CN113213899A - 一种耐高温材料 - Google Patents
一种耐高温材料 Download PDFInfo
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- CN113213899A CN113213899A CN202110473785.4A CN202110473785A CN113213899A CN 113213899 A CN113213899 A CN 113213899A CN 202110473785 A CN202110473785 A CN 202110473785A CN 113213899 A CN113213899 A CN 113213899A
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- 239000000463 material Substances 0.000 title claims abstract description 44
- 239000000843 powder Substances 0.000 claims abstract description 173
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 83
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 74
- 239000010431 corundum Substances 0.000 claims abstract description 68
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000007788 liquid Substances 0.000 claims abstract description 37
- 239000000945 filler Substances 0.000 claims abstract description 36
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000835 fiber Substances 0.000 claims abstract description 29
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 26
- 239000004917 carbon fiber Substances 0.000 claims abstract description 26
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 22
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910000423 chromium oxide Inorganic materials 0.000 claims abstract description 21
- 239000010433 feldspar Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000010453 quartz Substances 0.000 claims abstract description 14
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 11
- RGPUVZXXZFNFBF-UHFFFAOYSA-K diphosphonooxyalumanyl dihydrogen phosphate Chemical compound [Al+3].OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O RGPUVZXXZFNFBF-UHFFFAOYSA-K 0.000 claims abstract description 11
- 229940072033 potash Drugs 0.000 claims abstract description 11
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 11
- 235000015320 potassium carbonate Nutrition 0.000 claims abstract description 11
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 11
- 239000010703 silicon Substances 0.000 claims abstract description 11
