CN112457053A - 一种改性硅酸钙板及其表面处理方法以及应用 - Google Patents

一种改性硅酸钙板及其表面处理方法以及应用 Download PDF

Info

Publication number
CN112457053A
CN112457053A CN202011251691.4A CN202011251691A CN112457053A CN 112457053 A CN112457053 A CN 112457053A CN 202011251691 A CN202011251691 A CN 202011251691A CN 112457053 A CN112457053 A CN 112457053A
Authority
CN
China
Prior art keywords
calcium silicate
silicate board
sizing
modified calcium
primary
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202011251691.4A
Other languages
English (en)
Other versions
CN112457053B (zh
Inventor
丁永平
顾海兵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Langyuan Meisheng New Material Technology Co ltd
Original Assignee
Jiangsu Langyuan Meisheng New Material Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Langyuan Meisheng New Material Technology Co ltd filed Critical Jiangsu Langyuan Meisheng New Material Technology Co ltd
Priority to CN202011251691.4A priority Critical patent/CN112457053B/zh
Publication of CN112457053A publication Critical patent/CN112457053A/zh
Priority to PCT/CN2021/127223 priority patent/WO2022100453A1/zh
Priority to US17/614,516 priority patent/US20220348512A1/en
Application granted granted Critical
Publication of CN112457053B publication Critical patent/CN112457053B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • C04B41/524—Multiple coatings, comprising a coating layer of the same material as a previous coating layer
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • C04B41/5089—Silica sols, alkyl, ammonium or alkali metal silicate cements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/36—Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • B05D1/38—Successively applying liquids or other fluent materials, e.g. without intermediate treatment with intermediate treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/54—No clear coat specified
    • B05D7/544—No clear coat specified the first layer is let to dry at least partially before applying the second layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/14—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood board or veneer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00—Layered products comprising a layer of paper or cardboard
    • B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/08—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/042—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of wood
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/06—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/18—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/457—Non-superficial impregnation or infiltration of the substrate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48—Macromolecular compounds
    • C04B41/4853—Epoxides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61—Coating or impregnation
    • C04B41/62—Coating or impregnation with organic materials
    • C04B41/63—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61—Coating or impregnation
    • C04B41/65—Coating or impregnation with inorganic materials
    • C04B41/68—Silicic acid; Silicates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61—Coating or impregnation
    • C04B41/70—Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • C04B41/71—Coating or impregnation for obtaining at least two superposed coatings having different compositions at least one coating being an organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/028—Paper layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Finishing Walls (AREA)

Abstract

一种改性硅酸钙板，属于地板、装饰板技术领域，改性方法是将硅酸钙板浸渍于固含量在95%以上的二氧化硅溶液中,完全吸透至饱和,再将浸渍后的硅酸钙板干燥处理；在改性完成的硅酸钙板的任一面上进行施胶硬化，获得硅酸钙板，能使三胺浸渍纸与其直接热压贴合，表结合强度达到1MPa；木皮、防火板等材料与其冷贴，产品剥离强度均符合要求，有效提高了硅酸钙板的实用性。

