HRH,以及吡唑啉化合物,如Blankophor SN。优选的荧光剂是CAS-No 3426-43-5;CAS-No 35632-99-6;CAS-No 24565-13-7;CAS-No 12224-16-7;CAS-No 13863-31-5;CAS-No 4193-55-9;CAS-No 16090-02-1;CAS-No 133-66-4;CAS-No 68444-86-0;CAS-No27344-41-8的荧光剂。
最优选的荧光剂是:2-(4-苯乙烯基-3-磺基苯基)-2H-萘并(napthol)[1,2-d]三唑钠、4,4'-双{[(4-苯胺基-6-(N-甲基-N-2-羟乙基)氨基-1,3,5-三嗪-2-基)]氨基}芪-2-2'-二磺酸二钠、4,4'-双{[(4-苯胺基-6-吗啉基-1,3,5-三嗪-2-基)]氨基}芪-2-2'-二磺酸二钠以及4,4'-双(2-磺基苯乙烯基)联苯二钠。
调色染料
在制剂中存在调色染料是有益的。
染料在Color Chemistry Synthesis,Properties and Applications ofOrganic Dyes and Pigments,(H Zollinger,Wiley VCH,Zürich,2003)和IndustrialDyes Chemistry,Properties Applications.(K Hunger(ed),Wiley-VCH Weinheim 2003)中描述。
用于洗衣洗涤剂的染料优选在可见光范围(400-700nm)中的最大吸收处具有大于5000L mol-1cm-1,优选大于10000L mol-1cm-1的消光系数。
优选的染料发色团是偶氮、吖嗪、蒽醌、酞菁和三苯甲烷。偶氮、蒽醌、酞菁和三苯甲烷染料优选带有净阴离子电荷或不带电荷。吖嗪染料优选带有净阴离子或阳离子电荷。
蓝色或紫色调色染料是最优选的。在洗涤过程的洗涤或漂洗步骤期间,调色染料沉积到织物上,从而为织物提供可见的色调。在这方面,所述染料向白色布给予色调角240-345、更优选260-320、最优选270-300的蓝色或紫色。该测试中使用的白色布是经漂白的、非丝光处理的编织棉片。
调色染料在WO 2005/003274、WO 2006/032327(Unilever)、WO 2006/032397(Unilever)、WO 2006/045275(Unilever)、WO 06/027086(Unilever)、WO 2008/017570(Unilever)、WO 2008/141880(Unilever)、WO 2009/132870(Unilever)、WO 2009/141173(Unilever)、WO 2010/099997(Unilever)、WO 2010/102861(Unilever)、WO 2010/148624(Unilever)、WO 2008/087497(P&G)、WO 2011/011799(P&G)、WO 2012/054820(P&G)、WO2013/142495(P&G)和WO 2013/151970(P&G)中讨论。
可以使用调色染料的混合物。
调色染料发色团最优选选自单偶氮、双偶氮和吖嗪。
单偶氮染料优选含有杂环,并且最优选是噻吩染料。单偶氮染料优选是烷氧基化的,并且优选在pH=7时不带电荷或带阴离子电荷。烷氧基化噻吩染料在WO/2013/142495和WO/2008/087497中讨论。噻吩染料的优选示例如下所示:
双偶氮染料优选为磺化双偶氮染料。磺化双偶氮化合物的优选示例是直接紫7、直接紫9、直接紫11、直接紫26、直接紫31、直接紫35、直接紫40、直接紫41、直接紫51、直接紫66、直接紫99及其烷氧基化形式。
在WO2012/054058和WO2010/151906中讨论了烷氧基化双偶氮染料。
烷氧基化双偶氮染料的示例是:
吖嗪染料优选选自磺化吩嗪染料和阳离子吩嗪染料。优选的示例是酸性蓝98、酸性紫50、CAS-No 72749-80-5的染料、酸性蓝59,以及选自以下的吩嗪染料:
其中:
X3选自:-H;-F;-CH3;-C2H5;-OCH3;和-OC2H5;
X4选自:-H;-CH3;-C2H5;-OCH3;和-OC2H5;
Y2选自:-OH;-OCH2CH2OH;-CH(OH)CH2OH;-OC(O)CH3;和C(O)OCH3。
可如WO 2011/047987和WO 2012/119859中所述使用与乙氧基化物或丙氧基化聚乙烯亚胺共价结合的蒽醌染料。
所述调色染料优选以0.0001-0.1重量%存在于组合物中。取决于调色染料的性质,存在取决于调色染料的效力的优选范围,所述效力取决于类别和任何特定类别内的特定效力。如上所述,所述调色染料优选是蓝色或紫色调色染料。
香料
所述组合物优选包含香料。在由CFTA Publications出版的CTFA(Cosmetic,Toiletryand Fragrance Association)1992International Buyers Guide和由SchnellPublishing Co.出版的OPD 1993Chemicals Buyers Directory 80th Annual Edition中提供了香料的许多合适示例。
