CN113274302B - Composition, safe and refreshing cleansing water and preparation method thereof - Google Patents

Composition, safe and refreshing cleansing water and preparation method thereof Download PDF

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Publication number
CN113274302B
CN113274302B CN202110765745.7A CN202110765745A CN113274302B CN 113274302 B CN113274302 B CN 113274302B CN 202110765745 A CN202110765745 A CN 202110765745A CN 113274302 B CN113274302 B CN 113274302B
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safe
composition
refreshing
cleansing water
parts
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CN113274302A (en
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何益飞
刘倩
刘俏苑
麦庆梅
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Guangzhou Jiyan Cosmetics Technology Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/005Preparations for sensitive skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/008Preparations for oily skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • A61K2800/5922At least two compounds being classified in the same subclass of A61K8/18

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  • Cosmetics (AREA)

Abstract

The application belongs to the technical field of cosmetics, and particularly relates to a composition, safe and refreshing cleansing water and a preparation method thereof. The present application provides a composition comprising: C9-C12 alkanes, C13-C15 alkanes, and coco-caprylate/caprate; the mass ratio of the C9-C12 alkane, the C13-C15 alkane and the coco-caprylate/caprate is (10-18): (1-5): (1-5). The composition can improve the cleaning property and the makeup removing ability of the makeup removing product. Therefore, the composition, the safe and refreshing cleansing water and the preparation method thereof can replace the composition of D5, and can effectively solve the technical problems of low refreshing degree, high irritation and weak cleaning force of the existing cleansing products.

