CN113068900B - 一种天然茶籽饼合成中底板材的制备方法 - Google Patents

一种天然茶籽饼合成中底板材的制备方法 Download PDF

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CN113068900B
CN113068900B CN202110308987.3A CN202110308987A CN113068900B CN 113068900 B CN113068900 B CN 113068900B CN 202110308987 A CN202110308987 A CN 202110308987A CN 113068900 B CN113068900 B CN 113068900B
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林娟
林�建
林述琦
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HUAGUANG COLLEGE OF QUANZHOU
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Abstract

本发明公开一种天然茶籽饼合成中底板材的制备方法，通过如下步骤制备而成：高岭土和茶粕的选取，搅拌、混胶，水刺无纺布的骨架形成，热压成型，最后烘干，即可得到中底板材。本发明的一种天然茶籽饼合成中底板材的制备方法，其成型出来的中底板材中大部分原材料采用的是茶粕,而茶粕中含有12‑18％的茶皂素,利用良好的乳化、分解、发泡、湿润功能及消炎、杀菌、解毒、止痒、抗渗透的药理作用使中底板材具有良好的透气性,防潮,能杀灭脚部病菌,还能将脚部汗液吸收,增强了穿着舒适感,再配合胶粘体纤网片使整个中底板材的强度较高,达到穿着要求,定型效果佳,且无味无毒，对人体无副作用，生物降解性强。