Description

一种改性硅酸钙板及其表面处理方法以及应用
技术领域
本发明属于地板、装饰板技术领域，尤其涉及复合装饰板材的制备技术。
背景技术
随着人民生活水平的提高，对装饰材料的环保、阻燃、美观等要求愈来愈高。硅酸钙板是一种新颖装饰材料，它的稳定性、阻燃性、无甲醛、低成本等优势越来越迎合市场的需求。
但已知的硅酸钙板，多以无机材料如硅酸钙或碳酸钙等无机材料的粉末制成，更详细地说，以硅酸质与石灰质为主要成分，经制浆、抄制、 蒸养等工序制成，由于在高温高压下反应结晶而成，故实质上为众多的硅酸钙结晶粉末；也或是以水泥、硅沙、石绵等纤维加入添加物经抄取法或流浆法高压蒸养压制而成，然而，由于粉末间的结合力弱，当要在此类硅酸钙板的表面贴覆一表材时，较为靠近表材的粉末易被表材撕起而剥离，使表材难以牢固地贴合，也即表材相当容易被剥离，而细究其原因，即是因为硅酸钙板的结构松散，各粉末间的结合力小于粘胶的粘合力，使拉扯的力量直接传递至较为靠近的粉末，造成表材易将较为靠近的粉末一同剥离，实为施工上的困难之处。
中国专利公告号CN105859323B，公开了一种硅酸钙板表层处理方法，包含以下步骤：一、备一硅酸钙板：其中该硅酸钙板具有相对的一第一面与一第二面；二、涂布第一次水玻璃溶液：在该硅酸钙板的第一面涂布或喷洒重量百分浓度为a的水玻璃溶液，使水玻璃溶液渗入该硅酸钙板一预定厚度；三、涂布第二次水玻璃溶液：在该硅酸钙板的第一面涂布或喷洒重量百分浓度为b的水玻璃溶液，使水玻璃溶液渗入该硅酸钙板一预定厚度；其中，a小于b，且a与b皆分别大于30％但小于55％。该技术方案能使硅酸钙板表层结构密实而易于贴覆表材，表材可牢固地粘贴于硅酸钙板上不易剥离，也是对硅酸钙板的一种改性方法，但其只是简单的在需要与表材贴合的贴合面进行水玻璃涂布，让水玻璃浸入基板表面，长、宽尺寸为2400mm、1200mm的硅酸钙板也只涂布50克至60克，进入的深度只停留在浅表层，只能防止初级剥离，离现在市面上要求的抗剥落，抗弯折的硅酸钙板才存在技术问题，而且发现，这种基材处理后的硅酸钙板，用三胺浸渍纸与其热压是完全粘不住的。
发明内容,
本发明针对现有技术的不足，提供了一种可整体强化硅酸钙板的结构和密实度，方便与各种表材复合的改性硅酸钙板以及表层处理方法，能使三胺浸渍纸与基材直接热压贴合，表结合强度达到1MPa；木皮、防火板等材料与其冷贴，产品剥离强度均符合要求，有效提高了硅酸钙板的实用性。
为实现本发明目的，提供了以下技术方案：一种改性硅酸钙板，其特征在于改性方法是：将硅酸钙板浸渍于固含量在95%以上的二氧化硅溶液中,直至完全吸透至饱和,再将浸渍后的硅酸钙板干燥处理。通过完全浸渍基材来改性硅酸钙板，比现有技术中仅在表面涂覆涂层改性相比，提高了基材的内结合强度。
上述改性硅酸钙板的表面处理方法，包括在改性完成的硅酸钙板的任一面上进行施胶硬化，其特征在于施胶硬化包括涂胶、流平渗透、烘干、冷却、抛光。
作为优选，施胶硬化具体为：
（1）第一道施胶:一次涂胶、一次流平渗透、一次烘干、一次冷却、一次抛光；
（2）在第一道施胶后的面上进行第二道施胶:二次涂胶、二次烘干、二次抛光。
作为优选，第一道施胶中一次涂胶的上胶量为：当板材密度在900~950kg/m³，上胶量110-120g/m2；当板材密度在950~1100kg/m³，上胶量在90-100g/m2；当板材密度在1100~1300kg/m³，上胶量75-85g/m2。
作为优选，一次涂胶采用水性双组份环氧胶,与基材有更好的适用性。
作为优选，一次烘干以10~12m/min的速度进烘道，烘道设置温度130~150℃，烘道长度为10~15m。
作为优选，二次涂胶的上胶量为40~50g/m2。
作为优选，二次烘干以8-10m/min的速度进烘道，烘道设置温度130~150℃，烘道长度为10~15m。
作为优选，二次涂胶采用水性丙烯酸胶加固化剂异氰酸酯, 水性丙烯酸胶与异氰酸酯的重量配比为3.5-10：1,最佳配比为6-7:1,强度最高，便于量产化。
为实现本发明目的，提供了一种硅酸钙板的应用，其特征在于任一面上贴覆表材。
作为优选，表材包括：三胺浸渍纸，木皮，防火板。
作为优选，表材的贴覆方法包括高温热压，冷压。
本发明有益效果：
1. 通过对硅酸钙板改性，提高了基材的内结合强度；
2. 通过基材表面的涂胶处理，可使基材与其它各种表材相复合，不仅能使三胺浸渍纸与基材直接热压贴合，表结合强度达到1MPa以上，而且木皮、防火板等材料与其冷贴，产品剥离强度均符合要求，有效提高了硅酸钙板的实用性，适用范围更加广泛。
3. 贴覆表材后的终产品,降低了消费成本，环保无毒。
具体实施方式
实施例1
一种改性硅酸钙板，将硅酸钙板浸渍于固含量在95%以上的二氧化硅溶液中,完全吸透至饱和,再将浸渍后的硅酸钙板干燥处理。
分别对改性前的硅酸钙板和改性后的硅酸钙板进行内结合力检测，改性前为40kg/f，改性后为70 kg/f。
实施例2
将实施例1改性得到的硅酸钙板进行表面处理：即在改性完成的硅酸钙板的任一面上进行施胶硬化：
（1）第一道施胶:一次涂胶、一次流平渗透、一次烘干、一次冷却、一次抛光，第一道施胶中一次涂胶的上胶量为：当板材密度在910kg/m³，上胶量120g/m2，一次涂胶采用水性双组份环氧胶,一次烘干以10m/min的速度进烘道，烘道设置温度150℃，烘道长度为10m。
（2）在第一道施胶后的面上进行第二道施胶:二次涂胶、二次烘干、二次抛光，二次涂胶的上胶量为40g/m2，二次烘干以8m/min的速度进烘道，烘道设置温度150℃，烘道长度为10m，二次涂胶采用水性丙烯酸胶加固化剂异氰酸酯, 水性丙烯酸胶与异氰酸酯的重量配比为3.5：1。
实施例3-7，参考实施例2，第一道施胶和第二道施胶的参数调控如表一。
表一
Figure DEST_PATH_IMAGE001
实施例8-16，在上述实施2-7的硅酸钙板上贴覆表材，对成品进行剥离强度检测，具体见表二。
Figure 639950DEST_PATH_IMAGE002