Description

Composition, safe and refreshing cleansing water and preparation method thereof
Technical Field
The application belongs to the technical field of cosmetics, and particularly relates to a composition, safe and refreshing cleansing water and a preparation method thereof.
Background
Cyclopenta-polydimethylsiloxane compound (D5), which can bring dry and silky skin feel to the skin based on lower heat of vaporization and vapor pressure, is a makeup removing solvent frequently used in cosmetics, especially color cosmetic products. Research shows that D5 has potential bioaccumulation, the biological enrichment factor (BCF) of the D5 reaches 7060, the D5 can be accumulated in organisms after long-term use to generate a series of safety problems, and the risk of environmental pollution can be increased after the D5-containing cosmetics are washed with water after long-term use. Therefore, in view of safety, a group of D5 alternatives is needed to reduce the harm to human body and environment.
Disclosure of Invention
In view of the above, the present application aims to provide a composition and a safe and refreshing cleansing water and a preparation method thereof, and provides a composition which can replace D5 and can be used in a cleansing product to improve the cleansing property and cleansing power of the cleansing product.
The present application provides in a first aspect a composition comprising:
C9-C12 alkanes, C13-C15 alkanes, and coco-caprylate/caprate.
A composition according to the present application, wherein the mass ratio of the C9-C12 alkane, the C13-C15 alkane and the coco-caprylate/caprate is (10 to 18): (1~5): (1~5).
The application in a second aspect discloses the use of the composition for the preparation of a make-up removal product.
In a third aspect, the present application provides a safe and refreshing cleansing water comprising the composition.
In particular, the safe and refreshing cleansing water can be used for cleansing eyes, lips and faces.
The safe and refreshing makeup remover according to the application comprises 9-32 mass% of the composition in the safe and refreshing makeup remover.
A safe and refreshing cleansing water according to the application, wherein the mass content of the composition in the safe and refreshing cleansing water is 12-28 mass%.
The safe and refreshing cleansing water further comprises one or more of a humectant, a surfactant, a thickening agent, a bactericide and a pH regulator.
The safe and refreshing cleansing water comprises the following components in parts by mass based on 100 parts by mass of the total mass of the safe and refreshing cleansing water:
10 to 18 parts of C9-C12 alkane, 3238 parts of C13-C15 alkane, 3238 parts of zxft, 3262 parts of coconut oil alcohol-caprylate/caprate, 3262 parts of zxft, 0.2 to 1.7 parts of humectant, 0.1 to 1.0 part of surfactant, 0.1 to 1 part of thickener, 0.1 to 0.7 part of bactericide, 0.02 to 0.14 part of pH regulator and the balance of solvent.
The safe and refreshing cleansing water comprises the following components in parts by mass based on 100 parts by mass of the total mass of the safe and refreshing cleansing water:
16 parts of C9-C12 alkane, 2 parts of C13-C15 alkane, 2 parts of coconut oil alcohol-caprylate/caprate, 0.7 part of humectant, 0.3 part of surfactant, 0.6 part of thickener, 0.2 part of bactericide, 0.06 part of pH regulator and the balance of solvent.
A safe and refreshing cleansing water according to the application, wherein the surfactant is decyl glucoside; the humectant is panthenol and/or 1,2-hexanediol; the thickening agent is sodium chloride; the bactericide is polyhexamethylene biguanide; the pH regulator is sodium dihydrogen phosphate and/or sodium phosphate; the solvent is water.
The fourth aspect of the application provides a preparation method of safe and refreshing cleansing water, which comprises the following steps:
s1: mixing a humectant, a surfactant, a thickener, a bactericide, a pH regulator and a solvent, and heating to obtain a phase A;
s2: mixing C9-C12 alkane, C13-C15 alkane and coconut oil alcohol-caprylate/caprate to obtain phase B;
s3: and adding the phase B into the phase A, mixing, cooling and discharging to obtain the safe and refreshing cleansing water.
The preparation method of the safe and refreshing cleansing water comprises the following steps of (1) preparing a cleansing water, wherein the surfactant is decyl glucoside; the humectant is panthenol and/or 1,2-hexanediol; the thickening agent is sodium chloride; the bactericide is polyhexamethylene biguanide; the pH regulator is sodium dihydrogen phosphate and/or sodium phosphate; the solvent is water.
Compared with the prior art, the application has the following advantages and effects:
in the application, C9-C12 alkane, C13-C15 alkane and coco-caprylate/caprate are used in a matching way to have a synergistic effect, can be used as a group of D5 substitutes, and has high biological safety. The composition can be used for preparing makeup removing products, particularly the makeup removing products for eyes and lips, can effectively remove various grease on the inner surface and the outer surface of the skin, also can prevent the loss of skin moisture, and has the characteristics of refreshing, strong makeup removing capability, mildness and no irritation.
Drawings
In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below.
FIG. 1 is a graph showing the comparative effect of the products of example 1 and comparative examples 4 and 5 on the makeup dissolving effect of lip glaze;
fig. 2 is a comparative graph of makeup dissolving effect of the products of examples 1 and 4, 5 of the present application on mascara.
Detailed Description
The application provides a composition, safe and refreshing cleansing water and a preparation method thereof, which are used for solving the technical defects of low refreshing degree, high irritation and weak cleaning force of the existing cosmetic products in the prior art.
The technical solutions in the embodiments of the present application will be described clearly and completely below, and it should be understood that the described embodiments are only a part of the embodiments of the present application, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.
The present application provides in a first aspect a composition comprising:
C9-C12 alkanes, C13-C15 alkanes, and coco-caprylate/caprate.
In the application, the C9-C12 alkane is a light alkane, has the advantages of good spreadability, large contact area and biological safety, and can be fully diffused and volatilized on the skin. On one hand, the cleaning agent can be well compatible with various oils and fats, including coconut oil alcohol-caprylate/caprate, and the coconut oil alcohol-caprylate/caprate has a good dissolving effect on the crystal form sunscreen agent, so that the cleaning effect of the coconut oil alcohol-caprylate/caprate on the sunscreen product is promoted; on the other hand, the cleaning agent has good dissolving capacity on various toner, so that the cleaning agent has good cleaning effect on lip makeup, eye makeup and base makeup products containing more toner; in addition, the skin-care agent has extremely low boiling point, so that the skin-care agent can bring refreshing skin feeling to the skin; the C13-C15 alkane is environment-friendly and easy to degrade, can be prepared by a green process based on natural oil, has light weight, good spreadability and high boiling point, can relieve the drying discomfort of the skin caused by the volatilization of the C9-C12 alkane, and can bring the silky skin feeling to the skin when being matched with the C9-C12 alkane. The coco oil alcohol-caprylate/caprate is 100% of natural renewable resources, is easy to biodegrade, can be used as an emollient, can bring fresh skin feeling to the skin by being matched with C9-C12 alkane and C13-C15 alkane, and has excellent cleaning capability.
Specifically, the surfactant is decyl glucoside.
Specifically, the humectant is panthenol and 1,2-hexanediol.
Specifically, the thickener is sodium chloride.
Specifically, the bactericide is polyhexamethylene biguanide.
Specifically, the pH regulator is sodium dihydrogen phosphate and sodium phosphate.
Specifically, the solvent is water.
The raw materials and reagents used in the following examples are commercially available or self-made.
The C9-C12 alkanes of the following examples were purchased from Kelain chemical (China) Co., ltd under the product name Plantasens Flash 80.
The C13-C15 alkanes of the following examples were purchased from Kelain chemical (China) Co., ltd under the product name Plantasens Flash 100.
Cocoanol-caprylate/caprate of the following examples was purchased from Leibokang daily chemical (Shanghai) Inc. under the trade name Liponate ™ CCC MB.
The components are not limited to the specific commodities, and the same products produced by other companies can be used, and can be prepared and used according to the specifications of the commodities.
Example 1~7
The embodiment of the application provides a preparation method of various safe and refreshing cleansing water, which specifically comprises the following steps:
the safe and refreshing cleansing water of the embodiment 1-the embodiment 7 is prepared according to the formula (in parts by mass) of the table 1, and the specific steps comprise:
in the embodiment, the formula of the product in the embodiment 1 is as follows, wherein the total mass of the cleansing water is 100 parts by mass:
78.14 parts of water, 0.20 part of panthenol, 0.60 part of sodium chloride, 0.04 part of sodium dihydrogen phosphate, 0.02 part of sodium phosphate, 0.30 part of decyl glucoside, 0.20 part of polyhexamethylene biguanide, 0.50 part of 1,2-hexanediol, 2.00 parts of coco caprylate/caprate, 16.00 parts of C9-C12 alkane and 2.00 parts of C13-C15 alkane.
