CN112585144A - 有机金属配合物、包含其的高聚物、混合物、组合物及有机电子器件 - Google Patents
有机金属配合物、包含其的高聚物、混合物、组合物及有机电子器件 Download PDFInfo
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- CN112585144A CN112585144A CN201980051104.6A CN201980051104A CN112585144A CN 112585144 A CN112585144 A CN 112585144A CN 201980051104 A CN201980051104 A CN 201980051104A CN 112585144 A CN112585144 A CN 112585144A
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- 125000002524 organometallic group Chemical group 0.000 title claims abstract description 82
- 239000000203 mixture Substances 0.000 title claims description 47
- 229920000642 polymer Polymers 0.000 title claims description 30
- 239000000463 material Substances 0.000 claims abstract description 115
- 239000003446 ligand Substances 0.000 claims description 43
- 125000003118 aryl group Chemical group 0.000 claims description 40
- 229910052757 nitrogen Inorganic materials 0.000 claims description 39
- 229910052751 metal Inorganic materials 0.000 claims description 33
- 239000002184 metal Substances 0.000 claims description 29
- 125000006413 ring segment Chemical group 0.000 claims description 19
- 125000003545 alkoxy group Chemical group 0.000 claims description 15
- 125000001072 heteroaryl group Chemical group 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 239000003960 organic solvent Substances 0.000 claims description 14
- 125000005309 thioalkoxy group Chemical group 0.000 claims description 13
- 230000000903 blocking effect Effects 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 150000001450 anions Chemical class 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
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- 230000005669 field effect Effects 0.000 claims description 9
- 230000007935 neutral effect Effects 0.000 claims description 9
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- 125000004093 cyano group Chemical group *C#N 0.000 claims description 8
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
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- ZBKFYXZXZJPWNQ-UHFFFAOYSA-N isothiocyanate group Chemical group [N-]=C=S ZBKFYXZXZJPWNQ-UHFFFAOYSA-N 0.000 claims description 7
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 7
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- MHOZZUICEDXVGD-UHFFFAOYSA-N pyrrolo[2,3-d]imidazole Chemical compound C1=NC2=CC=NC2=N1 MHOZZUICEDXVGD-UHFFFAOYSA-N 0.000 description 1
- ZCOSUVZGFDGWFV-UHFFFAOYSA-N pyrrolo[2,3-e]indole Chemical compound C1=CC2=NC=CC2=C2N=CC=C21 ZCOSUVZGFDGWFV-UHFFFAOYSA-N 0.000 description 1
- RQGPLDBZHMVWCH-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole Chemical compound C1=NC2=CC=NC2=C1 RQGPLDBZHMVWCH-UHFFFAOYSA-N 0.000 description 1
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- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 description 1
- ONCNIMLKGZSAJT-UHFFFAOYSA-N thieno[3,2-b]furan Chemical compound S1C=CC2=C1C=CO2 ONCNIMLKGZSAJT-UHFFFAOYSA-N 0.000 description 1
- VJYJJHQEVLEOFL-UHFFFAOYSA-N thieno[3,2-b]thiophene Chemical compound S1C=CC2=C1C=CS2 VJYJJHQEVLEOFL-UHFFFAOYSA-N 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 1
- 125000005259 triarylamine group Chemical group 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
- 125000005580 triphenylene group Chemical group 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- PCMOZDDGXKIOLL-UHFFFAOYSA-K yttrium chloride Chemical compound [Cl-].[Cl-].[Cl-].[Y+3] PCMOZDDGXKIOLL-UHFFFAOYSA-K 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K99/00—Subject matter not provided for in other groups of this subclass
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
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- C—CHEMISTRY; METALLURGY
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- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
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- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Electroluminescent Light Sources (AREA)
Abstract
公开了一种新型有机金属配合物，及其在有机电子器件，特别是在有机磷光发光二极管中的应用。还涉及包含有本发明的有机金属配合物的有机电子器件，特别是有机发光二极管，及其在显示及照明技术中的应用。通过器件结构优化，改变金属配合物在基质中的浓度，提高器件性能，实现高效高亮度高稳定的OLED器件，为全彩显示和照明应用提供了较好的材料选项。
Description
PCT国内申请，说明书已公开。
Claims (16)
- PCT国内申请，权利要求书已公开。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811300169 | 2018-11-02 | ||
| CN2018113001693 | 2018-11-02 | ||
| PCT/CN2019/109288 WO2020088186A1 (zh) | 2018-11-02 | 2019-09-30 | 有机金属配合物、包含其的高聚物、混合物、组合物及有机电子器件 |
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| CN112585144A true CN112585144A (zh) | 2021-03-30 |
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| WO (1) | WO2020088186A1 (zh) |
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| CN113354689B (zh) * | 2021-06-15 | 2022-09-23 | 江苏科技大学 | 一种含联苯衍生物配位的中性铱配合物及其制备方法和应用 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101896493A (zh) * | 2007-10-17 | 2010-11-24 | 巴斯夫欧洲公司 | 具有桥连碳烯配体的过渡金属配合物及其在oled中的用途 |
| TW201527484A (zh) * | 2014-01-15 | 2015-07-16 | Nat Univ Tsing Hua | 含雙唑類配基的銥金屬錯合物 |
| CN109608504A (zh) * | 2017-12-28 | 2019-04-12 | 广州华睿光电材料有限公司 | 有机金属配合物、聚合物、混合物、组合物和有机电子器件 |
| WO2019128848A1 (zh) * | 2017-12-28 | 2019-07-04 | 广州华睿光电材料有限公司 | 一种有机金属配合物，包含其的聚合物、混合物和组合物，及其在电子器件中的应用 |
-
2019
- 2019-09-30 WO PCT/CN2019/109288 patent/WO2020088186A1/zh active Application Filing
- 2019-09-30 CN CN201980051104.6A patent/CN112585144A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101896493A (zh) * | 2007-10-17 | 2010-11-24 | 巴斯夫欧洲公司 | 具有桥连碳烯配体的过渡金属配合物及其在oled中的用途 |
| TW201527484A (zh) * | 2014-01-15 | 2015-07-16 | Nat Univ Tsing Hua | 含雙唑類配基的銥金屬錯合物 |
| CN109608504A (zh) * | 2017-12-28 | 2019-04-12 | 广州华睿光电材料有限公司 | 有机金属配合物、聚合物、混合物、组合物和有机电子器件 |
| WO2019128848A1 (zh) * | 2017-12-28 | 2019-07-04 | 广州华睿光电材料有限公司 | 一种有机金属配合物，包含其的聚合物、混合物和组合物，及其在电子器件中的应用 |
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|---|---|
| WO2020088186A1 (zh) | 2020-05-07 |
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