CN101613182B - Pigment composition for preparing stained glass grains - Google Patents
Pigment composition for preparing stained glass grains Download PDFInfo
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- CN101613182B CN101613182B CN2009100409991A CN200910040999A CN101613182B CN 101613182 B CN101613182 B CN 101613182B CN 2009100409991 A CN2009100409991 A CN 2009100409991A CN 200910040999 A CN200910040999 A CN 200910040999A CN 101613182 B CN101613182 B CN 101613182B
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Abstract
The invention relates to a pigment composition for preparing stained glass grains, comprising the following components according to the parts by weight: 100-200 parts of polyacrylic emulsion or polyurethane dispersion, 2.5-6 parts of aziridine crosslinker, 3-6.5 parts of propyl trimethoxysilane coupling agent, 0.4-0.8 part of polyethylene wax and 25-65 parts of water based color paste. The pigment composition for preparing stained glass grains of the invention can be added in discarded and used glass grains and mixed to react and obtain gorgeous stained glass grains of which hardness can be comparable to ceramics and natural gravels.
Description
Technical field
The present invention relates to a kind of compositions of additives that is used to prepare stained glass, particularly relate to a kind of color compositions that is used to prepare stained glass grains.
Background technology
Along with domestic economy develop rapidly and the needs of beautifying city road and compatriots to the pay attention to day by day of traffic safety, color anti-skid road surface is widely used with anti-skidding, the aesthetic property of its excellence, and particularly highway sections such as bend, road climb and fall, deceleration driven are especially suitable.On the intensive urban road of people's overall height degree, carry out high-grade collocation of colour attractive in appearance pedestrian, vehicle are taken their own roads, fully rationally use road equipment, can also remove eye strain, guarantee urban road traffic safety by road pavement.
The colored aggregate that present China color anti-skid road surface is taken is mainly quartz sand, ceramic aggregate, and its shortcoming of these aggregates is that weathering resistance is relatively poor, generally uses the some months Receding colour comparatively serious.The starting material of these aggregates take more Mineral resources simultaneously, and ecotope is had considerable influence.
The recycling of cullet becomes a heat subject gradually, as utilizes cullet to produce mosaic, artificial marble, granolith, ceramic floor brick etc.At present, research for preparation stained glass aspect only only limits to how to prepare aspects such as stained glass floor tile, stained glass decorative block, stained glass mosaic, therefore, how discarded glass is rationally utilized, the research for preparing the stained glass grains aspect is the important topic that current industry is badly in need of research.
Summary of the invention
The objective of the invention is to, overcome the defective that the existing preparation stained glass grains exists, and a kind of new color compositions that is used to prepare stained glass grains is provided, technical problem to be solved is it to be added in the discarded glass crystal grain mix and react, it is gorgeous to produce color and luster brilliance, the stained glass grains of the comparable U.S. pottery of hardness, natural sandstone.
The object of the invention to solve the technical problems realizes by the following technical solutions.According to a kind of color compositions that is used to prepare stained glass grains that the present invention proposes, in weight part, it comprises following component: 100～200 parts of ACRYLIC EMULSION; 2.5～6 parts of aziridine crosslinkers; 3～6.5 parts of propyl trimethoxy silicane coupling agents; 0.4～0.8 part of polyethylene wax; 25～65 parts of aqueous color pastes.
According to the color compositions that is used to prepare stained glass grains of the embodiment of the invention, in weight part, it comprises following component: 155 parts of ACRYLIC EMULSION; 4 parts of aziridine crosslinkers; 3.75 parts of propyl trimethoxy silicane coupling agents; 0.7 part of polyethylene wax; 45 parts of aqueous color pastes.
According to the color compositions that is used to prepare stained glass grains of the embodiment of the invention, described aqueous color paste is PR112 number bright red, PY74 number lemon yellow, PB15 pthalocyanine blue or PR101 iron oxide red.
By technique scheme, the advantage that the present invention has at least is: aziridine crosslinker adds water-fast to it in the aqueous acrylic emulsion, chemicals-resistant, sticking power high temperature resistant and on special substrate all improves significantly; The propyl trimethoxy silicane coupling agent is applied to water-borne coatingss such as water soluble acrylic acid and urethane, as adhesion promoters and linking agent, can improve bonding strength, water-repellancy, wear resistance, scrub resistance, scratch resistance and the chemical-resistant of glass crystal grain coating.
Above-mentioned explanation only is the general introduction of technical solution of the present invention, for can clearer understanding technique means of the present invention, and can be implemented according to the content of specification sheets, and for above-mentioned and other purposes, feature and advantage of the present invention can be become apparent, below especially exemplified by preferred embodiment, be described in detail as follows.
Embodiment
Reach technique means and the effect that predetermined goal of the invention is taked for further setting forth the present invention, below in conjunction with preferred embodiment, to its embodiment of color compositions, method, step, feature and the effect thereof that are used to prepare stained glass grains that foundation the present invention proposes, describe in detail as after.
The present invention utilizes the discarded glass of different sizes, be made into the glass fragment of 0.1～5mm particle diameter, the stained glass grains of preparation is through the crystal glass crystal that high temperature crystallization is fired and the later stage special process is handled, traditional aggregates such as the comparable U.S. pottery of its hardness, natural sandstone.Because glass crystal is transparent logical clear, shape differs, and external light is formed multidirectional reflective refraction, and assumed appearance layer gloss is more bright-coloured, and irregular shape is added nature doubly; Simultaneously, transparent glass crystal can effectively be filtered infrared rays and the ultraviolet ray in the sunlight, crystal caloric receptivity itself is reduced, and effectively protect outer aqueous color paste, increases the chromatograph life-span.
Quartzy coating is used for glass coloring, can make urethane have high anti-UV light, and is wear-resistant and adapt to the ability of Changes in weather.The use of natural aqueous color paste is the application (being used for industry, automobile and building trade) of high-performance coating.Natural aqueous color paste coating is normally translucent, and the formulation color paint that is applied in the glass coloring can produce translucent color, and the light of some amount is passed through.Light sees through glass and filters infrared rays and ultraviolet ray, has therefore increased the life-span of coloured coating, even outermost surface is worn, color effects also can come out by glass display clearly, also can be arranged very long work-ing life even therefore be exposed to the sun under burning sun.
What aqueous color paste of the present invention adopted is the toning mill base series product that Degussa (degussa), aqueous architectural coating are produced with factory.Shown in the following table 1 is the production schedule of different colours mill base.
The toning mill base production schedule of table 1 different colours
D*=increases dark sun-proof grade with respect to blue wool standard (1 is poor, and 8 is best)
The polymerization single polymerization monomer that is adopted among the preparation method of the present invention can be aqueous acrylic emulsion or polyurethane dispersing liquid.
The coupling agent that is adopted among the preparation method of the present invention is the propyl trimethoxy silicane series products, as: 3-(phenyl amino) propyl trimethoxy silicane, γ-amine propyl trimethoxy silicane, 3-aminopropyl trimethoxysilane or n-propyl trimethoxy silicane.
The linking agent that is adopted among the preparation method of the present invention is the polyfunctional aziridine linking agent, and as CX-100, XAMA 220, PFAZ 321 and PFAZ 322 contain 3 aziridine groups, have higher molecular weight, low volatility, and outward appearance is light yellow transparent liquid.
The unit of following weight part can be gram, kilogram or ton.
Embodiment 1
The discarded glass grain of having pulverized that takes by weighing 10000 parts is put into stirrer, and the glass grain is wanted clean free from dust.With 100 parts ACRYLIC EMULSION, 2.5 parts aziridine crosslinker, 3 parts propyl trimethoxy silicane coupling agent, 0.4 part polyethylene wax, 25 parts PR112 large red aqueous color paste, five kinds of material mixing together, after stirring, and put into stirrer and glass grain stir about 5～10min.The glass crystal grain of catching color is delivered to about drying plant oven dry 5min by travelling belt, and bake out temperature is set between 50～120 ℃, and with the red glass crystal grain mass dryness fraction after coming out of the stove, loose not conglomeration is good.