The preparation of the product of example 1 is as follows:
the method comprises the following steps: mixing and stirring panthenol, sodium chloride, sodium dihydrogen phosphate, sodium phosphate, decyl glucoside, polyhexamethylene biguanide and 1,2-hexanediol in water uniformly, heating to 85 ℃, and keeping the temperature for 5min to obtain a phase A;
step two: premixing C9-C12 alkane, C13-C15 alkane and coconut oil alcohol-caprylate/caprate uniformly to obtain phase B;
step three: adding the phase B into the phase A, stirring uniformly, cooling to 25 ℃, and discharging to obtain the safe and refreshing cleansing water.
The product of example 2~7 was prepared by reference to the preparation of example 1 except the amounts of the components were used. It can be seen that the content of the composition in example 1 was 20 mass%, the content of the composition in example 2 was 12 mass%, the content of the composition in example 3 was 28 mass%, the content of the composition in example 4 was 25 mass%, the content of the composition in example 5 was 16 mass%, the content of the composition in example 6 was 9 mass%, and the content of the composition in example 7 was 32 mass%. The amounts of the respective components in table 1 are each expressed in% by mass of each in makeup remover.
TABLE 1
Figure DEST_PATH_IMAGE001
Figure 643994DEST_PATH_IMAGE002
Comparative example 1~5
The product of comparative example 1~4 was prepared with reference to the preparation of example 1 except that comparative example 1 replaced coco-caprylate/caprate with glyceryl behenate/eicosanoate; comparative example 2 replacement of C9-C12 alkanes with isomeric hexadecanes; comparative example 3 palm oil was used instead of C13-15 alkanes; comparative example 4 a composition consisting of C9-C12 alkanes, C13-C15 alkanes and coco-caprylate/caprate was replaced with cyclopentadimethylsiloxane. Comparative example 5 a perfect diary amino acid instantaneous clear eye-lip makeup remover was used.
Test example 1
The application test example provides the sensory performance tests of the products of examples 1 to 7 and comparative examples 1 to 5, wherein the sensory performance tests comprise the freshness, the irritation and the cleaning power, and the specific method comprises the following steps:
50 women, aged 30 + -10 years, were selected by first applying the same amount of lip glaze product to the lips and the same amount of mascara product to the eyes, and then adding the same amount of make-up remover product of example 1~7 and comparative example 1~5 to the make-up remover cotton. The testers evaluated the skin feel and effect according to the makeup removal process and the makeup removed. The testers scored according to the scoring criteria and finally counted all the scores to calculate the average, and the results of the cleanability, irritation and clean-ability scores of the products of example 1~7 and comparative example 1~5 are shown in table 2.
The scoring criteria were as follows:
refreshing degree: 1 minute: the eyes are greasy and are blurred, and the eyes cannot be opened; and 2, dividing: the eye-paste degree is acceptable due to some greasy; and 3, dividing: in the later stage, the skin is somewhat greasy but not sticky to the eyes; and 4, dividing: the product is relatively fresh and cool; and 5, dividing: it is very fresh and cool.
Irritation: 1 minute: very irritating, eyes are hot, and the mouth is very painful after the mouth is removed; and 2, dividing: irritation, some eye irritation, but acceptable levels; and 3, dividing: no stimulation is carried out; and 4, dividing: the temperature is relatively mild; and 5, dividing: is very mild.
Cleaning force: 1 minute: a difference; and 2, dividing: poor performance; and 3, dividing: generally; and 4, dividing: better; and 5, dividing: good results are obtained.
TABLE 2 product freshness, irritation and clean force scores for example 1~7 and comparative example 1~5
Figure DEST_PATH_IMAGE003
Table 2 shows that the product of example 1~7 has a higher freshness, irritation and cleaning score; in the case of the same total amount of the composition, compared to the product prepared in example 1, the product has different degrees of defects in the freshness, irritation and cleaning power after the coconut oil alcohol-caprylate/caprate is replaced by glyceryl behenate/eicosanoate in comparative example 1, C9-C12 alkane is replaced by isomeric hexadecane in comparative example 2, C13-C15 alkane is replaced by palm oil in comparative example 3, and all the composition components are replaced by cyclopentasimethicone in comparative example 4.
Comparative example 5 is a commercially available perfect diary amino acid instantaneous cleansing lip makeup remover, which does not contain any component of the composition, and does not have the same refreshing degree, irritation and cleansing power performance as those of example 1 after use, compared to example 1.
