CN113698626B - 一种软质纳米颗粒稳定的硅油乳液及其制备方法 - Google Patents

一种软质纳米颗粒稳定的硅油乳液及其制备方法 Download PDF

Info

Publication number
CN113698626B
CN113698626B CN202111031699.4A CN202111031699A CN113698626B CN 113698626 B CN113698626 B CN 113698626B CN 202111031699 A CN202111031699 A CN 202111031699A CN 113698626 B CN113698626 B CN 113698626B
Authority
CN
China
Prior art keywords
silicone oil
emulsion
parts
soft
oil emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202111031699.4A
Other languages
English (en)
Other versions
CN113698626A (zh
Inventor
沈军炎
杨雷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang University Of Technology Shaoxing Keqiao Research Institute Co ltd
Zhejiang Sci Tech University ZSTU
Original Assignee
Zhejiang University Of Technology Shaoxing Keqiao Research Institute Co ltd
Zhejiang Sci Tech University ZSTU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang University Of Technology Shaoxing Keqiao Research Institute Co ltd, Zhejiang Sci Tech University ZSTU filed Critical Zhejiang University Of Technology Shaoxing Keqiao Research Institute Co ltd
Priority to CN202111031699.4A priority Critical patent/CN113698626B/zh
Publication of CN113698626A publication Critical patent/CN113698626A/zh
Application granted granted Critical
Publication of CN113698626B publication Critical patent/CN113698626B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04Polysiloxanes
    • C08J2383/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04Polysiloxanes
    • C08J2483/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明属于纺织助剂技术领域,具体涉及一种软质纳米颗粒稳定的硅油乳液,其质量配比如下:氨基硅油20‑30份、乳化剂2‑8份、软质纳米颗粒乳液3‑32份、pH调节剂0.8‑1.5份、去离子水50‑60份,并提供了具体的制备方法。本发明解决解决传统硅油乳液稳定性差和纺织品整理效果差的问题,具备优良的乳液稳定性,纤维上附着性好,能够有效地提高纺织品的透气性以及柔软性,由此提高了其实用性以及舒适性;同时其具有成本低廉、工艺简单的特点。

