CN112409828A - 一种用于高温炉窑远红外节能型辐射涂料 - Google Patents
一种用于高温炉窑远红外节能型辐射涂料 Download PDFInfo
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- CN112409828A CN112409828A CN202011325978.7A CN202011325978A CN112409828A CN 112409828 A CN112409828 A CN 112409828A CN 202011325978 A CN202011325978 A CN 202011325978A CN 112409828 A CN112409828 A CN 112409828A
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- 230000005855 radiation Effects 0.000 title claims abstract description 114
- 238000000576 coating method Methods 0.000 title claims abstract description 105
- 239000011248 coating agent Substances 0.000 title claims abstract description 103
- 239000002994 raw material Substances 0.000 claims abstract description 37
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000010453 quartz Substances 0.000 claims abstract description 30
- 239000000843 powder Substances 0.000 claims abstract description 20
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 18
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims abstract description 15
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011019 hematite Substances 0.000 claims abstract description 15
- 229910052595 hematite Inorganic materials 0.000 claims abstract description 15
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 claims abstract description 15
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052622 kaolinite Inorganic materials 0.000 claims abstract description 15
- 239000010445 mica Substances 0.000 claims abstract description 15
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 15
- 229910052627 muscovite Inorganic materials 0.000 claims abstract description 15
- 229910003445 palladium oxide Inorganic materials 0.000 claims abstract description 15
- JQPTYAILLJKUCY-UHFFFAOYSA-N palladium(ii) oxide Chemical compound [O-2].[Pd+2] JQPTYAILLJKUCY-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000835 fiber Substances 0.000 claims abstract description 14
- 229910052788 barium Inorganic materials 0.000 claims abstract description 11