- 239000011787 zinc oxide Substances 0.000 claims abstract description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims description 68
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 36
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 30
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 30
- 235000012239 silicon dioxide Nutrition 0.000 claims description 27
- 239000000377 silicon dioxide Substances 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 25
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 20
- 238000000227 grinding Methods 0.000 claims description 15
- 238000007873 sieving Methods 0.000 claims description 15
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 15
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 10
- 239000004743 Polypropylene Substances 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 10
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 10
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000005011 phenolic resin Substances 0.000 claims description 10
- 229920001568 phenolic resin Polymers 0.000 claims description 10
- -1 polypropylene Polymers 0.000 claims description 10
- 229920001155 polypropylene Polymers 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 230000003213 activating effect Effects 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 229910052681 coesite Inorganic materials 0.000 claims description 5
- 229910052906 cristobalite Inorganic materials 0.000 claims description 5
- 239000010439 graphite Substances 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 5
- 239000010443 kyanite Substances 0.000 claims description 5
- 229910052850 kyanite Inorganic materials 0.000 claims description 5
- UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 claims description 5
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 229910052594 sapphire Inorganic materials 0.000 claims description 5
- 239000010980 sapphire Substances 0.000 claims description 5
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 5
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052682 stishovite Inorganic materials 0.000 claims description 5
- 229910003468 tantalcarbide Inorganic materials 0.000 claims description 5
- 229910052905 tridymite Inorganic materials 0.000 claims description 5
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims description 5
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 claims description 5
- 235000015110 jellies Nutrition 0.000 claims description 2
- 239000008274 jelly Substances 0.000 claims description 2
- 239000011819 refractory material Substances 0.000 claims 4
- 229910052751 metal Inorganic materials 0.000 abstract description 11
- 239000002184 metal Substances 0.000 abstract description 11
- 238000009835 boiling Methods 0.000 abstract description 5
- 238000004880 explosion Methods 0.000 abstract description 4
- 239000011810 insulating material Substances 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 4
- FNMTVMWFISHPEV-AATRIKPKSA-N dipropan-2-yl (e)-but-2-enedioate Chemical compound CC(C)OC(=O)\C=C\C(=O)OC(C)C FNMTVMWFISHPEV-AATRIKPKSA-N 0.000 abstract description 3
- 238000009413 insulation Methods 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 238000005336 cracking Methods 0.000 abstract 1
- 239000000498 cooling water Substances 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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Abstract
本发明公开了一种耐高温材料,具体涉及耐高温材料技术领域,包括以下材料:白刚玉、棕刚玉、氧化铝微粉、刚玉粉、硅微粉、氧化铬粉、蓝晶石粉、溶度为60wt%的液体磷酸、溶度为60wt%的液体磷酸二氢铝、碳纤维、石英纤维、氧化锌、钾长石。本发明通过加入石英纤维、耐磨填料、耐高温填料、高聚体衍生物‑富马酸二异丙酯C10H1604粉末和锆粉末,将其敷在任何材料表面就形成了微多孔的耐高温隔热材料,可以经受3000℃火焰直接烤,而被保护的材料温度仅仅处于敷设前的温度,从而降低了循环水容器破裂使得低温循环水与高温沸腾金属液体接触对金属液的质量造成浪费和损失,而且导致爆炸危险的问题,从而可以实现安全和低成本的隔热。
Description
技术领域
本发明涉及耐高温材料技术领域,更具体地说,本发明涉及一种耐高温材料。
背景技术
在对金属进行加工的过程中,往往需要对金属进行高温熔融处理,而在对沸腾金属液体进行操作的过程中,目前最好的选择仍然是使用循环水,而循环水在使用时往往需要装载在容器中使用,但是现有技术中的循环水装载容器耐热性较差,一旦装载循环水的容器受热破裂,就导致冷却水漏出,使得低温冷却水与高温沸腾金属液体接触不仅会对金属液的质量造成影响,造成浪费和损失,而且极易导致爆炸危险,使得安全隐患较大,因此本发明的目的就是制造一种可以直接对抗3000℃火焰的物质,用以实现安全且低成本的隔热目的。
发明内容
为了克服现有技术的上述缺陷,本发明提供了一种耐高温材料,本发明所要解决的技术问题是:现有技术中的循环水装载容器耐热性较差,一旦装载循环水的容器受热破裂,就导致冷却水漏出,使得低温冷却水与高温沸腾金属液体接触不仅会对金属液的质量造成影响,造成浪费和损失,而且极易导致爆炸危险,使得安全隐患较大的问题。
