CN113636867A - 一种棕色釉超耐热陶瓷煲 - Google Patents
一种棕色釉超耐热陶瓷煲 Download PDFInfo
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- 239000000919 ceramic Substances 0.000 title claims abstract description 28
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 42
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 42
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 32
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910052642 spodumene Inorganic materials 0.000 claims abstract description 28
- -1 silicon dioxide modified acrylate Chemical class 0.000 claims abstract description 26
- 239000004575 stone Substances 0.000 claims abstract description 22
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 21
- 239000010453 quartz Substances 0.000 claims abstract description 21
- 239000000440 bentonite Substances 0.000 claims abstract description 20
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 20
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 20
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 18
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 17
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 17
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims abstract description 17
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 17
- 229910001634 calcium fluoride Inorganic materials 0.000 claims abstract description 17
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052637 diopside Inorganic materials 0.000 claims abstract description 17
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims abstract description 17
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910000018 strontium carbonate Inorganic materials 0.000 claims abstract description 17
- 238000010304 firing Methods 0.000 claims abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 11
- 230000000996 additive effect Effects 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims description 11
- 241000251468 Actinopterygii Species 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 4
- 229910000271 hectorite Inorganic materials 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 229910052573 porcelain Inorganic materials 0.000 claims description 3
- 229910000906 Bronze Inorganic materials 0.000 abstract description 2