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000010459 dolomite Substances 0.000 claims abstract description 11
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 11
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims abstract description 11
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims abstract description 11
- -1 sodium ammonium sulfide Chemical compound 0.000 claims abstract description 9
- 238000005245 sintering Methods 0.000 claims description 33
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 32
- 239000008367 deionised water Substances 0.000 claims description 25
- 229910021641 deionized water Inorganic materials 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 23
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 23
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 23
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 23
- 239000012530 fluid Substances 0.000 claims description 22
- 239000003973 paint Substances 0.000 claims description 21
- 238000001035 drying Methods 0.000 claims description 20
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 18
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 18
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 17
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- 229910052593 corundum Inorganic materials 0.000 claims description 15
- 239000010431 corundum Substances 0.000 claims description 15
- 229910021532 Calcite Inorganic materials 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 229910052586 apatite Inorganic materials 0.000 claims description 14
- 229910002113 barium titanate Inorganic materials 0.000 claims description 14
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 claims description 14
- 229910000464 lead oxide Inorganic materials 0.000 claims description 14
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 14
- 239000001095 magnesium carbonate Substances 0.000 claims description 14
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 14
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 14
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 claims description 14
- 229910052903 pyrophyllite Inorganic materials 0.000 claims description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 13
- 239000011701 zinc Substances 0.000 claims description 13
- 229910052725 zinc Inorganic materials 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 11
- 238000005303 weighing Methods 0.000 claims description 11
- 230000001680 brushing effect Effects 0.000 claims description 10
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 10
- 238000005507 spraying Methods 0.000 claims description 10
- WUXMRGFKTFJKQO-UHFFFAOYSA-M N.[Na+].[SH-] Chemical compound N.[Na+].[SH-] WUXMRGFKTFJKQO-UHFFFAOYSA-M 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- CVYXAGFFVZOEDJ-UHFFFAOYSA-L [O-2].[Zr+4].P(=O)([O-])([O-])O Chemical compound [O-2].[Zr+4].P(=O)([O-])([O-])O CVYXAGFFVZOEDJ-UHFFFAOYSA-L 0.000 claims description 4
- 239000010428 baryte Substances 0.000 claims description 4
- 229910052601 baryte Inorganic materials 0.000 claims description 4
- 229960004887 ferric hydroxide Drugs 0.000 claims description 4
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 abstract description 5
- 239000011777 magnesium Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 3
- 230000002035 prolonged effect Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 229920000742 Cotton Polymers 0.000 abstract 4
- 239000010456 wollastonite Substances 0.000 abstract 1
- 229910052882 wollastonite Inorganic materials 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 15
- 238000002360 preparation method Methods 0.000 description 10
- 238000010304 firing Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 238000007710 freezing Methods 0.000 description 5
- 230000008014 freezing Effects 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 4
- 241001391944 Commicarpus scandens Species 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
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Abstract