Description

一种天然茶籽饼合成中底板材的制备方法
技术领域
本发明涉及鞋材料领域，特别涉及一种鞋中底板材的制备方法。
背景技术
众所周知，茶粕是野山茶油果实榨油后剩下的渣。茶籽粉中含有 12-18％的茶皂素,不含任何添加物,其颜色为深咖啡色。茶皂素是一种天然非复方型表面活性剂,其有良好的乳化、分解、发泡、湿润功能，同时它还具有消炎、杀菌、解毒、消炎、止痒、抗渗透等药理作用。
鞋底的中底板直接承受人体重量，并将所受重力传递到外底和鞋跟，可以隔离脚与地面，缓冲地面对脚的作用。中底板除受弯曲、挤压、摩擦的作用外，还受脚汗、鞋内湿度、温度等的影响，因此，中底板除了具有常规的稳定性外，还要求具有一定的透气性，避免脚部发生疾病。然而，常见的中底板有纤维中底板和中底纸板，纤维中底板是指涤纶短纤针刺后经过浸胶而成，中底纸板是将纸浆和胶水压制成板材，纤维中底板和中底纸板虽满足是鞋底所需的强度稳定性外，但是透气性。
随着人民卫生保健水平的不断提高，应用天然植物下脚料和环保生产工艺，研发具有卫生保健环保的鞋类产品，是人类必须开展的科学研究项目。
有鉴于此，本发明人对上述问题进行深入研究，遂由本案产生。
发明内容
有鉴于此，本发明的目的在于提供一种天然茶籽饼合成中底板材的制备方法，其制备出来的中底板材无味无毒，对人体无副作用，生物降解性强，定型效果佳，能吸收汗液及杀菌作用，并具有良好的稳定性、透气性及防潮性。
为了达成上述目的，本发明的解决方案是：一种天然茶籽饼合成中底板材的制备方法，通过如下步骤制备而成：
步骤一、原料选取，选取高岭土和其细度为120-130目，含水量为12-14％的茶粕，且高岭土与茶粕的重量份比为1：6；
步骤二、搅拌，将步骤一的高岭土和茶粕倒入干粉搅拌机内搅拌，搅拌25-30分钟，得到混合粉；
步骤三、混胶，将步骤二的混合粉投入碎浆机中，并在碎浆机中丁腈橡胶胶粘剂进行搅拌混合35-40分钟，得到混胶粉，且混合粉与丁腈橡胶胶粘剂的重量份比为7：3；
步骤四、骨架形成，将水刺无纺布放入乳胶池中浸泡10分钟，浸泡后水刺无纺布转入循环传送带上进行常温晾干8-10分钟，形成胶粘体纤网片；
步骤五、热压成型，将热压机的工作平台上平铺一层混胶粉形成下混胶粉板坯，此下混胶粉板坯的厚度为3-4mm，热压机在热压温度 160-170℃，热压压力为3-4兆帕的条件下对下混胶粉板坯热压3-4 分钟，热压后得到压实板坯，之后在压实板坯的顶面平铺一层胶粘体纤网片，在胶粘体纤网片上平铺一层由步骤三的混胶粉堆成的厚度达到3-4mm的上混胶粉板坯，最后在热压机在热压温度160-170℃，热压压力为2-3兆帕的条件下对上混胶粉板坯热压6-7分钟，得到其厚度为3-4mm的紧实板材；
步骤六、烘干，将步骤五的紧实板材输入至烘干机中烘干60-65 分钟，即可得到中底板材。
上述步骤六中,所述烘干机的工作压力为0.8MPa,烘干时间为60 分钟。
上述步骤一中,选取10公斤的高岭土和60公斤的茶粕,步骤三中混合粉的重量份为70公斤,丁腈橡胶胶粘剂的重量份是30公斤。
上述步骤五中,上述下混胶粉板坯的热压压力为3.5兆帕,上述上混胶粉板坯的热压压力为2.0兆帕。
采用上述技术方案后，本发明的一种天然茶籽饼合成中底板材的制备方法，其成型出来的中底板材中大部分原材料采用的是茶粕,而茶粕中含有12-18％的茶皂素,利用良好的乳化、分解、发泡、湿润功能及消炎、杀菌、解毒、止痒、抗渗透的药理作用使中底板材具有良好的透气性,防潮,能杀灭脚部病菌,还能将脚部汗液吸收,增强了穿着舒适感,再配合胶粘体纤网片使整个中底板材的强度较高,达到穿着要求,定型效果佳,且无味无毒，对人体无副作用，生物降解性强。
具体实施方式
为了进一步解释本发明的技术方案，下面通过具体实施例来对本发明进行详细阐述。
本发明的解决方案是：一种天然茶籽饼合成中底板材的制备方法，通过如下步骤制备而成：
步骤一、原料选取，选取高岭土和其细度为120-130目，含水量为12-14％的茶粕，且高岭土与茶粕的重量份比为1：6；具体的是选取60分斤的茶粕和10分斤的高岭土；
步骤二、搅拌，将步骤一的高岭土和茶粕倒入干粉搅拌机内搅拌，搅拌25-30分钟，得到混合粉；
步骤三、混胶，将步骤二的混合粉投入碎浆机中，并在碎浆机中丁腈橡胶胶粘剂进行搅拌混合35-40分钟，得到混胶粉，且混合粉与丁腈橡胶胶粘剂的重量份比为7：3；此步骤中,因压榨后得到的茶粕，里面仍然含有少许油气、茶皂素、多糖、多酚、糖萜素、黄酮、蛋白等主要活性成分,而丁腈橡胶胶粘剂它的最大的优点是耐油性好,剥离强度高,对脂肪烃和非氧化性酸具有良好的抵抗力，可以在加热和加压过程中硫化,加热时，液态粘料分子可进一步聚合和交联成体型网状结构，形成不溶、不熔的固态胶接层而达到胶接的目的,则利用丁腈橡胶胶粘剂一方面能去除油气,另一方面还可起到胶接目的；
步骤四、骨架形成，将水刺无纺布放入乳胶池中浸泡10分钟，使乳胶穿过水刺无纺布,浸泡后水刺无纺布转入循环传送带上进行常温晾干8-10分钟，形成胶粘体纤网片；
步骤五、热压成型，将热压机的工作平台上平铺一层混胶粉形成下混胶粉板坯，此下混胶粉板坯的厚度为3-4mm，优佳为3mm,热压机在热压温度160-170℃，热压压力为3-4兆帕的条件下进行第一次热压,即对下混胶粉板坯热压3-4分钟，优佳的是,热压压力为3.5兆帕, 热压时间为3分钟,热压后得到压实板坯，之后在压实板坯的顶面平铺一层步骤四的胶粘体纤网片，在胶粘体纤网片上平铺一层由步骤三的混胶粉堆成的厚度达到3-4mm的上混胶粉板坯，上混胶粉板坯的厚度优佳为3mm,最后在热压机在热压温度160-170℃，热压压力为2-3 兆帕的条件下进行第二次热压,即对上混胶粉板坯热压6-7分钟，优佳的是,此次热压压力为2.0兆帕,热压时间为6分钟,最终得到其厚度为3-4mm的紧实板材；在此步骤中,因混胶粉的含水率低,弹性大, 在成型时需要采用两段式加压才可使上混胶粉板坯和下混胶粉板坯成型；
步骤六、烘干，将步骤五的紧实板材输入至烘干机中烘干60-65 分钟，即可得到中底板材，烘干时，工作压力优佳为0.8MPa,烘干时间为60分钟。
本发明的一种天然茶籽饼合成中底板材的制备方法，其制备的中底板材所检测到的物理性能是：表面粗糙度≤0.4微米，水份含量≤ 6％，密度:0.45g/cm3，耐曲挠指数≥1.4，剥离强度≥0.24KN/m，浸水抗张0.26kN/m。
本发明的一种天然茶籽饼合成中底板材的制备方法，由于中底板质量要求是多方面的，其柔软性、尺寸稳定性和定型性要好，层间剥离强度、耐曲挠强度和耐湿摩擦强度要高，还具有一定的密度和吸水率等，其中柔软和强度是最要的质量要求；因此，采用纯天然的茶粕时通过丁腈橡胶胶粘剂的粘性易于茶粕成型成饼状，并配合高岭土的强度，使饼状的茶粕强度较高，再有配合中间的胶粘体纤网片对整个中底板材起到骨架作用，不但对整个中底板材的强度明显提高，层间剥离强度也达到标准，再利用丁腈橡胶胶粘剂使胶粘体纤网片与混胶粉之间实现结合；在成型时，利用干法热压使混胶粉板坯蒸发水分较少，无需再加金属垫网，因此，无需进行硬压光也能使成型出来的双面光的中底板材；在热压过程中茶粕、高岭土以及丁腈橡胶胶粘剂起着十分重要的增塑补强作用，少量水分不仅使胶粘体纤网片变得较为柔软，混胶粉板坯也容易被压实压密，更重要的是可以降低木质素和半纤维素等复合形成的高分子物质的玻璃化转变温度，使大分子链段和大分子本身的相互扩散运动更容易进行；最后的烘干工序中，随着水分的蒸发和板材的逐渐冷却，这些高聚物大分子又重新被束缚起来，从而完成各分子间的重组过程，使整个中底板材的密实性更佳。
本发明的一种天然茶籽饼合成中底板材的制备方法，有益效果：整个中底板材的主要原材料采用的是废弃的茶粕，使成型出来的中底板材中大部分原材料采用的是茶粕,而茶粕中含有12-18％的茶皂素, 利用良好的乳化、分解、发泡、湿润功能及消炎、杀菌、解毒、止痒、抗渗透的药理作用使中底板材具有良好的透气性,防潮,能杀灭脚部病菌,还能将脚部汗液吸收,增强了穿着舒适感,再配合胶粘体纤网片使整个中底板材的强度较高,达到穿着要求,定型效果佳,整个配方无味无毒，对人体无副作用，生物降解性强。
上述实施例并非限定本发明的具体方式，任何所属技术领域的普通技术人员对其所做的适当变化或修饰，皆应视为不脱离本发明的专利范畴。