Claims (10)

1.一种改性硅酸钙板，其特征在于改性方法是：将硅酸钙板浸渍于固含量在95%以上的二氧化硅溶液中,完全吸透至饱和,再将浸渍后的硅酸钙板干燥处理。
2.如权利要求1所述改性硅酸钙板的表面处理方法，包括在改性完成的硅酸钙板的任一面上进行施胶硬化，其特征在于施胶硬化包括涂胶、流平渗透、烘干、冷却、抛光。
3.根据权利要求2所述的改性硅酸钙板的表面处理方法，其特征在于施胶硬化具体为：
（1）第一道施胶:一次涂胶、一次流平渗透、一次烘干、一次冷却、一次抛光；
（2）在第一道施胶后的面上进行第二道施胶:二次涂胶、二次烘干、二次抛光。
4.根据权利要求3所述的改性硅酸钙板的表面处理方法，其特征在于第一道施胶中一次涂胶的上胶量为：当板材密度在900~950kg/m³，上胶量110-120g/m2；当板材密度在950~1100kg/m³，上胶量在90-100g/m2；当板材密度在1100~1300kg/m³，上胶量75-85g/m2；一次涂胶采用水性双组份环氧胶,与基材有更好的适用性，一次烘干以10~12m/min的速度进烘道，烘道设置温度130~150℃，烘道长度为10~15m。
5.根据权利要求3所述的改性硅酸钙板的表面处理方法，其特征在于二次涂胶的上胶量为40~50g/m2。
6.根据权利要求3所述的改性硅酸钙板的表面处理方法，其特征在于二次烘干以8-10m/min的速度进烘道，烘道设置温度130~150℃，烘道长度为10~15m。
7. 根据权利要求3所述的改性硅酸钙板的表面处理方法，其特征在于二次涂胶采用水性丙烯酸胶加固化剂异氰酸酯, 水性丙烯酸胶与异氰酸酯的重量配比为3.5-10：1。
8.根据权利要求7所述的改性硅酸钙板的表面处理方法，其特征在于水性丙烯酸胶与异氰酸酯的重量配比为6-7:1。
9.权利要求2-8之一所述硅酸钙板的应用，其特征在于硅酸钙板的任一面上贴覆表材。
10.根据权利要求9所述硅酸钙板的应用，其特征在于表材包括三胺浸渍纸，木皮，防火板，表材的贴覆方法包括高温热压，冷压。
CN202011251691.4A 2020-11-11 2020-11-11 一种改性硅酸钙板及其表面处理方法以及应用 Active CN112457053B (zh)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN202011251691.4A CN112457053B (zh) 2020-11-11 2020-11-11 一种改性硅酸钙板及其表面处理方法以及应用
PCT/CN2021/127223 WO2022100453A1 (zh) 2020-11-11 2021-10-29 一种改性硅酸钙板及其表面处理方法以及应用
US17/614,516 US20220348512A1 (en) 2020-11-11 2021-10-29 Modified calcium silicate board and surface treatment method and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011251691.4A CN112457053B (zh) 2020-11-11 2020-11-11 一种改性硅酸钙板及其表面处理方法以及应用

Publications (2)

Publication Number Publication Date
CN112457053A true CN112457053A (zh) 2021-03-09
CN112457053B CN112457053B (zh) 2022-07-15

Family

ID=74825416

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011251691.4A Active CN112457053B (zh) 2020-11-11 2020-11-11 一种改性硅酸钙板及其表面处理方法以及应用

Country Status (3)

Country Link
US (1) US20220348512A1 (zh)
CN (1) CN112457053B (zh)
WO (1) WO2022100453A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022100453A1 (zh) * 2020-11-11 2022-05-19 江苏朗园美盛新材料科技有限公司 一种改性硅酸钙板及其表面处理方法以及应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52104527A (en) * 1976-02-28 1977-09-02 Matsushita Electric Works Ltd Method of coating with inorganic silicate paint
CN201649509U (zh) * 2010-05-06 2010-11-24 芦长江 一种彩面硅酸钙板
CN102673082A (zh) * 2012-04-12 2012-09-19 成都帝龙新材料有限公司 一种以硅酸钙为基材板的饰面板制造工艺
CN105859323A (zh) * 2015-01-21 2016-08-17 蔡承宗 硅酸钙板表层处理方法
CN207660224U (zh) * 2017-11-25 2018-07-27 广东耀东华装饰材料科技有限公司 一种耐火防水板
CN109322457A (zh) * 2018-10-11 2019-02-12 湖南安雅达建材科技有限公司 一种无机复合板材及其制造方法
CN111823692A (zh) * 2020-07-27 2020-10-27 安徽三棵树涂料有限公司 一种表面贴实木木皮的硅酸钙板的生产方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101775892A (zh) * 2009-12-30 2010-07-14 浙江德维地板有限公司 一种阻燃复合地板及其制造方法
CN112457053B (zh) * 2020-11-11 2022-07-15 江苏朗园美盛新材料科技有限公司 一种改性硅酸钙板及其表面处理方法以及应用

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52104527A (en) * 1976-02-28 1977-09-02 Matsushita Electric Works Ltd Method of coating with inorganic silicate paint
CN201649509U (zh) * 2010-05-06 2010-11-24 芦长江 一种彩面硅酸钙板
CN102673082A (zh) * 2012-04-12 2012-09-19 成都帝龙新材料有限公司 一种以硅酸钙为基材板的饰面板制造工艺
CN105859323A (zh) * 2015-01-21 2016-08-17 蔡承宗 硅酸钙板表层处理方法
CN207660224U (zh) * 2017-11-25 2018-07-27 广东耀东华装饰材料科技有限公司 一种耐火防水板
CN109322457A (zh) * 2018-10-11 2019-02-12 湖南安雅达建材科技有限公司 一种无机复合板材及其制造方法
CN111823692A (zh) * 2020-07-27 2020-10-27 安徽三棵树涂料有限公司 一种表面贴实木木皮的硅酸钙板的生产方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
崔玉民，陶栋梁，殷榕灿: "《绿色环保功能涂料》", 31 January 2019 *
李肇强: "《现代涂料的生产及应用》", 31 March 2017 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022100453A1 (zh) * 2020-11-11 2022-05-19 江苏朗园美盛新材料科技有限公司 一种改性硅酸钙板及其表面处理方法以及应用

Also Published As

Publication number Publication date
US20220348512A1 (en) 2022-11-03
WO2022100453A1 (zh) 2022-05-19
CN112457053B (zh) 2022-07-15

Similar Documents

Publication Publication Date Title
CN110746174A (zh) 一种a级防火矿物质板及其制备方法
CN101963029B (zh) 一种门用复合防火板及其制作方法
CN111300568B (zh) 一种改性三聚氰胺甲醛树脂浸渍液及其制备方法和应用
JP2021094842A (ja) 木質材料複合板及びその製造方法
CN112457053B (zh) 一种改性硅酸钙板及其表面处理方法以及应用
CN106626699A (zh) 一种防火防水装饰板材的制造方法
CN104139445B (zh) 无醛胶合室内胶合板或地板基材的制造方法
CN110181645A (zh) 水泥刨花板及其制备工艺和应用
CN111778766A (zh) 一种硅酸钙板热压贴面三聚氰胺浸渍纸及其制作方法
CN101323193A (zh) 木皮与石膏板表面复合工艺
CN110484047B (zh) 一种腻平粘结料及其制备方法
CN108608518A (zh) 一种微调式组合拼装式建筑装饰板及其制备方法
CN108612279A (zh) 一种外墙防火阻燃型复合保温装饰板材及其制备方法
CN206769270U (zh) 一种pp复合板
CN116396102A (zh) 一种纤维水泥板用无机水性渗透剂及其制备方法和应用
RU2015886C1 (ru) Способ производства строительных материалов с облагороженной поверхностью
LU500652B1 (en) Manufacturing Method of High-stability Formaldehyde-free Plywood
CN109080243A (zh) 一种无机装饰板及其制作工艺
AU2020103246A4 (en) High-strength eucalyptus and poplar composite veneer laminate and manufacturing method thereof
CN109129757A (zh) 新型喷射式壁面装饰材料及其制备方法
CN221437435U (zh) 一种防龟裂高阻燃柔性三胺饰面无机板材
CN115366205B (zh) 一种防开裂三聚氰胺浸胶装饰墙板的生产工艺
CN211164393U (zh) 环保防潮细木工板
CN108240077A (zh) 新型喷射式壁面装饰材料及其制备方法
CN117162201A (zh) 一种轻质难燃板

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant