CN113576947A - Organic silicon shampoo and preparation method thereof - Google Patents
Organic silicon shampoo and preparation method thereof Download PDFInfo
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- CN113576947A CN113576947A CN202010707605.XA CN202010707605A CN113576947A CN 113576947 A CN113576947 A CN 113576947A CN 202010707605 A CN202010707605 A CN 202010707605A CN 113576947 A CN113576947 A CN 113576947A
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- shampoo
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- organic silicon
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- 239000002453 shampoo Substances 0.000 title claims abstract description 55
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 50
- 239000010703 silicon Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 238000003756 stirring Methods 0.000 claims abstract description 91
- 239000002994 raw material Substances 0.000 claims abstract description 49
- 239000011159 matrix material Substances 0.000 claims abstract description 27
- 239000000284 extract Substances 0.000 claims abstract description 26
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 238000001816 cooling Methods 0.000 claims abstract description 20
- 208000003251 Pruritus Diseases 0.000 claims abstract description 19
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 19
- 230000003266 anti-allergic effect Effects 0.000 claims abstract description 18
- 230000007803 itching Effects 0.000 claims abstract description 18
- 229930014626 natural product Natural products 0.000 claims abstract description 18
- 229940046000 sodium isostearoyl lactylate Drugs 0.000 claims abstract description 16
- FOSNFLMXYRQNAF-UHFFFAOYSA-M sodium;2-[2-(16-methylheptadecanoyloxy)propanoyloxy]propanoate Chemical compound [Na+].CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C([O-])=O FOSNFLMXYRQNAF-UHFFFAOYSA-M 0.000 claims abstract description 16
- 229940049292 n-(3-(dimethylamino)propyl)octadecanamide Drugs 0.000 claims abstract description 15
- WWVIUVHFPSALDO-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C WWVIUVHFPSALDO-UHFFFAOYSA-N 0.000 claims abstract description 15
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 12
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 12
- 229920002907 Guar gum Polymers 0.000 claims abstract description 5
- 239000000665 guar gum Substances 0.000 claims abstract description 5
- 229960002154 guar gum Drugs 0.000 claims abstract description 5
- 235000010417 guar gum Nutrition 0.000 claims abstract description 5
- 229940104256 sodium taurate Drugs 0.000 claims abstract description 5
- GWLWWNLFFNJPDP-UHFFFAOYSA-M sodium;2-aminoethanesulfonate Chemical compound [Na+].NCCS([O-])(=O)=O GWLWWNLFFNJPDP-UHFFFAOYSA-M 0.000 claims abstract description 5
- 239000011259 mixed solution Substances 0.000 claims description 52
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 42
- 239000011734 sodium Substances 0.000 claims description 32
- 229910052708 sodium Inorganic materials 0.000 claims description 32
- BTMZHHCFEOXAAN-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;2-dodecylbenzenesulfonic acid Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O BTMZHHCFEOXAAN-UHFFFAOYSA-N 0.000 claims description 30
- 229940105956 tea-dodecylbenzenesulfonate Drugs 0.000 claims description 30
- 238000005303 weighing Methods 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- 239000000419 plant extract Substances 0.000 claims description 26
- 125000002091 cationic group Chemical group 0.000 claims description 23
- 239000001913 cellulose Substances 0.000 claims description 23
- 229920002678 cellulose Polymers 0.000 claims description 23
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 21
- 244000303965 Cyamopsis psoralioides Species 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 20
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 13
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 13
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 13
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 13
- 229940100608 glycol distearate Drugs 0.000 claims description 13
- 239000003755 preservative agent Substances 0.000 claims description 10
- 230000002335 preservative effect Effects 0.000 claims description 10
- 229920000289 Polyquaternium Polymers 0.000 claims description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- 241000208680 Hamamelis mollis Species 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- 235000008524 evening primrose extract Nutrition 0.000 claims description 5
- 239000010475 evening primrose oil Substances 0.000 claims description 5
- 229940089020 evening primrose oil Drugs 0.000 claims description 5
- 229940118846 witch hazel Drugs 0.000 claims description 5
- AJBZENLMTKDAEK-UHFFFAOYSA-N 3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-1,2,3,4,5,6,7,7a,9,10,11,11b,12,13,13a,13b-hexadecahydrocyclopenta[a]chrysene-4,9-diol Chemical compound CC12CCC(O)C(C)(C)C1CCC(C1(C)CC3O)(C)C2CCC1C1C3(C)CCC1C(=C)C AJBZENLMTKDAEK-UHFFFAOYSA-N 0.000 claims description 4
- 235000003880 Calendula Nutrition 0.000 claims description 4
- 240000001432 Calendula officinalis Species 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 229940064064 purslane extract Drugs 0.000 claims description 4
- 229920000136 polysorbate Polymers 0.000 claims description 2
- 229950008882 polysorbate Drugs 0.000 claims description 2
- NRWCNEBHECBWRJ-UHFFFAOYSA-M trimethyl(propyl)azanium;chloride Chemical compound [Cl-].CCC[N+](C)(C)C NRWCNEBHECBWRJ-UHFFFAOYSA-M 0.000 claims 1
- 229920002545 silicone oil Polymers 0.000 abstract description 21
- 239000000839 emulsion Substances 0.000 abstract description 17
- 210000004761 scalp Anatomy 0.000 abstract description 17
- 239000002131 composite material Substances 0.000 abstract description 13
- 230000009286 beneficial effect Effects 0.000 abstract description 6
- 230000002209 hydrophobic effect Effects 0.000 abstract description 4
- 229940095673 shampoo product Drugs 0.000 abstract description 4
- 238000009825 accumulation Methods 0.000 abstract description 3
- 239000002105 nanoparticle Substances 0.000 abstract description 3
- 239000007908 nanoemulsion Substances 0.000 abstract 1
- 239000011343 solid material Substances 0.000 abstract 1
- -1 polydimethylsiloxane Polymers 0.000 description 29
- 230000000694 effects Effects 0.000 description 18
- 238000005406 washing Methods 0.000 description 15
- 239000004205 dimethyl polysiloxane Substances 0.000 description 11
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 11
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 11
- 229940048109 sodium methyl cocoyl taurate Drugs 0.000 description 11
- 239000000377 silicon dioxide Substances 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 229940057950 sodium laureth sulfate Drugs 0.000 description 10
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000004519 grease Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 229940094506 lauryl betaine Drugs 0.000 description 7
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 7
- 230000003648 hair appearance Effects 0.000 description 6
- 206010016807 Fluid retention Diseases 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 230000007794 irritation Effects 0.000 description 5
- 230000003020 moisturizing effect Effects 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 3
- 150000003863 ammonium salts Chemical group 0.000 description 3
- 239000002216 antistatic agent Substances 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 230000000638 stimulation Effects 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000001139 anti-pruritic effect Effects 0.000 description 2
- 239000003908 antipruritic agent Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 230000003766 combability Effects 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000005556 hormone Substances 0.000 description 2
- 229940088597 hormone Drugs 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000036619 pore blockages Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 244000234609 Portulaca oleracea Species 0.000 description 1
- 235000001855 Portulaca oleracea Nutrition 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229940002386 calendula officinalis extract Drugs 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000006694 eating habits Nutrition 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- IZWSFJTYBVKZNK-UHFFFAOYSA-N lauryl sulfobetaine Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS([O-])(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-N 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 210000004877 mucosa Anatomy 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229940068977 polysorbate 20 Drugs 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- PYNUOAIJIQGACY-UHFFFAOYSA-N propylazanium;chloride Chemical compound Cl.CCCN PYNUOAIJIQGACY-UHFFFAOYSA-N 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- KKDONKAYVYTWGY-UHFFFAOYSA-M sodium;2-(methylamino)ethanesulfonate Chemical compound [Na+].CNCCS([O-])(=O)=O KKDONKAYVYTWGY-UHFFFAOYSA-M 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
- A61P17/04—Antipruritics
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P37/00—Drugs for immunological or allergic disorders
- A61P37/08—Antiallergic agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/21—Emulsions characterized by droplet sizes below 1 micron
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Abstract
The invention discloses an organic silicon shampoo and a preparation method thereof, wherein the organic silicon shampoo contains a dimethiconol emulsion with a nano particle size, a composite natural product antiallergic itching relieving extract, methyl cocoyl sodium taurate, cocoamide methyl MEA (methyl MEA), ethylene glycol distearate, sodium isostearoyl lactylate, stearamidopropyl dimethylamine, guar gum hydroxypropyl trimethyl ammonium chloride, cocoamidopropyl betaine and other matrix components. The preparation method comprises the steps of dispersing, mixing and stirring the solid materials uniformly, keeping the mixture at a medium and high temperature for a certain time, cooling, adding the mixture at a low temperature, and mixing the mixture uniformly. The silicone shampoo related to the technical scheme of the invention selects the dimethiconol nano-emulsion as the main raw material, increases the hydrophilicity of the silicone oil, solves the problem that the hydrophobic silicone oil in the existing shampoo product is accumulated on the scalp, and achieves the beneficial effect of low accumulation of the nano-silicone oil emulsion.
Description
Technical Field
The invention belongs to the technical field of cosmetics, and particularly relates to an organic silicon shampoo and a preparation method thereof.
Background
Modern researches have shown that the cuticle of hair, which is composed of scales, plays a role in protection, and the inside is a hydrophilic lipid layer with the purpose of keeping moisture and elasticity of hair. However, the cuticle is very fragile, and the main purpose is to remove excessive dust and grease in the ordinary hair washing process, but the anionic surfactant in the hair washing water easily causes the hair scales to lift, so that the hair is rough and easy to agglomerate, and the hair scales are further damaged due to the increase of friction force during combing, so that a mild and low-irritation washing and protecting product is always sought as an important subject. Along with the continuous improvement of the living standard of people in recent years, the demand of low-stimulation hair washing, nourishing and protecting products is increasing, and the demand is higher and higher.
In the early days, people combed hair with vegetable oils, using the lubricating effect of grease, thereby reducing the damage generated when combing hair. At present, silicone oil has the best softening effect on hair, and cannot be perfectly replaced by other types of grease, and the organic silicon compounds which are generally used in hair washing and caring products on the market mainly comprise polydimethylsiloxane, amino-terminated polydimethylsiloxane and dimethiconol. However, because silicone oil is insoluble in water and is easy to remain on the scalp, and if personal hygiene is not well cleaned, living and eating habits are irregular, so that the hormone level of a body is disordered, excessive accumulation of sebum is likely to be caused, pores are easy to block over time, and a mild hair washing and nourishing product needs to be developed.
Disclosure of Invention
The invention aims to provide an organosilicon shampoo which takes a dimethiconol emulsion with a nano particle size as a main raw material and has the effects of mildly nourishing and protecting hair, keeping the hair fluffy and soft, being convenient to comb and being not easy to break.
The invention also aims to provide a preparation method of the organic silicon shampoo.
An organic silicon shampoo is composed of the following raw materials: premix components, silicone phase components, plant extracts and other matrix components.
Further, the organic silicon shampoo is prepared from the following raw materials in parts by weight: 15-90 parts of a premixed component, 2.0-10 parts of an organic silicon phase component, 2.0-10 parts of a plant extract and 6.0-30 parts of other matrix components.
Further, the organosilicon shampoo comprises the premixed components in parts by weight as follows: 1.0-20.0 parts of methyl cocoyl sodium taurate, 1.0-10.0 parts of alpha-alkenyl sodium sulfonate, 1.0-20.0 parts of sodium lauryl polyether sulfate, 1.0-5.0 parts of cocoamidomethyl MEA, 1.0-5.0 parts of glycol distearate, 1.0-5.0 parts of sodium isostearoyl lactylate, 1.0-5.0 parts of stearamidopropyl dimethylamine, 1.0-5.0 parts of guar gum hydroxypropyl trimethyl ammonium chloride, 1.0-5.0 parts of cationic cellulose and 5.0-25.0 parts of water.
Further, the organic silicon shampoo comprises the following raw materials in parts by weight: 2.0-10.0 parts of dimethiconol (and) triethanolamine dodecylbenzene sulfonate.
Furthermore, the organic silicon component comprises the following raw materials in parts by weight: 10-100 nm of dimethiconol (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY101) 1.0-5.0 parts and 100-500 nm of dimethiconol (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY102) 1.0-5.0 parts.
Further, the other matrix components of the organic silicon shampoo are prepared from the following raw materials in parts by weight: 1.0-5.0 parts of disodium ethylene diamine tetraacetate, 71.0-5.0 parts of polyquaternium, 1.0-20.0 parts of cocamidopropyl betaine, 0.1 part of preservative, 1.0 part of essence, 0.5 part of composite natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid and-201.0 parts of polysorbate.
Further, the plant extract of the organic silicon shampoo is prepared from the following raw materials in parts by weight: 1.0-5 parts of calendula extract, 1.0-5 parts of purslane extract, 0.5-1.2 parts of evening primrose oil and 1.0-2.5 parts of witch hazel extract.
A preparation method of an organic silicon shampoo comprises the following steps:
s1: weighing raw materials in the premixed components according to a proportion, dispersing the guar hydroxypropyl trimethyl ammonium chloride and the cationic cellulose in a proper amount of water completely in advance, adding the mixture, mixing and stirring, heating to 70-80 ℃, starting the stirring speed to 20-30 RPM, and fully stirring for 10-30 min to form a uniform mixed solution;
s2: weighing raw materials of the organic silicon phase component according to a proportion, adding the mixed solution in S1, continuously heating to 80-95 ℃, reducing the stirring speed to 10-20 RPM, fully stirring and dissolving the mixture, and keeping the temperature for 20-40 min;
s3: and continuously stirring and cooling to 30-45 ℃, weighing the raw materials in other matrix components according to a ratio, sequentially stirring and adding, uniformly stirring, cooling to room temperature, sequentially adding the plant extract, and uniformly stirring to obtain the organic silicon shampoo, wherein the weight ratio of the premixed component to the organic silicon phase component to the plant extract to the other matrix components is (15-90): (2.0-10): (2.0-10): (6.0-30).
The invention has the beneficial effects that:
a large number of experiments show that the added nano polydimethylsiloxane alcohol emulsion can effectively improve the hair quality, increase the water retention of the hair, improve the combing performance, reduce the silicone oil deposition risk of the scalp and improve the glossiness of the hair. The invention provides an organosilicon shampoo and a preparation method thereof, wherein no hormone component is added in the raw materials, the irritation to scalp and hair is low, the organosilicon shampoo is suitable for wide crowds, the nanometer silicone oil emulsion is selected as the main raw material, the hydrophilicity of the silicone oil is utilized, the nanometer silicone oil emulsion can be effectively attached to the hydrophilic layer of the hair, damaged hair scales are smoothed, the moisturizing effect is achieved, the problem that hydrophobic silicone oil in the existing shampoo product is gathered on the scalp is solved, the beneficial effect that the nanometer silicone oil emulsion is low in aggregation on the scalp is achieved, the pore blocking risk is further reduced, and meanwhile, the effects of smooth hair quality, full gloss, good combing performance and difficulty in breaking are brought; and a protective film can be formed by utilizing the sealing property of the grease to keep the stable moisture content in the hair, thereby achieving the effects of nourishing and protecting the hair. The used components have safe sources and low stimulation, and the functions of part of the raw materials in the invention are explained as follows:
(1) sodium methyl cocoyl taurate. The cleaning agent is prepared by condensing natural fatty acid and sodium methyl taurate, is an amino acid surfactant, has good cleaning power and small irritation, and is a component which can be used safely. The shampoo provided by the invention can provide good cleaning power, and has low irritation to the scalp and is mild. Can impart moisturizing and refreshing effects to hair.
(2) Cocamide methyl MEA. Is a nonionic surfactant, and shows excellent thickening, foaming and foam stabilizing performances in a system. Meanwhile, the cleaning agent has good wetting, decontaminating and deoiling performances.
(3) Sodium isostearoyl lactylate. The water retention agent has good moisture retention effect, has oleophylic and hydrophilic characteristics, has good affinity to skin and hair by ester groups and lactyl groups in the structure, slows down the loss speed of surface moisture, and achieves the water retention effect.
(4) Stearamidopropyl dimethylamine. The hair conditioner is used as a conditioning agent and an antistatic agent in a system, so that the hair is bright and soft, and the dry and wet combing performance of the hair is improved.
(5) Guar hydroxypropyl trimonium chloride. The antistatic agent is used as an antistatic agent in a system, can effectively improve combing property, has excellent conditioning performance and improves the adhesive capacity of effective substances.
(6) Cocamidopropyl betaine. The soft conditioning agent has excellent foamability, obvious thickening property and lower irritation in a system, can obviously improve the stability of products, and has good hard water resistance, antistatic property and biodegradability.
(7) Dimethiconol. In the system, the hair conditioner is used as a softening agent and a hair conditioner, and can increase smoothness of hair without greasy feeling and give gloss. The nanometer particle size can effectively improve the wet cleaning and dry combing performance and can keep smooth feeling and luster for a long time. The composition is nontoxic and has no irritation to skin and mucosa.
(8) An antiallergic and antipruritic extractive solution is prepared from natural products. The natural plant biological compound conditioner is used as a conditioner in the system, and the natural plant biological compound is used as a conditioner, and plays a role in diminishing inflammation, sterilizing, improving microbial flora growth environment, relieving skin and relieving, relieving itching, reducing the secretion speed of grease in the scalp, improving local micro-environment of hair, and further achieving an effect of taking root and fixing hair.
Compared with the existing shampoo products, the invention has the following beneficial effects:
(1) the nanometer-sized dimethiconol emulsion can effectively improve the hair quality, increase the water retention of the hair, improve the combability and improve the glossiness of the hair.
(2) The compound natural product antiallergic itching relieving extract is utilized to reduce the sensitivity of the scalp to external stimulation and effectively control the problems of scalp itching and the like; meanwhile, the dimethiconol is attached to the surface of the hair, so that the damaged hair scales are effectively repaired, a layer of protective film is formed, the moisture in the hair is stably kept, the combing property of the hair is effectively improved, and the effects of hair nourishing and protecting are achieved.
(3) The invention uses the polydimethylsiloxane-siloxane alcohol which is an organic silicon compound with changed structure, utilizes the nanotechnology to form a nano-scale organic silicon emulsion product with small colloidal particles under the shearing action, and the nano-silicone oil emulsion increases the hydrophilicity of silicone oil, so that the nano-silicone oil emulsion can be attached to a hydrophilic layer of hair, smooth damaged hair scales, play a role in moisturizing, solve the problem that hydrophobic silicone oil in the existing shampoo product is gathered on the scalp, achieve the beneficial effect of low accumulation of the nano-silicone oil emulsion on the scalp, further reduce the risk of pore blockage, and simultaneously bring the effects of smooth hair quality, full gloss, good combing property and difficult breakage; and a protective film can be formed by utilizing the sealing property of the grease to keep the stable moisture content in the hair, so that the hair care effect is achieved.
Detailed Description
The present invention is further illustrated by the following specific examples, which are not intended to limit the invention in any way. Reagents, methods and apparatus used in the present invention are conventional in the art unless otherwise indicated.
An organosilicon shampoo is prepared from sodium methyl cocoyl taurate, alpha-alkenyl sulfonate, sodium laureth sulfate, methyl MEA, glycol distearate, sodium isostearoyl lactylate, stearamidopropyl dimethylamine, guar hydroxypropyl trimethyl ammonium chloride, cationic cellulose, water, 10-100 nm of poly (dimethylsiloxy alcohol) (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY101), 100-500 nm of poly (dimethylsiloxy alcohol) (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY102), disodium ethylene diamine tetraacetate, polyquaternary ammonium salt-7, cocamidopropyl betaine, antiseptic, essence, composite natural product antiallergic and antipruritic extractive solution (trade name: HONY604), citric acid, polysorbate-20, calendula extract, citric acid, and/or sodium laureth sulfate, Purslane extract, evening primrose oil and witch hazel extract.
Further, the organic silicon shampoo comprises the following components in parts by weight: 1.0-20.0 parts of methyl cocoyl sodium taurate, 1.0-10.0 parts of alpha-alkenyl sodium sulfonate, 1.0-20.0 parts of sodium lauryl polyether sulfate, 1.0-5.0 parts of cocamide methyl MEA, 1.0-5.0 parts of glycol distearate, 1.0-5.0 parts of sodium isostearoyl lactylate, 1.0-5.0 parts of stearamidopropyl dimethylamine, 1.0-5.0 parts of guar hydroxypropyl trimethyl ammonium chloride, 1.0-5.0 parts of cationic cellulose, 5.0-25.0 parts of water, 1.0-5.0 parts of 10-100 nm polydimethylsiloxane (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY101), 1.0-5.0 parts of 100-500 nm polydimethylsiloxane (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY102), 1.0-5.0 parts of disodium ethylenediaminetetraacetate, 1.0-5.0 parts of polyquaternary ammonium salt, 0-5.0 parts of sodium alpha-alkenyl sulfonate, 1.0-1.0 part of sodium lauryl sulfobetaine, 1.0-5.0 parts of essence, 1.0-5 parts of betaine (trade name: HONY102), 1.0 parts of essence, 1.0 parts of sodium laurylpropyl betaine, 1.0-5 parts of sodium laurylpolyoxolate sodium laurylpolyamide, 0.5 part of composite natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid, 201.0 parts of polysorbate-201.0 parts, 1.0-5 parts of calendula extract, 1.0-5 parts of purslane extract, 0.5-1.2 parts of evening primrose oil and 1.0-2.5 parts of witch hazel extract.
Further, the organic silicon shampoo comprises the following components in parts by weight: 5.0 to 20.0 parts of methyl cocoyl sodium taurate, 3.0 to 10.0 parts of alpha-alkenyl sodium sulfonate, 5.0 to 20.0 parts of sodium lauryl polyether sulfate, 2.0 to 5.0 parts of cocamide methyl MEA, 1.0 to 4.0 parts of glycol distearate, 1.0 to 4.0 parts of sodium isostearoyl lactylate, 1.0 to 4.0 parts of stearamidopropyl dimethylamine, 1.0 to 4.0 parts of guar hydroxypropyl trimethyl ammonium chloride, 1.0 to 5.0 parts of cationic cellulose, 10.0 to 25.0 parts of water, 1.0 to 5.0 parts of 10 to 100 nanometers of poly dimethyl siloxane alcohol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY101), 1.0 to 5.0 parts of 100 to 500 nanometers of poly dimethyl siloxane alcohol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY102), 1.0 to 3.0 parts of disodium ethylenediamine tetraacetate, 3 to 3.0 parts of polyquaternary ammonium salt, 3.0 to 10.0 parts of sodium cocoyl sulfate, 1.0 to 10.0 parts of betaine propyl ammonium chloride, 1.0 to 4 parts of essence, 10 parts of sodium isostearyl alcohol, 1.0 to 4 parts of sodium isostearoyl lactylate, 1.0 to 5 parts of sodium isostearyl alcohol (sodium lauryl lactylate), 1.0 to 5 parts of sodium lauryl betaine (and 1.0 to 5 parts of sodium lauryl betaine, and 1.0 parts of sodium lauryl betaine (and 1.0 to 5 parts of sodium lauryl betaine) of sodium lauryl betaine (trade name: HONY101) and sodium lauryl betaine, and sodium lauryl betaine, 0.5 part of compound natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid, 201.0 parts of polysorbate-201.0 parts, 3 parts of calendula officinalis extract, 3 parts of purslane herb extract, 0.9 part of evening primrose oil and 1.7 parts of witch hazel extract.
According to the invention, 10-100 nm of poly (dimethylsiloxy alcohol) (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY101), 100-500 nm of poly (dimethylsiloxy alcohol) (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY102), sodium methyl cocoyl taurate, cocamidomethyl MEA (MeaMEA), cocamidopropyl betaine and the composite natural product antiallergic itching-relieving extract are reasonably compatible, so that the combing property of washed hair can be effectively improved, the moisturizing property of the hair can be improved, and damaged hair scales can be repaired. The hair washing agent can remove dust and redundant grease on hair and scalp in the hair washing process, can also solve the problem that the sheets of hair are warped due to the anionic surfactant in the hair washing water, and avoids a series of problems that the hair becomes coarse, the friction force is increased, the hair is easy to tangle and knot, the mutual friction is further aggravated to the damage of the scales of the hair in the combing process, and the like. (1) The nanometer-sized dimethiconol emulsion can effectively improve the hair quality, increase the water retention of the hair, improve the combability and improve the glossiness of the hair. (2) The compound natural product antiallergic itching relieving extract is utilized to reduce the sensitivity of the scalp to external stimulation and effectively control the problems of scalp itching and the like; meanwhile, the nano-scale dimethiconol effectively repairs damaged hair scales to form a layer of protective film, stably keeps moisture in hair, effectively improves the combing property of the hair, and achieves the effects of hair nourishing and hair care. Thereby enabling the surface of the hair to be smoother and bringing the effects of smooth, tough, easy to comb and glossy hair.
The present invention will be further described with reference to specific examples, but is not limited thereto.
Example 1
The preparation method of the organic silicon shampoo comprises the following steps of:
(1) weighing the premixed component raw materials according to the following weight parts: 18.0 parts of sodium methyl cocoyl taurate, 5.0 parts of alpha-sodium alkenyl sulfonate, 12.0 parts of sodium laureth sulfate, 5.0 parts of cocamide methyl MEA, 3.0 parts of glycol distearate, 4.0 parts of sodium isostearoyl lactylate, 2.0 parts of stearamidopropyl dimethylamine, 2.0 parts of guar hydroxypropyl trimethyl ammonium chloride, 2.0 parts of cationic cellulose and 24.1 parts of water; completely dispersing guar hydroxypropyl trimethyl ammonium chloride and cationic cellulose with a proper amount of water, adding, mixing and stirring, heating to 70-80 ℃, starting the stirring speed to 20-30 RPM, and fully stirring for 10-30 min to form a uniform mixed solution;
(2) weighing the organic silicon phase component raw materials according to the following weight parts: 10-100 nm of dimethiconol (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY101)1.0 parts and 100-500 nm of dimethiconol (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY102)1.0 parts; adding the mixed solution obtained in the step (1) into the mixed solution under stirring, continuously heating the mixed solution to 80-95 ℃, reducing the stirring speed to 10-20 RPM (revolutions per minute), fully stirring the mixed solution for dissolving, and keeping the temperature for 20-40 min;
(3) stirring the mixture, cooling to 30-45 ℃, and weighing other matrix component raw materials in parts by weight: 1.0 part of disodium ethylene diamine tetraacetate, 72.0 parts of polyquaternium, 15.0 parts of cocamidopropyl betaine, 0.1 part of preservative, 1.0 part of essence, 0.5 part of composite natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid and 201.0 parts of polysorbate-201.0; and (3) adding the mixed solution obtained in the step (2) under stirring, cooling to room temperature after uniformly stirring, and sequentially adding the plant extracts to obtain the shampoo. Wherein the weight ratio of the premixed component, the organic silicon phase component, the plant extract and other matrix components is 77.1: 2.0: 2.0: 20.9.
example 2
The preparation method of the organic silicon shampoo comprises the following steps of:
(1) weighing the premixed component raw materials according to the following weight parts: 18.0 parts of sodium methyl cocoyl taurate, 5.0 parts of alpha-sodium alkenyl sulfonate, 12.0 parts of sodium laureth sulfate, 5.0 parts of cocamide methyl MEA, 3.0 parts of glycol distearate, 4.0 parts of sodium isostearoyl lactylate, 2.0 parts of stearamidopropyl dimethylamine, 2.0 parts of guar hydroxypropyl trimethyl ammonium chloride, 2.0 parts of cationic cellulose and 23.1 parts of water; completely dispersing guar hydroxypropyl trimethyl ammonium chloride and cationic cellulose with a proper amount of water, adding, mixing and stirring, heating to 70-80 ℃, starting the stirring speed to 20-30 RPM, and fully stirring for 10-30 min to form a uniform mixed solution;
(2) weighing the organic silicon phase component raw materials according to the following weight parts: 2.0 parts of 10-100 nm poly dimethyl silica alkanol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY101) and 1.0 part of 100-500 nm poly dimethyl silica alkanol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY 102); adding the mixed solution obtained in the step (1) into the mixed solution under stirring, continuously heating the mixed solution to 80-95 ℃, reducing the stirring speed to 10-20 RPM (revolutions per minute), fully stirring the mixed solution for dissolving, and keeping the temperature for 20-40 min;
(3) stirring the mixture, cooling to 30-45 ℃, and weighing other matrix component raw materials in parts by weight: 1.0 part of disodium ethylene diamine tetraacetate, 72.0 parts of polyquaternium, 15.0 parts of cocamidopropyl betaine, 0.1 part of preservative, 1.0 part of essence, 0.5 part of composite natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid and 201.0 parts of polysorbate-201.0; and (3) adding the mixed solution obtained in the step (2) under stirring, cooling to room temperature after uniformly stirring, and sequentially adding the plant extracts to obtain the shampoo. Wherein the weight ratio of the premixed component, the organic silicon phase component, the plant extract and other matrix components is 76.1: 3.0: 3.0: 20.9.
example 3
The preparation method of the organic silicon shampoo comprises the following steps of:
(1) weighing the premixed component raw materials according to the following weight parts: 18.0 parts of sodium methyl cocoyl taurate, 5.0 parts of alpha-sodium alkenyl sulfonate, 12.0 parts of sodium laureth sulfate, 5.0 parts of cocamide methyl MEA, 3.0 parts of glycol distearate, 4.0 parts of sodium isostearoyl lactylate, 2.0 parts of stearamidopropyl dimethylamine, 2.0 parts of guar hydroxypropyl trimethyl ammonium chloride, 2.0 parts of cationic cellulose and 22.1 parts of water; completely dispersing guar hydroxypropyl trimethyl ammonium chloride and cationic cellulose with a proper amount of water, adding, mixing and stirring, heating to 70-80 ℃, starting the stirring speed to 20-30 RPM, and fully stirring for 10-30 min to form a uniform mixed solution;
(2) weighing the organic silicon phase component raw materials according to the following weight parts: 3.0 parts of 10-100 nm poly dimethyl silica alkanol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY101) and 1.0 part of 100-500 nm poly dimethyl silica alkanol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY 102); adding the mixed solution obtained in the step (1) into the mixed solution under stirring, continuously heating the mixed solution to 80-95 ℃, reducing the stirring speed to 10-20 RPM (revolutions per minute), fully stirring the mixed solution for dissolving, and keeping the temperature for 20-40 min;
(3) stirring the mixture, cooling to 30-45 ℃, and weighing other matrix component raw materials in parts by weight: 1.0 part of disodium ethylene diamine tetraacetate, 72.0 parts of polyquaternium, 15.0 parts of cocamidopropyl betaine, 0.1 part of preservative, 1.0 part of essence, 0.5 part of composite natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid and 201.0 parts of polysorbate-201.0; and (3) adding the mixed solution obtained in the step (1) under stirring, cooling to room temperature after uniformly stirring, and sequentially adding plant extracts to obtain the shampoo. Wherein the weight ratio of the premixed component, the organic silicon phase component, the plant extract and other matrix components is 75.1: 4.0: 4.0: 20.9.