When construction, can can directly construct in surfaces such as concrete, pitch, floor tile, mud watt or timber with the red glass crystal grain of above-mentioned preparation, perhaps add coating such as paint, glue to be applied on metope, the ground, the terrace that is made into is more economical than ceramic tile, long service life, the cost performance height.
The examining report that the test effect of glass crystal grain coating is provided by national communication safety features quality supervision and test center (project supervision inspection center of the Ministry of Communications), as shown in table 2 below:
The performance and the test result of the red glass crystal grain coating among table 2 embodiment 2
Embodiment 2
The discarded glass grain of having pulverized that takes by weighing 10000 parts is put into stirrer, and the glass grain is wanted clean free from dust.With 150 parts ACRYLIC EMULSION, 4 parts aziridine crosslinker, 4.5 parts propyl trimethoxy silicane coupling agent, 0.6 part polyethylene wax, 40 parts the aqueous color paste of PB15 pthalocyanine blue, five kinds of material mixing together, after stirring, and put into stirrer and glass grain stir about 5～10min.The glass crystal grain of catching color is delivered to about drying plant oven dry 10min by travelling belt, and bake out temperature is set between 50～120 ℃, and with the blue glass crystal grain mass dryness fraction after coming out of the stove, loose not conglomeration is good.
When construction, can can directly construct in surfaces such as concrete, pitch, floor tile, mud watt or timber with the blue glass crystal grain of above-mentioned preparation, perhaps add coating such as paint, glue to be applied on metope, the ground, the terrace that is made into is more economical than ceramic tile, long service life, the cost performance height.
The examining report that the test effect of glass crystal grain coating is provided by national communication safety features quality supervision and test center (project supervision inspection center of the Ministry of Communications), as shown in table 3 below:
The performance and the test result of the blue glass crystal grain coating among table 3 embodiment 3
Embodiment 3
The discarded glass grain of having pulverized that takes by weighing 10000 parts is put into stirrer, and the glass grain is wanted clean free from dust.With 155 parts ACRYLIC EMULSION, 4 parts aziridine crosslinker, 3.75 parts propyl trimethoxy silicane coupling agent, 0.7 part polyethylene wax, 45 parts PY74 number lemon yellow aqueous color paste, five kinds of material mixing together, after stirring, and put into stirrer and glass grain stir about 5～10min.The glass crystal grain of catching color is delivered to about drying plant oven dry 10min by travelling belt, and bake out temperature is set between 50～120 ℃, and with the yellow glass crystal grain mass dryness fraction after coming out of the stove, loose not conglomeration is good.
When construction, can can directly construct in surfaces such as concrete, pitch, floor tile, mud watt or timber with the yellow glass crystal grain of above-mentioned preparation, perhaps add coating such as paint, glue to be applied on metope, the ground, the terrace that is made into is more economical than ceramic tile, long service life, the cost performance height.
The examining report that the test effect of glass crystal grain coating is provided by national communication safety features quality supervision and test center (project supervision inspection center of the Ministry of Communications), as shown in table 4 below:
The performance and the test result of the yellow glass crystal grain coating among table 4 embodiment 4
The above, it only is preferred embodiment of the present invention, be not that the present invention is done any pro forma restriction, though the present invention discloses as above with preferred embodiment, yet be not in order to limit the present invention, any those skilled in the art, in not breaking away from the technical solution of the present invention scope, when the technology contents that can utilize above-mentioned announcement is made a little change or is modified to the equivalent embodiment of equivalent variations, in every case be not break away from the technical solution of the present invention content, according to technical spirit of the present invention to any simple modification that above embodiment did, equivalent variations and modification all still belong in the scope of technical solution of the present invention.
