CN104710720B - A kind of reflecting marking is with base material and base material, the manufacture method of reflecting marking band - Google Patents
A kind of reflecting marking is with base material and base material, the manufacture method of reflecting marking band Download PDFInfo
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- CN104710720B CN104710720B CN201510150174.0A CN201510150174A CN104710720B CN 104710720 B CN104710720 B CN 104710720B CN 201510150174 A CN201510150174 A CN 201510150174A CN 104710720 B CN104710720 B CN 104710720B
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Abstract
The invention discloses reflecting marking band base material, including SBS8～15 part；EVA2～6 part；5～10 parts of quartz sand；7～12 parts of Colophonium；3～6 parts of Petropols；30～50 parts of wollastonite in powder；20～40 parts of Calcium Carbonate；1～8 part of pigment；2～5 parts of plasticizer；1～2 part of paraffin；8～15 parts of glass microballoon.Additionally, the invention also discloses the manufacture method of base material and reflecting marking band.The present invention reflecting marking band base material with ground, the preferable compatibility of Colophonium, the high advantage of toughness.
Description
Technical field
The present invention relates to the manufacture method of reflecting marking band, belongs to marker technical field.
Background technology
Reflective marker belt also known as preforming road reflective marking tape, are that, using macromolecule flexible polymeric thing, pigment combines and forms
A kind of Novel light-reflecting material.Reflective marker belt is mainly used in highway pavement instruction：Such as zebra crossing, center double solid line, track boundary
Line, word, arrow etc..Suitable for Colophonium, cement, various road surfaces and the metopes such as the solidifying soil of reflective marker belt reflective marker belt, marble are mixed.
Reflector segment in reflective marker belt is the glass microballoon retroreflecting principle with high index of refraction, is located after focusing
The advanced technologies of reason are made.It can postback distant place direct light line reflection at light, no matter having good inverse on daytime or night
Reflection optical property.Especially evening, the high-visibility as daytime can be played.Using this high-visibility reflecting sign
Thread highway graticule, no matter user is, at remote place, or in the case where light or scattered light are disturbed, can to compare
Relatively easily found by nighttime driving person.
Reflective marker belt is in use, due to being laid on ground, long-term to be infiltrated by rainwater, the intensity to base material
There is very high requirement with the degree of adhesion of road pavement.
Existing like product, employs complicated processing method：First at carrier (reticular fiber base material or adhesive band base)
Special-purpose adhesive laid on, then reflecting sheet material is cut into the sheet material of certain size on request, roll it is smooth after which is assembled
It is pasted onto on carrier, and rolls sizing.Also have a class not use carrier, but intensity decrease, at the same paste when pair
Ground has high demands, and particularly asphalt roads, irregular road surface cannot be pasted substantially, even if be stained with the life-span very short cannot make
With.
The content of the invention
It is an object of the invention to provide a kind of reflecting marking band, with the preferable compatibility and toughness.
It is, up to above-mentioned purpose, in one embodiment of the present of invention, to provide a kind of reflecting marking band base material, the base material is included
Following components：
Styrene butadiene styrene block copolymer (SBS) SBS8～15 part；
Ethylene-vinyl acetate copolymer EVA2～6 part；5～10 parts of quartz sand；
7～12 parts of Colophonium；3～6 parts of Petropols；30～50 parts of wollastonite in powder；20～40 parts of Calcium Carbonate；
1～8 part of pigment；2～5 parts of plasticizer；1～2 part of paraffin；8～15 parts of glass microballoon.
Preferably, no more than 1 part of oleamide and no more than 1 part of antioxidant can also be included.
For this purpose, the invention also discloses the preparation method of above-mentioned base material is：
By styrene butadiene styrene block copolymer (SBS) SBS of formula ratio, ethylene-vinyl acetate copolymer EVE, pine
Knead after perfume, Petropols, wollastonite in powder, Calcium Carbonate and pigment Hybrid Heating, be subsequently adding plasticizer, paraffin, glass microballoon
Knead with quartz sand.
In order to implement above-mentioned technology, the invention also discloses the preparation method of reflecting marking band, the method includes：
Mixing, by styrene butadiene styrene block copolymer (SBS) SBS of formula ratio, ethylene-vinyl acetate copolymer
Knead after EVE, Colophonium, Petropols, wollastonite in powder, Calcium Carbonate and pigment Hybrid Heating, be subsequently adding plasticizer, paraffin, glass
Mixture is released after glass microballon and quartz sand mixing；
Pressing mold, it is compressing in feeding mould after mixture is softened, obtain molded substrate；
Upper reflecting coating, is uniformly coated with reflecting coating on molded substrate surface, then by reflective glass beads uniform embedding system
In coating surface, reflecting sheet material is made after intensification dry solidification；
Isolation, in the bottom surface coated with adhesive of reflecting sheet material, and is isolated using isolated material；
Cut out, reflecting sheet material is cut into into predetermined required form.