优选地,所述香料包含以下的至少一种香型(note)(化合物):α-异甲基紫罗酮,水杨酸苄酯;香茅醇;香豆素;己基肉桂醛;芳樟醇;2-甲基戊酸乙基酯;辛醛;乙酸苄酯;3,7-二甲基-1,6-辛二烯-3-醇3-乙酸酯;2-(1,1-二甲基乙基)-环己醇1-乙酸酯;δ-大马酮(damascone);β-紫罗酮;乙酸三环癸烯酯(verdyl acetate);十二醛;己基肉桂醛(hexylcinnamic aldehyde);环十五内酯;苯乙酸2-苯基乙基酯;水杨酸戊酯;β-石竹烯;十一碳烯酸乙酯;邻氨基苯甲酸香叶酯;α-鸢尾酮;β-苯基乙基苯甲酸酯;α-檀香醇;雪松醇;乙酸柏木酯;甲酸柏木酯(cedry formate);水杨酸环己酯;γ-十二内酯,和β-苯乙基苯基乙酸酯。
香料的有用组分包括天然和合成来源的材料。它们包括单一化合物和混合物。这类组分的具体示例可见于现有文献,例如,Fenaroli's Handbook of FlavorIngredients,1975,CRC Press;Synthetic Food Adjuncts,1947,M.B.Jacobs著,VanNostrand编辑;或Perfume and Flavor Chemicals,S.Arctander著,1969,Montclair,N.J.(USA)中。
在制剂中存在多种香料组分是常见的。在本发明的组合物中,设想将存在四种或更多种、优选五种或更多种、更优选六种或更多种或者甚至七种或更多种不同的香料组分。
在香料混合物中,优选15-25重量%是头香。头香是由Poucher(Journal of theSociety of Cosmetic Chemists 6(2):80[1955])所定义的。优选的头香选自柑桔油、芳樟醇、乙酸芳樟酯、薰衣草、二氢月桂烯醇、玫瑰醚和顺-3-己醇。
国际日用香精香料协会已在2011年发布了香氛成分(香料)的清单(http:// www.ifraorg.org/en-us/ingredients#.U7Z4hPldWzk)。国际日用香料研究所提供了具有安全性信息的香料(香氛)数据库。
香料头香可用于提示本发明的白度和亮度益处。一些或所有香料可以被包封,有利于包封的典型香料组分包括具有相对低的沸点的那些,优选沸点小于300℃,优选为100-250℃的那些。包封具有低CLog P(即,具有被分配到水中的更高倾向的那些),优选具有小于3.0的CLog P的香料组分也是有利的。这些具有相对低沸点和相对低CLog P的材料被称为“延迟释香(delayed blooming)”的香料成分,并且包含以下材料中的一种或多种:己酸烯丙酯、乙酸戊酯、丙酸戊酯、茴香醛、苯甲醚、苯甲醛、乙酸苄酯、苄基丙酮、苯甲醇、甲酸苄酯、异戊酸苄酯、丙酸苄酯、β-γ己烯醇、樟脑胶、左旋-香芹酮、d-香芹酮、肉桂醇、甲酸肉桂酯(cinamyl formate)、顺-茉莉酮、顺-3-己烯基乙酸酯、枯茗醇、cyclal c、二甲基苄基甲醇、二甲基苄基甲醇乙酸酯、乙酸乙酯、乙酰乙酸乙酯、乙基戊基酮、苯甲酸乙酯、丁酸乙酯、乙基己基酮、乙基苯基乙酸酯、桉树脑、丁香酚、乙酸葑酯(fenchyl acetate)、floracetate(三环癸烯基乙酸酯)、frutene(三环癸烯基丙酸酯)、香叶醇、己烯醇、乙酸己烯酯、乙酸己酯、甲酸己酯、龙葵醇(hydratropic alcohol)、羟基香茅醛、茚酮、异戊醇、异薄荷酮、乙酸异胡薄荷酯(isopulegyl acetate)、异喹啉酮、女贞醛、芳樟醇、芳樟醇氧化物、甲酸芳樟酯、薄荷酮、薄荷基苯乙酮(menthyl acetphenone)、甲基戊基酮、邻氨基苯甲酸甲酯、苯甲酸甲酯、甲基苄基乙酸酯(methylbenyl acetate)、甲基丁香酚、甲基庚烯酮、甲基庚炔碳酸酯(methyl heptine carbonate)、甲基庚基酮、甲基己基酮、甲基苯基甲基乙酸酯、水杨酸甲酯、甲基-n-甲基邻氨基苯甲酸酯、橙花醇、辛内酯、辛醇、对甲酚、对甲酚甲基醚、对甲氧基苯乙酮、对甲基苯乙酮、苯氧乙醇、苯基乙醛、苯基乙基乙酸酯、苯基乙基醇、苯基乙基二甲基甲醇、乙酸异戊二烯酯、龙脑酸丙酯(propyl bornate)、胡薄荷酮、玫瑰醚、黄樟素、4-萜品烯醇(4-terpinenol)、α-萜品烯醇和/或苯乙醛二甲醇缩醛(viridine)。多种香料组分存在于制剂中是常见的。在本发明的组合物中,设想将有来自上文给出的延迟释香香料的给定列表的四种或更多种,优选五种或更多种,更优选六种或更多种,或甚至七种或更多种不同的香料组分存在于香料中。
本发明可以应用的另一组香料是所谓的“芳香疗法”材料。这些包括也用于香水中的许多组分,包括精油如鼠尾草、桉树、天竺葵、薰衣草、肉豆蔻干皮(Mace)提取物、橙花油、肉豆蔻、留兰香、甜紫罗兰叶和缬草的组分。
优选的是洗衣处理组合物不含过氧漂白剂,例如过碳酸钠、过硼酸钠和过酸。
聚合物
所述组合物可包含一种或多种其他聚合物。示例为羧甲基纤维素、聚(乙二醇)、聚(乙烯醇)、聚羧酸酯如聚丙烯酸酯、马来酸/丙烯酸共聚物和甲基丙烯酸月桂酯/丙烯酸共聚物。
在烷基足够长以形成支链或环状链的情况下,烷基包括支链、环状和直链烷基链。所述烷基基团优选是直链或支链的,最优选是直链的。
辅助成分
所述洗涤剂组合物任选地包含一种或多种洗衣辅助成分。
为防止制剂的氧化,抗氧化剂可存在于制剂中。
术语“辅助成分”包括:香料、分散剂、稳定剂、pH调节剂、金属离子调节剂、着色剂、增白剂、染料、气味调节剂、前香料、环糊精、香料、溶剂、去污聚合物、防腐剂、抗微生物剂、氯清除剂、防缩水剂、织物挺括剂、去斑剂、抗氧化剂、抗蚀剂、增稠剂(bodying agent)、悬垂及形态调节剂、光滑剂、静电控制剂、褶皱调节剂、卫生处理剂、消毒剂、微生物控制剂、霉控制剂、霉菌控制剂、抗病毒剂、抗菌剂、干燥剂、抗污剂、去污剂、恶臭控制剂、织物清新剂、氯漂白剂气味控制剂、染料固定剂、染料转移抑制剂、调色染料、颜色保持剂、颜色恢复剂、复原剂、抗退色剂、增白剂、抗磨蚀剂、耐磨剂、织物完整剂、抗磨损剂和漂洗助剂、UV防护剂、光褪色抑制剂、驱虫剂、抗过敏剂、酶、阻燃剂、防水剂、织物舒适剂、水调节剂、抗收缩剂、抗拉伸剂及其组合。如果存在,这类助剂可以以组合物重量的0.1%-5%的含量使用。