Test example 2
The test examples of the application provide the effects of the products of the above examples 1 to 7 and comparative examples 1 to 5, including the degree of cleanliness and the makeup dissolving effect. The test method is as follows:
(1) 50 women were selected, age 30 + -10 years. Firstly, respectively smearing lipstick and mascara on the inner side of an arm, and measuring an initial color value by using a spectrophotometer after the product is aired for 15 minutes;
(2) Respectively taking equivalent products of example 1~7 and comparative example 1~5 from the makeup removing cotton, applying the products to an area where the makeup product is applied, and lifting the products after waiting for 15 seconds;
(3) Continuing waiting for 15 minutes, waiting for the makeup removing product of arm to remain to dry, measuring the color value with the color difference meter, and calculating the difference average value of the two color values measured by the color difference meter. As shown in fig. 1 and fig. 2, fig. 1 is a comparison graph of the makeup dissolving effect of the products of example 1 and comparative examples 4 and 5 on lip glaze; fig. 2 is a comparative graph of makeup dissolving effect of the products of example 1 and comparative examples 4 and 5 of the present application on mascara.
The results of the cleanliness tests for the products of example 1~7 and comparative example 1~5 are shown in table 3 (p < 0.001), where the Δ L values represent the difference in skin lightening before and after makeup removal, with a greater measurement indicating a brighter skin tone and more complete makeup removal; the value of delta a indicates the red-green value of the skin color, the smaller the measured value is, the skin color is not red, the more red the skin is stimulated, and the smaller the value of delta a is, the less stimulation is. The makeup dissolving effect of the products obtained in example 1 and comparative example 4~5 are shown in fig. 1 and 2.
TABLE 3 cleanliness test results for the products of example 1~7 and comparative example 1~5
Figure 436500DEST_PATH_IMAGE004
Table 3 shows that the example 1~7 product has both high cleaning power and low irritation. The increase in skin whiteness and decrease in skin color red-green value after application were lower for the comparative example 1~5 product than for example 1~7, indicating that the product of example 1 had greater cleaning intensity and less irritation after application.
Fig. 1-2 show that, compared with example 1, the product prepared by only adopting cyclopentasiloxane in comparative example 4 has no makeup dissolving effect, the product sold in comparative example 5 has poor makeup dissolving effect, and the composition with a specific content has stronger cleaning effect when being used for a makeup removing product.
The above experimental results show that the composition of the application can bring fresh skin feeling to the skin and has excellent cleaning ability by using the C9-C12 alkane, the C13-C15 alkane and the coconut oil alcohol-caprylate/caprate in a specific amount, has high biological safety, can effectively remove various oils in and on the skin and prevent the loss of skin moisture, and has the characteristics of being fresh, strong in makeup removing force, mild and non-irritating.
In summary, the present application provides a composition and a safe and refreshing cleansing water and a preparation method thereof. The composition consists of C9-C12 alkane, C13-C15 alkane and coconut oil alcohol-caprylate/caprate, wherein the C9-C12 alkane has the advantages of good spreadability, large contact area and biological safety, the C13-C15 alkane can relieve the drying discomfort brought by the volatilization of the C9-C12 alkane to the skin, the coconut oil alcohol-caprylate/caprate can be used as an emollient, the three can bring fresh skin feeling to the skin by matching, the excellent cleaning capability is realized, the composition can be used as a group of D5 substitutes, and the biological safety is higher. The composition can be used for preparing makeup removing products, particularly the makeup removing products for eyes and lips, can effectively remove various grease on the inner surface and the outer surface of the skin, also can prevent the loss of skin moisture, and has the characteristics of refreshing, strong makeup removing capability, mildness and no irritation.
The foregoing is only a preferred embodiment of the present application and it should be noted that those skilled in the art can make several improvements and modifications without departing from the principle of the present application, and these improvements and modifications should also be considered as the protection scope of the present application.