The reflective surface glue of the present invention can be the coating with color, can be used for playing suggesting effect, and cross-linking agent is preferred
The cross-linking agent of polyester amine, can allow reflecting coating to be preferably attached on base material, and reflective glass beads can be allowed to adhere to
On reflecting coating.
In implementation process, Colophonium softening point is 85-95 DEG C to the present invention, acid number≤10mgkOH/g, ash≤0.1%；Stone
Oleoresin can be five copolymer of carbon, nine copolymer of nine copolymer of carbon and five-carbon of carbon；On reflecting coating, reflective glass beads is thin
Spend for 30 mesh～60 mesh；Binding agent can be thermal capacitance type, the acrylate pressure sensitive adhesive of rubber-type.
The pigment of the present invention can be selected as needed, and the conventional color of reflecting marking band is yellow, green, red
Color, white etc., therefore to make reflecting marking band embody above-mentioned color, the pigment of employing can also from yellow, green, redness,
White etc..
The present invention reflecting marking band can be pasted onto on all kinds of road surfaces that the public such as highway, square pass through be used to refer to and
Guiding pedestrian and vehicle are passed through in order.
The present invention reflecting marking band using method be：By needing, the road cleaning of sticking sign is clean, uses mark stroke
Go out the contour line of identification pattern, equably brush adhesive thickness moderate in the contour line at the back side and ground of mark, apply
Certain hour is hung after good, is firmly rubbed with finger contact glue-line, when finger does not take away when glue is parched just Pasting.
In sum, the present invention has advantages below：
1st, this product selects rational composition of raw materials so that base material is more easy to attach with ground, particularly Colophonium, out-of-flatness road
Road；Product has adhesive strength height, strong, water-fast, heat-resisting initial bonding strength, moisture-proof, aging resistance, long service life, good toughness, wearability
By force, the advantages of high mechanical strength.
2nd, this product low cost, simple production process, steady quality, both ensure that product strength and toughness, and had subtracted significantly
Lack operation, reduce cost.
Specific embodiment
Embodiment 1
The component of base material：
8 parts of styrene butadiene styrene block copolymer (SBS)；
Ethylene-vinyl acetate copolymer EVA2 parts；5 parts of quartz sand；
7 parts of Colophonium；3 parts of Petropols；30 parts of wollastonite in powder；20 parts of Calcium Carbonate；
1 part of yellow uitramarine；2 parts of dibutyl ester；1 part of paraffin；8 parts of the glass microballoon of 90 mesh.
Embodiment 2
The component of base material：
15 parts of styrene butadiene styrene block copolymer (SBS)；
6 parts of ethylene-vinyl acetate copolymer；10 parts of quartz sand；
12 parts of Colophonium；6 parts of Petropols；50 parts of wollastonite in powder；40 parts of Calcium Carbonate；
8 parts of Chinese white；5 parts of plasticizer dibutyl ester；2 parts of paraffin；100 15 parts of mesh glass microballoons.
Embodiment 3
The component of base material：
Styrene butadiene styrene block copolymer (SBS) SBS10 part；
Ethylene-vinyl acetate copolymer EVA4 parts；8 parts of quartz sand；
10 parts of Colophonium；5 parts of Petropols；40 parts of wollastonite in powder；30 parts of Calcium Carbonate；
4 parts of yellow uitramarine；3 parts of plasticizer；2 parts of paraffin；110 12 parts of mesh glass microballoons；1 part of oleamide；Antioxidant 1
Part.
Embodiment 4
The component of base material：
Styrene butadiene styrene block copolymer (SBS) SBS9 part；
Ethylene-vinyl acetate copolymer EVA4 parts；9 parts of quartz sand；
11 parts of Colophonium；6 parts of Petropols；38 parts of wollastonite in powder；35 parts of Calcium Carbonate；
4 parts of Chinese white；3 parts of plasticizer dibutyl ester；2 parts of paraffin；110 12 parts of mesh glass microballoons；0.5 part of oleamide；
1076 0.8 part of type antioxidants.
Embodiment 1 and embodiment 2 can make reflecting marking band base material using following methods.