本发明涉及高温炉窑涂料技术领域，尤其涉及一种用于高温炉窑远红外节能型辐射涂料，由以下重量份的原料组成：石英21‑26份、磷酸铝20‑24份、高岭石8‑13份、磷酸氧化锆0.5‑3份、硫化钠氨0.1‑0.3份、白云母25‑35份、云母粉8‑12份、硼灰石0.1‑0.3份、钡白云石1.2‑2份、低温石英33‑40份、赤铁矿50‑60份、绿铬矿0.05‑0.2份、松脂岩8‑12份、镁强粉0.5‑1.5份和氧化钯0.02‑0.08份，本发明提出的用于高温炉窑远红外节能型辐射涂料，产品经高温烧结后，在纤维棉上形成一烧结壳层，该烧结壳层与纤维棉承受力相当，可以牢固地附着于纤维棉，保护了纤维棉炉衬，大大延长了炉窑的使用寿命，同时由于该涂料采用是高发射率材料，达到了节能效果。
Description
技术领域
本发明涉及高温炉窑涂料技术领域，尤其涉及一种用于高温炉窑远红外节能型辐射涂料。
背景技术
远红外涂料是目前远红外加热器上普遍使用的高温涂料。近来，中国专利文献中公开了相关的涂料，专利申请CN1552779A公开了一种高温远红外涂料，该涂料主要组成为氧化锆、氧化铬、氧化铁、炭化硅、粘土、膨润土、钛白粉、棕刚玉；专利申请CN1361209A公开了一种高效的远红外涂料，其主要成分为氧化锆、氧化铁、氧化硅、氧化锰、苏州土等；专利CN1493626A公开了一种的远红外涂料，其主要成分为炭化硅、氧化铁、氧化钴、氧化锰、氧化铝、氧化铬、氧化镍等。专利申请CN1097780A公开了一种烤烟烘房的涂料，其主要成分为炭化硅和氧化铁。
现有远红红外辐射涂料针对耐火纤维材料使用时，表现出了高温稳定性差和远红外辐射率衰减快等问题。因此，通过组分设计获得用于耐火纤维材料的高温稳定、高辐射率的远红外辐射涂料，对于提高热工装备的热效率降低能耗具有重要意义。
因此，我们提出了一种用于高温炉窑远红外节能型辐射涂料用于解决上述问题。
发明内容
本发明的目的是为了解决现有技术中存在的缺点，而提出的一种用于高温炉窑远红外节能型辐射涂料。
一种用于高温炉窑远红外节能型辐射涂料，由以下重量份的原料组成：石英21-26份、磷酸铝20-24份、高岭石8-13份、磷酸氧化锆0.5-3份、硫化钠氨0.1-0.3份、白云母25-35份、云母粉8-12份、硼灰石0.1-0.3份、钡白云石1.2-2份、低温石英33-40份、赤铁矿50-60份、绿铬矿0.05-0.2份、金红石0.6-1.2份、方解石0.05-0.2份、钛酸钡0.05-0.2份、斜锆石0.5-1.5份、铝粉0.5-1.5份、碳酸镁0.05-0.2份、氧化铅0.03-0.1份、红锌矿0.05-0.15份、氢氧化氧铁0.02-0.1份、碳化硅0.6-2.4份、硫酸钡0.5-2份、叶腊石0.1-0.3份、刚玉0.3-0.5份、羧甲基纤维素20-30份、去离子水30-50份、松脂岩8-12份、镁强粉0.5-1.5份和氧化钯0.02-0.08份。
优选的，由以下重量份的原料组成：石英22-25份、磷酸铝21-23份、高岭石9-12份、磷酸氧化锆1-2.5份、硫化钠氨0.15-0.25份、白云母26-24份、云母粉9-11份、硼灰石0.05-0.25份、钡白云石1.4-1.8份、低温石英35-38份、赤铁矿52-58份、绿铬矿0.08-0.12份、金红石0.8-1.4份、方解石0.06-0.12份、钛酸钡0.07-0.13份、斜锆石0.6-1.2份、铝粉0.6-1.4份、碳酸镁0.07-0.12份、氧化铅0.04-0.09份、红锌矿0.08-0.12份、氢氧化氧铁0.03-0.06份、碳化硅0.9-1.9份、硫酸钡0.8-1.6份、叶腊石0.15-0.25份、刚玉0.34-0.45份、羧甲基纤维素22-28份、去离子水33-47份、松脂岩9-11份、镁强粉0.8-1.2份和氧化钯0.04-0.06份。
优选的，由以下重量份的原料组成：石英23.6份、磷酸铝22.1份、高岭石10.9份、磷酸氧化锆1.9份、硫化钠氨0.2份、白云母29.9份、云母粉9.5份、硼灰石0.2份、钡白云石1.6份、低温石英36.7份、赤铁矿55.5份、绿铬矿0.1份、金红石0.9份、方解石0.1份、钛酸钡0.1份、斜锆石0.9份、铝粉1份、碳酸镁0.1份、氧化铅0.06份、红锌矿0.1份、氢氧化氧铁0.05份、碳化硅1.7份、硫酸钡1份、叶腊石0.2份、刚玉0.4份、羧甲基纤维素25份、去离子水40份、松脂岩10份、镁强粉1份和氧化钯0.05份。
优选的，一种用于高温炉窑远红外节能型辐射涂料的制备方法，包括以下步骤：按比例称取所述原料，将去离子水加入到羧甲基纤维素内得到胶状流体，然后将剩余的原料加入到胶状流体内，充分搅拌，混合均匀，即可得到用于高温炉窑远红外节能型辐射涂料。
优选的，一种用于高温炉窑远红外节能型辐射涂料在纤维棉表面的应用。
优选的，一种远红外节能型辐射烧结壳层，用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面，经干燥、烧成制得。
优选的，所述用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面的方式为涂刷或喷涂。
优选的，将用于高温炉窑远红外节能型辐射涂料涂刷或喷涂在耐火纤维表面，干燥后形成350-450微米厚的涂层，在1200-1600℃下烧成4-6h后形成远红外节能型辐射烧结壳层。
本发明的有益效果是：
1、本发明提出的用于高温炉窑远红外节能型辐射涂料，产品经高温烧结后，在纤维棉上形成一烧结壳层，该烧结壳层与纤维棉承受力相当，可以牢固地附着于纤维棉，保护了纤维棉炉衬，大大延长了炉窑的使用寿命，同时由于该涂料采用是高发射率材料，达到了节能效果，同时也由于整个炉体喷涂了热辐射涂料形成了完整的面辐射，使得辐射场更加均匀，从而使被加热物体受热均匀，提高了产品质量。
2、本发明提出的用于高温炉窑远红外节能型辐射涂料中的镁强粉具有较强的耐酸碱腐蚀、耐污染和抗老化性能，为烧结壳层提供了优异的防腐性能，其延缓了一般高温远红外涂料发射率逐渐降低的速度，延长了烧结壳层的使用寿命。
3、本发明提出的用于高温炉窑远红外节能型辐射涂料，产品内部含有松脂岩，松脂岩能够有效的改善烧结壳层的膨胀系数，使得烧结壳层在升温或者降温过程中不容易破裂，保证烧结壳层能够正常使用，进一步的延长烧结壳层的使用寿命。
具体实施方式
下面结合具体实施例对本发明作进一步解说。
实施例1中，一种用于高温炉窑远红外节能型辐射涂料，由以下重量份的原料组成：石英21份、磷酸铝20份、高岭石8份、磷酸氧化锆0.5份、硫化钠氨0.1份、白云母25份、云母粉8份、硼灰石0.1份、钡白云石1.2份、低温石英33份、赤铁矿50份、绿铬矿0.05份、金红石0.6份、方解石0.05份、钛酸钡0.05份、斜锆石0.5份、铝粉0.5份、碳酸镁0.05份、氧化铅0.03份、红锌矿0.05份、氢氧化氧铁0.02份、碳化硅0.6份、硫酸钡0.5份、叶腊石0.1份、刚玉0.3份、羧甲基纤维素20份、去离子水30份、松脂岩8份、镁强粉0.5份和氧化钯0.02份。
一种用于高温炉窑远红外节能型辐射涂料的制备方法，包括以下步骤：按比例称取所述原料，将去离子水加入到羧甲基纤维素内得到胶状流体，然后将剩余的原料加入到胶状流体内，充分搅拌，混合均匀，即可得到用于高温炉窑远红外节能型辐射涂料。
一种用于高温炉窑远红外节能型辐射涂料在纤维棉表面的应用。
一种远红外节能型辐射烧结壳层，用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面，经干燥、烧成制得。
所述用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面的方式为涂刷或喷涂。
将用于高温炉窑远红外节能型辐射涂料涂刷或喷涂在耐火纤维表面，干燥后形成350-450微米厚的涂层，在1200℃下烧成6h后形成远红外节能型辐射烧结壳层
实施例2中，一种用于高温炉窑远红外节能型辐射涂料，由以下重量份的原料组成：石英26份、磷酸铝24份、高岭石13份、磷酸氧化锆3份、硫化钠氨0.3份、白云母35份、云母粉12份、硼灰石0.3份、钡白云石2份、低温石英40份、赤铁矿60份、绿铬矿0.2份、金红石1.2份、方解石0.2份、钛酸钡0.2份、斜锆石1.5份、铝粉1.5份、碳酸镁0.2份、氧化铅0.1份、红锌矿0.15份、氢氧化氧铁0.1份、碳化硅2.4份、硫酸钡2份、叶腊石0.3份、刚玉0.5份、羧甲基纤维素30份、去离子水50份、松脂岩12份、镁强粉1.5份和氧化钯0.08份。
一种用于高温炉窑远红外节能型辐射涂料的制备方法，包括以下步骤：按比例称取所述原料，将去离子水加入到羧甲基纤维素内得到胶状流体，然后将剩余的原料加入到胶状流体内，充分搅拌，混合均匀，即可得到用于高温炉窑远红外节能型辐射涂料。
一种用于高温炉窑远红外节能型辐射涂料在纤维棉表面的应用。
一种远红外节能型辐射烧结壳层，用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面，经干燥、烧成制得。
所述用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面的方式为涂刷或喷涂。
将用于高温炉窑远红外节能型辐射涂料涂刷或喷涂在耐火纤维表面，干燥后形成350-450微米厚的涂层，在1600℃下烧成4h后形成远红外节能型辐射烧结壳层
实施例3中，由以下重量份的原料组成：石英22份、磷酸铝21份、高岭石9份、磷酸氧化锆1份、硫化钠氨0.15份、白云母26份、云母粉9份、硼灰石0.05份、钡白云石1.4份、低温石英35份、赤铁矿52份、绿铬矿0.08份、金红石0.8份、方解石0.06份、钛酸钡0.07份、斜锆石0.6份、铝粉0.6份、碳酸镁0.07份、氧化铅0.04份、红锌矿0.08份、氢氧化氧铁0.03份、碳化硅0.9份、硫酸钡0.8份、叶腊石0.15份、刚玉0.34份、羧甲基纤维素22份、去离子水33份、松脂岩9份、镁强粉0.8份和氧化钯0.04份。