本发明将通过以下非限制性实施例进一步描述。
实施例
在293K下将含有10重量%的表面活性剂(其余为水)的洗衣洗涤剂添加到6°fH(法国硬度)水中,得到0.2g/L表面活性剂水溶液。
将10ml的溶液置于2.2cm直径的管中并塞住。将该管倒置40次以产生泡沫并且拍摄该管的照片。然后以1mg等份添加污物(soil),并且重复倒置过程和照相循环直到添加4mg总污物。污物是重量比为5:5:1的橄榄油:水:高岭土+0.13重量%面粉的乳液。高岭土购自Sigma-Aldrich。
泡沫的高度测量为泡沫的弯月面和顶部之间的差值。实验值是2个重复管的平均。
为1-4mg污物绘制了污物水平对泡沫高度的图,并使用回归分析(Microsoftexcel的LINEST函数)将直线拟合到点。
梯度是每单位污渍的泡沫水平变化(Δ泡沫),并且截距是最大泡沫(泡沫Max)的量度。下表中给出了值以及标准误差(±值)。预期值是基于包含水平以线性关系从100%的值计算的。
鲸蜡硬脂基是C16和C18直链饱和链的混合物。
月桂基是C12直链饱和链。
用*标记的值是本发明的,其它值是比较的。
从100%表面活性剂的泡沫Max实验的误差计算泡沫Max预期的误差极限。
观察到的实验和预期之间的差异大于误差。
令人惊奇的是,月桂基和C16和/或C18醚硫酸盐按所要求的重量比的混合物产生的泡沫(泡沫Max实验)低于预期(泡沫Max预期),并且污渍的减少(Δ泡沫)高于预期(实验值小于所计算的预期值)。
实施例2
在293K下将含有10重量%的表面活性剂(其余为水)的洗衣洗涤剂添加到6°fH(法国硬度)水中,得到0.15g/L表面活性剂水溶液。
将10ml的溶液置于2.2cm直径的管中并塞住。将该管倒置40次以产生泡沫并且拍摄该管的照片。然后以1mg等份添加污物,并且重复倒置过程和照相循环直到添加4mg总污物。污物是重量比为5:5:1的橄榄油:水:高岭土+0.13重量%面粉的乳液。高岭土购自Sigma-Aldrich。不同批次的污物成分用于实施例1。
泡沫的高度测量为泡沫的弯月面和顶部之间的差值。实验值是3个重复管的平均。
为1-4mg污渍绘制了污物水平对泡沫高度的图,并使用回归分析(Microsoftexcel的LINEST函数)将直线拟合到点。
梯度是每单位污渍的泡沫水平变化(Δ泡沫),并且截距是最大泡沫(泡沫Max)的量度。下表中给出了值以及标准误差(±值)。预期值是基于包含水平以线性关系从100%的值计算的。
油基是具有平均6摩尔的乙氧基化的单不饱和C18链。
月桂基是具有平均3摩尔的乙氧基化的C12直链饱和链。
用*标记的值是本发明的,其它值是比较的。
由100%表面活性剂的泡沫Max实验的误差计算泡沫Max预期的误差极限。
88:12的月桂基:油基(7.3:1的比率)比较例相当好地反映了现有技术的教导(其为8.5重量%月桂基比0.7重量%油基(其给出约12:1的比率)),因为其更接近于本发明的5:1到1:8范围的端点。
表面活性剂混合物的泡沫Max实验值显著低于预期值,除了88:12的月桂基:油基,其中该值在误差内。与现有技术混合物相比,所要求保护的材料的混合物的改进泡沫技术效果的改进百分比更好。
令人惊奇的是,月桂基和C16和/或C18醚硫酸盐按所要求的重量比的混合物产生的泡沫(泡沫Max实验)显著低于预期(泡沫Max预期),并且污渍的减少(Δ泡沫)高于预期(实验值小于所计算的预期值)。
Claims (11)
1.一种洗涤剂组合物,其包含:
(a)2-25重量%,优选3-20重量%,最优选4-15重量%的式R1-(OCH2CH2)mOSO3H的醇醚硫酸盐,其中R1是饱和或单不饱和的,优选饱和的,直链C12和/或C14烷基链并且其中m为1-4,优选1.5-3.5;和
(b)2-25重量%,优选3-20重量%,最优选4-15重量%的式R2-(OCH2CH2)nOSO3H的醇醚硫酸盐,其中R2是饱和或单不饱和的直链C16和C18烷基链,并且n为5-20,优选6-14,更优选7-13,最优选7-12;
其中(a)与(b)的重量比为5:1至1:8,优选4:1至1:4,更优选2:1至1:2,甚至更优选1.5:1至1:1.5。
2.根据权利要求1所述的洗涤剂组合物,其中所述组合物包含0.2-50重量%,优选1-40重量%,更优选1.5-30重量%,甚至更优选2-25重量%,最优选4-15重量%的表面活性剂(a)和(b)之外的另外的表面活性剂,其中所述表面活性剂选自:阴离子、非离子或两性表面活性剂及其混合物。
3.根据权利要求2所述的洗涤剂组合物,其中所述另外的表面活性剂包含阴离子和/或非离子表面活性剂。
4.根据权利要求2或权利要求3任一项所述的洗涤剂组合物,其包含0.5-10重量%,优选1-8重量%,更优选1.5-6重量%,最优选2-5重量%的非离子表面活性剂,其中所述非离子表面活性剂是饱和和单-不饱和的脂族醇乙氧基化物,优选地选自具有平均5-30个乙氧基化物的C12-C20直链伯醇乙氧基化物,更优选地具有平均5-25个乙氧基化物的C16-C18。