- 239000010974 bronze Substances 0.000 abstract description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical group [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000011521 glass Substances 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract description 2
- 238000005245 sintering Methods 0.000 abstract description 2
- 239000002932 luster Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 8
- 239000002585 base Substances 0.000 description 7
- 239000003513 alkali Substances 0.000 description 6
- 229920005610 lignin Polymers 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- 238000000498 ball milling Methods 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000002002 slurry Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000010411 cooking Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229940094522 laponite Drugs 0.000 description 2
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
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Abstract
本发明涉及陶瓷制品制备领域，具体涉及一种棕色釉超耐热陶瓷煲，包括陶瓷煲坯体和棕色釉基料，所述棕色釉基料由石英、锂辉石、纳米二氧化硅改性丙烯酸酯、木鱼石粉、膨润土、硅酸锆、硅酸锆、三氧化二钇、碳酸锶、碳酸钡、透辉石、氟化钙、高岭土、锂瓷石、改性添加剂烧制而成。本发明可使陶瓷胚体在高温烧成时形成一种高温玻璃相，不仅能促进烧结，还能提高所得工艺品的断裂韧性、耐热性能和耐候性能，所得工艺品釉层外表呈现古铜色，色泽均匀，光泽度佳。
Description
技术领域
本发明涉及陶瓷制品制备领域，具体涉及一种棕色釉超耐热陶瓷煲。
背景技术
陶瓷煲作为烹饪炊具已有数千年的悠久历史，其以制造容易、造价低廉和安全卫生的优点，深受人们的喜爱。目前，传统的陶瓷煲普遍仅适宜煮、炖、蒸等烹调方式，这些烹调方式在大量汤汁水份的保护下，锅具受热较为均匀，温差变换小，因而对锅具的热性能要求相对要宽松一些，如果需要采用煎、炒、炸等高温、急火、温差大的加热方式，现有的陶瓷烹调器极易发生炸裂。
发明内容
为解决上述问题，本发明提供了一种棕色釉超耐热陶瓷煲，且具有优良的耐热性能。
为实现上述目的，本发明采取的技术方案为：
一种棕色釉超耐热陶瓷煲，包括陶瓷煲坯体和棕色釉基料，所述棕色釉基料由石英、锂辉石、纳米二氧化硅改性丙烯酸酯、木鱼石粉、膨润土、硅酸锆、三氧化二钇、改性脂环胺固化剂烧制而成。
进一步地，所述棕色釉基料由以下重量份的原料烧制而成：
石英10份、锂辉石50份、纳米二氧化硅改性丙烯酸酯5份、木鱼石粉3份、膨润土15份、硅酸锆5份、硅酸锆1份、三氧化二钇1份、碳酸锶4份、碳酸钡4份、透辉石1.5份、氟化钙2份、高岭土7份、锂瓷石5.5份、改性添加剂1份。
进一步地，所述棕色釉基料由以下重量份的原料烧制而成：
石英15份、锂辉石60份、纳米二氧化硅改性丙烯酸酯10份、木鱼石粉5份、膨润土20份、硅酸锆10份、硅酸锆1份、三氧化二钇3份、碳酸锶4份、碳酸钡4份、透辉石2.5份、氟化钙4份、高岭土9份、锂瓷石7.5份、改性添加剂1份。
进一步地，所述棕色釉基料由以下重量份的原料烧制而成：
石英12.5份、锂辉石55份、纳米二氧化硅改性丙烯酸酯7.5份、木鱼石粉4份、膨润土17.5份、硅酸锆7.5份、硅酸锆1份、三氧化二钇2份、碳酸锶4份、碳酸钡4份、透辉石3.5份、氟化钙3份、高岭土8份、锂瓷石6.5份、改性添加剂1份。
进一步地，所述棕色釉基料由以下重量份的原料烧制而成：
石英12份、锂辉石55份、纳米二氧化硅改性丙烯酸酯7份、木鱼石粉4份、膨润土17份、硅酸锆7份、硅酸锆1份、三氧化二钇2份、碳酸锶4份、碳酸钡4份、透辉石3份、氟化钙3份、高岭土8份、锂瓷石6份、改性添加剂1份。
进一步地，所述棕色釉基料由以下重量份的原料烧制而成：
石英13份、锂辉石55份、纳米二氧化硅改性丙烯酸酯7.5份、木鱼石粉4份、膨润土17.5份、硅酸锆7.5份、硅酸锆1份、三氧化二钇2份、碳酸锶4份、碳酸钡4份、透辉石3.5份、氟化钙3份、高岭土8份、锂瓷石7份、改性添加剂1份。
本发明具有以下有益效果：
可使陶瓷胚体在高温烧成时形成一种高温玻璃相，不仅能促进烧结，还能提高所得工艺品的断裂韧性、耐热性能和耐候性能，所得工艺品釉层外表呈现古铜色，色泽均匀，光泽度佳。
具体实施方式
为了使本发明的目的及优点更加清楚明白，以下结合实施例对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
实施例1
一种棕色釉超耐热陶瓷煲，通过以下方法制备所得：
S1、将硅藻泥30份、石英20份、氧化铝15份、滑石粉10份、Y2O3 1份混合后，以混合料：球：水重量比为1 ：1.5 ：0.8装入球磨设备，球磨20小时，待料浆陈腐24小时后，过200目筛，得泥浆；
S2、将泥浆与3份改性脂环胺固化剂混合搅拌均匀后，注入模具，20min 后脱模，取出坯体，烘干、修坯上水，得陶瓷泥坯体；
S3、按重量份称取：石英10份、锂辉石50份、纳米二氧化硅改性丙烯酸酯5份、木鱼石粉3份、膨润土15份、硅酸锆5份、硅酸锆1份、三氧化二钇1份、碳酸锶4份、碳酸钡4份、透辉石1.5份、氟化钙2份、高岭土7份、锂瓷石5.5份、改性磺化碱木素1份；
S4、将称取的石英、锂辉石、纳米二氧化硅改性丙烯酸酯、木鱼石粉、膨润土、硅酸锆、硅酸锆、三氧化二钇、碳酸锶、碳酸钡、透辉石、氟化钙、高岭土、锂瓷石、改性磺化碱木素混合后，以混合料：球：水重量比为1 ：1.5 ：0.8装入球磨设备，球磨30小时，过200目筛，收集备用；
S5、将称取的纳米二氧化硅改性丙烯酸酯、改性脂环胺固化剂与磨机研磨的釉料进行搅拌混合，混合温度200-300℃，自然冷却后加入物料总量的80-90％的水，继续搅拌混合，即制得棕色釉；
S6、将制备好的陶瓷煲坯体浸入所述的棕色釉中5-10s，捞出，干燥至施釉釉面的含水率低于10％；
S7、将干燥后的陶瓷煲坯体放入煅烧炉中进行煅烧，煅烧升温至1100-1300℃，煅烧7-8h，保温10-20min，煅烧完成后自然冷却，即制得该棕色釉耐热陶瓷煲。
实施例2
S3、按重量份称取：石英15份、锂辉石60份、纳米二氧化硅改性丙烯酸酯10份、木鱼石粉5份、膨润土20份、硅酸锆10份、硅酸锆1份、三氧化二钇3份、碳酸锶4份、碳酸钡4份、透辉石2.5份、氟化钙4份、高岭土9份、锂瓷石7.5份、改性磺化碱木素1份；
其余同实施例1。
实施例3
S3、按重量份称取：石英12.5份、锂辉石55份、纳米二氧化硅改性丙烯酸酯7.5份、木鱼石粉4份、膨润土17.5份、硅酸锆7.5份、硅酸锆1份、三氧化二钇2份、碳酸锶4份、碳酸钡4份、透辉石3.5份、氟化钙3份、高岭土8份、锂瓷石6.5份、改性磺化碱木素1份；
其余同实施例1。
实施例4
S3、按重量份称取：石英12份、锂辉石55份、纳米二氧化硅改性丙烯酸酯7份、木鱼石粉4份、膨润土17份、硅酸锆7份、硅酸锆1份、三氧化二钇2份、碳酸锶4份、碳酸钡4份、透辉石3份、氟化钙3份、高岭土8份、锂瓷石6份、改性磺化碱木素1份；
其余同实施例1。
实施例5
S3、按重量份称取：石英13份、锂辉石55份、纳米二氧化硅改性丙烯酸酯7.5份、木鱼石粉4份、膨润土17.5份、硅酸锆7.5份、硅酸锆1份、三氧化二钇2份、碳酸锶4份、碳酸钡4份、透辉石3.5份、氟化钙3份、高岭土8份、锂瓷石7份、改性磺化碱木素1份；
其余同实施例1。
实施例6
S3、按重量份称取：石英13份、锂辉石25份、纳米二氧化硅改性丙烯酸酯8份、木鱼石粉4份、膨润土18份、硅酸锆8份、三氧化二钇2份、改性脂环胺固化剂4份；
其余同实施例1。
实施例1-实施例6所得的棕色釉耐热陶瓷煲的性能检测结果为：耐热温度为1300-1550℃，在20-600℃之间热交换15次均未破裂。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以作出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。
Claims (6)
1.一种棕色釉超耐热陶瓷煲，包括陶瓷煲坯体和棕色釉基料，其特征在于，所述棕色釉基料由石英、锂辉石、纳米二氧化硅改性丙烯酸酯、木鱼石粉、膨润土、硅酸锆、三氧化二钇、改性脂环胺固化剂烧制而成。
2.如权利要求1所述的一种棕色釉超耐热陶瓷煲，其特征在于，所述棕色釉基料由以下重量份的原料烧制而成：石英10份、锂辉石50份、纳米二氧化硅改性丙烯酸酯5份、木鱼石粉3份、膨润土15份、硅酸锆5份、硅酸锆1份、三氧化二钇1份、碳酸锶4份、碳酸钡4份、透辉石1.5份、氟化钙2份、高岭土7份、锂瓷石5.5份、改性添加剂1份。
3.如权利要求1所述的一种棕色釉超耐热陶瓷煲，其特征在于，所述棕色釉基料由以下重量份的原料烧制而成：石英15份、锂辉石60份、纳米二氧化硅改性丙烯酸酯10份、木鱼石粉5份、膨润土20份、硅酸锆10份、硅酸锆1份、三氧化二钇3份、碳酸锶4份、碳酸钡4份、透辉石2.5份、氟化钙4份、高岭土9份、锂瓷石7.5份、改性添加剂1份。
4.如权利要求1所述的一种棕色釉超耐热陶瓷煲，其特征在于，所述棕色釉基料由以下重量份的原料烧制而成：石英12.5份、锂辉石55份、纳米二氧化硅改性丙烯酸酯7.5份、木鱼石粉4份、膨润土17.5份、硅酸锆7.5份、硅酸锆1份、三氧化二钇2份、碳酸锶4份、碳酸钡4份、透辉石3.5份、氟化钙3份、高岭土8份、锂瓷石6.5份、改性添加剂1份。
5.如权利要求1所述的一种棕色釉超耐热陶瓷煲，其特征在于，所述棕色釉基料由以下重量份的原料烧制而成：石英12份、锂辉石55份、纳米二氧化硅改性丙烯酸酯7份、木鱼石粉4份、膨润土17份、硅酸锆7份、硅酸锆1份、三氧化二钇2份、碳酸锶4份、碳酸钡4份、透辉石3份、氟化钙3份、高岭土8份、锂瓷石6份、改性添加剂1份。
6.如权利要求1所述的一种棕色釉超耐热陶瓷煲，其特征在于，所述棕色釉基料由以下重量份的原料烧制而成：石英13份、锂辉石55份、纳米二氧化硅改性丙烯酸酯7.5份、木鱼石粉4份、膨润土17.5份、硅酸锆7.5份、硅酸锆1份、三氧化二钇2份、碳酸锶4份、碳酸钡4份、透辉石3.5份、氟化钙3份、高岭土8份、锂瓷石7份、改性添加剂1份。
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