Claims (3)
1. color compositions that is used to prepare stained glass grains, it is characterized in that: in weight part, it comprises following component:
100～200 parts of ACRYLIC EMULSION;
2.5～6 parts of aziridine crosslinkers;
3～6.5 parts of propyl trimethoxy silicane coupling agents;
0.4～0.8 part of polyethylene wax;
25～65 parts of aqueous color pastes.
2. the color compositions that is used to prepare stained glass grains according to claim 1 is characterized in that: in weight part, it comprises following component:
155 parts of ACRYLIC EMULSION;
4 parts of aziridine crosslinkers;
3.75 parts of propyl trimethoxy silicane coupling agents;
0.7 part of polyethylene wax;
45 parts of aqueous color pastes.
3. the color compositions that is used to prepare stained glass grains according to claim 1 and 2 is characterized in that: described aqueous color paste is PR112 number bright red, PY74 number lemon yellow, PB15 pthalocyanine blue or PR101 iron oxide red.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100409991A CN101613182B (en) | 2009-07-10 | 2009-07-10 | Pigment composition for preparing stained glass grains |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100409991A CN101613182B (en) | 2009-07-10 | 2009-07-10 | Pigment composition for preparing stained glass grains |
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| Publication Number | Publication Date |
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| CN101613182A CN101613182A (en) | 2009-12-30 |
| CN101613182B true CN101613182B (en) | 2011-01-19 |
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| CN2009100409991A Expired - Fee Related CN101613182B (en) | 2009-07-10 | 2009-07-10 | Pigment composition for preparing stained glass grains |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559717B (en) * | 2014-12-25 | 2017-05-24 | 澳达树熊涂料(惠州)有限公司 | Low-cost high-performance water-based two-component polyurethane coating and method for preparing same |
| CN107640888B (en) * | 2017-09-20 | 2020-07-14 | 陕西科技大学 | Preparation method of colored facing glass mosaic |
| CN114836988A (en) * | 2022-04-24 | 2022-08-02 | 沈阳化工大学 | Preparation method of zero-water-absorption color road marking material |
| CN116904065A (en) * | 2023-08-29 | 2023-10-20 | 英科卡乐油墨(湖北)有限公司 | Water-based matte oil |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5472737A (en) * | 1994-06-09 | 1995-12-05 | Anders; Irving | Phosphorescent highway paint composition |
| US5665793A (en) * | 1994-06-09 | 1997-09-09 | Anders; Irving | Phosphorescent highway paint composition |
| CN1329119A (en) * | 2000-06-16 | 2002-01-02 | 上海航伟科技发展有限公司 | Ethylene propylene terpolymer and its production method |
| CN101412864A (en) * | 2007-10-29 | 2009-04-22 | 芜湖力特尔涂料制造有限公司 | Self-drying glass ink and preparation thereof |
-
2009
- 2009-07-10 CN CN2009100409991A patent/CN101613182B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5472737A (en) * | 1994-06-09 | 1995-12-05 | Anders; Irving | Phosphorescent highway paint composition |
| US5665793A (en) * | 1994-06-09 | 1997-09-09 | Anders; Irving | Phosphorescent highway paint composition |
| CN1329119A (en) * | 2000-06-16 | 2002-01-02 | 上海航伟科技发展有限公司 | Ethylene propylene terpolymer and its production method |
| CN101412864A (en) * | 2007-10-29 | 2009-04-22 | 芜湖力特尔涂料制造有限公司 | Self-drying glass ink and preparation thereof |
Non-Patent Citations (2)
| Title |
|---|
| JP特开2004-231917A 2004.08.19 |
| 孙道兴等."水性快干耐磨纳米复合道路标志涂料的研制".《中国涂料》.2006,第21卷(第12期),第28-30页. |
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| CN101613182A (en) | 2009-12-30 |
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Granted publication date: 20110119 Termination date: 20120710 |