CN1126791C - 热塑性丙烯腈-丁二烯-苯乙烯型模塑组合物 - Google Patents
热塑性丙烯腈-丁二烯-苯乙烯型模塑组合物 Download PDFInfo
- Publication number
- CN1126791C CN1126791C CN97122611A CN97122611A CN1126791C CN 1126791 C CN1126791 C CN 1126791C CN 97122611 A CN97122611 A CN 97122611A CN 97122611 A CN97122611 A CN 97122611A CN 1126791 C CN1126791 C CN 1126791C
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- China
- Prior art keywords
- weight
- particle diameter
- butadiene polymer
- vinylbenzene
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims abstract description 37
- 239000002245 particle Substances 0.000 claims abstract description 32
- 238000009826 distribution Methods 0.000 claims abstract description 27
- 229920001577 copolymer Polymers 0.000 claims abstract description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 27
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 26
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 12
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- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
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- 238000002360 preparation method Methods 0.000 description 13
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- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000004159 Potassium persulphate Substances 0.000 description 3
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- 239000002585 base Substances 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
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- 230000000052 comparative effect Effects 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 229940051250 hexylene glycol Drugs 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
- 235000019394 potassium persulphate Nutrition 0.000 description 3
- 238000010526 radical polymerization reaction Methods 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 2
- KLSLBUSXWBJMEC-UHFFFAOYSA-N 4-Propylphenol Chemical compound CCCC1=CC=C(O)C=C1 KLSLBUSXWBJMEC-UHFFFAOYSA-N 0.000 description 2
- IGSBHTZEJMPDSZ-UHFFFAOYSA-N 4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine Chemical compound C1CC(N)C(C)CC1CC1CC(C)C(N)CC1 IGSBHTZEJMPDSZ-UHFFFAOYSA-N 0.000 description 2
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
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- 239000000654 additive Substances 0.000 description 2
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- 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 description 2
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- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
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- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
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- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000011243 crosslinked material Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- KEIQPMUPONZJJH-UHFFFAOYSA-N dicyclohexylmethanediamine Chemical class C1CCCCC1C(N)(N)C1CCCCC1 KEIQPMUPONZJJH-UHFFFAOYSA-N 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229920006017 homo-polyamide Polymers 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Description
实施例 | ABS接枝聚合物1(重量份) | ABS接枝聚合物2(重量份) | ABS接枝聚合物3(重量份) | ABS接枝聚合物4(重量份) | ABS接枝聚合物5(重量份) | 树脂成分1(重量份) | 树脂成分1(重量份) |
1 | 15 | - | - | 15 | - | 70 | - |
2(比较) | - | 15 | - | 15 | - | 70 | - |
3(比较) | - | - | 15 | 15 | - | 70 | - |
4(比较) | 15 | - | - | - | 15 | 70 | - |
5 | 18.75 | - | - | 18.75 | - | 62.5 | - |
6(比较) | - | 18.75 | - | 18.75 | - | 62.5 | - |
7(比较) | - | - | 18.75 | 18.75 | - | 62.5 | - |
8(比较) | 18.75 | - | - | - | 18.75 | 62.5 | - |
9 | 21 | - | - | 9 | - | 40 | 30 |
10(比较) | - | 21 | - | 9 | - | 40 | 30 |
11(比较) | - | - | 21 | 9 | - | 40 | 30 |
12(比较) | 21 | - | - | - | 9 | 40 | 30 |