example 4
The preparation method of the organic silicon shampoo comprises the following steps of:
(1) weighing the premixed component raw materials according to the following weight parts: 18.0 parts of sodium methyl cocoyl taurate, 5.0 parts of alpha-sodium alkenyl sulfonate, 12.0 parts of sodium laureth sulfate, 5.0 parts of cocamide methyl MEA, 3.0 parts of glycol distearate, 4.0 parts of sodium isostearoyl lactylate, 2.0 parts of stearamidopropyl dimethylamine, 2.0 parts of guar hydroxypropyl trimethyl ammonium chloride, 2.0 parts of cationic cellulose and 21.1 parts of water; completely dispersing the guar hydroxypropyl trimethyl ammonium chloride and the cationic cellulose in a proper amount of water, adding the mixture, mixing and stirring, heating to 70-80 ℃, starting the stirring speed to 20-30 RPM, and fully stirring for 10-30 min to form a uniform mixed solution;
(2) weighing the organic silicon phase component raw materials according to the following weight parts: 4.0 parts of 10-100 nm poly dimethyl silica alkanol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY101) and 1.0 part of 100-500 nm poly dimethyl silica alkanol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY 102); adding the mixed solution obtained in the step (1) into the mixed solution under stirring, continuously heating the mixed solution to 80-95 ℃, reducing the stirring speed to 10-20 RPM (revolutions per minute), fully stirring the mixed solution for dissolving, and keeping the temperature for 20-40 min;
(3) stirring the mixture, cooling to 30-45 ℃, and weighing other matrix component raw materials in parts by weight: 1.0 part of disodium ethylene diamine tetraacetate, 72.0 parts of polyquaternary ammonium salt, 15.0 parts of cocamidopropyl betaine, 0.1 part of preservative, 1.0 part of essence, 0.5 part of composite natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid and 201.0 parts of polysorbate-201.0; and (3) adding the mixed solution obtained in the step (2) under stirring, cooling to room temperature after uniformly stirring, and sequentially adding the plant extracts to obtain the shampoo. Wherein the weight ratio of the premixed component, the organic silicon phase component, the plant extract and other matrix components is 74.1: 5.0: 5.0: 20.9.
example 5
The preparation method of the organic silicon shampoo comprises the following steps of:
(1) weighing the premixed component raw materials according to the following weight parts: 18.0 parts of sodium methyl cocoyl taurate, 5.0 parts of alpha-sodium alkenyl sulfonate, 12.0 parts of sodium laureth sulfate, 5.0 parts of cocamide methyl MEA, 3.0 parts of glycol distearate, 4.0 parts of sodium isostearoyl lactylate, 2.0 parts of stearamidopropyl dimethylamine, 2.0 parts of guar hydroxypropyl trimethyl ammonium chloride, 2.0 parts of cationic cellulose and 16.1 parts of water; completely dispersing the guar hydroxypropyl trimethyl ammonium chloride and the cationic cellulose in a proper amount of water, adding the mixture, mixing and stirring, heating to 70-80 ℃, starting the stirring speed to 20-30 RPM, and fully stirring for 10-30 min to form a uniform mixed solution;
(2) weighing the organic silicon phase component raw materials according to the following weight parts: 5.0 parts of 10-100 nm poly dimethyl siloxane alcohol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY101) and 5.0 parts of 100-500 nm poly dimethyl siloxane alcohol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY 102); adding the mixed solution obtained in the step (1) into the mixed solution under stirring, continuously heating the mixed solution to 80-95 ℃, reducing the stirring speed to 10-20 RPM (revolutions per minute), fully stirring the mixed solution for dissolving, and keeping the temperature for 20-40 min;
(3) stirring the mixture, cooling to 30-45 ℃, and weighing other matrix component raw materials in parts by weight: 1.0 part of disodium ethylene diamine tetraacetate, 72.0 parts of polyquaternium, 15.0 parts of cocamidopropyl betaine, 0.1 part of preservative, 1.0 part of essence, 0.5 part of composite natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid and 201.0 parts of polysorbate-201.0; and (3) adding the mixed solution obtained in the step (2) under stirring, uniformly stirring, and sequentially adding the plant extracts to obtain the shampoo. Wherein the weight ratio of the premixed component, the organic silicon phase component, the plant extract and other matrix components is 69.1: 10.0: 10.0: 20.9.
example 6
The preparation method of the organic silicon shampoo comprises the following steps of:
(1) weighing the premixed component raw materials according to the following weight parts: 18.0 parts of sodium methyl cocoyl taurate, 5.0 parts of alpha-sodium alkenyl sulfonate, 12.0 parts of sodium laureth sulfate, 5.0 parts of cocamide methyl MEA, 3.0 parts of glycol distearate, 4.0 parts of sodium isostearoyl lactylate, 2.0 parts of stearamidopropyl dimethylamine, 2.0 parts of guar hydroxypropyl trimethyl ammonium chloride, 2.0 parts of cationic cellulose and 18.1 parts of water; completely dispersing the guar hydroxypropyl trimethyl ammonium chloride and the cationic cellulose in a proper amount of water, adding the mixture, mixing and stirring, heating to 70-80 ℃, starting the stirring speed to 20-30 RPM, and fully stirring for 10-30 min to form a uniform mixed solution;
(2) weighing the organic silicon phase component raw materials according to the following weight parts: 5.0 parts of 10-100 nm poly dimethyl siloxane alcohol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY101) and 3.0 parts of 100-500 nm poly dimethyl siloxane alcohol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY 102); adding the mixed solution obtained in the step (1) into the mixed solution under stirring, continuously heating the mixed solution to 80-95 ℃, reducing the stirring speed to 10-20 RPM (revolutions per minute), fully stirring the mixed solution for dissolving, and keeping the temperature for 20-40 min;
(3) stirring the mixture, cooling to 30-45 ℃, and weighing other matrix component raw materials in parts by weight: 1.0 part of disodium ethylene diamine tetraacetate, 72.0 parts of polyquaternium, 15.0 parts of cocamidopropyl betaine, 0.1 part of preservative, 1.0 part of essence, 0.5 part of composite natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid and 201.0 parts of polysorbate-201.0; and (3) adding the mixed solution obtained in the step (2) under stirring, cooling to room temperature after uniformly stirring, and sequentially adding the plant extracts to obtain the shampoo. Wherein the weight ratio of the premixed component, the organic silicon phase component, the plant extract and other matrix components is 71.1: 8.0: 8.0: 20.9.
example 7
The preparation method of the organic silicon shampoo comprises the following steps of:
(1) weighing the following raw materials of the premixed components by weight, 18.0 parts of sodium methyl cocoyl taurate, 5.0 parts of alpha-alkenyl sodium sulfonate, 12.0 parts of sodium laureth sulfate, 5.0 parts of cocamide methyl MEA, 3.0 parts of glycol distearate, 4.0 parts of sodium isostearoyl lactylate, 2.0 parts of stearamidopropyl dimethylamine, 2.0 parts of guar gum hydroxypropyl trimethyl ammonium chloride, 2.0 parts of cationic cellulose and 19.1 parts of water. Completely dispersing the guar hydroxypropyl trimethyl ammonium chloride and the cationic cellulose in a proper amount of water, adding the mixture, mixing and stirring, heating to 70-80 ℃, starting the stirring speed to 20-30 RPM, and fully stirring for 10-30 min to form a uniform mixed solution;
(2) weighing the organic silicon phase component raw materials according to the following weight parts: 4.0 parts of 10-100 nm poly dimethyl silica alkanol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY101) and 3.0 parts of 100-500 nm poly dimethyl silica alkanol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY 102); adding the mixed solution obtained in the step (1) into the mixed solution under stirring, continuously heating the mixed solution to 80-95 ℃, reducing the stirring speed to 10-20 RPM (revolutions per minute), fully stirring the mixed solution for dissolving, and keeping the temperature for 20-40 min;
(3) stirring the mixture, cooling to 30-45 ℃, and weighing other matrix component raw materials in parts by weight: 1.0 part of disodium ethylene diamine tetraacetate, 72.0 parts of polyquaternium, 15.0 parts of cocamidopropyl betaine, 0.1 part of preservative, 1.0 part of essence, 0.5 part of composite natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid and 201.0 parts of polysorbate-201.0; and (3) adding the mixed solution obtained in the step (2) under stirring, cooling to room temperature after uniformly stirring, and sequentially adding the plant extracts to obtain the shampoo. Wherein the weight ratio of the premixed component, the organic silicon phase component, the plant extract and other matrix components is 72.1: 7.0: 7.0: 20.9.
example 8
The preparation method of the organic silicon shampoo comprises the following steps of:
(1) weighing the raw materials of the premixed components according to the following parts by weight, 18.0 parts of sodium methyl cocoyl taurate, 5.0 parts of alpha-alkenyl sodium sulfonate, 12.0 parts of sodium laureth sulfate, 5.0 parts of cocamide methyl MEA, 3.0 parts of glycol distearate, 4.0 parts of sodium isostearoyl lactylate, 2.0 parts of stearamidopropyl dimethylamine, 2.0 parts of guar gum hydroxypropyl trimethyl ammonium chloride, 2.0 parts of cationic cellulose and 20.1 parts of water; completely dispersing the guar hydroxypropyl trimethyl ammonium chloride and the cationic cellulose in a proper amount of water, adding the mixture, mixing and stirring, heating to 70-80 ℃, starting the stirring speed to 20-30 RPM, and fully stirring for 10-30 min to form a uniform mixed solution;
(2) weighing the organic silicon phase component raw materials according to the following weight parts: 3.0 parts of 10-100 nm poly dimethyl silica alkanol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY101) and 3.0 parts of 100-500 nm poly dimethyl silica alkanol (and) triethanolamine dodecyl benzene sulfonate (trade name: HONY 102); adding the mixed solution obtained in the step (1) into the mixed solution under stirring, continuously heating the mixed solution to 80-95 ℃, reducing the stirring speed to 10-20 RPM (revolutions per minute), fully stirring the mixed solution for dissolving, and keeping the temperature for 20-40 min;
(3) stirring the mixture, cooling to 30-45 ℃, and weighing other matrix component raw materials in parts by weight: 1.0 part of disodium ethylene diamine tetraacetate, 72.0 parts of polyquaternium, 15.0 parts of cocamidopropyl betaine, 0.1 part of preservative, 1.0 part of essence, 0.5 part of composite natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid and 201.0 parts of polysorbate-201.0; and (3) adding the mixed solution obtained in the step (2) under stirring, cooling to room temperature after uniformly stirring, and sequentially adding the plant extracts to obtain the shampoo. Wherein the weight ratio of the premixed component, the organic silicon phase component, the plant extract and other matrix components is 73.1: 6.0: 6.0: 20.9.
evaluation of efficacy
The test name is: dry combing and Wet combing test of Hair
Test objects: several deoiled tresses, 45cm in length, weighed about 15 g.
The test method comprises the following steps: (1) firstly, carrying out dry combing test on hair bundles as a dry combing test result before washing; (2) then, a wet combing test is carried out by applying shampoo, and the wet combing result after washing is taken as a wet combing result. The specific method comprises the following steps: using each example product to wash 3 groups of hair strands respectively, taking an average value of test results, firstly wetting the hair, uniformly coating shampoo on the hair strands, rubbing for 100 seconds, fixing the water speed, washing for 100 seconds, and testing the wet combing property after the washing is finished; (3) as a contrast, the hair comb is washed by water, and the specific steps are carried out by using shampoo as well, so that the hair comb is used as a wet combing result before washing; (4) fixing the wind speed and the temperature by using a blower, drying the hair bundle, and performing a dry combing test as a dry combing result after washing.
Grading standard: by using a sensory evaluation method, the full score is 10 points, the 10 points are that the hair is easy to comb, the 1 point effect is the worst, and the hair is seriously tangled, dry and harsh during combing. In order to ensure the accuracy of the experimental results, the wet combing performance of the hair bundle after being cleaned is required to be tested within 10 seconds.