Claims (5)

1.一种天然茶籽饼合成中底板材的制备方法，其特征在于，通过如下步骤制备而成：
步骤一、原料选取，选取高岭土和其细度为120-130目，含水量为12-14％的茶粕，且高岭土与茶粕的重量份比为1：6；
步骤二、搅拌，将步骤一的高岭土和茶粕倒入干粉搅拌机内搅拌，搅拌25-30分钟，得到混合粉；
步骤三、混胶，将步骤二的混合粉投入碎浆机中，并在碎浆机中丁腈橡胶胶粘剂进行搅拌混合35-40分钟，得到混胶粉，且混合粉与丁腈橡胶胶粘剂的重量份比为7：3；
步骤四、骨架形成，将水刺无纺布放入乳胶池中浸泡10分钟，浸泡后水刺无纺布转入循环传送带上进行常温晾干8-10分钟，形成胶粘体纤网片；
步骤五、热压成型，将热压机的工作平台上平铺一层混胶粉形成下混胶粉板坯，此下混胶粉板坯的厚度为3-4mm，热压机在热压温度160-170℃，热压压力为3-4兆帕的条件下对下混胶粉板坯热压3-4分钟，热压后得到压实板坯，之后在压实板坯的顶面平铺一层胶粘体纤网片，在胶粘体纤网片上平铺一层由步骤三的混胶粉堆成的厚度达到3-4mm的上混胶粉板坯，最后在热压机在热压温度160-170℃，热压压力为2-3兆帕的条件下对上混胶粉板坯热压6-7分钟，得到其厚度为3-4mm的紧实板材；
步骤六、烘干，将步骤五的紧实板材输入至烘干机中烘干60-65分钟，即可得到中底板材。
2.如权利要求1所述的一种天然茶籽饼合成中底板材的制备方法，其特征在于：上述步骤六中,所述烘干机的工作压力为0.8MPa,烘干时间为60分钟。
3.如权利要求1所述的一种天然茶籽饼合成中底板材的制备方法，其特征在于：上述步骤一中,选取10公斤的高岭土和60公斤的茶粕,步骤三中混合粉的重量份为70公斤,丁腈橡胶胶粘剂的重量份是30公斤。
4.如权利要求1所述的一种天然茶籽饼合成中底板材的制备方法，其特征在于：上述步骤五中,上述下混胶粉板坯的热压压力为3.5兆帕,上述上混胶粉板坯的热压压力为2.0兆帕。
5.如权利要求1所述的一种天然茶籽饼合成中底板材的制备方法，其特征在于：上述热压机的热源为饱和蒸汽。
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