5.根据权利要求2-4任一项所述的洗涤剂组合物,其包含0.5-20重量%,更优选1-16重量%,甚至更优选1.5-14重量%,最优选2-12重量%的阴离子表面活性剂(a)和(b)之外的另外的阴离子表面活性剂,其中所述阴离子表面活性剂选自C12-C18烷基醚羧酸盐;C16-C18甘油单酯的柠檬酸酯(citrem)、C16-C18甘油单酯的酒石酸酯(tatem)和C16-C18甘油单酯的二乙酰基酒石酸酯(datem);和具有包含约8至约22个碳原子的烷基基团的有机硫酸和磺酸的水溶性碱金属盐;及其混合物;最优选地,所述阴离子表面活性剂选自C16-C18烷基醚羧酸盐;C16-C18甘油单酯的柠檬酸酯(citrem),C16-C18甘油单酯的酒石酸酯(tatem)和C16-C18甘油单酯的二乙酰基酒石酸酯(datem)和磺酸盐,例如直链烷基苯磺酸盐;及其混合物。
6.根据前述权利要求任一项所述的洗涤剂组合物,其中所述组合物包含0.5-15重量%,更优选0.75-15重量%,甚至更优选1-12重量%,最优选1.5-10重量%的清洁增效剂,其选自抗再沉积聚合物;去污聚合物;烷氧基化多羧酸酯及其混合物。
7.根据权利要求6所述的洗涤剂组合物,其中所述抗再沉积聚合物是烷氧基化聚胺;和/或去污聚合物是聚酯去污聚合物。
8.根据权利要求6或权利要求7所述的洗涤剂组合物,其中所述去污聚合物是聚酯去污聚合物。
9.根据前述权利要求任一项所述的洗涤剂组合物,其中所述组合物是洗衣洗涤剂组合物,优选洗衣液体洗涤剂组合物。
10.根据前述权利要求任一项所述的洗涤剂组合物,其中所述组合物包含选自以下的一种或多种酶:脂肪酶、蛋白酶、α-淀粉酶、纤维素酶、过氧化物酶/氧化酶、果胶酸裂解酶和甘露聚糖酶或其混合物,优选脂肪酶、蛋白酶、α-淀粉酶、纤维素酶及其混合物,其中本发明的组合物中每种酶的含量为0.0001重量%-0.1重量%。
11.一种处理纺织品的家用方法,所述方法包括以下步骤:用0.5-20g/L的权利要求1-10任一项所述的洗涤剂组合物的水溶液处理纺织品,并且任选地干燥所述纺织品。
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Family Cites Families (90)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1296839A (zh) | 1969-05-29 | 1972-11-22 | ||
GB1372034A (en) | 1970-12-31 | 1974-10-30 | Unilever Ltd | Detergent compositions |
US3812041A (en) * | 1972-06-23 | 1974-05-21 | Colgate Palmolive Co | Non-gelling heavy duty liquid laundry detergent |
IE38506B1 (en) * | 1972-11-13 | 1978-03-29 | Procter & Gamble | Detergent compositions |
DK187280A (da) | 1980-04-30 | 1981-10-31 | Novo Industri As | Ruhedsreducerende middel til et fuldvaskemiddel fuldvaskemiddel og fuldvaskemetode |
JPS5784708A (en) * | 1980-11-18 | 1982-05-27 | Kao Corp | Improving agent for filtration/dehydration property of metal hydroxide slurry |
US4760025A (en) | 1984-05-29 | 1988-07-26 | Genencor, Inc. | Modified enzymes and methods for making same |
DE3684398D1 (de) | 1985-08-09 | 1992-04-23 | Gist Brocades Nv | Lipolytische enzyme und deren anwendung in reinigungsmitteln. |
EP0258068B1 (en) | 1986-08-29 | 1994-08-31 | Novo Nordisk A/S | Enzymatic detergent additive |
NZ221627A (en) | 1986-09-09 | 1993-04-28 | Genencor Inc | Preparation of enzymes, modifications, catalytic triads to alter ratios or transesterification/hydrolysis ratios |
EP0305216B1 (en) | 1987-08-28 | 1995-08-02 | Novo Nordisk A/S | Recombinant Humicola lipase and process for the production of recombinant humicola lipases |
JPS6474992A (en) | 1987-09-16 | 1989-03-20 | Fuji Oil Co Ltd | Dna sequence, plasmid and production of lipase |
DK6488D0 (da) | 1988-01-07 | 1988-01-07 | Novo Industri As | Enzymer |
EP0394352B1 (en) | 1988-01-07 | 1992-03-11 | Novo Nordisk A/S | Enzymatic detergent |
JP3079276B2 (ja) | 1988-02-28 | 2000-08-21 | 天野製薬株式会社 | 組換え体dna、それを含むシュードモナス属菌及びそれを用いたリパーゼの製造法 |
JP2728531B2 (ja) | 1988-03-24 | 1998-03-18 | ノボ ノルディスク アクティーゼルスカブ | セルラーゼ調製品 |
US5648263A (en) | 1988-03-24 | 1997-07-15 | Novo Nordisk A/S | Methods for reducing the harshness of a cotton-containing fabric |
GB8915658D0 (en) | 1989-07-07 | 1989-08-23 | Unilever Plc | Enzymes,their production and use |
JP3112937B2 (ja) | 1990-04-14 | 2000-11-27 | カリ―ヒエミー アクチエンゲゼルシヤフト | アルカリ性バチルスーリパーゼ、これをコード化するdna配列およびこのリパーゼを生産するバチルス |
DE69129988T2 (de) | 1990-09-13 | 1999-03-18 | Novo Nordisk As | Lipase-varianten |
US5292796A (en) | 1991-04-02 | 1994-03-08 | Minnesota Mining And Manufacturing Company | Urea-aldehyde condensates and melamine derivatives comprising fluorochemical oligomers |
ATE136055T1 (de) | 1991-04-30 | 1996-04-15 | Procter & Gamble | Gerüstsubstanzhaltige flüssigwaschmittel mit borsäure-polyolkomplex zur ptoteolytischen enzyminhibierung |
EP0511456A1 (en) | 1991-04-30 | 1992-11-04 | The Procter & Gamble Company | Liquid detergents with aromatic borate ester to inhibit proteolytic enzyme |
DK28792D0 (da) | 1992-03-04 | 1992-03-04 | Novo Nordisk As | Nyt enzym |
DK72992D0 (da) | 1992-06-01 | 1992-06-01 | Novo Nordisk As | Enzym |
DK88892D0 (da) | 1992-07-06 | 1992-07-06 | Novo Nordisk As | Forbindelse |
PL306812A1 (en) | 1993-04-27 | 1995-04-18 | Gist Brocades Nv | Novel lipase variants suitable for use in detergents |
DK52393D0 (zh) | 1993-05-05 | 1993-05-05 | Novo Nordisk As | |
JP2859520B2 (ja) | 1993-08-30 | 1999-02-17 | ノボ ノルディスク アクティーゼルスカブ | リパーゼ及びそれを生産する微生物及びリパーゼ製造方法及びリパーゼ含有洗剤組成物 |
BR9407808A (pt) | 1993-10-13 | 1997-05-06 | Novo Nordisk As | Variante de peroxidase com melhorada estabilidade para peróxido de hidrogenio em condições alcalinas composição de alvejamento e composição detergente |
ATE361355T1 (de) | 1993-10-14 | 2007-05-15 | Procter & Gamble | Proteasehaltige reinigungsmittel |
JPH07143883A (ja) | 1993-11-24 | 1995-06-06 | Showa Denko Kk | リパーゼ遺伝子及び変異体リパーゼ |
ATE222604T1 (de) | 1994-02-22 | 2002-09-15 | Novozymes As | Methode zur herstellung einer variante eines lipolytischen enzymes |
ATE305031T1 (de) | 1994-03-29 | 2005-10-15 | Novozymes As | Alkalische amylase aus bacellus |
AU2524695A (en) | 1994-05-04 | 1995-11-29 | Genencor International, Inc. | Lipases with improved surfactant resistance |
AU2884595A (en) | 1994-06-20 | 1996-01-15 | Unilever Plc | Modified pseudomonas lipases and their use |
AU2884695A (en) | 1994-06-23 | 1996-01-19 | Unilever Plc | Modified pseudomonas lipases and their use |
BE1008998A3 (fr) | 1994-10-14 | 1996-10-01 | Solvay | Lipase, microorganisme la produisant, procede de preparation de cette lipase et utilisations de celle-ci. |
US5827719A (en) | 1994-10-26 | 1998-10-27 | Novo Nordisk A/S | Enzyme with lipolytic activity |
JPH08228778A (ja) | 1995-02-27 | 1996-09-10 | Showa Denko Kk | 新規なリパーゼ遺伝子及びそれを用いたリパーゼの製造方法 |
CN101955921A (zh) | 1995-03-17 | 2011-01-26 | 诺沃奇梅兹有限公司 | 新的内切葡聚糖酶 |
DE69633825T2 (de) | 1995-07-14 | 2005-11-10 | Novozymes A/S | Modifiziertes enzym mit lipolytischer aktivität |
ATE267248T1 (de) | 1995-08-11 | 2004-06-15 | Novozymes As | Neuartige lipolytische enzyme |
CN100362100C (zh) | 1996-09-17 | 2008-01-16 | 诺沃奇梅兹有限公司 | 纤维素酶变体 |
AU730286B2 (en) | 1996-10-08 | 2001-03-01 | Novo Nordisk A/S | Diaminobenzoic acid derivatives as dye precursors |
MA24811A1 (fr) | 1997-10-23 | 1999-12-31 | Procter & Gamble | Compositions de lavage contenant des variantes de proteases multisubstituees |
DE19813057A1 (de) * | 1998-03-25 | 1999-09-30 | Henkel Kgaa | Flüssige Körperreinigungsmittel |
EP2011864B1 (en) | 1999-03-31 | 2014-12-31 | Novozymes A/S | Polypeptides having alkaline alpha-amylase activity and nucleic acids encoding same |
US6939702B1 (en) | 1999-03-31 | 2005-09-06 | Novozymes A/S | Lipase variant |
EP1214426A2 (en) | 1999-08-31 | 2002-06-19 | Novozymes A/S | Novel proteases and variants thereof |
CN1337553A (zh) | 2000-08-05 | 2002-02-27 | 李海泉 | 地下观光游乐园 |
CA2419896C (en) | 2000-08-21 | 2014-12-09 | Novozymes A/S | Subtilase enzymes |
DE10162728A1 (de) | 2001-12-20 | 2003-07-10 | Henkel Kgaa | Neue Alkalische Protease aus Bacillus gibsonii (DSM 14393) und Wasch-und Reinigungsmittel enthaltend diese neue Alkalische Protease |
GB0314210D0 (en) | 2003-06-18 | 2003-07-23 | Unilever Plc | Laundry treatment compositions |
ATE516347T1 (de) | 2003-10-23 | 2011-07-15 | Novozymes As | Protease mit verbesserter stabilität in detergentien |
US8535927B1 (en) | 2003-11-19 | 2013-09-17 | Danisco Us Inc. | Micrococcineae serine protease polypeptides and compositions thereof |
GB0420203D0 (en) | 2004-09-11 | 2004-10-13 | Unilever Plc | Laundry treatment compositions |
GB0421145D0 (en) | 2004-09-23 | 2004-10-27 | Unilever Plc | Laundry treatment compositions |
EP2009088B1 (en) | 2004-09-23 | 2010-02-24 | Unilever PLC | Laundry treatment compositions |
DE102004052007B4 (de) | 2004-10-25 | 2007-12-06 | Müller Weingarten AG | Antriebssystem einer Umformpresse |
AU2007263009A1 (en) | 2006-06-23 | 2007-12-27 | Akzo Nobel N.V. | Process for preparation of alkoxylated alkylamines / alkyl ether amines with peaked distribution |
ZA200804295B (en) | 2006-08-10 | 2009-09-30 | Unilever Plc | Shading composition |
ES2355763T3 (es) | 2007-01-19 | 2011-03-30 | THE PROCTER & GAMBLE COMPANY | Composición para el cuidado en el lavado de ropa que comprende un agente blanqueante para sustratos celulósicos. |
CN101679919B (zh) | 2007-05-18 | 2011-11-23 | 荷兰联合利华有限公司 | 三苯并二*嗪染料 |
DE102007038031A1 (de) | 2007-08-10 | 2009-06-04 | Henkel Ag & Co. Kgaa | Mittel enthaltend Proteasen |
CA2709609C (en) | 2008-01-04 | 2013-05-28 | The Procter & Gamble Company | Glycosyl hydrolase enzyme and fabric hueing agent containing compositions |
EP2085070A1 (en) | 2008-01-11 | 2009-08-05 | Procter & Gamble International Operations SA. | Cleaning and/or treatment compositions |
US20090217463A1 (en) | 2008-02-29 | 2009-09-03 | Philip Frank Souter | Detergent composition comprising lipase |
US20090217464A1 (en) | 2008-02-29 | 2009-09-03 | Philip Frank Souter | Detergent composition comprising lipase |
BRPI0910682B1 (pt) | 2008-05-02 | 2020-09-24 | Unilever N.V. | Grânulo de corante tonalizante que produzem menos manchas, e, composição detergente granular para lavar roupas |
ES2443822T3 (es) | 2008-05-20 | 2014-02-20 | Unilever N.V. | Composición de matizado |
HUE042847T2 (hu) | 2008-06-06 | 2019-07-29 | Procter & Gamble | A 44 xiloglukanáz család egyik variánsát tartalmazó felületaktív készítmény |
WO2010099997A1 (en) | 2009-03-05 | 2010-09-10 | Unilever Plc | Dye radical initiators |
EP2406327B1 (en) | 2009-03-12 | 2013-08-14 | Unilever PLC | Dye-polymers formulations |
WO2010148624A1 (en) | 2009-06-26 | 2010-12-29 | Unilever Plc | Dye polymers |
BR112012009256A2 (pt) | 2009-10-23 | 2017-06-06 | Unilever Nv | composição de tratamento de lavagem de tecidos, método doméstico de tratamento de tecidos, e, poliamina covalentemente ligada a um corante reativo |
EP2630197B1 (en) | 2010-10-22 | 2019-03-06 | Milliken & Company | Bis-azo colorants for use as bluing agents |
WO2012054058A1 (en) | 2010-10-22 | 2012-04-26 | The Procter & Gamble Company | Bis-azo colorants for use as bluing agents |
US20120101018A1 (en) | 2010-10-22 | 2012-04-26 | Gregory Scot Miracle | Bis-azo colorants for use as bluing agents |
WO2011011799A2 (en) | 2010-11-12 | 2011-01-27 | The Procter & Gamble Company | Thiophene azo dyes and laundry care compositions containing the same |
US9790453B2 (en) | 2011-03-10 | 2017-10-17 | Conopco, Inc. | Dye polymer |
WO2013142486A1 (en) | 2012-03-19 | 2013-09-26 | The Procter & Gamble Company | Laundry care compositions containing dyes |
WO2013151970A1 (en) | 2012-04-03 | 2013-10-10 | The Procter & Gamble Company | Laundry detergent composition comprising water-soluble phthalocyanine compound |
DE102012016462A1 (de) | 2012-08-18 | 2014-02-20 | Clariant International Ltd. | Verwendung von Polyestern in Wasch- und Reinigungsmitteln |
EP2786742A1 (de) * | 2013-04-02 | 2014-10-08 | Evonik Industries AG | Kosmetika enthaltend Rhamnolipide |
EP2966160A1 (en) | 2014-07-09 | 2016-01-13 | Clariant International Ltd. | Storage-stable compositions comprising soil release polymers |
WO2017162378A1 (en) * | 2016-03-21 | 2017-09-28 | Unilever Plc | Laundry detergent composition |
EP3440170B1 (en) * | 2016-04-08 | 2020-04-08 | Unilever PLC | Laundry detergent composition |
EP3424976A1 (en) | 2017-07-07 | 2019-01-09 | Clariant International Ltd | Alkoxylated polycarboxylic acid esters |
CN110869480B (zh) | 2017-07-07 | 2021-08-13 | 联合利华知识产权控股有限公司 | 增白组合物 |
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2020
- 2020-05-28 BR BR112021025261A patent/BR112021025261A2/pt unknown
- 2020-05-28 US US17/621,675 patent/US20220372397A1/en active Pending
- 2020-05-28 WO PCT/EP2020/064851 patent/WO2020259947A1/en active Application Filing
- 2020-05-28 EP EP20728059.5A patent/EP3990599B1/en active Active
- 2020-05-28 CN CN202080045586.7A patent/CN113993981A/zh active Pending
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US20220372397A1 (en) | 2022-11-24 |
WO2020259947A1 (en) | 2020-12-30 |
BR112021025261A2 (pt) | 2022-04-26 |
AR119249A1 (es) | 2021-12-01 |
ZA202109361B (en) | 2023-10-25 |
EP3990599A1 (en) | 2022-05-04 |
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