CN113248994A - Real stone paint and preparation method thereof - Google Patents
Real stone paint and preparation method thereof Download PDFInfo
- Publication number
- CN113248994A CN113248994A CN202110685074.3A CN202110685074A CN113248994A CN 113248994 A CN113248994 A CN 113248994A CN 202110685074 A CN202110685074 A CN 202110685074A CN 113248994 A CN113248994 A CN 113248994A
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- stone
- paint
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a stone-like paint which is prepared from the following raw materials in percentage by weight: 65-75% of natural colored sand, 12-18% of polyacrylic acid, 0.1-0.3% of chloromethyl isothiazolinone, 0.15-0.25% of modified hydroxyethyl cellulose, 0.4-0.6% of propylene glycol, 0.05-0.15% of pH regulator, 0.15-0.25% of sodium carboxylate, 0.02-0.04% of polyoxyethylene-polyacrylamide ether, 0.4-0.6% of mildew preventive and the balance of water. Meanwhile, the invention provides a preparation method of the stone-like paint, and the stone-like paint prepared by the method has excellent weather resistance.
Description
Technical Field
The invention relates to the technical field of paint, in particular to real stone paint and a preparation method thereof.
Background
The stone-like paint has decorative effect similar to that of marble and granite. It is mainly made up by using natural stone powder with various colours, and can be used for imitating stone effect of external wall of building, so that it is also called liquid stone.
The building decorated by the stone paint has natural and real natural color, gives people elegant, harmonious and solemn aesthetic feeling, and is suitable for indoor and outdoor decoration of various buildings. Especially, the decoration on the curved surface building is vivid and lifelike, and has an effect of returning to nature. The stone-like paint has the features of fire prevention, water resistance, acid and alkali resistance, pollution resistance, no toxicity, no smell, strong adhesion, fastness and the like, and can effectively prevent the corrosion of the external severe environment to the building and prolong the service life of the building.
The existing stone-like paints on the market are various in types, but the acid-base resistance and the weather resistance are generally poor.
Disclosure of Invention
In order to solve the technical problems, the invention provides the stone-like paint and the preparation method thereof, and the stone-like paint prepared by the invention has better weather resistance.
The stone-like paint comprises the following raw materials in percentage by weight:
65-75 parts of natural color sand
Polyacrylic acid 12-18
Chloromethyl isothiazolinone 0.1-0.3
0.15-0.25 of modified hydroxyethyl cellulose
0.4-0.6 parts of propylene glycol
pH regulator 0.05-0.15
Sodium carboxylate 0.15-0.25
Polyoxyethylene-poly (propanol amine ether) 0.02-0.04
0.4-0.6 of mildew preventive
The balance being water.
Further, the mildew preventive comprises the following raw materials in parts by weight: 1.5 parts of dioctyl sodium sulfosuccinate, 1.5 parts of alkyl glycoside and 2 parts of dodecyl dimethyl hydroxypropyl dodecyl ammonium chloride.
Further, the pH regulator is NaOH with the mass concentration of 10%.
Further, the sodium carboxylate is sodium polycarboxylate.
Further, the percentage content of each raw material is as follows:
natural color sand 70
Polyacrylic acid 15
Chloromethyl isothiazolinone 0.2
Modified hydroxyethyl cellulose 0.18
Propylene glycol 0.5
pH regulator 0.1
Sodium carboxylates 0.2
Polyoxyethylene Polyoxypropylamine Ether 0.03
Mildew preventive 0.5
The balance being water.
The invention also provides a preparation method of the stone-like paint, which comprises the following specific steps: mixing polyacrylic acid, modified hydroxypropyl cellulose and water, adding the raw materials except the natural color stone, mixing, adding the natural color stone, and mixing.
In conclusion, polyacrylic acid and modified hydroxyethyl cellulose are adopted to react to form a resin film, then a dispersing agent mildew inhibitor and other auxiliaries are added, and natural colored stone is added, so that the prepared stone-like paint has excellent weather resistance.
Detailed Description
The present invention will be described in further detail with reference to examples.