为实现上述目的,本发明提供如下技术方案:一种耐高温材料,包括以下材料:
白刚玉、棕刚玉、氧化铝微粉、刚玉粉、硅微粉、氧化铬粉、蓝晶石粉、溶度为60wt%的液体磷酸、溶度为60wt%的液体磷酸二氢铝、碳纤维、石英纤维、氧化锌、钾长石、二氧化硅、苯乙烯、氯化聚丙烯、乙酸乙酯、松香树脂、酚醛树脂、三乙胺、对苯二酚、去离子水、高聚体衍生物-富马酸二异丙酯C10H1604粉末、锆粉末、醋酸乙烯液体、耐高温填料、耐磨填料、乙醇。
一种耐高温材料,包括以下制备方法制备而成:
S1、将质量份为15-25的白刚玉进行粉碎,并研磨成粉末过150-200目筛,再将质量份为20-30的棕刚玉进行粉碎,并研磨成粉末过150-200目筛,并将研磨完成的白刚玉粉和棕刚玉粉一起置于搅拌设备内进行均匀的混合,然后取质量份为15-20的氧化铝微粉、质量份为10-15的刚玉粉、质量份为3-5的硅微粉、质量份为1-5的氧化铬粉和质量份为7-10的蓝晶石粉置于搅拌设备中与白刚玉粉和棕刚玉粉进行混合处理,中低速混合3-5min之后加入质量份为3-8且溶度为60wt%的液体磷酸和质量份为5-10且溶度为60wt%的液体磷酸二氢铝,继续混合5-8min,得到混合物。
S2、将质量份为15-20的碳纤维在2000-3000℃的条件下进行石墨处理,然后通过阳极氧化的方式进行活化,得到可用的碳纤维,且碳纤维的数均纤维长度为30-1000μm,将可用的碳纤维与质量份为15-20的石英纤维进行均匀混合,得到混合纤维。
S3、先将质量份为1-2的氧化锌、质量份为1-2的钾长石、质量份为1-2的二氧化硅分别研磨成粒径为纳米级别的颗粒,得到纳米级氧化锌粉末、纳米级钾长石粉末和纳米级二氧化硅粉末,备用,然后将质量份为40-50的苯乙烯、质量份为35-40的氯化聚丙烯、质量份为25-30的乙酸乙酯、质量份为15-20的松香树脂、质量份为15-18的酚醛树脂、质量份为15-23的三乙胺、质量份为5-8的对苯二酚、质量份为5-10的去离子水以及纳米级氧化锌粉末、纳米级钾长石粉末和纳米级二氧化硅粉末放入反应釜中,在50-60℃的温度下搅拌均匀,然后再加热至80-100℃,继续搅拌并反应55-65min,得到粘剂。
S4、取质量份为32的高聚体衍生物-富马酸二异丙酯C10H1604粉末和质量份为25的锆粉末作为主料放入搅拌设备进行混合处理,混合的过程中倒入质量份为20的醋酸乙烯液体,继续进行混合5min之后加入质量份为25-30的混合物,再次混合2-3min后加入质量份为25-35的耐高温填料和质量份为25-35的耐磨填料,混合均匀后加入质量份为70的乙醇,并在21-28℃的室温下充分混合,混合完成之后升温到45℃,并将湿度控制在10%的干燥环境中等待乙醇完全蒸发,再倒入质量份为25-35的混合纤维和粘接进行均匀混合,形成软质具有可塑性的胶状物。
作为本发明的进一步方案:所述耐高温填料是氧化铝、二氧化硅和氧化锆中的一种或者是几种粉末的混合物。
作为本发明的进一步方案:所述耐磨填料是碳化硅、碳化钛、碳化钨、碳化铌、碳化钽中的一种或者是几种粉末的混合物。
作为本发明的进一步方案:所述氧化铝微粉的粒度小于或等于0.045mm、氧化铝微粉中的Al2O3含量大于或等于99wt%,刚玉粉的粒度小于或等于0.074mm、刚玉粉中的Al2O3含量大于或等于97wt%,硅微粉中SiO2含量大于或等于92wt%,蓝晶石粉中Al2O3含量为53~58wt%,氧化铬粉的粒度小于或等于0.045mm、氧化铬粉中的Cr2O3含量大于或等于99wt%。
作为本发明的进一步方案:所述S4中乙醇的浓度为99%。
本发明的有益效果在于:
本发明通过加入石英纤维、耐磨填料、耐高温填料、高聚体衍生物-富马酸二异丙酯C10H1604粉末和锆粉末,且石英纤维本身的耐高温性能具有一定的力学强度,而且又因为加入了耐磨填料和耐高温填料,从而赋予了耐高温材料的耐磨和耐水性,且高聚体衍生物-富马酸二异丙酯C10H1604粉末和锆粉末的加入使得本发明耐高温材料不仅耐化学腐蚀性好,耐高温性好,且耐磨效果较佳,将其敷在任何材料表面就形成了微多孔的耐高温隔热材料,可以经受3000℃火焰直接烤,而被保护的材料温度仅仅处于敷设前的温度,从而降低了循环水容器破裂使得低温循环水与高温沸腾金属液体接触对金属液的质量造成浪费和损失,而且导致爆炸危险的问题,从而可以实现安全和低成本的隔热。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例1:
一种耐高温材料,包括以下材料:
白刚玉、棕刚玉、氧化铝微粉、刚玉粉、硅微粉、氧化铬粉、蓝晶石粉、溶度为60wt%的液体磷酸、溶度为60wt%的液体磷酸二氢铝、碳纤维、石英纤维、氧化锌、钾长石、二氧化硅、苯乙烯、氯化聚丙烯、乙酸乙酯、松香树脂、酚醛树脂、三乙胺、对苯二酚、去离子水、高聚体衍生物-富马酸二异丙酯C10H1604粉末、锆粉末、醋酸乙烯液体、耐高温填料、耐磨填料、乙醇。
一种耐高温材料,包括以下制备方法制备而成:
S1、将质量份为15-25的白刚玉进行粉碎,并研磨成粉末过150-200目筛,再将质量份为20-30的棕刚玉进行粉碎,并研磨成粉末过150-200目筛,并将研磨完成的白刚玉粉和棕刚玉粉一起置于搅拌设备内进行均匀的混合,然后取质量份为15-20的氧化铝微粉、质量份为10-15的刚玉粉、质量份为3-5的硅微粉、质量份为1-5的氧化铬粉和质量份为7-10的蓝晶石粉置于搅拌设备中与白刚玉粉和棕刚玉粉进行混合处理,中低速混合3-5min之后加入质量份为3-8且溶度为60wt%的液体磷酸和质量份为5-10且溶度为60wt%的液体磷酸二氢铝,继续混合5-8min,得到混合物。
S2、将质量份为15-20的碳纤维在2000-3000℃的条件下进行石墨处理,然后通过阳极氧化的方式进行活化,得到可用的碳纤维,且碳纤维的数均纤维长度为30-1000μm,将可用的碳纤维与质量份为15的石英纤维进行均匀混合,得到混合纤维。
S3、先将质量份为1-2的氧化锌、质量份为1-2的钾长石、质量份为1-2的二氧化硅分别研磨成粒径为纳米级别的颗粒,得到纳米级氧化锌粉末、纳米级钾长石粉末和纳米级二氧化硅粉末,备用,然后将质量份为40-50的苯乙烯、质量份为35-40的氯化聚丙烯、质量份为25-30的乙酸乙酯、质量份为15-20的松香树脂、质量份为15-18的酚醛树脂、质量份为15-23的三乙胺、质量份为5-8的对苯二酚、质量份为5-10的去离子水以及纳米级氧化锌粉末、纳米级钾长石粉末和纳米级二氧化硅粉末放入反应釜中,在50-60℃的温度下搅拌均匀,然后再加热至80-100℃,继续搅拌并反应55-65min,得到粘剂。
S4、取质量份为32的高聚体衍生物-富马酸二异丙酯C10H1604粉末和质量份为25的锆粉末作为主料放入搅拌设备进行混合处理,混合的过程中倒入质量份为20的醋酸乙烯液体,继续进行混合5min之后加入质量份为25-30的混合物,再次混合2-3min后加入质量份为25的耐高温填料和质量份为25的耐磨填料,混合均匀后加入质量份为70的乙醇,并在21-28℃的室温下充分混合,混合完成之后升温到45℃,并将湿度控制在10%的干燥环境中等待乙醇完全蒸发,再倒入质量份为25-35的混合纤维和粘接进行均匀混合,形成软质具有可塑性的胶状物。
耐高温填料是氧化铝、二氧化硅和氧化锆中的一种或者是几种粉末的混合物。
耐磨填料是碳化硅、碳化钛、碳化钨、碳化铌、碳化钽中的一种或者是几种粉末的混合物。
氧化铝微粉的粒度小于或等于0.045mm、氧化铝微粉中的Al2O3含量大于或等于99wt%,刚玉粉的粒度小于或等于0.074mm、刚玉粉中的Al2O3含量大于或等于97wt%,硅微粉中SiO2含量大于或等于92wt%,蓝晶石粉中Al2O3含量为53~58wt%,氧化铬粉的粒度小于或等于0.045mm、氧化铬粉中的Cr2O3含量大于或等于99wt%。
S4中乙醇的浓度为99%。
实施例2:
一种耐高温材料,包括以下材料:
白刚玉、棕刚玉、氧化铝微粉、刚玉粉、硅微粉、氧化铬粉、蓝晶石粉、溶度为60wt%的液体磷酸、溶度为60wt%的液体磷酸二氢铝、碳纤维、石英纤维、氧化锌、钾长石、二氧化硅、苯乙烯、氯化聚丙烯、乙酸乙酯、松香树脂、酚醛树脂、三乙胺、对苯二酚、去离子水、高聚体衍生物-富马酸二异丙酯C10H1604粉末、锆粉末、醋酸乙烯液体、耐高温填料、耐磨填料、乙醇。
一种耐高温材料,包括以下制备方法制备而成:
S1、将质量份为15-25的白刚玉进行粉碎,并研磨成粉末过150-200目筛,再将质量份为20-30的棕刚玉进行粉碎,并研磨成粉末过150-200目筛,并将研磨完成的白刚玉粉和棕刚玉粉一起置于搅拌设备内进行均匀的混合,然后取质量份为15-20的氧化铝微粉、质量份为10-15的刚玉粉、质量份为3-5的硅微粉、质量份为1-5的氧化铬粉和质量份为7-10的蓝晶石粉置于搅拌设备中与白刚玉粉和棕刚玉粉进行混合处理,中低速混合3-5min之后加入质量份为3-8且溶度为60wt%的液体磷酸和质量份为5-10且溶度为60wt%的液体磷酸二氢铝,继续混合5-8min,得到混合物。
S2、将质量份为15-20的碳纤维在2000-3000℃的条件下进行石墨处理,然后通过阳极氧化的方式进行活化,得到可用的碳纤维,且碳纤维的数均纤维长度为30-1000μm,将可用的碳纤维与质量份为18的石英纤维进行均匀混合,得到混合纤维。
S3、先将质量份为1-2的氧化锌、质量份为1-2的钾长石、质量份为1-2的二氧化硅分别研磨成粒径为纳米级别的颗粒,得到纳米级氧化锌粉末、纳米级钾长石粉末和纳米级二氧化硅粉末,备用,然后将质量份为40-50的苯乙烯、质量份为35-40的氯化聚丙烯、质量份为25-30的乙酸乙酯、质量份为15-20的松香树脂、质量份为15-18的酚醛树脂、质量份为15-23的三乙胺、质量份为5-8的对苯二酚、质量份为5-10的去离子水以及纳米级氧化锌粉末、纳米级钾长石粉末和纳米级二氧化硅粉末放入反应釜中,在50-60℃的温度下搅拌均匀,然后再加热至80-100℃,继续搅拌并反应55-65min,得到粘剂。
S4、取质量份为32的高聚体衍生物-富马酸二异丙酯C10H1604粉末和质量份为25的锆粉末作为主料放入搅拌设备进行混合处理,混合的过程中倒入质量份为20的醋酸乙烯液体,继续进行混合5min之后加入质量份为25-30的混合物,再次混合2-3min后加入质量份为30的耐高温填料和质量份为30的耐磨填料,混合均匀后加入质量份为70的乙醇,并在21-28℃的室温下充分混合,混合完成之后升温到45℃,并将湿度控制在10%的干燥环境中等待乙醇完全蒸发,再倒入质量份为25-35的混合纤维和粘接进行均匀混合,形成软质具有可塑性的胶状物。
耐高温填料是氧化铝、二氧化硅和氧化锆中的一种或者是几种粉末的混合物。
耐磨填料是碳化硅、碳化钛、碳化钨、碳化铌、碳化钽中的一种或者是几种粉末的混合物。
氧化铝微粉的粒度小于或等于0.045mm、氧化铝微粉中的Al2O3含量大于或等于99wt%,刚玉粉的粒度小于或等于0.074mm、刚玉粉中的Al2O3含量大于或等于97wt%,硅微粉中SiO2含量大于或等于92wt%,蓝晶石粉中Al2O3含量为53~58wt%,氧化铬粉的粒度小于或等于0.045mm、氧化铬粉中的Cr2O3含量大于或等于99wt%。
实施例3:
一种耐高温材料,包括以下材料:
白刚玉、棕刚玉、氧化铝微粉、刚玉粉、硅微粉、氧化铬粉、蓝晶石粉、溶度为60wt%的液体磷酸、溶度为60wt%的液体磷酸二氢铝、碳纤维、石英纤维、氧化锌、钾长石、二氧化硅、苯乙烯、氯化聚丙烯、乙酸乙酯、松香树脂、酚醛树脂、三乙胺、对苯二酚、去离子水、高聚体衍生物-富马酸二异丙酯C10H1604粉末、锆粉末、醋酸乙烯液体、耐高温填料、耐磨填料、乙醇。
一种耐高温材料,包括以下制备方法制备而成:
S1、将质量份为15-25的白刚玉进行粉碎,并研磨成粉末过150-200目筛,再将质量份为20-30的棕刚玉进行粉碎,并研磨成粉末过150-200目筛,并将研磨完成的白刚玉粉和棕刚玉粉一起置于搅拌设备内进行均匀的混合,然后取质量份为15-20的氧化铝微粉、质量份为10-15的刚玉粉、质量份为3-5的硅微粉、质量份为1-5的氧化铬粉和质量份为7-10的蓝晶石粉置于搅拌设备中与白刚玉粉和棕刚玉粉进行混合处理,中低速混合3-5min之后加入质量份为3-8且溶度为60wt%的液体磷酸和质量份为5-10且溶度为60wt%的液体磷酸二氢铝,继续混合5-8min,得到混合物。
S2、将质量份为15-20的碳纤维在2000-3000℃的条件下进行石墨处理,然后通过阳极氧化的方式进行活化,得到可用的碳纤维,且碳纤维的数均纤维长度为30-1000μm,将可用的碳纤维与质量份为20的石英纤维进行均匀混合,得到混合纤维。
S3、先将质量份为1-2的氧化锌、质量份为1-2的钾长石、质量份为1-2的二氧化硅分别研磨成粒径为纳米级别的颗粒,得到纳米级氧化锌粉末、纳米级钾长石粉末和纳米级二氧化硅粉末,备用,然后将质量份为40-50的苯乙烯、质量份为35-40的氯化聚丙烯、质量份为25-30的乙酸乙酯、质量份为15-20的松香树脂、质量份为15-18的酚醛树脂、质量份为15-23的三乙胺、质量份为5-8的对苯二酚、质量份为5-10的去离子水以及纳米级氧化锌粉末、纳米级钾长石粉末和纳米级二氧化硅粉末放入反应釜中,在50-60℃的温度下搅拌均匀,然后再加热至80-100℃,继续搅拌并反应55-65min,得到粘剂。
S4、取质量份为32的高聚体衍生物-富马酸二异丙酯C10H1604粉末和质量份为25的锆粉末作为主料放入搅拌设备进行混合处理,混合的过程中倒入质量份为20的醋酸乙烯液体,继续进行混合5min之后加入质量份为25-30的混合物,再次混合2-3min后加入质量份为35的耐高温填料和质量份为35的耐磨填料,混合均匀后加入质量份为70的乙醇,并在21-28℃的室温下充分混合,混合完成之后升温到45℃,并将湿度控制在10%的干燥环境中等待乙醇完全蒸发,再倒入质量份为25-35的混合纤维和粘接进行均匀混合,形成软质具有可塑性的胶状物。
耐高温填料是氧化铝、二氧化硅和氧化锆中的一种或者是几种粉末的混合物。
耐磨填料是碳化硅、碳化钛、碳化钨、碳化铌、碳化钽中的一种或者是几种粉末的混合物。
氧化铝微粉的粒度小于或等于0.045mm、氧化铝微粉中的Al2O3含量大于或等于99wt%,刚玉粉的粒度小于或等于0.074mm、刚玉粉中的Al2O3含量大于或等于97wt%,硅微粉中SiO2含量大于或等于92wt%,蓝晶石粉中Al2O3含量为53~58wt%,氧化铬粉的粒度小于或等于0.045mm、氧化铬粉中的Cr2O3含量大于或等于99wt%。
对比例1:
购买市面上的耐高温材料进行对比。
根据实施例1-3和对比例1得出下表:
最高承受温度 | 耐磨度 | 强度 | |
实施例1 | 3500℃ | 较佳 | 较高 |
实施例2 | 3350℃ | 较佳 | 较高 |
实施例3 | 3580℃ | 较佳 | 较高 |
对比例1 | 1500-2000℃ | 易磨损 | 一般 |
由上表中的对比可知:与市面上购买的耐高温材料相比,本发明制备的耐高温材料不仅可以承受3000℃以上的高温,而且耐磨度较佳,且强度较高。
最后应说明的几点是:虽然,上文中已经用一般性说明及具体实施例对本发明作了详尽的描述,但在本发明的基础上,以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。
Claims (6)
1.一种耐高温材料,其特征在于,包括以下材料:
白刚玉、棕刚玉、氧化铝微粉、刚玉粉、硅微粉、氧化铬粉、蓝晶石粉、溶度为60wt%的液体磷酸、溶度为60wt%的液体磷酸二氢铝、碳纤维、石英纤维、氧化锌、钾长石、二氧化硅、苯乙烯、氯化聚丙烯、乙酸乙酯、松香树脂、酚醛树脂、三乙胺、对苯二酚、去离子水、高聚体衍生物-富马酸二异丙酯C10H1604粉末、锆粉末、醋酸乙烯液体、耐高温填料、耐磨填料、乙醇。
2.一种耐高温材料,其特征在于,包括以下制备方法制备而成:
S1、将质量份为15-25的白刚玉进行粉碎,并研磨成粉末过150-200目筛,再将质量份为20-30的棕刚玉进行粉碎,并研磨成粉末过150-200目筛,并将研磨完成的白刚玉粉和棕刚玉粉一起置于搅拌设备内进行均匀的混合,然后取质量份为15-20的氧化铝微粉、质量份为10-15的刚玉粉、质量份为3-5的硅微粉、质量份为1-5的氧化铬粉和质量份为7-10的蓝晶石粉置于搅拌设备中与白刚玉粉和棕刚玉粉进行混合处理,中低速混合3-5min之后加入质量份为3-8且溶度为60wt%的液体磷酸和质量份为5-10且溶度为60wt%的液体磷酸二氢铝,继续混合5-8min,得到混合物;
S2、将质量份为15-20的碳纤维在2000-3000℃的条件下进行石墨处理,然后通过阳极氧化的方式进行活化,得到可用的碳纤维,且碳纤维的数均纤维长度为30-1000μm,将可用的碳纤维与质量份为15-20的石英纤维进行均匀混合,得到混合纤维;
S3、先将质量份为1-2的氧化锌、质量份为1-2的钾长石、质量份为1-2的二氧化硅分别研磨成粒径为纳米级别的颗粒,得到纳米级氧化锌粉末、纳米级钾长石粉末和纳米级二氧化硅粉末,备用,然后将质量份为40-50的苯乙烯、质量份为35-40的氯化聚丙烯、质量份为25-30的乙酸乙酯、质量份为15-20的松香树脂、质量份为15-18的酚醛树脂、质量份为15-23的三乙胺、质量份为5-8的对苯二酚、质量份为5-10的去离子水以及纳米级氧化锌粉末、纳米级钾长石粉末和纳米级二氧化硅粉末放入反应釜中,在50-60℃的温度下搅拌均匀,然后再加热至80-100℃,继续搅拌并反应55-65min,得到粘剂;
S4、取质量份为32的高聚体衍生物-富马酸二异丙酯C10H1604粉末和质量份为25的锆粉末作为主料放入搅拌设备进行混合处理,混合的过程中倒入质量份为20的醋酸乙烯液体,继续进行混合5min之后加入质量份为25-30的混合物,再次混合2-3min后加入质量份为25-35的耐高温填料和质量份为25-35的耐磨填料,混合均匀后加入质量份为70的乙醇,并在21-28℃的室温下充分混合,混合完成之后升温到45℃,并将湿度控制在10%的干燥环境中等待乙醇完全蒸发,再倒入质量份为25-35的混合纤维和粘接进行均匀混合,形成软质具有可塑性的胶状物。
3.根据权利要求1所述的一种耐高温材料,其特征在于:所述耐高温填料是氧化铝、二氧化硅和氧化锆中的一种或者是几种粉末的混合物。
4.根据权利要求1所述的一种耐高温材料,其特征在于:所述耐磨填料是碳化硅、碳化钛、碳化钨、碳化铌、碳化钽中的一种或者是几种粉末的混合物。
5.根据权利要求1所述的一种耐高温材料,其特征在于:所述氧化铝微粉的粒度小于或等于0.045mm、氧化铝微粉中的Al2O3含量大于或等于99wt%,刚玉粉的粒度小于或等于0.074mm、刚玉粉中的Al2O3含量大于或等于97wt%,硅微粉中SiO2含量大于或等于92wt%,蓝晶石粉中Al2O3含量为53~58wt%,氧化铬粉的粒度小于或等于0.045mm、氧化铬粉中的Cr2O3含量大于或等于99wt%。
6.根据权利要求1所述的一种耐高温材料,其特征在于:所述S4中乙醇的浓度为99%。
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