TABLE 1 Dry combing and Wet combing before and after shampoo application (mean) for each group of subjects
The results are shown in table 1, the wet combing effect of examples 5 and 6 is best and significantly better than the commercial product, and the dry combing effect of example 5 is best and significantly better than the commercial product; the use of examples 1 to 8 can effectively improve wet combing performance, wherein in examples 1 to 5, combing performance is significantly improved with the increase of the content of the dimethiconol emulsion with the nano particle size, and in examples 5 to 8, dry combing performance of hair can be significantly improved. Therefore, the organic silicon shampoo has excellent dry-wet combing performance and wide applicable population, the technical scheme utilizes the nano silicone oil emulsion as the main raw material to increase the hydrophilicity of the silicone oil, so that the nano silicone oil emulsion can be effectively attached to the hydrophilic layer of the hair, smooth damaged hair scales, play a role in moisturizing, solve the problem that hydrophobic silicone oil in the existing shampoo product is gathered on the scalp, achieve the beneficial effect of low aggregation of the nano silicone oil emulsion on the scalp, further reduce the risk of pore blockage, and simultaneously bring about the effects of smooth hair quality, full gloss, good combing performance and difficult breakage; and a protective film can be formed by utilizing the sealing property of the grease to keep the stable moisture content in the hair, thereby achieving the effects of nourishing and protecting the hair.
The foregoing is for the purpose of illustrating the invention only and various simple changes and modifications within the spirit of the invention made by those skilled in the art should fall within the scope of the invention.
Claims (8)
1. The organic silicon shampoo is characterized by comprising the following raw materials: premix components, silicone phase components, plant extracts and other matrix components.
2. The silicone shampoo as claimed in claim 1, wherein the silicone shampoo is prepared from the following raw materials in parts by weight: 15-90 parts of a premixed component, 2.0-10 parts of an organic silicon phase component, 2.0-10 parts of a plant extract and 6.0-30 parts of other matrix components.
3. The silicone shampoo as claimed in claim 2, wherein the premixed component comprises the following raw materials in parts by weight: 1.0-20.0 parts of methyl cocoyl sodium taurate, 1.0-10.0 parts of alpha-alkenyl sodium sulfonate, 1.0-20.0 parts of sodium lauryl polyether sulfate, 1.0-5.0 parts of cocoamidomethyl MEA, 1.0-5.0 parts of glycol distearate, 1.0-5.0 parts of sodium isostearoyl lactylate, 1.0-5.0 parts of stearamidopropyl dimethylamine, 1.0-5.0 parts of guar gum hydroxypropyl trimethyl ammonium chloride, 1.0-5.0 parts of cationic cellulose and 5.0-25.0 parts of water.
4. The silicone shampoo as claimed in claim 3, wherein the silicone component comprises the following raw materials in parts by weight: 2.0-10.0 parts of dimethiconol (and) triethanolamine dodecylbenzene sulfonate.
5. The organosilicon shampoo and the preparation method thereof according to claim 4, wherein the organosilicon component comprises the following raw materials in parts by weight: 10-100 nm of dimethiconol (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY101) 1.0-5.0 parts and 100-500 nm of dimethiconol (and) triethanolamine dodecylbenzene sulfonate (trade name: HONY102) 1.0-5.0 parts.
6. The silicone shampoo according to claim 5, wherein the other matrix components comprise the following raw materials in parts by weight: 1.0-5.0 parts of disodium ethylene diamine tetraacetate, 71.0-5.0 parts of polyquaternium, 1.0-20.0 parts of cocamidopropyl betaine, 0.1 part of preservative, 1.0 part of essence, 0.5 part of natural product antiallergic itching relieving extract (trade name: HONY604), 0.3 part of citric acid and-201.0 parts of polysorbate.
7. The silicone shampoo as claimed in claim 6, wherein the plant extract is prepared from the following raw materials in parts by weight: 1.0-5 parts of calendula extract, 1.0-5 parts of purslane extract, 0.5-1.2 parts of evening primrose oil and 1.0-2.5 parts of witch hazel extract.
8. The silicone shampoo and the preparation method thereof according to claim 7, wherein the silicone shampoo comprises the following components in parts by weight: the method comprises the following steps:
s1: weighing raw materials in the premixed components according to a proportion, dispersing the guar propyl trimethyl ammonium chloride and the cationic cellulose in a proper amount of water completely in advance, adding the mixture, mixing and stirring, heating to 70-80 ℃, starting the stirring speed to 20-30 RPM, and fully stirring for 10-30 min to form a uniform mixed solution;
s2: weighing raw materials in the organic silicon phase component according to a proportion, adding the mixed solution in S1, continuously heating to 80-95 ℃, reducing the stirring speed to 10-20 RPM, fully stirring and dissolving the mixture, and keeping the temperature for 20-40 min;
s3: and continuously stirring and cooling to 30-45 ℃, weighing the raw materials in other matrix components according to a ratio, sequentially stirring and adding, uniformly stirring, cooling to room temperature, sequentially adding the plant extract, and uniformly stirring to obtain the organic silicon shampoo, wherein the weight ratio of the premixed component to the organic silicon phase component to the plant extract to the other matrix components is (15-90): (2.0-10): (2.0-10): (6.0-30).
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| CN116196240A (en) * | 2022-12-30 | 2023-06-02 | 广州市勇辉精细化工有限公司 | Hair-loss-preventing and hair-fixing shampoo containing natural plant components and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106955248A (en) * | 2017-03-31 | 2017-07-18 | 上海浦大工贸有限公司 | A kind of plant profit supports shampoo and its method for preparing extractive and preparation method thereof |
| CN111374902A (en) * | 2020-04-03 | 2020-07-07 | 广州骐源生物科技有限公司 | Anti-hair loss and hair-fixing shampoo composition containing fibroin and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106955248A (en) * | 2017-03-31 | 2017-07-18 | 上海浦大工贸有限公司 | A kind of plant profit supports shampoo and its method for preparing extractive and preparation method thereof |
| CN111374902A (en) * | 2020-04-03 | 2020-07-07 | 广州骐源生物科技有限公司 | Anti-hair loss and hair-fixing shampoo composition containing fibroin and preparation method thereof |
Cited By (2)
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|---|---|---|---|---|
| CN116196240A (en) * | 2022-12-30 | 2023-06-02 | 广州市勇辉精细化工有限公司 | Hair-loss-preventing and hair-fixing shampoo containing natural plant components and preparation method thereof |
| CN116196240B (en) * | 2022-12-30 | 2023-09-15 | 广州市勇辉精细化工有限公司 | Hair-loss-preventing and hair-fixing shampoo containing natural plant components and preparation method thereof |
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