Example 1
The preparation method comprises the steps of uniformly mixing 18kg of polyacrylic acid, 0.25kg of modified hydroxypropyl cellulose and 15.51kg of water, adding 0.1kg of chloromethyl isothiazolinone, 0.4kg of propylene glycol, 0.15kg of sodium carboxylate, 0.04kg of polyoxyethylene-polyoxypropylene ether and 0.4kg of mildew preventive, uniformly mixing, adjusting the pH value by using 0.15kg of pH regulator, adding 65kg of natural color stone, and uniformly mixing.
The mildew preventive comprises the following raw materials in parts by weight: 2 parts of dioctyl sodium sulfosuccinate, 2 parts of alkyl glycoside and 3 parts of dodecyl dimethyl hydroxypropyl dodecyl glucoside ammonium chloride. The pH regulator is NaOH with the mass concentration of 10%. The sodium carboxylate is sodium polycarboxylate.
Example 2
The preparation method comprises the steps of uniformly mixing 12kg of polyacrylic acid, 0.15kg of modified hydroxypropyl cellulose and 11.03kg of water, adding 0.3kg of chloromethyl isothiazolinone, 0.6kg of propylene glycol, 0.25kg of sodium carboxylate, 0.02kg of polyoxyethylene-polyoxypropylene ether and 0.6kg of mildew preventive, uniformly mixing, adjusting the pH value by using 0.05kg of pH regulator, adding 75kg of natural color stone, and uniformly mixing.
The mildew preventive comprises the following raw materials in parts by weight: 2 parts of dioctyl sodium sulfosuccinate, 2 parts of alkyl glycoside and 3 parts of dodecyl dimethyl hydroxypropyl dodecyl glucoside ammonium chloride. The pH regulator is NaOH with the mass concentration of 10%. The sodium carboxylate is sodium polycarboxylate.
Example 3
Taking 15kg of polyacrylic acid, 0.2kg of modified hydroxypropyl cellulose and 13.27kg of water, uniformly mixing, adding 0.2kg of chloromethyl isothiazolinone, 0.5kg of propylene glycol, 0.2kg of sodium carboxylate, 0.03kg of polyoxyethylene-polyallylamine ether and 0.5kg of mildew preventive, uniformly mixing, adjusting the pH value by using 0.1kg of pH regulator, adding 65kg of natural color stone, and uniformly mixing.
The mildew preventive comprises the following raw materials in parts by weight: 2 parts of dioctyl sodium sulfosuccinate, 2 parts of alkyl glycoside and 3 parts of dodecyl dimethyl hydroxypropyl dodecyl glucoside ammonium chloride. The pH regulator is NaOH with the mass concentration of 10%. The sodium carboxylate is sodium polycarboxylate.
Effect test
The products prepared in examples 1 to 3 were tested, and the specific test results are shown in the following table:
as can be seen from the above examples, the stone-like paint prepared by the invention has excellent stain resistance, weather resistance, strength and other properties.
The present embodiment is only for explaining the present invention, and it is not limited to the present invention, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present invention.
Claims (6)
1. The stone-like paint is characterized by comprising the following raw materials in percentage by weight:
65-75 parts of natural color sand
Polyacrylic acid 12-18
Chloromethyl isothiazolinone 0.1-0.3
0.15-0.25 of modified hydroxyethyl cellulose
0.4-0.6 parts of propylene glycol
pH regulator 0.05-0.15
Sodium carboxylate 0.15-0.25
Polyoxyethylene-poly (propanol amine ether) 0.02-0.04
0.4-0.6 of mildew preventive
The balance being water.
2. The stone-like paint as claimed in claim 1, wherein the mildew preventive comprises the following raw materials in parts by weight: 2 parts of dioctyl sodium sulfosuccinate, 2 parts of alkyl glycoside and 3 parts of dodecyl dimethyl hydroxypropyl dodecyl glucoside ammonium chloride.
3. The stone-like paint as claimed in claim 1, wherein the pH regulator is NaOH with a mass concentration of 10%.
4. The stone-like paint as claimed in claim 1, wherein the sodium carboxylate is a sodium polycarboxylate.
5. The stone-like paint as claimed in claim 1, wherein the percentage of each raw material is as follows:
natural color sand 70
Polyacrylic acid 15 (resin)
Chloromethyl isothiazolinone 0.2 (Bactericidal)
Modified hydroxyethyl cellulose 0.18 (thickening)
Propylene glycol 0.5 (stabilizer)
pH regulator 0.1
Sodium carboxylates 0.2
Polyoxyethylene Polyoxypropylamine Ether 0.03
Mildew preventive 0.5
The balance being water.
