CN113233764A - 仿古白绿釉料及其制备方法、仿古白绿釉陶瓷制品的制备方法 - Google Patents
仿古白绿釉料及其制备方法、仿古白绿釉陶瓷制品的制备方法 Download PDFInfo
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- 239000000919 ceramic Substances 0.000 title claims abstract description 53
- 239000000463 material Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 24
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 16
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 16
- 239000010433 feldspar Substances 0.000 claims abstract description 16
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000010453 quartz Substances 0.000 claims abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002689 soil Substances 0.000 claims abstract description 13
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 12
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052959 stibnite Inorganic materials 0.000 claims abstract description 12
- IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 12
- 239000010456 wollastonite Substances 0.000 claims abstract description 12
- 239000004575 stone Substances 0.000 claims abstract description 11
- 239000011787 zinc oxide Substances 0.000 claims abstract description 11
- 238000010438 heat treatment Methods 0.000 claims description 34
- 238000010304 firing Methods 0.000 claims description 23
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- 229910001710 laterite Inorganic materials 0.000 claims description 9
- 239000011504 laterite Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 6
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052863 mullite Inorganic materials 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 230000000052 comparative effect Effects 0.000 description 5
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- 230000007547 defect Effects 0.000 description 2
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- 239000002994 raw material Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明公开了一种仿古白绿釉料及其制备方法、仿古白绿釉陶瓷制品的制备方法，属于陶瓷技术领域。本发明的仿古白绿釉料，其特征在于，包括按照质量份数计的如下组分：高岭土70~80份，长石6~8份，石英5~7份，氧化锌2~5份，碳酸钙3~6份，辉锑矿石13~20份，硅灰石7~8份，白垩土6~9份，辉绿岩11~17份，氧化铁1~3份，麦饭石5~11份。制得仿古白绿釉陶瓷制品釉面稳定性强，强度大，具有陈旧感。
Description
技术领域
本发明属于陶瓷技术领域，具体涉及一种仿古白绿釉料及其制备方法、仿古白绿釉陶瓷制品的制备方法。
背景技术
陶瓷制品，在我国已经是家家必备的物品，无论是餐具还是工艺品，已经是随处可见了。然而，无论是餐具还是工艺品，现在大多数产品都是比较光鲜艳丽、创新的陶瓷制品，而看起来比较具有年代感的陶瓷制品大多数都是祖辈传承下来的，市面上也比较少见，而具有年代感的陶瓷制品其外表面会有破碎的感觉，同样具有一定的观赏性。因此，如何制备具有年代感的陶瓷制品具有一定的意义。
发明内容
本发明的目的在于克服现有技术的不足，提供一种具有一定年代感视觉效果的仿古白绿釉料，及用其制备而成的陶瓷制品。
本发明采用如下技术方案：
仿古白绿釉料，包括按照质量份数计的如下组分：高岭土70～80份，长石6～8份，石英5～7份，氧化锌2～5份，碳酸钙3～6份，辉锑矿石13～20份，硅灰石7～8份，白垩土6～9份，辉绿岩11～17份，氧化铁1～3份，麦饭石5～11份。
所述的仿古白绿釉料的制备方法，包括如下步骤：
步骤一、破碎
按照所述质量份数计，将所述高岭土、长石、石英、碳酸钙、辉锑矿石、硅灰石、白垩土、辉绿岩和麦饭石分别进行破碎然后混合搅拌，得破碎料，并过筛后备用；
步骤二、球磨
按照所述质量份数计，将步骤一所得破碎料和所述氧化锌、氧化铁混合后，进行球磨，并过筛得球磨料；
步骤三、捶打
通过捶打机进行捶打，得捶打料；
步骤四、调节浓度
将水加入到步骤三所得捶打料中，调节其浓度后，用离心机出去悬浮液，即得仿古白绿釉料。
仿古白绿釉陶瓷制品的制备方法，步骤如下：
对陶瓷坯体进行上釉，釉料为仿古白绿釉，然后将上釉后的陶瓷坯体进行烧制，自然冷却后进行打磨，得仿古白绿釉陶瓷制品。
进一步的，所述陶瓷坯体包括按照质量份数计的如下组分：红土70～80份，高岭土70～80份，长石7～10份，石英5～7份，废弃红土陶瓷10～15份，莫来石13～18份。
进一步的，其上釉时分2～3次，每次间隔5～10min，每次釉层0.2～0.4mm。
进一步的，所述烧制过程具体如下：
预热段：以1.3～1.7℃/min的升温速率加热至280～320℃；
烧制一段：以2.7～3.5℃/min升温速率加热至750～800℃；
烧制二段：以2.0～2.5℃/min升温速率加热至1250～1270℃，恒温20～30min。
进一步的，所述打磨时采用打磨器打磨15～20min。
本发明与现有技术相比，具有以下有益效果：
第一、为了使得陶瓷产品外表面具有破损的视觉感，通过采用少量的氧化铁和碳酸钙，使其在烧制过程中产生气体，形成类似凹坑缺陷的陈旧感，其利用了硅灰石的耐热性能，在烧制过程中的温度变化较大，可以有效稳定釉面的成型；
第二、通过捶打机对釉料进行捶打时，粒径小，可以使得原料结构形成扁平状，且各类组分分错叠加，有助于形成不规则釉面，即凹坑状。
第三、在烧制过程中，烧制一段的升温速率明显比预热段快很多，这个升温速度是申请人通过长期测试的结果，有助于形成辉锑矿石、辉绿岩和氧化铁在烧制过程中形成白绿釉面，且不会破坏釉面和陶瓷坯体的结合；
第四、在坯体中加入了红土，并利用莫来石进行补强，通过红土可以有效还原其陈旧感，透过釉面的破损面可以看到内部坯体，而红土再配合白绿釉的效果，可以很好的还原其历经风雨的陈旧感。
具体实施方式
本发明所采用的原料均为市售品。
实施例1
仿古白绿釉料，包括按照质量份数计的如下组分：高岭土70份，长石6份，石英5份，氧化锌2份，碳酸钙3份，辉锑矿石13份，硅灰石7份，白垩土6份，辉绿岩11份，氧化铁1份，麦饭石5份。
仿古白绿釉料的制备方法，包括如下步骤：
步骤一、破碎
按照所述质量份数计，将所述高岭土、长石、石英、碳酸钙、辉锑矿石、硅灰石、白垩土、辉绿岩和麦饭石分别进行破碎然后混合搅拌，得破碎料，并过筛后备用；
步骤二、球磨
按照所述质量份数计，将步骤一所得破碎料和所述氧化锌、氧化铁混合后，进行球磨，并过筛得球磨料；
步骤三、捶打
通过捶打机进行捶打，得捶打料；
步骤四、调节浓度
将水加入到步骤三所得捶打料中，调节其浓度后，用离心机出去悬浮液，即得仿古白绿釉料。
仿古白绿釉陶瓷制品的制备方法，步骤如下：
对陶瓷坯体进行上釉，上釉次数为2次，每次间隔5min，每次釉层0.2mm。其中，釉料为仿古白绿釉，然后将上釉后的陶瓷坯体进行烧制，自然冷却后进行打磨，所述打磨时采用打磨器打磨15min，得仿古白绿釉陶瓷制品。
其中，所述陶瓷坯体包括按照质量份数计的如下组分：红土70份，高岭土70份，长石7份，石英5份，废弃红土陶瓷10份，莫来石13份。
其中，所述烧制过程具体如下：
预热段：以1.3℃/min的升温速率加热至280℃；
烧制一段：以2.7℃/min升温速率加热至750℃；
烧制二段：以2.0℃/min升温速率加热至1250℃，恒温20min。
实施例2
仿古白绿釉料，包括按照质量份数计的如下组分：高岭土75份，长石7份，石英6份，氧化锌3份，碳酸钙5份，辉锑矿石16份，硅灰石8份，白垩土7份，辉绿岩14份，氧化铁2份，麦饭石7份。
仿古白绿釉料的制备方法，包括如下步骤：
步骤一、破碎
按照所述质量份数计，将所述高岭土、长石、石英、碳酸钙、辉锑矿石、硅灰石、白垩土、辉绿岩和麦饭石分别进行破碎然后混合搅拌，得破碎料，并过筛后备用；
步骤二、球磨
按照所述质量份数计，将步骤一所得破碎料和所述氧化锌、氧化铁混合后，进行球磨，并过筛得球磨料；
步骤三、捶打
通过捶打机进行捶打，得捶打料；
步骤四、调节浓度
将水加入到步骤三所得捶打料中，调节其浓度后，用离心机出去悬浮液，即得仿古白绿釉料。
仿古白绿釉陶瓷制品的制备方法，步骤如下：
对陶瓷坯体进行上釉，上釉次数为3次，每次间隔8min，每次釉层0.3mm。其中，釉料为仿古白绿釉，然后将上釉后的陶瓷坯体进行烧制，自然冷却后进行打磨，所述打磨时采用打磨器打磨18min，得仿古白绿釉陶瓷制品。
其中，所述陶瓷坯体包括按照质量份数计的如下组分：红土75份，高岭土75份，长石8份，石英6份，废弃红土陶瓷12份，莫来石15份。
其中，所述烧制过程具体如下：
预热段：以1.4℃/min的升温速率加热至300℃；
烧制一段：以3.0℃/min升温速率加热至780℃；
烧制二段：以2.2℃/min升温速率加热至1260℃，恒温25min。
实施例3
仿古白绿釉料，包括按照质量份数计的如下组分：高岭土80份，长石8份，石英7份，氧化锌5份，碳酸钙6份，辉锑矿石20份，硅灰石8份，白垩土9份，辉绿岩17份，氧化铁3份，麦饭石11份。
仿古白绿釉料的制备方法，包括如下步骤：
步骤一、破碎
按照所述质量份数计，将所述高岭土、长石、石英、碳酸钙、辉锑矿石、硅灰石、白垩土、辉绿岩和麦饭石分别进行破碎然后混合搅拌，得破碎料，并过筛后备用；
步骤二、球磨
按照所述质量份数计，将步骤一所得破碎料和所述氧化锌、氧化铁混合后，进行球磨，并过筛得球磨料；
步骤三、捶打
通过捶打机进行捶打，得捶打料；
步骤四、调节浓度
将水加入到步骤三所得捶打料中，调节其浓度后，用离心机出去悬浮液，即得仿古白绿釉料。
仿古白绿釉陶瓷制品的制备方法，步骤如下：
对陶瓷坯体进行上釉，上釉次数为3次，每次间隔10min，每次釉层0.4mm。其中，釉料为仿古白绿釉，然后将上釉后的陶瓷坯体进行烧制，自然冷却后进行打磨，所述打磨时采用打磨器打磨20min，得仿古白绿釉陶瓷制品。
其中，所述陶瓷坯体包括按照质量份数计的如下组分：红土80份，高岭土80份，长石10份，石英7份，废弃红土陶瓷15份，莫来石18份。
其中，所述烧制过程具体如下：
预热段：以1.7℃/min的升温速率加热至320℃；
烧制一段：以3.5℃/min升温速率加热至800℃；
烧制二段：以2.5℃/min升温速率加热至1270℃，恒温30min。
对照例1
和实施例1相比，陶瓷坯体不含有红土。
对照例2
和实施例1相比，烧制过程为：以2.0℃/min升温速率加热至1250℃，恒温20min，然后自然冷却。
将上述实施例1～3和对照例1～2制得的产品进行检测，检测结果如下表1：
1、按照GB/T4100-2006进行耐低浓度酸和碱检测；
2、GB/T 3534-2002进行检测可容性铅、可容性镉含量；
3、GB/T 15614-2015进行检测光泽度；
表1为实施例1～3和对照例1～2制得的仿古白绿釉陶瓷制品的测试结果：
表1
从表1中可得，实施例1～3制得的产品和对照例1～2相比较，虽然光泽度没有对照例1及对照例2的高，但是，这是这样的光泽度使得白绿釉面有仿古陈旧感效果，正是本发明技术制得的陶瓷制品所要的产品效果。
以上所述是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本发明的保护范围。
Claims (7)
1.仿古白绿釉料，其特征在于，包括按照质量份数计的如下组分：高岭土70~80份，长石6~8份，石英5~7份，氧化锌2~5份，碳酸钙3~6份，辉锑矿石13~20份，硅灰石7~8份，白垩土6~9份，辉绿岩11~17份，氧化铁1~3份，麦饭石5~11份。
2.权利要求1所述的仿古白绿釉料的制备方法，其特征在于，包括如下步骤：
步骤一、破碎
按照所述质量份数计，将所述高岭土、长石、石英、碳酸钙、辉锑矿石、硅灰石、白垩土、辉绿岩和麦饭石分别进行破碎然后混合搅拌，得破碎料，并过筛后备用；
步骤二、球磨
按照所述质量份数计，将步骤一所得破碎料和所述氧化锌、氧化铁混合后，进行球磨，并过筛得球磨料；
步骤三、捶打
通过捶打机进行捶打，得捶打料；
步骤四、调节浓度
将水加入到步骤三所得捶打料中，调节其浓度后，用离心机出去悬浮液，即得仿古白绿釉料。
3.仿古白绿釉陶瓷制品的制备方法，其特征在于，步骤如下：
对陶瓷坯体进行上釉，釉料为仿古白绿釉，然后将上釉后的陶瓷坯体进行烧制，自然冷却后进行打磨，得仿古白绿釉陶瓷制品。
4.根据有权利要求3所述的仿古白绿釉陶瓷制品的制备方法，其特征在于，所述陶瓷坯体包括按照质量份数计的如下组分：红土70~80份，高岭土70~80份，长石7~10份，石英5~7份，废弃红土陶瓷10~15份，莫来石13~18份。
5.根据权利要求3所述的仿古白绿釉陶瓷制品的制备方法，其特征在于，其上釉次数为2~3次，每次间隔5~10min，每次釉层0.2~0.4mm。
6.根据有权利要求3所述的仿古白绿釉陶瓷制品的制备方法，其特征在于，所述烧制过程具体如下：
预热段：以1.3~1.7℃/min的升温速率加热至280~320℃；
烧制一段：以2.7~3.5℃/min升温速率加热至750~800℃；
烧制二段：以2.0~2.5℃/min升温速率加热至1250~1270℃，恒温20~30min。
7.根据有权利要求3所述的仿古白绿釉陶瓷制品的制备方法，其特征在于，所述打磨时采用打磨器打磨15~20min。
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