Claims (11)

1. A composition, comprising:
dodecane, a mixture of tridecane and pentadecane, coco-octanoate/decanoate;
the mass ratio of said dodecane, said mixture of tridecane and pentadecane, said coconut oil alcohol-octanoate/decanoate is (10 to 18): (1~5): (1~5).
2. Use of the composition of claim 1 for the preparation of a make-up removal product.
3. A safe and refreshing cleansing water comprising the composition of claim 1.
4. The safe and refreshing cleansing water according to claim 3, wherein the mass content of the composition in the safe and refreshing cleansing water is from 9 to 32 mass%.
5. The safe and refreshing cleansing water according to claim 4, wherein the composition is contained in the safe and refreshing cleansing water in an amount of 12 to 28% by mass.
6. The safe and refreshing makeup remover according to any of claims 3~5, further comprising one or more of a humectant, a surfactant, a thickener, a bactericide, and a pH adjuster.
7. The safe and refreshing cleansing water according to claim 6, which is characterized by comprising the following components in parts by mass based on 100 parts by mass of the total mass of the safe and refreshing cleansing water:
10 to 18 parts of dodecane, 1~5 parts of a mixture of tridecane and pentadecane, 1~5 parts of coconut oil alcohol-caprylate/caprate, 0.2 to 1.7 parts of a humectant, 0.1 to 1.0 part of a surfactant, 0.1 to 1 part of a thickener, 0.1 to 0.7 part of a bactericide, 0.02 to 0.14 part of a pH regulator and the balance of a solvent.
8. The safe and refreshing cleansing water according to claim 7, which is characterized by comprising the following components in parts by mass based on 100 parts by mass of the total mass of the safe and refreshing cleansing water:
16 parts of dodecane, 2 parts of a mixture of tridecane and pentadecane, 2 parts of coconut oil alcohol-caprylate/caprate, 0.7 part of humectant, 0.3 part of surfactant, 0.6 part of thickener, 0.2 part of bactericide, 0.06 part of pH regulator and the balance of solvent.
9. The safe and refreshing cleansing water according to claim 7 or 8, wherein the surfactant is decyl glucoside; the humectant is panthenol and/or 1,2-hexanediol; the thickening agent is sodium chloride; the bactericide is polyhexamethylene biguanide; the pH regulator is sodium dihydrogen phosphate and/or sodium phosphate; the solvent is water.
10. A method for preparing a safe and refreshing cleansing water according to any one of claims 3 to 9, comprising the steps of:
step S1: mixing a humectant, a surfactant, a thickener, a bactericide, a pH regulator and a solvent, and heating to obtain a phase A;
step S2: mixing dodecane, a mixture of tridecane and pentadecane, coco-caprylate/caprate to obtain phase B;
and step S3: and adding the phase B into the phase A, mixing, cooling and discharging to obtain the safe and refreshing cleansing water.
11. The method of claim 10, wherein the surfactant is decyl glucoside; the humectant is panthenol and/or 1,2-hexanediol; the thickening agent is sodium chloride; the bactericide is polyhexamethylene biguanide; the pH regulator is sodium dihydrogen phosphate and/or sodium phosphate; the solvent is water.
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CN107648073A (en) * 2017-11-10 2018-02-02 广州神采化妆品有限公司 A kind of gentle oil-containing makeup removing foam
CN107693386A (en) * 2017-10-20 2018-02-16 广州神采化妆品有限公司 A kind of man's composite skin care product and its application
CN107929086A (en) * 2017-11-22 2018-04-20 珀莱雅化妆品股份有限公司 One kind shakes thickening type bilayer make up remover and preparation method thereof
CN107982086A (en) * 2017-12-08 2018-05-04 广州环亚化妆品科技有限公司 One kind makeup removing gel and preparation method thereof
CN109789062A (en) * 2016-10-11 2019-05-21 阿佐罗Ag·艾诺尼亚 Cosmetics water-in-oil microemulsion

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CN108030764B (en) * 2017-12-28 2020-11-24 花安堂生物科技集团有限公司 Double-layer cleansing lotion and preparation method thereof
CN110420152B (en) * 2019-08-20 2022-09-13 中山中研化妆品有限公司 Refreshing and mild double-layer cleansing lotion and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101780017A (en) * 2010-02-26 2010-07-21 杨北平 Mild cosmetic composite
CN109789062A (en) * 2016-10-11 2019-05-21 阿佐罗Ag·艾诺尼亚 Cosmetics water-in-oil microemulsion
CN107693386A (en) * 2017-10-20 2018-02-16 广州神采化妆品有限公司 A kind of man's composite skin care product and its application
CN107648073A (en) * 2017-11-10 2018-02-02 广州神采化妆品有限公司 A kind of gentle oil-containing makeup removing foam
CN107929086A (en) * 2017-11-22 2018-04-20 珀莱雅化妆品股份有限公司 One kind shakes thickening type bilayer make up remover and preparation method thereof
CN107982086A (en) * 2017-12-08 2018-05-04 广州环亚化妆品科技有限公司 One kind makeup removing gel and preparation method thereof

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