CN112805272A - 包含具有mfi型骨架的沸石材料的模制品 - Google Patents

包含具有mfi型骨架的沸石材料的模制品 Download PDF

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Publication number
CN112805272A
CN112805272A CN201980066414.5A CN201980066414A CN112805272A CN 112805272 A CN112805272 A CN 112805272A CN 201980066414 A CN201980066414 A CN 201980066414A CN 112805272 A CN112805272 A CN 112805272A
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CN
China
Prior art keywords
zeolitic material
molded article
mfi
type framework
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201980066414.5A
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English (en)
Chinese (zh)
Inventor
A-N·帕乌莱斯库
H-J·卢茨伊勒
U·穆勒
D·里德尔
J·H·泰勒斯
M·韦伯
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BASF SE
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BASF SE
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Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN112805272A publication Critical patent/CN112805272A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
    • B22C1/18—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents
    • B22C1/181—Cements, oxides or clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/001—Calcining
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/22—After treatment, characterised by the effect to be obtained to destroy the molecular sieve structure or part thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201980066414.5A 2018-10-09 2019-10-09 包含具有mfi型骨架的沸石材料的模制品 Pending CN112805272A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP18199428.6 2018-10-09
EP18199428 2018-10-09
PCT/EP2019/077372 WO2020074586A1 (en) 2018-10-09 2019-10-09 A molding comprising a zeolitic material having framework type mfi

Publications (1)

Publication Number Publication Date
CN112805272A true CN112805272A (zh) 2021-05-14

Family

ID=63862001

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980066414.5A Pending CN112805272A (zh) 2018-10-09 2019-10-09 包含具有mfi型骨架的沸石材料的模制品

Country Status (9)

Country Link
US (1) US20210346942A1 (enExample)
EP (1) EP3864010A1 (enExample)
JP (1) JP7560452B2 (enExample)
KR (1) KR102863394B1 (enExample)
CN (1) CN112805272A (enExample)
MX (1) MX2021004084A (enExample)
SG (1) SG11202102455SA (enExample)
WO (1) WO2020074586A1 (enExample)
ZA (1) ZA202103028B (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2024543122A (ja) 2021-11-22 2024-11-19 ビーエーエスエフ ソシエタス・ヨーロピア エポキシ化触媒及びその調製方法
KR20240115875A (ko) 2021-11-29 2024-07-26 바스프 에스이 과산화수소 활성화를 위한 촉매
EP4688762A1 (en) 2023-04-06 2026-02-11 Basf Se Start-up method for a process for preparing an olefin oxide
KR20260018107A (ko) 2023-05-31 2026-02-06 바스프 에스이 과산화수소 활성화를 위한 촉매 성형체
EP4719665A1 (en) 2023-05-31 2026-04-08 Basf Se Catalyst for epoxidation of propylene
WO2026104463A1 (en) 2024-11-13 2026-05-21 Basf Se Improved epoxidation catalyst
WO2026104452A1 (en) 2024-11-13 2026-05-21 Basf Se Catalyst for epoxidation of propylene

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1301599A (zh) * 1999-12-24 2001-07-04 中国石油化工集团公司 一种钛硅分子筛及其制备方法
CN1370131A (zh) * 1999-08-20 2002-09-18 巴斯福股份公司 结晶态沸石固体的制备
CN102740968A (zh) * 2009-11-27 2012-10-17 巴斯夫欧洲公司 制备钛沸石催化剂的方法
CN103708493A (zh) * 2013-11-26 2014-04-09 华东师范大学 具有mfi结构钛硅分子筛及其制备方法
CN105358251A (zh) * 2013-07-05 2016-02-24 丹麦技术大学 用于生产沸石和类沸石的方法
CN105848781A (zh) * 2013-10-23 2016-08-10 巴斯夫欧洲公司 疏水性沸石材料的模制品及其制备方法
CN108250161A (zh) * 2016-12-28 2018-07-06 中国石油化工股份有限公司 烯丙醇氧化方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8785670B2 (en) * 2010-12-07 2014-07-22 Basf Se Process for the production of propylene oxide
MY188483A (en) * 2014-09-29 2021-12-14 China Petroleum & Chem Corp Olefin oxidation process, reaction apparatus and system
EP3615208A1 (en) * 2017-04-24 2020-03-04 Basf Se A molding comprising a zeolitic material, phosphorous, one or more metals and a binder

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1370131A (zh) * 1999-08-20 2002-09-18 巴斯福股份公司 结晶态沸石固体的制备
CN1301599A (zh) * 1999-12-24 2001-07-04 中国石油化工集团公司 一种钛硅分子筛及其制备方法
CN102740968A (zh) * 2009-11-27 2012-10-17 巴斯夫欧洲公司 制备钛沸石催化剂的方法
CN105358251A (zh) * 2013-07-05 2016-02-24 丹麦技术大学 用于生产沸石和类沸石的方法
CN105848781A (zh) * 2013-10-23 2016-08-10 巴斯夫欧洲公司 疏水性沸石材料的模制品及其制备方法
CN103708493A (zh) * 2013-11-26 2014-04-09 华东师范大学 具有mfi结构钛硅分子筛及其制备方法
CN108250161A (zh) * 2016-12-28 2018-07-06 中国石油化工股份有限公司 烯丙醇氧化方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
MENG LIU 等: "Highly Selective Epoxidation of Propylene in a Low-Pressure Continuous Slurry Reactor and the Regeneration of Catalyst", IND. ENG. CHEM. RES., vol. 54, 4 May 2015 (2015-05-04), pages 5416 - 5426 *

Also Published As

Publication number Publication date
EP3864010A1 (en) 2021-08-18
SG11202102455SA (en) 2021-04-29
BR112021005279A2 (pt) 2021-06-15
MX2021004084A (es) 2021-06-04
KR102863394B1 (ko) 2025-09-22
JP2022512656A (ja) 2022-02-07
JP7560452B2 (ja) 2024-10-02
WO2020074586A1 (en) 2020-04-16
ZA202103028B (en) 2025-09-25
KR20210066913A (ko) 2021-06-07
US20210346942A1 (en) 2021-11-11

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