By styrene butadiene styrene block copolymer (SBS) SBS of formula ratio, ethylene-vinyl acetate copolymer EVE, pine
Perfume, Petropols, wollastonite in powder, Calcium Carbonate and pigment knead 5min after being mixed and heated to 50 DEG C, are subsequently adding plasticizer two pungent
Fat kneads 2min, adds the paraffin mixing 3min of formula ratio；Glass microballoon and quartz sand mixing are eventually adding, when temperature is 80
DEG C when release mixture；Obtain reflecting marking band base material.
Embodiment 3 and embodiment 4 can make reflecting marking band base material using following methods.
By styrene butadiene styrene block copolymer (SBS) SBS of formula ratio, ethylene-vinyl acetate copolymer EVE, pine
Perfume, Petropols, wollastonite in powder, Calcium Carbonate and pigment knead 4min after being mixed and heated to 55 DEG C, are subsequently adding plasticizer two pungent
Fat kneads 3min, adds the paraffin of formula ratio, oleamide, antioxidant mixing 2min；It is eventually adding glass microballoon and stone
Sand is kneaded, and releases mixture when temperature is 85 DEG C；Obtain reflecting marking band base material.
Embodiment 5
Reflecting marking band base material is made reflecting marking band to comprise the following steps：
Pressing mold, feeds the mixture into extruder, after softening, enters back in mould, thereon at 90 DEG C～140 DEG C
It is put into the molded substrate that grid enhancement layer is pressed into required width and thickness using pressure roller；
Upper reflecting coating, is uniformly coated with reflecting coating, reflective surface glue 3 part of the reflecting coating by yellow on molded substrate surface
Mix with 2 parts of cross-linking agent.Then the reflective glass beads of 40 mesh uniform embedding system is warming up to into 70 DEG C on reflecting coating surface
Dry solidification, makes reflecting sheet material afterwards；
Isolation, in the bottom surface coated with adhesive of reflecting sheet material, and is isolated using isolated material；
Cut out, reflecting sheet material is cut into into predetermined required form.
The reflecting marking band by made by the raw material of 1～embodiment of embodiment 4 is tested,.By CNS GB/
T 7125-1999 and GB 7753-1987 test the gross thickness and longitudinal tensile strength of the reflective adhesive tape, by Ministry of Communications of China
The method of industry standard JT/T 493-2003 that customization is ordered, with FB-94 type reflex reflection ability meters, (test condition is：Observation
1.05 ° of angle, 86.5 ° of angle of incidence) test the retro-reflecting coefficient (unit of the reflective adhesive tape：mcd/x-1/m-1).Observation test knot
Fruit is listed in table 1：
Table 1：The reflecting marking band inspection result of 1～embodiment of embodiment 4
Claims (12)
1. a kind of reflecting marking band base material, including following components：
Styrene butadiene styrene block copolymer (SBS) SBS8～15 part；
Ethylene-vinyl acetate copolymer EVA2～6 part；5～10 parts of quartz sand；
7～12 parts of Colophonium；3～6 parts of Petropols；30～50 parts of wollastonite in powder；20～40 parts of Calcium Carbonate；
1～8 part of pigment；2～5 parts of plasticizer；1～2 part of paraffin；8～15 parts of glass microballoon.
2. base material as claimed in claim 1, it is characterised in that：Also include 0～1 part of oleamide, 0～1 part of antioxidant.
3. base material as claimed in claim 1, it is characterised in that：The fineness of the glass microballoon is more than 80 mesh.
4. base material as claimed in claim 1, it is characterised in that：The plasticizer is dibutyl ester.
5. the method for preparing base material described in claim 1, comprises the following steps：
By styrene butadiene styrene block copolymer (SBS) SBS of formula ratio, ethylene-vinyl acetate copolymer EVE, Colophonium,
Knead after Petropols, wollastonite in powder, Calcium Carbonate and pigment Hybrid Heating, be subsequently adding plasticizer, paraffin, glass microballoon and stone
Sand is kneaded.
6. preparation method as claimed in claim 5, it is characterised in that：Comprise the following steps
By styrene butadiene styrene block copolymer (SBS) SBS of formula ratio, ethylene-vinyl acetate copolymer EVE, Colophonium,
Petropols, wollastonite in powder, Calcium Carbonate and pigment knead 3min～10min after being mixed and heated to 40 DEG C～60 DEG C, are subsequently adding
Plasticizer kneads 1min～3min, adds the paraffin mixing 2min～3min of formula ratio；It is eventually adding glass microballoon and quartz
Sand is kneaded, and releases mixture when temperature is 70 DEG C～90 DEG C.