实施例 | aK RT(kJ/m2) | ak -40℃(kJ/m2) | HC(N/mm2) | Vicat B(℃) | MVI(cm3/10min) | 光泽度 |
1 | 16.2 | 7.7 | 107 | 99 | 37.4 | 97 |
2(比较) | 14.5 | 6.2 | 101 | 99 | 35.1 | 94 |
3(比较) | 15.9 | 6.6 | 108 | 100 | 36.7 | 93 |
4(比较) | 15.0 | 6.4 | 103 | 98 | 34.9 | 93 |
5 | 26.8 | 16.5 | 94 | 99 | 20.7 | 95 |
6(比较) | 20.5 | 8.5 | 91 | 99 | 18.8 | 93 |
7(比较) | 22.5 | 9.9 | 94 | 100 | 20.4 | 92 |
8(比较) | 21.8 | 9.0 | 92 | 99 | 18.8 | 93 |
9 | 22.5 | 10.0 | 103 | 105 | 8.7 | 93 |
10(比较) | 17.5 | 7.2 | 97 | 104 | 8.4 | 90 |
11(比较) | 18.1 | 7.6 | 102 | 105 | 9.0 | 88 |
12(比较) | 18.8 | 7.8 | 98 | 104 | 8.5 | 88 |
Claims (6)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19649255.6 | 1996-11-28 | ||
DE19649255A DE19649255A1 (de) | 1996-11-28 | 1996-11-28 | Thermoplastische Hochglanz-Formmassen vom ABS-Typ |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1188118A CN1188118A (zh) | 1998-07-22 |
CN1126791C true CN1126791C (zh) | 2003-11-05 |
Family
ID=7812981
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN97122611A Expired - Lifetime CN1126791C (zh) | 1996-11-28 | 1997-11-28 | 热塑性丙烯腈-丁二烯-苯乙烯型模塑组合物 |
Country Status (9)
Country | Link |
---|---|
US (1) | US5883189A (zh) |
EP (1) | EP0845496B1 (zh) |
JP (1) | JP4181652B2 (zh) |
CN (1) | CN1126791C (zh) |
AR (1) | AR010316A1 (zh) |
AU (1) | AU738243B2 (zh) |
BR (1) | BR9706037A (zh) |
DE (2) | DE19649255A1 (zh) |
ES (1) | ES2210447T3 (zh) |
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US5852124A (en) * | 1996-08-06 | 1998-12-22 | Chi Mei Corporation | Rubber-modified styrenic resin composition |
DE19926622A1 (de) * | 1999-06-11 | 2000-12-14 | Bayer Ag | Thermoplastische Formmassen |
DE10008418A1 (de) * | 2000-02-23 | 2001-08-30 | Bayer Ag | ABS-Formmassen mit verbesserter Verarbeitbarkeit und hohem Glanz |
DE10008420A1 (de) | 2000-02-23 | 2001-08-30 | Bayer Ag | Polymerzusammensetzungen mit verbesserter Eigenschaftskonstanz |
DE10008419A1 (de) | 2000-02-23 | 2001-08-30 | Bayer Ag | Polymerzusammensetzungen mit verbesserter Eigenschaftskonstanz |
CN1170882C (zh) | 2000-03-09 | 2004-10-13 | 拜尔公司 | 含有接枝橡胶的聚碳酸酯模塑组合物 |
US6828380B2 (en) * | 2000-03-09 | 2004-12-07 | Bayer Aktiengesellschaft | Thermoplastic molding materials based on special graft rubber components |
DE10014610A1 (de) * | 2000-03-24 | 2001-09-27 | Bayer Ag | Thermoplastische Polyvinylcyclohexan-Formmassen mit verbesserten Eigenschaften |
JP4056712B2 (ja) * | 2000-10-24 | 2008-03-05 | 三井化学株式会社 | 耐フロン性ゴム変性ポリスチレン組成物 |
KR20020036556A (ko) | 2000-11-10 | 2002-05-16 | 노기호 | 총고형분 함량이 높은 아크릴로니트릴-부타디엔-스티렌라텍스의 제조방법 |
DE10060411A1 (de) | 2000-12-05 | 2002-06-06 | Bayer Ag | Thermoplastische Formmassen |
DE10060410A1 (de) | 2000-12-05 | 2002-06-06 | Bayer Ag | Thermoplastische Formmassen |
DE10137782A1 (de) * | 2001-08-02 | 2003-02-13 | Bayer Ag | Polymerzusammensetzung mit verbesserter Eigenschaftskonstanz |
KR100469866B1 (ko) * | 2001-12-24 | 2005-02-02 | 제일모직주식회사 | 내후성 및 내충격성이 향상된 열가소성 수지조성물 및 그제조방법 |
DE10223646A1 (de) * | 2002-05-28 | 2003-12-11 | Bayer Ag | Verfahren zur Herstellung von ABS-Zusammensetzungen mit verbesserten Zähigkeitseigenschaften |
US8153730B2 (en) * | 2003-11-26 | 2012-04-10 | Fina Technology, Inc. | Polyolefin blends used as masterbatch concentrates |
US20060040076A1 (en) * | 2004-08-18 | 2006-02-23 | Franzyshen Stephen K | Formable film for cold-form, blister-type pharmaceutical packaging |
KR100653503B1 (ko) * | 2004-08-19 | 2006-12-04 | 주식회사 엘지화학 | 고무강화 열가소성 수지의 제조방법 및 이를 이용한고무강화 열가소성 수지 조성물 |
EP1752478A1 (en) | 2005-08-08 | 2007-02-14 | Basf Aktiengesellschaft | A process for the production of a graft copolymer having a bimodal particle distribution. |
KR100779159B1 (ko) * | 2005-08-30 | 2007-11-28 | 주식회사 엘지화학 | 열가소성 수지 조성물 및 그 제조방법 |
DE102007045959A1 (de) | 2007-09-26 | 2009-04-09 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von Kautschuklatices mit definiertem stabilem Gelgehalt für die ABS-Herstellung |
KR101129980B1 (ko) | 2007-12-18 | 2012-03-28 | 주식회사 엘지화학 | 스티렌계 열가소성 수지 조성물 및 이를 이용한 가전제품의내상용 압출 시트 |
EP2288960B1 (en) * | 2008-06-12 | 2012-12-26 | Milestone AV Technologies LLC | Universal projector interface with sustainable alignment |
DE102009015039A1 (de) * | 2009-03-26 | 2010-09-30 | Bayer Materialscience Ag | Schlagzähmodifizierte Polycarbonat-Zusammensetzungen zur Herstellung metallisierter Formkörper mit homogenem Oberflächenglanz |
EP2623289A4 (en) * | 2010-10-01 | 2016-08-24 | Asahi Kasei Chemicals Corp | INJECTION MOLDED OBJECT, SHOCK-RESISTANT, VERY REFLECTIVE AND NON-COATING, AND PRODUCTION PROCESS |
EP2657258A1 (de) * | 2012-04-23 | 2013-10-30 | Bayer MaterialScience AG | Verfahren zur Herstellung von ABS-Zusammensetzungen mit verbesserter Oberfläche nach Wärme-Feucht-Lagerung |
CN102994024A (zh) * | 2012-12-19 | 2013-03-27 | 青岛海尔软件有限公司 | 一种丁腈橡胶-丙烯酸酯uv固化压敏胶的制备方法 |
WO2016162557A1 (en) * | 2015-04-10 | 2016-10-13 | Ineos Styrolution Group Gmbh | Process for the production of thermoplastic moulding compounds |
WO2016198508A1 (en) * | 2015-06-12 | 2016-12-15 | Ineos Styrolution Group Gmbh | Process for the production of thermoplastic moulding compounds |
CN107001747B (zh) | 2015-08-31 | 2019-10-01 | 株式会社Lg化学 | 热塑性树脂和包含该热塑性树脂的热塑性树脂组合物 |
CN109219621B (zh) | 2015-12-02 | 2021-01-12 | 英力士苯领集团股份公司 | 生产具有改进性能的abs塑料的方法 |
KR101884972B1 (ko) * | 2015-12-04 | 2018-08-02 | 주식회사 엘지화학 | 무광 및 유광이 우수한 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
EP3464467B1 (en) | 2016-06-06 | 2020-03-18 | INEOS Styrolution Group GmbH | Process for producing a stabilizer dispersion and process for producing a thermoplastic composition stabilized with the stabilizer dispersion |
CN112322015B (zh) * | 2020-10-16 | 2022-06-24 | 金发科技股份有限公司 | 一种聚碳酸酯/聚苯乙烯合金及其制备方法和应用 |
WO2024028309A1 (de) | 2022-08-04 | 2024-02-08 | Ineos Styrolution Group Gmbh | Thermoplastische abs-formmassen mit einer guten eigenschaftskombination von verarbeitbarkeit und oberflächenqualität |
WO2024194289A1 (en) | 2023-03-21 | 2024-09-26 | Ineos Styrolution Group Gmbh | Process for the preparation of a thermoplastic molding composition with good color stability |
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- 1996-11-28 DE DE19649255A patent/DE19649255A1/de not_active Withdrawn
-
1997
- 1997-11-17 EP EP97120060A patent/EP0845496B1/de not_active Expired - Lifetime
- 1997-11-17 ES ES97120060T patent/ES2210447T3/es not_active Expired - Lifetime
- 1997-11-17 DE DE59710956T patent/DE59710956D1/de not_active Expired - Lifetime
- 1997-11-21 JP JP33655697A patent/JP4181652B2/ja not_active Expired - Fee Related
- 1997-11-21 US US08/975,561 patent/US5883189A/en not_active Expired - Lifetime
- 1997-11-27 BR BR9706037A patent/BR9706037A/pt not_active IP Right Cessation
- 1997-11-27 AR ARP970105589A patent/AR010316A1/es not_active Application Discontinuation
- 1997-11-27 AU AU46889/97A patent/AU738243B2/en not_active Ceased
- 1997-11-28 CN CN97122611A patent/CN1126791C/zh not_active Expired - Lifetime
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CN1053075A (zh) * | 1990-01-02 | 1991-07-17 | 陶氏化学公司 | 具有良好光泽和光泽敏感性降低的三峰分布abs组合物 |
Also Published As
Publication number | Publication date |
---|---|
US5883189A (en) | 1999-03-16 |
EP0845496B1 (de) | 2003-11-05 |
CN1188118A (zh) | 1998-07-22 |
EP0845496A3 (de) | 1998-08-05 |
DE59710956D1 (de) | 2003-12-11 |
JP4181652B2 (ja) | 2008-11-19 |
AR010316A1 (es) | 2000-06-07 |
JPH10158343A (ja) | 1998-06-16 |
BR9706037A (pt) | 1999-07-06 |
DE19649255A1 (de) | 1998-06-04 |
ES2210447T3 (es) | 2004-07-01 |
AU4688997A (en) | 1998-06-04 |
EP0845496A2 (de) | 1998-06-03 |
AU738243B2 (en) | 2001-09-13 |
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