一种用于高温炉窑远红外节能型辐射涂料的制备方法，包括以下步骤：按比例称取所述原料，将去离子水加入到羧甲基纤维素内得到胶状流体，然后将剩余的原料加入到胶状流体内，充分搅拌，混合均匀，即可得到用于高温炉窑远红外节能型辐射涂料。
一种用于高温炉窑远红外节能型辐射涂料在纤维棉表面的应用。
一种远红外节能型辐射烧结壳层，用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面，经干燥、烧成制得。
所述用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面的方式为涂刷或喷涂。
将用于高温炉窑远红外节能型辐射涂料涂刷或喷涂在耐火纤维表面，干燥后形成350-450微米厚的涂层，在1300℃下烧成5h后形成远红外节能型辐射烧结壳层
实施例4中，由以下重量份的原料组成：石英25份、磷酸铝23份、高岭石12份、磷酸氧化锆2.5份、硫化钠氨0.25份、白云母24份、云母粉11份、硼灰石0.25份、钡白云石1.8份、低温石英38份、赤铁矿58份、绿铬矿0.12份、金红石1.4份、方解石0.12份、钛酸钡0.13份、斜锆石1.2份、铝粉1.4份、碳酸镁0.12份、氧化铅0.09份、红锌矿0.12份、氢氧化氧铁0.06份、碳化硅1.9份、硫酸钡1.6份、叶腊石0.25份、刚玉0.45份、羧甲基纤维素28份、去离子水47份、松脂岩11份、镁强粉1.2份和氧化钯0.06份。
一种用于高温炉窑远红外节能型辐射涂料的制备方法，包括以下步骤：按比例称取所述原料，将去离子水加入到羧甲基纤维素内得到胶状流体，然后将剩余的原料加入到胶状流体内，充分搅拌，混合均匀，即可得到用于高温炉窑远红外节能型辐射涂料。
一种用于高温炉窑远红外节能型辐射涂料在纤维棉表面的应用。
一种远红外节能型辐射烧结壳层，用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面，经干燥、烧成制得。
所述用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面的方式为涂刷或喷涂。
将用于高温炉窑远红外节能型辐射涂料涂刷或喷涂在耐火纤维表面，干燥后形成350-450微米厚的涂层，在1500℃下烧成5h后形成远红外节能型辐射烧结壳层
实施例5中，由以下重量份的原料组成：石英23.6份、磷酸铝22.1份、高岭石10.9份、磷酸氧化锆1.9份、硫化钠氨0.2份、白云母29.9份、云母粉9.5份、硼灰石0.2份、钡白云石1.6份、低温石英36.7份、赤铁矿55.5份、绿铬矿0.1份、金红石0.9份、方解石0.1份、钛酸钡0.1份、斜锆石0.9份、铝粉1份、碳酸镁0.1份、氧化铅0.06份、红锌矿0.1份、氢氧化氧铁0.05份、碳化硅1.7份、硫酸钡1份、叶腊石0.2份、刚玉0.4份、羧甲基纤维素25份、去离子水40份、松脂岩10份、镁强粉1份和氧化钯0.05份。
一种用于高温炉窑远红外节能型辐射涂料的制备方法，包括以下步骤：按比例称取所述原料，将去离子水加入到羧甲基纤维素内得到胶状流体，然后将剩余的原料加入到胶状流体内，充分搅拌，混合均匀，即可得到用于高温炉窑远红外节能型辐射涂料。
一种用于高温炉窑远红外节能型辐射涂料在纤维棉表面的应用。
一种远红外节能型辐射烧结壳层，用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面，经干燥、烧成制得。
所述用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面的方式为涂刷或喷涂。
将用于高温炉窑远红外节能型辐射涂料涂刷或喷涂在耐火纤维表面，干燥后形成350-450微米厚的涂层，在1400℃下烧成5h后形成远红外节能型辐射烧结壳层。
对比例1中，由以下重量份的原料组成：石英23.6份、磷酸铝22.1份、高岭石10.9份、磷酸氧化锆1.9份、硫化钠氨0.2份、白云母29.9份、云母粉9.5份、硼灰石0.2份、钡白云石1.6份、低温石英36.7份、赤铁矿55.5份、绿铬矿0.1份、金红石0.9份、方解石0.1份、钛酸钡0.1份、斜锆石0.9份、铝粉1份、碳酸镁0.1份、氧化铅0.06份、红锌矿0.1份、氢氧化氧铁0.05份、碳化硅1.7份、硫酸钡1份、叶腊石0.2份、刚玉0.4份、羧甲基纤维素25份、去离子水40份、镁强粉1份和氧化钯0.05份。
一种用于高温炉窑远红外节能型辐射涂料的制备方法，包括以下步骤：按比例称取所述原料，将去离子水加入到羧甲基纤维素内得到胶状流体，然后将剩余的原料加入到胶状流体内，充分搅拌，混合均匀，即可得到用于高温炉窑远红外节能型辐射涂料。
