CN1133316A - Light reflection sign for road and adhesion agent preparation method - Google Patents
Light reflection sign for road and adhesion agent preparation method Download PDFInfo
- Publication number
- CN1133316A CN1133316A CN 96100713 CN96100713A CN1133316A CN 1133316 A CN1133316 A CN 1133316A CN 96100713 CN96100713 CN 96100713 CN 96100713 A CN96100713 A CN 96100713A CN 1133316 A CN1133316 A CN 1133316A
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- China
- Prior art keywords
- road
- reflecting
- acrylic resin
- mixing machine
- mark band
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- Road Signs Or Road Markings (AREA)
- Road Repair (AREA)
Abstract
The present invention relates to a new-type road safety light-reflecting line made up by using natural rubber and acrylic resin as base material, adding pigment (titanium pigment or chrome yellow, filling material (calcium carbonate, barium sulfate, talcum powder, sea urchin roe paste powder), additive (dioctyl (0-) phthalate, silane coupling agent, machine oil) and reflecting material (glass bead) according to a certain proportion, and making them pass through a certain technological process. Besides, it also provides a binding agent making the light-reflecting line adhere to the road surface. Its cost is low and service life is long.
Description
The present invention relates to a kind of compound, especially for a kind of be base-material with natural rubber and acrylic resin, be equipped with the new road safety notice that pigment, stopping composition, additive, light reflecting material process again---road is with the compound method of reflecting mark band and tackiness agent thereof.
At present, transport development both at home and abroad is rapid, and is also more and more higher for the requirement of sign safety features.Originally, the graticule sign that is used for road surface was mainly solvent-borne type and hot-melting type two big classes.Solvent based coating normal temperature is brushing down, and dry slow (about 30 minutes), in the life-span short (less than three months), (comprehensive cost is higher than 100 yuan/m to the cost height in two years
2) etc. weak point; Thermosol coating need be heated again and could be constructed down to 180 ° of-220 ℃ of high temperature, and difficulty of construction is big, and safety coefficient little (with the fire heating) is polluted big, is subjected to temperature to influence weak points such as serious.So, this roadmarking of two types, the very difficult needs that adapt to current traffic.
The objective of the invention is to overcome the weak point in the above prior art, and a kind of " road with the compound method of reflecting mark band and tackiness agent thereof " be provided, this reflecting mark band production unit is uncomplicated, product cost is low, long service life, pollution-free, night sighting is high, its tackiness agent is to be used for the special adhesive specially that reflecting mark band and pavement of road carrier adhere to each other.
Now that road is as follows with composition, compound method and some starting material feature division of reflecting mark band and tackiness agent thereof:
One, road reflecting mark band:
1, moiety: (weight percent)
A, base-material:
BC-08-S thermoplastic acrylic resin 18-23
Natural rubber 7-10
B, pigment:
Titanium dioxide or chrome yellow: 13-18
C, stopping composition:
Lime carbonate 10-15
Barium sulfate 6-12
Talcum powder 15-20
Sea urchin roe paste powder 1-3
D, light reflecting material:
Glass microballon 18-23
E, additive:
Adjacent this dioctyl phthalate dioctyl ester 1.5-3
Silane coupling agent 0.5-1
Machine oil 2-5
2, compound method:
1., machine oil, titanium dioxide (or chrome yellow) are mixed in small-sized mixing machine, standby,
2., natural rubber was plasticated on rubber mixing machine 10-15 minute, the mixture in then will be 1. adds to mixing on the rubber mixing machine, plasticates, and roll release is standby,
3., will acrylic resin, stopping composition (four kinds of material), adjacent this dioctyl phthalate dioctyl ester silane coupling agent add in " ∨ " type mixing machine and mix,
4., will be 2., 3. in mixture mixing on rubber mixing machine, roll release goes out " hair-videotape ", promptly with the tape of burr, the belt of non-moulding just,
5., hair-videotape is depressed into 1.5mm thickness, is cut into the wide belt of 100-300mm on rolling press,
6., 100-300mm is wide, belt that 1.5mm is thick, on the conveying belt with the spray gun spraying on the acrylic paint of " commercially available " as non-skid finish, and plant light reflecting material---glass microballon with bead-implanting device, with tape feed roller finished belt is rolled into 5m
2/ volume so far, has been finished the process for preparation (referring to process flow sheet) of reflecting mark band.
3, raw-material feature:
1., base-material: acrylic resin must be used thermoplastic resin, at normal temperatures, resin be coated with 4 glasss of viscosity, must not be lower than 300 seconds, solid content can not be lower than 52%, natural rubber is the best with No. three smoked sheets of Thailand,
2., pigment: titanium dioxide is selected rutile-type for use, and requiring refractive index is 1.7-2.7, and chrome yellow is selected deep chrome yellow for use, and color and luster is equivalent to GR, 5 grades of photostabilization, water-soluble, oozing property of oil is 1 grade, acid resistance, alkali resistance are 3 grades,
3., light reflecting material: it is more than 1.5 that glass microballon is selected refractive index for use, and particle dia is 0.1-0.3mm,
4., stopping composition: fineness is selected 300 orders for use, and oil number is less than 20.