Description

一种软质纳米颗粒稳定的硅油乳液及其制备方法
技术领域
本发明属于纺织助剂技术领域,具体涉及一种软质纳米颗粒稳定的硅油乳液及其制备方法。
背景技术
硅油因具有链段柔顺、表面张力小等特点,其对织物柔软性有显著的提升效果,广泛应用于织物柔软与仿真整理。目前市场上常使用的织物后整理剂以氨基硅油乳液为主,但是其储存稳定性较差,普遍易破乳,易黄变,整理后的织物憎水、不吸汗,很大程度影响织物的舒适感和外观。传统硅油乳液主要是通过静电稳定化、降低界面张力和借助表面活性剂或可溶性大分子的空间位阻稳定相结合来实现乳液稳定。由于常规乳化剂(如表面活性剂等)在油水界面上会发生动态交换,导致硅油难以乳化均匀分散在体系中。因此,传统硅油乳液在热力学上并不稳定,随着时间的推移,由于聚结、絮凝和奥斯特瓦尔德成熟而破乳,导致乳液失效。此外,随着消费者对舒适生活方式的追求,功能性纺织品市场快速发展,开发新型硅油乳液产品来取代传统的硅油产品已变得越来越紧迫,急需设计合成出各种新型硅油乳液产品以满足人们对织物的柔软性、白度、亲水性和润湿性的需要。
发明内容
针对现有技术中的问题,本发明提供一种软质纳米颗粒稳定的硅油乳液,解决解决传统硅油乳液稳定性差和纺织品整理效果差的问题,具备优良的乳液稳定性,纤维上附着性好,能够有效地提高纺织品的透气性以及柔软性,由此提高了其实用性以及舒适性;同时其具有成本低廉、工艺简单的特点。
为实现以上技术目的,本发明的技术方案是:
一种软质纳米颗粒稳定的硅油乳液,其质量配比如下:
氨基硅油20-30份、乳化剂2-8份、软质纳米颗粒乳液3-32份、pH调节剂0.8-1.5份、去离子水50-60份。
所述乳化剂采用聚氧乙烯醚月桂酸酯、异构十三醇乙氧基化物、脂肪酸甲酯乙氧基化物中的一种或几种。
所述软质纳米颗粒乳液为聚丙烯酸丁酯乳液(PBA,150nm)、聚丙烯酸丙酯乳液(PPA,120nm)、聚丙烯酸异辛酯乳液(PEHA,170nm)中的至少一种,上述三种乳液的含固量均为30%。
所述pH调节剂采用醋酸。
所述硅油乳液的制备方法,包括:
将氨基硅油、pH调节剂和去离子水混合加入反应容器中,在室温下以800-1500rpm的转速搅拌10-30min,然后边搅拌边加入软质纳米颗粒乳液和乳化剂,并继续搅拌30-90min,得到乳白色且均匀分散的硅油乳液。该原料搅拌过程中可根据需要进行先后调节。
上述软质纳米颗粒稳定的硅油乳液在纺织品整理中的应用。
从以上描述可以看出,本发明具备以下优点:
1.本发明解决解决传统硅油乳液稳定性差和纺织品整理效果差的问题,具备优良的乳液稳定性,纤维上附着性好,能够有效地提高纺织品的透气性以及柔软性,由此提高了其实用性以及舒适性;同时其具有成本低廉、工艺简单的特点。
2.本发明软质颗粒可以在油水界面伸展变形,增加了界面吸附能和颗粒覆盖面积,对乳液分散稳定性的提升更加显著,因此,软质颗粒对硅油具有更好的乳化性能,形成的乳液稳定性更好,对织物的手感和柔软性等方面影响小。
3.本发明中的软质纳米颗粒稳定的硅油乳液通过吸附在油水界面的软质纳米颗粒形成物理屏障,通过体积排斥阻隔界面油水相互作用和液滴接触,且这种吸附在界面上的颗粒的行为是不可逆的。
4.本发明将其应用于纺织品后处理中,使得通过乳液整理后的纺织品保持优良的透气性和柔软性,从而满足了现代人们对纺织品舒适性的需求。本发明提供的乳化工艺简单,其过程易于实施和控制,利于推广生产,同时具有很强的可设计性,便于工艺调整,所获得材料在纺织品、化妆品等领域具有广阔的应用前景。
附图说明
图1是对比例1、实施例2和3所制的软质纳米颗粒稳定的硅油乳液的乳液性能;
图2是应用例1-3在扫描电镜下整理面料的表观形貌。
具体实施方式
结合图1至图2,详细说明本发明的一个具体实施例,但不对本发明的权利要求做任何限定。
实施例1
一种软质纳米颗粒稳定的硅油乳液的制备方法,包括以下步骤:
(1)将26重量份氨基硅油、2重量份乳化剂聚氧乙烯醚月桂酸酯放入反应容器内进行高速剪切乳化,搅拌时间为90min,转速为900r/min,搅拌温度为室温;
(2)在步骤(1)得到的体系中加入醋酸调节pH至5.0-7.0;
(3)在步骤(2)得到的体系中加缓慢18重量份聚丙烯酸异辛酯乳液(PEHA,170nm),继续搅拌60-90min,得到所述软质纳米颗粒稳定的硅油乳液。
实施例2
一种软质纳米颗粒稳定的硅油乳液的制备方法,包括以下步骤:
(1)将26重量份氨基硅油、2重量份乳化剂异构十三醇乙氧基化物和4重量份聚丙烯酸丁酯乳液(PBA,150nm)放入反应容器内进行高速剪切乳化,搅拌时间为30min,转速为900r/min,搅拌温度为室温;
(2)在步骤(1)得到的体系中加入醋酸调节pH至5.0-7.0,得到所述软质纳米颗粒稳定的硅油乳液。
实施例3
一种软质纳米颗粒稳定的硅油乳液的制备方法,包括以下步骤:
