CN113682000A - 一种防水透气弹力面料及其制备方法 - Google Patents
一种防水透气弹力面料及其制备方法 Download PDFInfo
- Publication number
- CN113682000A CN113682000A CN202110893519.7A CN202110893519A CN113682000A CN 113682000 A CN113682000 A CN 113682000A CN 202110893519 A CN202110893519 A CN 202110893519A CN 113682000 A CN113682000 A CN 113682000A
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- Prior art keywords
- layer
- waterproof breathable
- fabric
- elastic
- fiber
- Prior art date
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Abstract
本发明公开了一种防水透气弹力面料及其制备方法,所述防水透气弹力面料由内到外包括面料本体和设置在面料本体上的防水透气层,所述面料本体包括亲肤抗菌里层和弹性表层,所述弹性表层位于亲肤抗菌里层的上方,所述弹性表层和亲肤抗菌里层通过竹纤维层连接;所述弹性表层上端表面设有防水透气层,所述防水透气层采用纳米粒子材料喷涂在面料本体弹性表层的上端表面。本发明的防水透气弹力面料尺寸稳定,手感柔软舒适,具有优异的防水防风性、透气性以及高弹性,本发明的面料制备方法简单且安全环保,能够实现产业化规模化的生产加工。
Description
技术领域
本发明涉及面料技术领域,具体涉及一种防水透气弹力面料及其制备方法。
背景技术
随着现代纺织业的不断发展和人民生活水平的提高,消费者对面料的功能化要求越来越高,在满足舒适性能的基础上,越来越多风格迥异,功能丰富的面料开始出现。人们对面料的功能性、舒适性、安全性、保健性和环保性等都有更高的要求,尤其是在户外运动中,对服装面料的防水、防风、透气、保暖甚至抗菌性能有更高的要求。
在功能性纺织面料中,防水透气弹性面料是纺织产品研究开发的热点,中国专利CN109177370A公开了一种三层复合防水透气面料,包括面料内层、面料夹层和防水层;面料内层和面料夹层的表面均粘结有橡胶柱;防水层为防水透气薄膜;制备的面料具有良好的透气性和防风防水保暖性,上述专利存在的不足是面料内层与面料夹层间通过胶黏剂粘合,橡胶柱间等间距粘结子在面料内层和面料夹层表面,防水透气薄膜是通过聚氨酯热熔胶热压复合与面料夹层表面,多种结构间采用环氧树脂胶黏剂、聚氨酯热熔胶,会使得纺织面料的舒适度降低,面料防水防风性能持久性不佳,面料使用寿命缩短,以及该三层防水透气面料的弹性较差,也不具有抗菌性。
中国专利CN103587193A公开了一种防风防水透气面料,面料依次包括外层、面料层和里层,所述外层、面料层和里层压合在一起,其中外层为防风防水透气膜,面料层为织物,里层为四管道纤维材料层。其中所述防风防水透气膜为微孔聚氨酯膜;所述外层外还设置有保护层,所述保护层为聚偏氟乙烯喷涂膜。该纺织面料虽然防水透气性能优异,但面料采用的材料弹性和力学性能上稍显不足。
发明内容
有鉴于此,本发明提供一种防水透气弹力面料及其制备方法,以解决上述技术问题。
本发明提供如下技术方案:
一种防水透气弹力面料,所述防水透气弹力面料由内到外包括面料本体和设置在面料本体上的防水透气层,所述面料本体包括亲肤抗菌里层和弹性表层,所述弹性表层位于亲肤抗菌里层的上方,所述弹性表层和亲肤抗菌里层通过竹纤维层连接;所述弹性表层上端表面设有防水透气层,所述防水透气层采用纳米粒子材料喷涂在面料本体弹性表层的上端表面。
优选地,所述弹性表层包括重量占比为的40%~60%的莫代尔纤维、20%~30%的海藻炭纤维和20%~30%的MS舒弹纤维。
优选地,所述亲肤抗菌里层包括重量占比为30%~40%抗菌聚酯纤维、40%~55%的棉纤维和5%~30%的麻纤维。
更优选地,所述弹性表层和亲肤抗菌里层通过竹纤维层粘结连接,所述竹纤维层中的竹纤维的长度为50mm~80mm,细度为1.3dtex~1.65dtex。
优选地,所述亲肤抗菌里层和竹纤维层上开设有若干均匀分布间距恒定的微型孔洞,所述亲肤抗菌里层和竹纤维层上的微型孔洞位置交错设置。
优选地,所述防水透气层为防水透气纳米薄膜层,所述防水透气纳米薄膜层采用纳米薄膜材料均匀喷涂在弹性表层上端表面,所述纳米薄膜材料的粒径为50nm~300nm。
更优选地,所述纳米薄膜材料按重量份计,包括以下组分:50份~60份聚偏四氟乙烯、10份~30份聚偏四氟乙烯、5份~10份硬脂酸镁、1份~3份紫外线吸收剂、助剂1份~3份。
更优选地,所述纳米薄膜材料按重量份计,包括以下组分:55份聚偏四氟乙烯、20份聚偏四氟乙烯、5份硬脂酸镁、1.5份紫外线吸收剂、助剂3份。
更优选地,所述纳米薄膜材料的制备方法包括以下步骤:将所述重量份的聚偏四氟乙烯、硬脂酸镁、紫外线吸收剂、助剂混合,在60℃~80℃下搅拌2h~6h,超声处理1h~2h,送入双螺杆挤出机熔融、混炼、挤出、冷却、切粒、干燥、粉碎、研磨后制得纳米薄膜材料。
本发明另一目的在于提供一种上述防水透气弹力面料的制备方法,包括以下步骤:
(1)将莫代尔纤维、海藻炭纤维、MS舒弹纤维按重量比经混纺工艺加工后,利用针织机编织,制得弹性表层;
(2)将抗菌聚酯纤维、棉纤维、麻纤维按重量比经混纺工艺加工后,利用针织机编织,制得亲肤抗菌里层;
(3)将步骤(2)制得的亲肤抗菌里层与竹纤维层进行粘结,再将步骤(1)制得的弹性表层粘结在竹纤维层上,制得面料坯体;
(4)将步骤(3)制得的面料坯体在整理液中浸扎处理2h~4h,取出后烘干,得到面料本体;将纳米薄膜材料溶解在溶剂中,利用喷涂机由上往下匀速喷涂在面料本体上,经烘烤、冷却后,制得防水透气弹力面料。
优选地,所述亲肤抗菌里层的厚度为0.2mm~0.4mm;弹性表层的厚度为0.4mm~0.6mm;竹纤维层的厚度为0.05mm~0.5mm;防水透气层的厚度为0.1mm~0.3mm。
从上述的技术方案可以看出,本发明的有益效果是:
(1)本发明的防水透气弹力面料尺寸稳定,手感柔软舒适,具有优异的防水防风性、透气性以及高弹性,本发明的面料制备方法简单且安全环保,能够实现产业化规模化的生产加工。
(2)本发明的防水透气弹力面料结构为面料本体的亲肤抗菌里层、竹纤维层、弹性表面和防水透气层,亲肤抗菌里层采用抗菌聚酯纤维、棉纤维、麻纤维加工而成,亲肤抗菌层与人体皮肤接触,利用棉纤维能够确保面料的舒适性,解决麻纤维刚性大、有刺痒感的缺点,同时保证了里层的抗菌性和吸湿放湿性。面料本体的弹性表层中的MS舒弹纤维能够使得面料具有良好的强度、弹性和韧性,且能最大限度的长期保持弹性、柔软舒适性,将其与莫代尔纤维、海藻炭纤维混纺编织,在确保表层面料弹性的同时,使得弹性表层柔软顺滑,质地细腻;竹纤维层连接亲肤抗菌层和弹性表层,不仅使得面料具有优异的吸湿透气性,还使得面料具有良好的抗菌性。
(3)本发明的防水透气弹力面料在面料本体外喷涂防水透气纳米薄膜层,纳米薄膜材料采用具有疏水性的原料,在有效保证良好透气性和舒适性的情况下,显著的提高了面料的防水性,且面料尺寸稳定。
具体实施方式
为使本发明的目的、技术方案和优点更加清楚明白,下面结合实施方式,对本发明做进一步详细说明。在此,本发明的示意性实施方式及其说明用于解释本发明,但并不作为对本发明的限定。
实施例1
一种防水透气弹力面料及其制备方法
防水透气弹力面料,所述防水透气弹力面料由内到外包括面料本体和设置在面料本体上的防水透气层,所述面料本体包括亲肤抗菌里层和弹性表层,所述弹性表层位于亲肤抗菌里层的上方,所述弹性表层和亲肤抗菌里层通过竹纤维层连接;所述弹性表层上端表面设有防水透气层,所述防水透气层采用纳米粒子材料喷涂在面料本体弹性表层的上端表面。
上述弹性表层包括重量占比为的40%的莫代尔纤维、30%的海藻炭纤维和30%的MS舒弹纤维。上述亲肤抗菌里层包括重量占比为30%抗菌聚酯纤维、40%的棉纤维和30%的麻纤维。上述弹性表层和亲肤抗菌里层通过竹纤维层粘结连接,上述竹纤维层中的竹纤维的长度为50mm,细度为1.3dtex。上述亲肤抗菌里层和竹纤维层上开设有若干均匀分布间距恒定的微型孔洞,上述亲肤抗菌里层和竹纤维层上的微型孔洞位置交错设置。
上述防水透气层为防水透气纳米薄膜层,上述防水透气纳米薄膜层采用纳米薄膜材料均匀喷涂在弹性表层上端表面,上述纳米薄膜材料的粒径为50nm。上述纳米薄膜材料按重量份计,包括以下组分:50kg聚偏四氟乙烯、10kg聚偏四氟乙烯、5kg硬脂酸镁、1kg紫外线吸收剂、助剂1kg。
上述纳米薄膜材料的制备方法包括以下步骤:将上述重量份的聚偏四氟乙烯、硬脂酸镁、紫外线吸收剂、助剂混合,在60℃下搅拌2h,超声处理1h,送入双螺杆挤出机熔融、混炼、挤出、冷却、切粒、干燥、粉碎、研磨后制得纳米薄膜材料。
上述防水透气弹力面料的制备方法,包括以下步骤:
(1)将莫代尔纤维、海藻炭纤维、MS舒弹纤维按重量比经混纺工艺加工后,利用针织机编织,制得弹性表层;
(2)将抗菌聚酯纤维、棉纤维、麻纤维按重量比经混纺工艺加工后,利用针织机编织,制得亲肤抗菌里层;
(3)将步骤(2)制得的亲肤抗菌里层与竹纤维层进行粘结,再将步骤(1)制得的弹性表层粘结在竹纤维层上,制得面料坯体;
(4)将步骤(3)制得的面料坯体在整理液中浸扎处理2h,取出后烘干,得到面料本体;将纳米薄膜材料溶解在溶剂中,利用喷涂机由上往下匀速喷涂在面料本体上,经烘烤、冷却后,制得防水透气弹力面料。
上述亲肤抗菌里层的厚度为0.2mm;弹性表层的厚度为0.4mm;竹纤维层的厚度为0.05mm~0.5mm;防水透气层的厚度为0.1mm。
实施例2
一种防水透气弹力面料及其制备方法
与实施例1的区别为:
弹性表层包括重量占比为的45%的莫代尔纤维、25%的海藻炭纤维和30%的MS舒弹纤维。亲肤抗菌里层包括重量占比为30%抗菌聚酯纤维、45%的棉纤维和25%的麻纤维。弹性表层和亲肤抗菌里层通过竹纤维层粘结连接,竹纤维层中的竹纤维的长度为55mm,细度为1.4dtex。纳米薄膜材料的粒径为80nm。纳米薄膜材料按重量份计,包括以下组分:55kg聚偏四氟乙烯、15kg聚偏四氟乙烯、7kg硬脂酸镁、1.5kg紫外线吸收剂、助剂1.2kg。
纳米薄膜材料的制备方法包括以下步骤:将上述重量份的聚偏四氟乙烯、硬脂酸镁、紫外线吸收剂、助剂混合,在65℃下搅拌3h,超声处理1.5h,送入双螺杆挤出机熔融、混炼、挤出、冷却、切粒、干燥、粉碎、研磨后制得纳米薄膜材料。
上述防水透气弹力面料的制备方法,包括以下步骤:
(1)将莫代尔纤维、海藻炭纤维、MS舒弹纤维按重量比经混纺工艺加工后,利用针织机编织,制得弹性表层;
(2)将抗菌聚酯纤维、棉纤维、麻纤维按重量比经混纺工艺加工后,利用针织机编织,制得亲肤抗菌里层;
(3)将步骤(2)制得的亲肤抗菌里层与竹纤维层进行粘结,再将步骤(1)制得的弹性表层粘结在竹纤维层上,制得面料坯体;
(4)将步骤(3)制得的面料坯体在整理液中浸扎处理3h,取出后烘干,得到面料本体;将纳米薄膜材料溶解在溶剂中,利用喷涂机由上往下匀速喷涂在面料本体上,经烘烤、冷却后,制得防水透气弹力面料。
上述亲肤抗菌里层的厚度为0.25mm;弹性表层的厚度为0.45mm;竹纤维层的厚度为0.1mm;防水透气层的厚度为0.15mm。
实施例3
一种防水透气弹力面料及其制备方法
与实施例1的区别为:
弹性表层包括重量占比为的50%的莫代尔纤维、25%的海藻炭纤维和25%的MS舒弹纤维。亲肤抗菌里层包括重量占比为35%抗菌聚酯纤维、45%的棉纤维和20%的麻纤维。弹性表层和亲肤抗菌里层通过竹纤维层粘结连接,竹纤维层中的竹纤维的长度为60mm,细度为1.5dtex。纳米薄膜材料的粒径为50nm~300nm。纳米薄膜材料按重量份计,包括以下组分纳米薄膜材料按重量份计,包括以下组分:55kg聚偏四氟乙烯、20kg聚偏四氟乙烯、5kg硬脂酸镁、1.5kg紫外线吸收剂、助剂3kg。
纳米薄膜材料的制备方法包括以下步骤:将上述重量份的聚偏四氟乙烯、硬脂酸镁、紫外线吸收剂、助剂混合,在670℃下搅拌5h,超声处理2h,送入双螺杆挤出机熔融、混炼、挤出、冷却、切粒、干燥、粉碎、研磨后制得纳米薄膜材料。
上述防水透气弹力面料的制备方法,包括以下步骤:
(1)将莫代尔纤维、海藻炭纤维、MS舒弹纤维按重量比经混纺工艺加工后,利用针织机编织,制得弹性表层;
(2)将抗菌聚酯纤维、棉纤维、麻纤维按重量比经混纺工艺加工后,利用针织机编织,制得亲肤抗菌里层;
(3)将步骤(2)制得的亲肤抗菌里层与竹纤维层进行粘结,再将步骤(1)制得的弹性表层粘结在竹纤维层上,制得面料坯体;
(4)将步骤(3)制得的面料坯体在整理液中浸扎处理4h,取出后烘干,得到面料本体;将纳米薄膜材料溶解在溶剂中,利用喷涂机由上往下匀速喷涂在面料本体上,经烘烤、冷却后,制得防水透气弹力面料。
上述亲肤抗菌里层的厚度为0.3mm;弹性表层的厚度为0.5mm;竹纤维层的厚度为0.2mm;防水透气层的厚度为0.2mm。
实施例4
一种防水透气弹力面料及其制备方法
与实施例1的区别为:
弹性表层包括重量占比为的55%的莫代尔纤维、20%的海藻炭纤维和25%的MS舒弹纤维。亲肤抗菌里层包括重量占比为35%抗菌聚酯纤维、45%的棉纤维和20%的麻纤维。弹性表层和亲肤抗菌里层通过竹纤维层粘结连接,竹纤维层中的竹纤维的长度为75mm,细度为1.55dtex。纳米薄膜材料的粒径为260nm。纳米薄膜材料按重量份计,包括以下组分:58kg聚偏四氟乙烯、28kg聚偏四氟乙烯、8kg硬脂酸镁、2.6kg紫外线吸收剂、助剂2.5kg。
纳米薄膜材料的制备方法包括以下步骤:将上述重量份的聚偏四氟乙烯、硬脂酸镁、紫外线吸收剂、助剂混合,在75℃下搅拌5h,超声处理2h,送入双螺杆挤出机熔融、混炼、挤出、冷却、切粒、干燥、粉碎、研磨后制得纳米薄膜材料。
上述防水透气弹力面料的制备方法,包括以下步骤:
(1)将莫代尔纤维、海藻炭纤维、MS舒弹纤维按重量比经混纺工艺加工后,利用针织机编织,制得弹性表层;
(2)将抗菌聚酯纤维、棉纤维、麻纤维按重量比经混纺工艺加工后,利用针织机编织,制得亲肤抗菌里层;
(3)将步骤(2)制得的亲肤抗菌里层与竹纤维层进行粘结,再将步骤(1)制得的弹性表层粘结在竹纤维层上,制得面料坯体;
(4)将步骤(3)制得的面料坯体在整理液中浸扎处理3.5h,取出后烘干,得到面料本体;将纳米薄膜材料溶解在溶剂中,利用喷涂机由上往下匀速喷涂在面料本体上,经烘烤、冷却后,制得防水透气弹力面料。
上述亲肤抗菌里层的厚度为0.35mm;弹性表层的厚度为0.5mm;竹纤维层的厚度为0.4mm;防水透气层的厚度为0.25mm。
实施例5
一种防水透气弹力面料及其制备方法
与实施例1的区别为:
弹性表层包括重量占比为的60%的莫代尔纤维、20%的海藻炭纤维和20%的MS舒弹纤维。亲肤抗菌里层包括重量占比为40%抗菌聚酯纤维、40%~55%的棉纤维和20%的麻纤维。弹性表层和亲肤抗菌里层通过竹纤维层粘结连接,竹纤维层中的竹纤维的长度为50mm~80mm,细度为1.65dtex。纳米薄膜材料的粒径为300nm。纳米薄膜材料按重量份计,包括以下组分:60kg聚偏四氟乙烯、30kg聚偏四氟乙烯、10kg硬脂酸镁、3kg紫外线吸收剂、助剂3kg。
纳米薄膜材料的制备方法包括以下步骤:将上述重量份的聚偏四氟乙烯、硬脂酸镁、紫外线吸收剂、助剂混合,在80℃下搅拌6h,超声处理2h,送入双螺杆挤出机熔融、混炼、挤出、冷却、切粒、干燥、粉碎、研磨后制得纳米薄膜材料。
上述防水透气弹力面料的制备方法,包括以下步骤:
(1)将莫代尔纤维、海藻炭纤维、MS舒弹纤维按重量比经混纺工艺加工后,利用针织机编织,制得弹性表层;
(2)将抗菌聚酯纤维、棉纤维、麻纤维按重量比经混纺工艺加工后,利用针织机编织,制得亲肤抗菌里层;
(3)将步骤(2)制得的亲肤抗菌里层与竹纤维层进行粘结,再将步骤(1)制得的弹性表层粘结在竹纤维层上,制得面料坯体;
(4)将步骤(3)制得的面料坯体在整理液中浸扎处理4h,取出后烘干,得到面料本体;将纳米薄膜材料溶解在溶剂中,利用喷涂机由上往下匀速喷涂在面料本体上,经烘烤、冷却后,制得防水透气弹力面料。
上述亲肤抗菌里层的厚度为0.4mm;弹性表层的厚度为0.6mm;竹纤维层的厚度为0.05mm~0.5mm0.5mm;防水透气层的厚度为0.3mm。
试验例
为了确定本发明制备的防水透气弹力面料的性能,现对实施例1~5制备的防水透气弹力面料分别进行性能测试:
测试实施例1~5制备的防水透气弹力面料的抗菌性能、防水性能和透气性能。
(1)抗菌性能:按照GB/T20944.3-2008的方法和标准测定面料对大肠杆菌抑菌率;
(2)拒水性:按照AATCC22-2005的方法和标准检测面料的表面拒水性;
(3)透湿率[g/(m2·24h)]:按照GBT12704.1-2009的方法和标准检测面料的透湿率;
(4)透气量(m/s)×10-3:按照GBT5453-1997的方法和标准检测面料的透气量。
测试结果如表1所示。
表1
大肠杆菌抑菌率(%) | 拒水性 | 透湿率[g/(m<sup>2</sup>·24h)] | 透气量(m/s)×10<sup>-3</sup> | |
实施例1 | 99.69 | 4 | 3800 | 320 |
实施例2 | 99.99 | 4 | 3600 | 310 |
实施例3 | 99.85 | 4 | 3700 | 320 |
实施例4 | 99.99 | 4 | 3600 | 310 |
实施例5 | 99.36 | 4 | 3500 | 300 |
以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明实施例可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (10)
1.一种防水透气弹力面料,其特征在于,所述防水透气弹力面料由内到外包括面料本体和设置在面料本体上的防水透气层,所述面料本体包括亲肤抗菌里层和弹性表层,所述弹性表层位于亲肤抗菌里层的上方,所述弹性表层和亲肤抗菌里层通过竹纤维层连接;所述弹性表层上端表面设有防水透气层,所述防水透气层采用纳米粒子材料喷涂在面料本体弹性表层的上端表面。
2.根据权利要求1所述的防水透气弹力面料,其特征在于,所述弹性表层包括重量占比为的40%~60%的莫代尔纤维、20%~30%的海藻炭纤维和20%~30%的MS舒弹纤维。
3.根据权利要求1所述的防水透气弹力面料,其特征在于,所述亲肤抗菌里层包括重量占比为30%~40%抗菌聚酯纤维、40%~55%的棉纤维和5%~30%的麻纤维。
4.根据权利要求1所述的防水透气弹力面料,其特征在于,所述弹性表层和亲肤抗菌里层通过竹纤维层粘结连接,所述竹纤维层中的竹纤维的长度为50mm~80mm,细度为1.3dtex~1.65dtex。
5.根据权利要求1所述的防水透气弹力面料,其特征在于,所述亲肤抗菌里层和竹纤维层上开设有若干均匀分布间距恒定的微型孔洞,所述亲肤抗菌里层和竹纤维层上的微型孔洞位置交错设置。
6.根据权利要求1所述的防水透气弹力面料,其特征在于,所述防水透气层为防水透气纳米薄膜层,所述防水透气纳米薄膜层采用纳米薄膜材料均匀喷涂在弹性表层上端表面,所述纳米薄膜材料的粒径为50nm~300nm。
7.根据权利要求6所述的防水透气弹力面料,其特征在于,所述纳米薄膜材料按重量份计,包括以下组分:50份~60份聚偏四氟乙烯、10份~30份聚偏四氟乙烯、5份~10份硬脂酸镁、1份~3份紫外线吸收剂、助剂1份~3份。
8.根据权利要求7所述的防水透气弹力面料,其特征在于,所述纳米薄膜材料的制备方法包括以下步骤:将所述重量份的聚偏四氟乙烯、硬脂酸镁、紫外线吸收剂、助剂混合,在60℃~80℃下搅拌2h~6h,超声处理1h~2h,送入双螺杆挤出机熔融、混炼、挤出、冷却、切粒、干燥、粉碎、研磨后制得纳米薄膜材料。
9.根据权利要求1~8任意一项所述的防水透气弹力面料的制备方法,其特征在于,包括以下步骤:
(1)将莫代尔纤维、海藻炭纤维、MS舒弹纤维按重量比经混纺工艺加工后,利用针织机编织,制得弹性表层;
(2)将抗菌聚酯纤维、棉纤维、麻纤维按重量比经混纺工艺加工后,利用针织机编织,制得亲肤抗菌里层;
(3)将步骤(2)制得的亲肤抗菌里层与竹纤维层进行粘结,再将步骤(1)制得的弹性表层粘结在竹纤维层上,制得面料坯体;
(4)将步骤(3)制得的面料坯体在整理液中浸扎处理2h~4h,取出后烘干,得到面料本体;将纳米薄膜材料溶解在溶剂中,利用喷涂机由上往下匀速喷涂在面料本体上,经烘烤、冷却后,制得防水透气弹力面料。
10.根据权利要求9所述的防水透气弹力面料的制备方法,其特征在于,所述亲肤抗菌里层的厚度为0.2mm~0.4mm;弹性表层的厚度为0.4mm~0.6mm;竹纤维层的厚度为0.05mm~0.5mm;防水透气层的厚度为0.1mm~0.3mm。
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