Now will produce road and use the as follows of white with xanchromatic reflecting mark band embodiment division:
Embodiment 1: the road compound method of white reflection colored belt:
1, composition, proportioning: (weight percent)
BC-08-S thermoplastic acrylic resin 18
No. three smoked sheet natural rubbers 7 of Thailand
Titanium dioxide 14
Lime carbonate 13
Barium sulfate 8
Talcum powder 17
Sea urchin roe paste powder 1
Glass microballon 18
Adjacent this dioctyl phthalate dibutyl ester 1.5
Trimethoxy vinyl silanes 0.5
Machine oil 2
2, compound method is with the above.
Embodiment 2: road is with the compound method of yellow reflecting mark band:
1, composition, proportioning: (weight percent)
BC-08-S thermoplastic propene resin 18
No. three smoked sheets 7 of Thailand
Titanium dioxide 14
Lime carbonate 13
Barium sulfate 8
Talcum powder 17
Sea urchin roe paste powder 1
Glass microballon 18
Adjacent this dioctyl phthalate dibutyl ester 1.5
Trimethoxy vinyl silanes 0.5
Machine oil 22, compound method are with the above.Two, the compound method of reflecting sign strip for road adhesive therefor: 1, the composition of Zu Chenging, proportioning: (weight percent) 1., base-material:
BC-08-S acrylic resin 45-55 2., solvent or diluent:
Toluene 8-15
Dimethylbenzene 20-28
Acetone 5-8
Vinyl acetic monomer 8-15
Butanols 5-8 3., additive:
Adjacent this dibutyl carboxylic acid: 0.5-2
Titanate coupling agent: 1.5-22: compound method:
Above-mentioned various raw materials in sequence are added in the airtight agitator according to quantity, and mixing is composite adhesives.
3, material characteristics:
1., base-material: BC-08-S acrylic resin thermoplastic resin, viscosity (CPS) are that 250-1000, solid content are 52%
2., titanic acid ester: coupling agent a kind of, viscosity is 250 centipoises, can mix with varsol, strengthens combining of colored belt and road surface.
Embodiment 3: the compound method (weight percent) of used tackiness agent when road usefulness reflecting mark band and pavement of road carrier are bonding
1, composition, proportioning: (weight percent)
BC-08-S acrylic resin 45
Adjacent this dibutyl carboxylic acid 0.5
Titanate coupling agent 1.5
Dimethylbenzene 23
Acetone 5
Toluene 10
Vinyl acetic monomer 10
Butanols 5
2, compound method is identical with the method for making of above-mentioned " road reflecting mark band tackiness agent ".
3, using method: with tackiness agent as primer with hairbrush, roller or be sprayed on (the per kilogram tackiness agent can be coated with 3-5 square metre) on drop table road surface, the concrete road surface, then adhere to and get final product with reflecting mark band.
Good effect of the present invention:
1, road is uncomplicated with equipment, the instrument of reflecting mark band required usefulness in producing process for preparation, the investment of founding the factory is little,
2, the reflecting mark band of producing, its raw material is marketable material, easily buys. The cost of its product is low, long service life, pollution-free, night sighting is high,
3, the road adhesive is for being used for: reflecting mark band and pavement of road carrier adhere to Special adhesive specially together. Its adhesive is easily produced, cost is low, raw materials used Be marketable material, easily buy. Its adhesive can use at normal temperatures, and bond properties It is good, free from environmental pollution,
4, adopt this " road reflecting mark band and adhesive thereof ", on road Construction is fast, efficient is high, can adapt to " the surface road traffic of reform and opening-up age high speed development Cause " needs.
Claims (2)
1, a kind of road reflecting mark band is characterized in:
(1), the composition of Zu Chenging: weight percent
A, base-material:
BC-08-S thermoplastic acrylic resin 18-23
Natural rubber 7-10
B, pigment:
Titanium dioxide or chrome yellow: 13-18
C, stopping composition:
Lime carbonate 10-15
Barium sulfate 6-12
Talcum powder 15-20
Sea urchin roe paste powder 1-3
D, light reflecting material:
Glass microballon 18-23
E, additive:
Adjacent this dioctyl phthalate dioctyl ester 1.5-3.0
Silane coupling agent 0.5-1.0
Machine oil 2-5
(2), compound method:
1., machine oil, titanium dioxide (or chrome yellow) are mixed in small-sized mixing machine, standby,
2., natural rubber was plasticated on rubber mixing machine 10-15 minute, the mixture in then will be 1. adds to mixing on the rubber mixing machine, plasticates, take off roll standby,
3., with acrylic resin, four kinds of stopping composition, adjacent this dioctyl phthalate dioctyl ester, silane coupling agent (as: trimethoxy vinyl silanes), add in the mixing machine and mix,
4., will be 2., 3. in mixture mixing on rubber mixing machine, roll release goes out " hair-videotape ",
5., hair-videotape is depressed into 1.5mm thickness, is cut into the wide belt of 100-300mm on rolling press,
6., 100-300mm is wide, belt that 1.5mm is thick on the conveying belt with the spray gun spraying on the acrylic paint of " commercially available " as non-skid finish, and plant light reflecting material---glass microballon with bead-implanting device, with tape feed roller finished belt is rolled into 5m2 and rolls up.
2, road reflecting mark band according to claim 1 when being characterized in that this white or yellow reflecting mark band and pavement of road carrier adhere to (closing), needs with a kind of special adhesive specially the composition of this tackiness agent, proportioning (weight %):
1., base-material:
BC-08-S acrylic resin: 45-55
2., solvent or diluent:
Toluene 8-15
Toluene 20-28
Acetone: 5-2
Vinyl acetic monomer: 8-15
Butanols: 5-8
3., additive:
Adjacent this dibutyl carboxylic acid: 0.5-2.0
Titanate coupling agent: 1.5-2.0
The compound method of this tackiness agent:
With above-mentioned 1., 3., various raw materials in 2. successively in proportion amount be added in the airtight agitator, mix and be the tackiness agent of being prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96100713 CN1133316A (en) | 1996-01-29 | 1996-01-29 | Light reflection sign for road and adhesion agent preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96100713 CN1133316A (en) | 1996-01-29 | 1996-01-29 | Light reflection sign for road and adhesion agent preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1133316A true CN1133316A (en) | 1996-10-16 |
Family
ID=5116687
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 96100713 Pending CN1133316A (en) | 1996-01-29 | 1996-01-29 | Light reflection sign for road and adhesion agent preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1133316A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6242056B1 (en) * | 1998-05-08 | 2001-06-05 | Innovative Concepts Unlimited, Llc | Process for applying light-emission-enhancement microbead paint compositions |
| CN1076376C (en) * | 1999-01-29 | 2001-12-19 | 山东东明石化集团合成树脂厂 | Modified acrylic resin and preparing method thereof |
| CN1325586C (en) * | 2003-07-02 | 2007-07-11 | 张贵洲 | Thermoplastic fast-dry traffic paint |
| CN1977015B (en) * | 2005-01-19 | 2010-05-19 | Lg化学株式会社 | Acrylic pressure-sensitive adhesive composition with good re-workability |
| CN101864202A (en) * | 2010-06-29 | 2010-10-20 | 彩虹集团公司 | Glass paste for reflective panel |
| CN104011296A (en) * | 2011-09-22 | 2014-08-27 | 弗林特贸易公司 | Anti-skid high retroreflectivity preformed thermoplastic composites for runway applications |
| CN104387630A (en) * | 2014-12-10 | 2015-03-04 | 沈阳长顺电缆制造有限责任公司 | High-reflectivity rubber and preparation method thereof |
| CN104710720A (en) * | 2015-03-31 | 2015-06-17 | 四川省江油市豫蜀夜视利反光材料有限公司 | Reflective marking belt base material, base material and method for manufacturing reflective marking belt |
| CN109181192A (en) * | 2018-09-03 | 2019-01-11 | 安徽新恒辉反光材料有限公司 | A kind of roads reflecting material and preparation method thereof |
-
1996
- 1996-01-29 CN CN 96100713 patent/CN1133316A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6242056B1 (en) * | 1998-05-08 | 2001-06-05 | Innovative Concepts Unlimited, Llc | Process for applying light-emission-enhancement microbead paint compositions |
| CN1076376C (en) * | 1999-01-29 | 2001-12-19 | 山东东明石化集团合成树脂厂 | Modified acrylic resin and preparing method thereof |
| CN1325586C (en) * | 2003-07-02 | 2007-07-11 | 张贵洲 | Thermoplastic fast-dry traffic paint |
| CN1977015B (en) * | 2005-01-19 | 2010-05-19 | Lg化学株式会社 | Acrylic pressure-sensitive adhesive composition with good re-workability |
| CN101864202A (en) * | 2010-06-29 | 2010-10-20 | 彩虹集团公司 | Glass paste for reflective panel |
| CN104011296A (en) * | 2011-09-22 | 2014-08-27 | 弗林特贸易公司 | Anti-skid high retroreflectivity preformed thermoplastic composites for runway applications |
| CN104387630A (en) * | 2014-12-10 | 2015-03-04 | 沈阳长顺电缆制造有限责任公司 | High-reflectivity rubber and preparation method thereof |
| CN104710720A (en) * | 2015-03-31 | 2015-06-17 | 四川省江油市豫蜀夜视利反光材料有限公司 | Reflective marking belt base material, base material and method for manufacturing reflective marking belt |
| CN104710720B (en) * | 2015-03-31 | 2017-03-29 | 四川省江油市豫蜀夜视利反光材料有限公司 | A kind of reflecting marking is with base material and base material, the manufacture method of reflecting marking band |
| CN109181192A (en) * | 2018-09-03 | 2019-01-11 | 安徽新恒辉反光材料有限公司 | A kind of roads reflecting material and preparation method thereof |
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