6. The preparation method of the stone-like paint according to any one of claims 1 to 6 comprises the following specific steps: mixing polyacrylic acid and modified hydroxypropyl cellulose with water, adding the raw materials except natural color stone, mixing, adding natural color stone, and mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110685074.3A CN113248994A (en) | 2021-06-21 | 2021-06-21 | Real stone paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110685074.3A CN113248994A (en) | 2021-06-21 | 2021-06-21 | Real stone paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113248994A true CN113248994A (en) | 2021-08-13 |
Family
ID=77188887
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110685074.3A Withdrawn CN113248994A (en) | 2021-06-21 | 2021-06-21 | Real stone paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113248994A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103508698A (en) * | 2012-06-28 | 2014-01-15 | 江苏紫石化工科技有限公司 | Real stone paint and preparation method thereof |
| CN104250495A (en) * | 2014-09-27 | 2014-12-31 | 安徽铁创新材料科技有限公司 | Preparation process of natural color sand really stone paint |
| CN104609772A (en) * | 2014-12-26 | 2015-05-13 | 三棵树涂料股份有限公司 | Really stone paint and preparation method thereof |
| CN104789074A (en) * | 2015-05-06 | 2015-07-22 | 武汉德美涂料股份有限公司 | Novel natural stone paint and preparation method thereof |
| CN106172434A (en) * | 2016-06-27 | 2016-12-07 | 宁德师范学院 | A kind of QIANGYI biocide mildewcide and preparation method thereof |
| CN107286784A (en) * | 2017-06-05 | 2017-10-24 | 河北晨阳工贸集团有限公司 | One kind batch scrapes true mineral varnish of sand burning and preparation method thereof |
| CN110437700A (en) * | 2019-07-30 | 2019-11-12 | 安徽富瑞雪化工科技股份有限公司 | A kind of water-base epoxy lacquer and its preparation method and application |
| CN112778819A (en) * | 2019-11-07 | 2021-05-11 | 深圳市准能新材料有限公司 | Wetting dispersant and inorganic silicate coating |
-
2021
- 2021-06-21 CN CN202110685074.3A patent/CN113248994A/en not_active Withdrawn
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103508698A (en) * | 2012-06-28 | 2014-01-15 | 江苏紫石化工科技有限公司 | Real stone paint and preparation method thereof |
| CN104250495A (en) * | 2014-09-27 | 2014-12-31 | 安徽铁创新材料科技有限公司 | Preparation process of natural color sand really stone paint |
| CN104609772A (en) * | 2014-12-26 | 2015-05-13 | 三棵树涂料股份有限公司 | Really stone paint and preparation method thereof |
| CN104789074A (en) * | 2015-05-06 | 2015-07-22 | 武汉德美涂料股份有限公司 | Novel natural stone paint and preparation method thereof |
| CN106172434A (en) * | 2016-06-27 | 2016-12-07 | 宁德师范学院 | A kind of QIANGYI biocide mildewcide and preparation method thereof |
| CN107286784A (en) * | 2017-06-05 | 2017-10-24 | 河北晨阳工贸集团有限公司 | One kind batch scrapes true mineral varnish of sand burning and preparation method thereof |
| CN110437700A (en) * | 2019-07-30 | 2019-11-12 | 安徽富瑞雪化工科技股份有限公司 | A kind of water-base epoxy lacquer and its preparation method and application |
| CN112778819A (en) * | 2019-11-07 | 2021-05-11 | 深圳市准能新材料有限公司 | Wetting dispersant and inorganic silicate coating |
Non-Patent Citations (2)
| Title |
|---|
| 吕百龄: "《实用工业助剂全书》", 31 August 2001, 化学工业出版社 * |
| 雷生山: "高耐水性硅丙真石漆乳液的研究与应用", 《现代涂料与涂装》 * |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20210813 |