CN113978050A - 一种带有纳米抗污抗油面料的羽绒衬衫 - Google Patents

一种带有纳米抗污抗油面料的羽绒衬衫 Download PDF

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CN113978050A
CN113978050A CN202111225288.9A CN202111225288A CN113978050A CN 113978050 A CN113978050 A CN 113978050A CN 202111225288 A CN202111225288 A CN 202111225288A CN 113978050 A CN113978050 A CN 113978050A
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shirt
fouling
layer
oil
hydrophobic
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吴昆明
陈岩
刘汉春
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Gaofan Zhejiang Information Technology Co Ltd
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Abstract

本发明涉及一种带有纳米抗污抗油面料的羽绒衬衫，包括衬衣面料，衬衣里料，分别通过自洁粘接层粘接于衬衣面料外表面、衬衣里料内表面的外抗污抗油层、内保暖蓄热层，以及填充于衬衣面料和衬衣里料之间的羽绒；所述衬衣面料和衬衣里料均包括羊毛纤维；所述自洁粘接层包括光敏胶和石墨烯；所述外抗污抗油层、内保暖蓄热层均包括石墨烯、海藻炭、竹纤维素，所述外抗污抗油层、内保暖蓄热层表面均设置有疏水纹路，且疏水纹路内涂覆有超疏水蜡质。本发明通过外抗污抗油层表面的疏水纹路能够增加其表面的疏水能力，能够抗污抗油，另外疏水纹路为防三穗苔草条纹结构，并配合超疏水蜡质使用，更加提高了疏水能力。

Description

一种带有纳米抗污抗油面料的羽绒衬衫
技术领域
本发明属于羽绒衬衫领域，具体涉及一种带有纳米抗污抗油面料的羽绒衬衫。
背景技术
19世纪40年代，西式衬衫传入中国，衬衫最初多为男用，20世纪50年代渐被女子采用，现已成为常用服装之一，衬衫可以穿在内外上衣之间、也可单独穿用的上衣，现有的衬衫一般都比较单薄，当天气变凉以后如果只穿一件衬衫就容易着凉，因此出现了内部填充有羽绒的羽绒衬衫，既具备商务气息，油具有保暖效果，非常受大众喜爱；
但是现有的羽绒衬衫保暖性和透气性均较好，这就导致其抗污抗油效果较差，而由于羽绒衬衫为羽绒制品，因此在受到污染后就会导致其清洗较为麻烦，给用户带来了很多不便。
发明内容
本发明的目的就在于为了解决上述问题而提供一种带有纳米抗污抗油面料的羽绒衬衫。
本发明通过以下技术方案来实现上述目的：
一种带有纳米抗污抗油面料的羽绒衬衫，包括衬衣面料，衬衣里料，分别通过自洁粘接层粘接于衬衣面料外表面、衬衣里料内表面的外抗污抗油层、内保暖蓄热层，以及填充于衬衣面料和衬衣里料之间的羽绒；
所述衬衣面料和衬衣里料均包括羊毛纤维；
所述自洁粘接层包括光敏胶和石墨烯；
所述外抗污抗油层、内保暖蓄热层均包括石墨烯、海藻炭、竹纤维素，所述外抗污抗油层、内保暖蓄热层表面均设置有疏水纹路，且疏水纹路内涂覆有超疏水蜡质。
作为本发明的进一步优化方案，所述衬衣面料还包括聚酯纤维，且聚酯纤维与羊毛纤维按重量份数计分别为60-80份、20-40份。
作为本发明的进一步优化方案，所述自洁粘接层中石墨烯与光敏胶的质量比为1-2:10。
作为本发明的进一步优化方案，所述石墨烯、海藻炭、竹纤维素按重量份数计分别为20-30份、10-20份、50-70份。
作为本发明的进一步优化方案，所述超疏水蜡质按重量份数计包括氟季胺硅烷耦合剂75-88份、二氧化硅凝胶材料2-5份、海藻炭5-10份、竹纤维素5-10份。
作为本发明的进一步优化方案，所述超疏水蜡质涂覆于疏水纹路的槽底，且超疏水蜡质上表面位于疏水纹路槽口下方，所述疏水纹路为防三穗苔草条纹结构。
一种带有纳米抗污抗油面料的羽绒衬衫的制备方法，包括以下步骤：
S1、采用羊毛纤维纺织得到衬衣里料和衬衣面料；
S2、将氟季胺硅烷耦合剂、二氧化硅凝胶材料、海藻炭、竹纤维素混合，得到液体状的超疏水蜡质备用；
S3、利用湿法纺丝将混合的石墨烯、海藻炭、竹纤维素加工成网状纤维层，待网状纤维层未干燥之前采用印花辊进行表面辊压，得到表面带有疏水纹路的内保暖蓄热层，涂抹超疏水蜡质至疏水纹路内，干燥后得到外抗污抗油层；
S4、将光敏胶和石墨烯混合并涂覆于衬衣面料和衬衣里料的一侧表面，再将内保暖蓄热层和外抗污抗油层分别置于衬衣面料和衬衣里料的一侧表面，并通过紫外线光照射，得到一体化粘接的衬衣面料、外抗污抗油层，以及一体化粘接的衬衣里料、内保暖蓄热层；
S5、将衬衣里料与衬衣面料贴合，外抗污抗油层与内保暖蓄热层分别位于衬衣外表面和内表面，再将衬衣里料缝合于衬衣面料上并于衬衣面料和衬衣里料之间填充羽绒，得到羽绒衬衫。
作为本发明的进一步优化方案，步骤S1中的衬衣面料还可以采用羊毛纤维与聚酯纤维混纺制得。
作为本发明的进一步优化方案，步骤S3中，涂抹超疏水蜡质至疏水纹路内的方法为：在印花辊于网状纤维层表面辊压时，将超疏水蜡质涂抹于另一个印花辊的印花凸起表面，在印花辊转动压合网状纤维层时，超疏水蜡质附着于压合形成的疏水纹路内。
作为本发明的进一步优化方案，步骤S3中，采用印花辊进行网状纤维层表面辊压时加热至150℃。
本发明的有益效果在于：
1)本发明衬衣面料和里料中均采用羊毛纤维，在与外抗污抗油层、内保暖蓄热层通过自洁粘接层粘接复合时，采用紫外线灯光照射，不仅可以将衬衣面料与外抗污抗油层以及内保暖蓄热层与衬衣里料粘接在一起，而且羊毛纤维在紫外线光辐射下会打开毛鳞片，便于自洁粘接层的光敏胶和石墨烯与羊毛纤维结合，使得外抗污抗油层、内保暖蓄热层与衬衫面料和里料更加牢固的粘接固定，石墨烯与羊毛纤维充分结合，不易脱落，疏水疏油作用时间也更长，还具有较好的抗菌抑菌以及红外保暖功能；
2)本发明在外抗污抗油层、内保暖蓄热层表面均设置疏水纹路，疏水纹路产生的立体空间效果能够增加内保暖蓄热层的保暖蓄热效果，也避免跑绒，外抗污抗油层表面的疏水纹路能够增加其表面的疏水能力，能够抗污抗油，另外疏水纹路为防三穗苔草条纹结构，并配合超疏水蜡质使用，更加提高了疏水能力；
3)本发明通过在外抗污抗油层、内保暖蓄热层以及超疏水蜡质内均添加海藻炭和竹纤维素，能够提高整个衬衫面料的抗油污、抑菌效果；
4)本发明在超疏水蜡质内添加二氧化硅凝胶材料，其具有大的比表面积和高的孔洞率，因此将其添加至超疏水蜡质内，能够使得氟季胺硅烷耦合剂与其的结合性更强，延长超疏水蜡质疏水寿命。
具体实施方式
下面对本申请作进一步详细描述，有必要在此指出的是，以下具体实施方式只用于对本申请进行进一步的说明，不能理解为对本申请保护范围的限制，该领域的技术人员可以根据上述申请内容对本申请作出一些非本质的改进和调整。
实施例1
一种带有纳米抗污抗油面料的羽绒衬衫，包括衬衣面料，衬衣里料，分别通过自洁粘接层粘接于衬衣面料外表面、衬衣里料内表面的外抗污抗油层、内保暖蓄热层，以及填充于衬衣面料和衬衣里料之间的羽绒；
所述衬衣面料和衬衣里料均包括羊毛纤维；
所述自洁粘接层包括质量比为1.5:10的石墨烯和光敏胶；
所述外抗污抗油层、内保暖蓄热层按重量份数计均包括石墨烯25份、海藻炭15份、竹纤维素60份，所述外抗污抗油层、内保暖蓄热层表面均设置有疏水纹路，且疏水纹路内涂覆有超疏水蜡质，所述超疏水蜡质按重量份数计包括氟季胺硅烷耦合剂82份、二氧化硅凝胶材料3份、海藻炭7.5份、竹纤维素7.5份；所述超疏水蜡质涂覆于疏水纹路的槽底，且超疏水蜡质上表面位于疏水纹路槽口下方，所述疏水纹路为防三穗苔草条纹结构。
本实施例带有纳米抗污抗油面料的羽绒衬衫的制备方法如下：
S1、采用羊毛纤维纺织得到衬衣里料和衬衣面料；
S2、将氟季胺硅烷耦合剂、二氧化硅凝胶材料、海藻炭、竹纤维素混合，得到液体状的超疏水蜡质备用；
S3、利用湿法纺丝将混合的石墨烯、海藻炭、竹纤维素加工成网状纤维层，待网状纤维层未干燥之前采用印花辊进行表面辊压，得到表面带有疏水纹路的内保暖蓄热层，涂抹超疏水蜡质至疏水纹路内，干燥后得到外抗污抗油层；其中，采用印花辊进行网状纤维层表面辊压时加热至150℃；涂抹超疏水蜡质至疏水纹路内的方法为：
在印花辊于网状纤维层表面辊压时，将超疏水蜡质涂抹于另一个印花辊的印花凸起表面，在印花辊转动压合网状纤维层时，超疏水蜡质附着于压合形成的疏水纹路内；
S4、将光敏胶和石墨烯混合并涂覆于衬衣面料和衬衣里料的一侧表面，再将内保暖蓄热层和外抗污抗油层分别置于衬衣面料和衬衣里料的一侧表面，并通过紫外线光照射，得到一体化粘接的衬衣面料、外抗污抗油层，以及一体化粘接的衬衣里料、内保暖蓄热层；
S5、将衬衣里料与衬衣面料贴合，外抗污抗油层与内保暖蓄热层分别位于衬衣外表面和内表面，再将衬衣里料缝合于衬衣面料上并于衬衣面料和衬衣里料之间填充羽绒，得到羽绒衬衫。
实施例2
该实施例提供一种带有纳米抗污抗油面料的羽绒衬衫及其制备方法，羽绒衬衫及其制备方法与实施例1基本相同，区别在于：所述衬衣面料按重量份数计包括聚酯纤维70份、羊毛纤维30份，采用羊毛纤维与聚酯纤维混纺制得。
实施例3
该实施例提供一种带有纳米抗污抗油面料的羽绒衬衫及其制备方法，羽绒衬衫及其制备方法与实施例2基本相同，区别在于：
衬衣面料按重量份数计包括聚酯纤维60份、羊毛纤维40份；
自洁粘接层包括质量比为1:10的石墨烯和光敏胶；
外抗污抗油层、内保暖蓄热层按重量份数计均包括石墨烯20份、海藻炭20份、竹纤维素60份；
超疏水蜡质按重量份数计包括氟季胺硅烷耦合剂75份、二氧化硅凝胶材料5份、海藻炭10份、竹纤维素10份。
实施例4
该实施例提供一种带有纳米抗污抗油面料的羽绒衬衫及其制备方法，羽绒衬衫及其制备方法与实施例2基本相同，区别在于：
衬衣面料按重量份数计包括聚酯纤维80份、羊毛纤维20份；
自洁粘接层包括质量比为2:10的石墨烯和光敏胶；
外抗污抗油层、内保暖蓄热层按重量份数计均包括石墨烯30份、海藻炭20份、竹纤维素50份；
超疏水蜡质按重量份数计包括氟季胺硅烷耦合剂88份、二氧化硅凝胶材料2份、海藻炭10份、竹纤维素10份。
对比例1
该对比例提供一种带有纳米抗污抗油面料的羽绒衬衫及其制备方法，其羽绒衬衫及其制备步骤与实施例2基本相同，区别在于：自洁粘接层不采用光敏胶，采用其他树脂胶，且衬衣面料和衬衣里料中不添加羊毛纤维。
对比例2
该对比例提供一种带有纳米抗污抗油面料的羽绒衬衫及其制备方法，其羽绒衬衫及其制备步骤与实施例2基本相同，区别在于：自洁粘接层不添加石墨烯，外抗污抗油层、内保暖蓄热层以及超疏水蜡质中不添加竹纤维素和海藻炭。
对上述实施例1-4以及对比例1-2制得的羽绒衬衫进行抗油污等测试，拒油等级参考标准AATCC118-2002，耐污等级参照GB/T30159.1-2013《纺织品防污性能的检测和评价第一部分：耐沾污性》，抗菌率参照美国AATCCTestMethod100标准检测，测试得到以下数据：
拒油等级 耐污等级 大肠杆菌抑菌率(％)
实施例1 5 5 97
实施例2 6 6 93
实施例3 5 5 99
实施例4 6 6 94
对比例1 4 4 93
对比例2 4 4 83
由上表可知，本发明通过衬衫面料和衬衫里料中竹纤维素和海藻炭等的采用，外抗污抗油层表面的疏水纹路的设置以及超疏水蜡质的使用，能够增加其表面的疏水能力，实现抗污抗油，而衬衣面料和里料中均采用羊毛纤维，采用紫外线灯光照射，能够使得石墨烯与羊毛纤维充分结合，不易脱落，疏水疏油作用时间也更长，竹纤维素和海藻炭的添加使得衬衫具有较好的抑菌效果。
以上所述实施例仅表达了本发明的几种实施方式，其描述较为具体和详细，但并不能因此而理解为对本发明专利范围的限制。应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。