一种用于高温炉窑远红外节能型辐射涂料在纤维棉表面的应用。
一种远红外节能型辐射烧结壳层，用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面，经干燥、烧成制得。
所述用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面的方式为涂刷或喷涂。
将用于高温炉窑远红外节能型辐射涂料涂刷或喷涂在耐火纤维表面，干燥后形成350-450微米厚的涂层，在1400℃下烧成5h后形成远红外节能型辐射烧结壳层。
对比例2中，由以下重量份的原料组成：石英23.6份、磷酸铝22.1份、高岭石10.9份、磷酸氧化锆1.9份、硫化钠氨0.2份、白云母29.9份、云母粉9.5份、硼灰石0.2份、钡白云石1.6份、低温石英36.7份、赤铁矿55.5份、绿铬矿0.1份、金红石0.9份、方解石0.1份、钛酸钡0.1份、斜锆石0.9份、铝粉1份、碳酸镁0.1份、氧化铅0.06份、红锌矿0.1份、氢氧化氧铁0.05份、碳化硅1.7份、硫酸钡1份、叶腊石0.2份、刚玉0.4份、羧甲基纤维素25份、去离子水40份、松脂岩10份、和氧化钯0.05份。
一种用于高温炉窑远红外节能型辐射涂料的制备方法，包括以下步骤：按比例称取所述原料，将去离子水加入到羧甲基纤维素内得到胶状流体，然后将剩余的原料加入到胶状流体内，充分搅拌，混合均匀，即可得到用于高温炉窑远红外节能型辐射涂料。
一种用于高温炉窑远红外节能型辐射涂料在纤维棉表面的应用。
一种远红外节能型辐射烧结壳层，用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面，经干燥、烧成制得。
所述用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面的方式为涂刷或喷涂。
将用于高温炉窑远红外节能型辐射涂料涂刷或喷涂在耐火纤维表面，干燥后形成350-450微米厚的涂层，在1400℃下烧成5h后形成远红外节能型辐射烧结壳层。
对比例3中，由以下重量份的原料组成：石英23.6份、磷酸铝22.1份、高岭石10.9份、磷酸氧化锆1.9份、硫化钠氨0.2份、白云母29.9份、云母粉9.5份、硼灰石0.2份、钡白云石1.6份、低温石英36.7份、赤铁矿55.5份、绿铬矿0.1份、金红石0.9份、方解石0.1份、钛酸钡0.1份、斜锆石0.9份、铝粉1份、碳酸镁0.1份、氧化铅0.06份、红锌矿0.1份、氢氧化氧铁0.05份、碳化硅1.7份、硫酸钡1份、叶腊石0.2份、刚玉0.4份、羧甲基纤维素25份、去离子水40份和氧化钯0.05份。
一种用于高温炉窑远红外节能型辐射涂料的制备方法，包括以下步骤：按比例称取所述原料，将去离子水加入到羧甲基纤维素内得到胶状流体，然后将剩余的原料加入到胶状流体内，充分搅拌，混合均匀，即可得到用于高温炉窑远红外节能型辐射涂料。
一种用于高温炉窑远红外节能型辐射涂料在纤维棉表面的应用。
一种远红外节能型辐射烧结壳层，用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面，经干燥、烧成制得。
所述用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面的方式为涂刷或喷涂。
将用于高温炉窑远红外节能型辐射涂料涂刷或喷涂在耐火纤维表面，干燥后形成350-450微米厚的涂层，在1400℃下烧成5h后形成远红外节能型辐射烧结壳层。
将实施例1-5和对比例1-3中的高温炉窑远红外节能型辐射涂料涂刷在纤维棉表面，制成远红外节能型辐射烧结壳层后，在1300℃的高温炉内服役不同时间，取出测定其在8-22μm波段的辐射率，结果如表1所示。
表1
从表1可以看出，实施例1-5中，经过100天服役后，其辐射率仍能够达到94％以上，表明实施例1-5中的烧结壳层辐射性能优异，对比例1中未添加松脂岩，其辐射性能与实施例1-5接近，性能优异，对比例2中未添加镁强粉、对比例3中未添加镁强粉和松脂岩，均不含有镁强粉，结果对比例2和对比例3中的辐射性能均下降明显，观察烧结壳层发现，烧结壳层表面光泽暗淡，烧结壳层被局部腐蚀。
将实施例1-5和对比例1-3中的高温炉窑远红外节能型辐射涂料涂刷在纤维棉表面，制成远红外节能型辐射烧结壳层后放入高温炉，将高温炉加热至1500℃后关闭加热源，自然冷却至30℃，循环加热冷却不同的次数后，取出测定其在8-22μm波段的辐射率，结果如表2所示。
表2
从表2可以看出，实施例1-5中，经过100次加热冷却后，其辐射率仍能够达到95％以上，表明实施例1-5中的烧结壳层辐射性能优异，对比例2中未添加镁强粉，其辐射性能与实施例1-5接近，性能优异，对比例1中未添加松脂岩、对比例3中未添加镁强粉和松脂岩，均不含有松脂岩，结果对比例2和对比例3中的辐射性能均下降明显，观察烧结壳层发现，烧结壳层表面出现细小的裂纹，烧结壳层升温或者降温过程中发生了破裂。
本发明中，为了进一步的提高涂料的稳定性，使得烧结壳层在升温或者降温过程中不容易破裂，可以采用如下的制备方法：按比例称取所述原料，将去离子水加入到羧甲基纤维素内得到胶状流体，然后将剩余的原料加入到胶状流体内，充分搅拌，混合均匀，混合完毕后进行冷冻处理，冷冻处理的温度低于-20℃，物料冻结后，将物料在低温环境下破碎并充分研磨，研磨后颗粒经过100目-200目的筛网过筛，过筛完毕后，微波加热至室温，即可得到用于高温炉窑远红外节能型辐射涂料，通过冷冻以及冷冻环境下的研磨能够进一步的提高涂料组分之间混合的均匀性，最终进一步改善涂料的稳定性。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。
Claims (8)
1.一种用于高温炉窑远红外节能型辐射涂料，其特征在于，由以下重量份的原料组成：石英21-26份、磷酸铝20-24份、高岭石8-13份、磷酸氧化锆0.5-3份、硫化钠氨0.1-0.3份、白云母25-35份、云母粉8-12份、硼灰石0.1-0.3份、钡白云石1.2-2份、低温石英33-40份、赤铁矿50-60份、绿铬矿0.05-0.2份、金红石0.6-1.2份、方解石0.05-0.2份、钛酸钡0.05-0.2份、斜锆石0.5-1.5份、铝粉0.5-1.5份、碳酸镁0.05-0.2份、氧化铅0.03-0.1份、红锌矿0.05-0.15份、氢氧化氧铁0.02-0.1份、碳化硅0.6-2.4份、硫酸钡0.5-2份、叶腊石0.1-0.3份、刚玉0.3-0.5份、羧甲基纤维素20-30份、去离子水30-50份、松脂岩8-12份、镁强粉0.5-1.5份和氧化钯0.02-0.08份。
2.根据权利要求1所述的一种用于高温炉窑远红外节能型辐射涂料，其特征在于，由以下重量份的原料组成：石英22-25份、磷酸铝21-23份、高岭石9-12份、磷酸氧化锆1-2.5份、硫化钠氨0.15-0.25份、白云母26-24份、云母粉9-11份、硼灰石0.05-0.25份、钡白云石1.4-1.8份、低温石英35-38份、赤铁矿52-58份、绿铬矿0.08-0.12份、金红石0.8-1.4份、方解石0.06-0.12份、钛酸钡0.07-0.13份、斜锆石0.6-1.2份、铝粉0.6-1.4份、碳酸镁0.07-0.12份、氧化铅0.04-0.09份、红锌矿0.08-0.12份、氢氧化氧铁0.03-0.06份、碳化硅0.9-1.9份、硫酸钡0.8-1.6份、叶腊石0.15-0.25份、刚玉0.34-0.45份、羧甲基纤维素22-28份、去离子水33-47份、松脂岩9-11份、镁强粉0.8-1.2份和氧化钯0.04-0.06份。
3.根据权利要求2所述的一种用于高温炉窑远红外节能型辐射涂料，其特征在于，由以下重量份的原料组成：石英23.6份、磷酸铝22.1份、高岭石10.9份、磷酸氧化锆1.9份、硫化钠氨0.2份、白云母29.9份、云母粉9.5份、硼灰石0.2份、钡白云石1.6份、低温石英36.7份、赤铁矿55.5份、绿铬矿0.1份、金红石0.9份、方解石0.1份、钛酸钡0.1份、斜锆石0.9份、铝粉1份、碳酸镁0.1份、氧化铅0.06份、红锌矿0.1份、氢氧化氧铁0.05份、碳化硅1.7份、硫酸钡1份、叶腊石0.2份、刚玉0.4份、羧甲基纤维素25份、去离子水40份、松脂岩10份、镁强粉1份和氧化钯0.05份。
4.一种如权利要求1-3任一项权利要求所述的用于高温炉窑远红外节能型辐射涂料的制备方法，其特征在于，包括以下步骤：按比例称取所述原料，将去离子水加入到羧甲基纤维素内得到胶状流体，然后将剩余的原料加入到胶状流体内，充分搅拌，混合均匀，即可得到用于高温炉窑远红外节能型辐射涂料。
5.一种如权利要求1-3任一项权利要求所述的用于高温炉窑远红外节能型辐射涂料在纤维棉表面的应用。
6.一种远红外节能型辐射烧结壳层，其特征在于，所述远红外节能型辐射烧结壳层如权利要求1-3任一项权利要求所述的用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面，经干燥、烧成制得。
7.根据权利要求6所述的一种远红外节能型辐射烧结壳层，其特征在于，所述用于高温炉窑远红外节能型辐射涂料涂覆在纤维棉表面的方式为涂刷或喷涂。
8.根据权利要求6所述的一种远红外节能型辐射烧结壳层，其特征在于，将用于高温炉窑远红外节能型辐射涂料涂刷或喷涂在耐火纤维表面，干燥后形成350-450微米厚的涂层，在1200-1600℃下烧成4-6h后形成远红外节能型辐射烧结壳层。
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