(1)将26重量份氨基硅油、2重量份乳化剂异构十三醇乙氧基化物放入反应容器内进行高速剪切乳化,搅拌时间为90min,转速为900r/min,搅拌温度为室温;
(2)在步骤(1)得到的体系中加入醋酸调节pH至5.0-7.0;
(3)在步骤(2)得到的体系中加缓慢4重量份聚丙烯酸异辛酯乳液(PEHA,170nm),继续搅拌60-90min,得到所述软质纳米颗粒稳定的硅油乳液。
实施例4
一种软质纳米颗粒稳定的硅油乳液的制备方法,包括以下步骤:
(1)将26重量份氨基硅油、2重量份乳化剂脂肪酸甲酯乙氧基化物放入反应容器内进行高速剪切乳化,搅拌时间为90min,转速为900r/min,搅拌温度为室温;
(2)在步骤(1)得到的体系中加入醋酸调节pH至5.0-7.0;
(3)在步骤(2)得到的体系中加缓慢18重量份聚丙烯酸丁酯乳液(PBA,150nm),继续搅拌60-90min,得到所述软质纳米颗粒稳定的硅油乳液。
实施例5
一种软质纳米颗粒稳定的硅油乳液的制备方法,包括以下步骤:
(1)将26重量份氨基硅油、2重量份乳化剂脂肪酸甲酯乙氧基化物放入反应容器内进行高速剪切乳化,搅拌时间为90min,转速为900r/min,搅拌温度为室温;
(2)在步骤(1)得到的体系中加入醋酸调节pH至5.0~7.0;
(3)在步骤(2)得到的体系中加缓慢28重量份聚丙烯酸丙酯乳液(PPA,120nm),继续搅拌60~90min,得到所述软质纳米颗粒稳定的硅油乳液。
实施例1-5所制备的软质纳米颗粒稳定的硅油乳液的性能测试结果如表1所示,软质纳米颗粒稳定的硅油乳液离心稳定性均为优良,乳液外观乳白色半透明,稳定不分层。
表1
序号 乳化剂 软质纳米颗粒 乳液外观
1 聚氧乙烯醚月桂酸酯 PEHA 乳白色稳定乳液
2 异构十三醇乙氧基化物 PBA 乳白色稳定乳液
3 异构十三醇乙氧基化物 PEHA 乳白色稳定乳液
4 脂肪酸甲酯乙氧基化物 PBA 乳白色稳定乳液
5 脂肪酸甲酯乙氧基化物 PPA 乳白色稳定乳液
在制备软质纳米颗粒稳定的硅油乳液步骤中,乳化剂降低了混合体系中氨基硅油和水之间的界面张力,并在氨基硅油微滴表面形成较坚固的薄膜或由于乳化剂给出的电荷而在微滴表面形成双电层,阻止微滴彼此聚集。而软质纳米颗粒具有适合的亲水性,促使软质纳米颗粒在油水界面上与乳化剂一起形成物理屏障,通过体积排斥阻隔界面油水相互作用和液滴接触,且这种吸附在界面上的颗粒行为取决于软质纳米颗粒自身的润湿性,是不可逆的。因此,改变软质纳米颗粒的添加顺序不会影响硅油乳液的稳定性。
对比例1制备方法同实施例3,不同之处在于对比例1步骤(1)中未加入软质纳米颗粒,同时乳化剂异构十三醇乙氧基化物的用量提高至14重量份。
对比例1、实施例2和3所制的软质纳米颗粒稳定的硅油乳液的主要性能指标如下表
对比例1、实施例2和3所制的软质纳米颗粒稳定的硅油乳液的乳液性能,依次如图1所示,软质纳米颗粒稳定的硅油乳液具有良好的分散性。
应用例1
实施例4得到的硅油乳液配制成15g/L的整理液,以浸轧整理的方式整理涤纶长丝面料,在170℃下烘90s后得到整理后面料。
应用例2
将实施例4得到的硅油乳液配制成25g/L的整理液,以浸轧整理的方式整理涤纶长丝面料,在170℃下烘90s后得到整理后面料。
应用例3
将对比例1得到的硅油乳液配制成25g/L的整理液,以浸轧整理的方式整理涤纶长丝面料,在170℃下烘90s后得到整理后面料。
如图2所示,应用例1-3在扫描电镜下整理的表观形貌。
由上述实验结果可知,该制备方法制得的所述软质纳米颗粒稳定的硅油乳液具有优良的稳定性以及纤维上吸附性,可以有效应用于纺织品整理领域。
综上所述,本发明具有以下优点:
1.本发明解决解决传统硅油乳液稳定性差和纺织品整理效果差的问题,具备优良的乳液稳定性,纤维上附着性好,能够有效地提高纺织品的透气性以及柔软性,由此提高了其实用性以及舒适性;同时其具有成本低廉、工艺简单的特点。
2.本发明软质颗粒可以在油水界面伸展变形,增加了界面吸附能和颗粒覆盖面积,对乳液分散稳定性的提升更加显著,因此,软质颗粒对硅油具有更好的乳化性能,形成的乳液稳定性更好,对织物的手感和柔软性等方面影响小。
3.本发明中的软质纳米颗粒稳定的硅油乳液通过吸附在油水界面的软质纳米颗粒形成物理屏障,通过体积排斥阻隔界面油水相互作用和液滴接触,且这种吸附在界面上的颗粒的行为是不可逆的。
4.本发明将其应用于纺织品后处理中,使得通过乳液整理后的纺织品保持优良的透气性和柔软性,从而满足了现代人们对纺织品舒适性的需求。本发明提供的乳化工艺简单,其过程易于实施和控制,利于推广生产,同时具有很强的可设计性,便于工艺调整,所获得材料在纺织品、化妆品等领域具有广阔的应用前景。
可以理解的是,以上关于本发明的具体描述,仅用于说明本发明而并非受限于本发明实施例所描述的技术方案。本领域的普通技术人员应当理解,仍然可以对本发明进行修改或等同替换,以达到相同的技术效果;只要满足使用需要,都在本发明的保护范围之内。

Claims (5)

1.一种软质纳米颗粒稳定的硅油乳液,其特征在于:其质量配比如下:
氨基硅油20-30份、乳化剂2-8份、软质纳米颗粒乳液3-32份、pH调节剂0.8-1.5份、去离子水50-60份;所述软质纳米颗粒乳液为颗粒粒径为150nm的聚丙烯酸丁酯乳液、颗粒粒径为120nm的聚丙烯酸丙酯乳液、颗粒粒径为170nm的聚丙烯酸异辛酯乳液中的至少一种,上述三种乳液的含固量均为30%。
2.根据权利要求1所述的软质纳米颗粒稳定的硅油乳液,其特征在于:所述乳化剂采用聚氧乙烯醚月桂酸酯、异构十三醇乙氧基化物、脂肪酸甲酯乙氧基化物中的一种或几种。
3.根据权利要求1所述的软质纳米颗粒稳定的硅油乳液,其特征在于:所述pH调节剂采用醋酸。
4.根据权利要求1所述的软质纳米颗粒稳定的硅油乳液,其特征在于:所述硅油乳液的制备方法,包括:
将氨基硅油、pH调节剂和去离子水混合加入反应容器中,在室温下以800-1500rpm的转速搅拌10-30min,然后边搅拌边加入软质纳米颗粒乳液和乳化剂,并继续搅拌30-90min,得到乳白色且均匀分散的硅油乳液。
5.如权利要求1-4任意一项所述的软质纳米颗粒稳定的硅油乳液在纺织品整理中的应用。
CN202111031699.4A 2021-09-03 2021-09-03 一种软质纳米颗粒稳定的硅油乳液及其制备方法 Active CN113698626B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111031699.4A CN113698626B (zh) 2021-09-03 2021-09-03 一种软质纳米颗粒稳定的硅油乳液及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111031699.4A CN113698626B (zh) 2021-09-03 2021-09-03 一种软质纳米颗粒稳定的硅油乳液及其制备方法

Publications (2)

Publication Number Publication Date
CN113698626A CN113698626A (zh) 2021-11-26
CN113698626B true CN113698626B (zh) 2023-12-08

Family

ID=78659261

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111031699.4A Active CN113698626B (zh) 2021-09-03 2021-09-03 一种软质纳米颗粒稳定的硅油乳液及其制备方法

Country Status (1)