Claims (10)

1.一种带有纳米抗污抗油面料的羽绒衬衫，其特征在于：包括衬衣面料，衬衣里料，分别通过自洁粘接层粘接于衬衣面料外表面、衬衣里料内表面的外抗污抗油层、内保暖蓄热层，以及填充于衬衣面料和衬衣里料之间的羽绒；
所述衬衣面料和衬衣里料均包括羊毛纤维；
所述自洁粘接层包括光敏胶和石墨烯；
所述外抗污抗油层、内保暖蓄热层均包括石墨烯、海藻炭、竹纤维素，所述外抗污抗油层、内保暖蓄热层表面均设置有疏水纹路，且疏水纹路内涂覆有超疏水蜡质。
2.根据权利要求1所述的一种带有纳米抗污抗油面料的羽绒衬衫，其特征在于：所述衬衣面料还包括聚酯纤维，且聚酯纤维与羊毛纤维按重量份数计分别为60-80份、20-40份。
3.根据权利要求1所述的一种带有纳米抗污抗油面料的羽绒衬衫，其特征在于：所述自洁粘接层中石墨烯与光敏胶的质量比为1-2:10。
4.根据权利要求1所述的一种带有纳米抗污抗油面料的羽绒衬衫，其特征在于：所述石墨烯、海藻炭、竹纤维素按重量份数计分别为20-30份、10-20份、50-70份。
5.根据权利要求1所述的一种带有纳米抗污抗油面料的羽绒衬衫，其特征在于：所述超疏水蜡质按重量份数计包括氟季胺硅烷耦合剂75-88份、二氧化硅凝胶材料2-5份、海藻炭5-10份、竹纤维素5-10份。
6.根据权利要求1所述的一种带有纳米抗污抗油面料的羽绒衬衫，其特征在于：所述超疏水蜡质涂覆于疏水纹路的槽底，且超疏水蜡质上表面位于疏水纹路槽口下方，所述疏水纹路为防三穗苔草条纹结构。
7.一种带有纳米抗污抗油面料的羽绒衬衫的制备方法，其特征在于，包括以下步骤：
S1、采用羊毛纤维纺织得到衬衣里料和衬衣面料；
S2、将氟季胺硅烷耦合剂、二氧化硅凝胶材料、海藻炭、竹纤维素混合，得到液体状的超疏水蜡质备用；
S3、利用湿法纺丝将混合的石墨烯、海藻炭、竹纤维素加工成网状纤维层，待网状纤维层未干燥之前采用印花辊进行表面辊压，得到表面带有疏水纹路的内保暖蓄热层，涂抹超疏水蜡质至疏水纹路内，干燥后得到外抗污抗油层；
S4、将光敏胶和石墨烯混合并涂覆于衬衣面料和衬衣里料的一侧表面，再将内保暖蓄热层和外抗污抗油层分别置于衬衣面料和衬衣里料的一侧表面，并通过紫外线光照射，得到一体化粘接的衬衣面料、外抗污抗油层，以及一体化粘接的衬衣里料、内保暖蓄热层；
S5、将衬衣里料与衬衣面料贴合，外抗污抗油层与内保暖蓄热层分别位于衬衣外表面和内表面，再将衬衣里料缝合于衬衣面料上并于衬衣面料和衬衣里料之间填充羽绒，得到羽绒衬衫。
8.根据权利要求7所述的一种带有纳米抗污抗油面料的羽绒衬衫的制备方法，其特征在于：步骤S1中的衬衣面料还可以采用羊毛纤维与聚酯纤维混纺制得。
9.根据权利要求7所述的一种带有纳米抗污抗油面料的羽绒衬衫的制备方法，其特征在于：步骤S3中，涂抹超疏水蜡质至疏水纹路内的方法为：在印花辊于网状纤维层表面辊压时，将超疏水蜡质涂抹于另一个印花辊的印花凸起表面，在印花辊转动压合网状纤维层时，超疏水蜡质附着于压合形成的疏水纹路内。
10.根据权利要求7所述的一种带有纳米抗污抗油面料的羽绒衬衫的制备方法，其特征在于：步骤S3中，采用印花辊进行网状纤维层表面辊压时加热至150℃。
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CN201109807Y (zh) * 2007-09-03 2008-09-03 张家港市龙杰特种化纤有限公司 涤纶扁平丝
CN202603661U (zh) * 2012-05-14 2012-12-19 绍兴市康云来羽绒服装有限公司 保健型羽绒服
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CN109249655A (zh) * 2018-08-28 2019-01-22 江苏阳光股份有限公司 防风拒水型羊毛面料

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CN201109807Y (zh) * 2007-09-03 2008-09-03 张家港市龙杰特种化纤有限公司 涤纶扁平丝
CN202603661U (zh) * 2012-05-14 2012-12-19 绍兴市康云来羽绒服装有限公司 保健型羽绒服
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Application publication date: 20220128