7. preparation method as claimed in claim 5, it is characterised in that：In the step of adding paraffin, while adding Oleic acid
Amide and antioxidant.
8. the method for preparing reflecting marking band, comprises the following steps：
Mixing, by styrene butadiene styrene block copolymer (SBS) SBS of formula ratio, ethylene-vinyl acetate copolymer EVE,
Knead after Colophonium, Petropols, wollastonite in powder, Calcium Carbonate and pigment Hybrid Heating, be subsequently adding plasticizer, paraffin, glass micro-
Mixture is released after pearl and quartz sand mixing；
Pressing mold, it is compressing in feeding mould after mixture is softened, obtain molded substrate；
Upper reflecting coating, is uniformly coated with reflecting coating on molded substrate surface, then by reflective glass beads uniform embedding system anti-
Light coating surface, makes reflecting sheet material after intensification dry solidification；
Isolation, in the bottom surface coated with adhesive of reflecting sheet material, and is isolated using isolated material；
Cut out, reflecting sheet material is cut into into predetermined required form.
9. method as claimed in claim 8, it is characterised in that：In the step of adding paraffin, while adding oleamide
And antioxidant.
10. method as claimed in claim 8, it is characterised in that：
The molding process after softening at 90 DEG C～140 DEG C, enters back into shaping mould specifically, feed the mixture into extruder
In tool, the molded substrate that grid enhancement layer is pressed into required width and thickness using pressure roller is put into thereon；
The dry solidification temperature of the upper reflecting coating operation is 60 DEG C～80 DEG C.
11. methods as claimed in claim 8, it is characterised in that：The reflecting coating is by 2～4 parts of reflective surface glue and cross-linking agent 1
～2 parts of compositions.
12. methods as claimed in claim 11, it is characterised in that：The reflective surface glue is colored paint, and cross-linking agent is polyester
Amine cross-linking agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510150174.0A CN104710720B (en) | 2015-03-31 | 2015-03-31 | A kind of reflecting marking is with base material and base material, the manufacture method of reflecting marking band |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510150174.0A CN104710720B (en) | 2015-03-31 | 2015-03-31 | A kind of reflecting marking is with base material and base material, the manufacture method of reflecting marking band |
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| CN104710720A CN104710720A (en) | 2015-06-17 |
| CN104710720B true CN104710720B (en) | 2017-03-29 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3981833A1 (en) * | 2020-10-12 | 2022-04-13 | Kraton Polymers Research B.V. | Roadway surface compositions and pelletized binder materials thereof |
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| CN107162471A (en) * | 2016-12-23 | 2017-09-15 | 惠州兴鑫涂料化工有限公司 | A kind of pavement antiskid paint |
| US10801168B2 (en) * | 2017-08-16 | 2020-10-13 | Kraton Polymers Llc | Pelletized road marking binders and related methods |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078280A (en) * | 1992-05-04 | 1993-11-10 | 明尼苏达州采矿制造公司 | Conformable pavement marking tape |
| CN1133316A (en) * | 1996-01-29 | 1996-10-16 | 郑振乾 | Light reflection sign for road and adhesion agent preparation method |
| CN1167185A (en) * | 1996-06-05 | 1997-12-10 | 严翠华 | Adhesive stick type long-effect light-reflection material for sign on road surface |
| CN1260272A (en) * | 2000-01-27 | 2000-07-19 | 丁关金 | Roadway marking strip reflective sticking film coiled material |
-
2015
- 2015-03-31 CN CN201510150174.0A patent/CN104710720B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078280A (en) * | 1992-05-04 | 1993-11-10 | 明尼苏达州采矿制造公司 | Conformable pavement marking tape |
| CN1133316A (en) * | 1996-01-29 | 1996-10-16 | 郑振乾 | Light reflection sign for road and adhesion agent preparation method |
| CN1167185A (en) * | 1996-06-05 | 1997-12-10 | 严翠华 | Adhesive stick type long-effect light-reflection material for sign on road surface |
| CN1260272A (en) * | 2000-01-27 | 2000-07-19 | 丁关金 | Roadway marking strip reflective sticking film coiled material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3981833A1 (en) * | 2020-10-12 | 2022-04-13 | Kraton Polymers Research B.V. | Roadway surface compositions and pelletized binder materials thereof |
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| Publication number | Publication date |
|---|---|
| CN104710720A (en) | 2015-06-17 |
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