Country Link
CN (1) CN113698626B (zh)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007077178A (ja) * 2005-09-09 2007-03-29 Univ Kanagawa シリコーン型エマルション及びその製造方法
CN111441175A (zh) * 2020-06-02 2020-07-24 宁波沪东化学有限公司 一种氨基硅油乳液及其制备方法
CN111467984A (zh) * 2020-03-07 2020-07-31 中国科学院大学温州研究院(温州生物材料与工程研究所) 一种基于硅油和植物油的双元高内相乳液组合物
CN112280131A (zh) * 2020-11-06 2021-01-29 广东泰强化工实业有限公司 一种丙烯酸酯-氯丁胶乳的复合乳液及其制备方法
CN112457660A (zh) * 2019-09-09 2021-03-09 施乐公司 热塑性聚合物颗粒及其制备和使用方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9878296B2 (en) * 2013-10-11 2018-01-30 The University Of Massachusetts Stabilizing liquid drops of arbitrary shape by the interfacial jamming of nanoparticles
CN107130428B (zh) * 2017-06-15 2019-02-01 东华大学 一种超疏水织物及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007077178A (ja) * 2005-09-09 2007-03-29 Univ Kanagawa シリコーン型エマルション及びその製造方法
CN112457660A (zh) * 2019-09-09 2021-03-09 施乐公司 热塑性聚合物颗粒及其制备和使用方法
CN111467984A (zh) * 2020-03-07 2020-07-31 中国科学院大学温州研究院(温州生物材料与工程研究所) 一种基于硅油和植物油的双元高内相乳液组合物
CN111441175A (zh) * 2020-06-02 2020-07-24 宁波沪东化学有限公司 一种氨基硅油乳液及其制备方法
CN112280131A (zh) * 2020-11-06 2021-01-29 广东泰强化工实业有限公司 一种丙烯酸酯-氯丁胶乳的复合乳液及其制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Silicone oil emulsions stabilized by polymers and solid particles;Masami Kawaguchi;《Advances in Colloid and Interface Science》;第233卷;第186-199页 *
氨基硅油微乳液的制备及性能研究;张壮等;《天津工业大学学报》;第29卷(第6期);第42-46页 *

Also Published As

Publication number Publication date
CN113698626A (zh) 2021-11-26

Similar Documents

Publication Publication Date Title
CN107190382B (zh) 一种石墨烯改性的涤纶混纺织物及其制备方法
CN111287003B (zh) 一种水性石墨烯ptc导电染料及其制备方法和该染料处理的导电纤维
CN110295500B (zh) 一种使纯棉面料具备仿丝光凉感的面料整理方法
CN113698626B (zh) 一种软质纳米颗粒稳定的硅油乳液及其制备方法
CN115612312B (zh) 一种稳定性高的纳米纤维素染料分散液及其制备方法
CN101585968B (zh) 一种皮革加工过程用的阳离子蜡乳液及其制备方法
CN113308903B (zh) 一种水性丙烯酸酯涂层胶及其制备方法
CN103388195B (zh) 一种抗菌大豆蛋白纤维生产方法及其产品
CN112160155B (zh) 一种阻燃抗菌面料
CN109320100A (zh) 一种增强型玻璃纤维浸润剂
CN108530930A (zh) 一种抗菌环保缓冲包装材料的制备方法
CN113389043A (zh) 一种抗皱防污西服面料及其制备方法
CN110344160B (zh) 一种抗菌防静电的运动服面料及其制备方法
CN110735195B (zh) 一种含乳木果油的再生纤维素纤维及其制备方法
CN116657286A (zh) 超高强度碳纤维原丝用油剂及其制备方法
CN107892754B (zh) 一种多功能氧化聚乙烯蜡乳液及其制备方法
CN108411395B (zh) 导电纤维素纤维及其制备方法
CN107217488B (zh) 一种抗静电抑菌腈纶面料
CN110771692A (zh) 一种油茶籽油纳米乳液及其制备方法
CN107779983B (zh) 一种纳米材料改性的pbt纺丝的制备方法
CN111441175A (zh) 一种氨基硅油乳液及其制备方法
CN114318570B (zh) 一种凉感粘胶纤维用液体母料的制备方法及应用
CN113105650A (zh) 一种以毛刷状微球为稳定乳化剂的皮克林乳液及其制备方法
CN110643054A (zh) 一种甲基硅油乳液及其制造方法
CN113930963B (zh) 一种经纳米咖啡碳材料整理的真丝暖感面料的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant