CN112409614A - 一种防护纳米弹性鞋垫制备方法 - Google Patents
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Abstract
本发明涉及一种防护纳米弹性鞋垫制备方法，将天然橡胶投入开炼机进行塑炼，并将一定配比的丁腈橡胶加入到开炼机内与天然橡胶进行混炼，之后向开炼机内加入由盐酸洗必泰、纳米二氧化硅、沸石粉、电气石等材料配比制成的香料，并搅拌均匀，并依次加入配方量的增塑剂、碳酸钙、炭黑、氧化锌等材料进行混炼形成混炼胶；将混炼胶在压延机上制成胶片，然后通过挤出机压出到模具中进行硫化，硫化温度100℃硫化时间1h，之后从模具中取出，用切片机按要求厚度进行切片。通过该制备方法制备的鞋垫，具有除臭杀菌效果彻底，功能持续时间长，对人体无副作用，安全卫生、易于制作等特点，可广泛的应用到特种鞋。
Description
技术领域
本发明涉及一种防护纳米弹性鞋垫制备方法。
背景技术
特殊工种如五金制造业、林木业、探勘及救援作业的工作人员，需要在一些特殊环境下进行工作。因此，对于特殊工种的特种安全防护鞋需要作出新的设计。由于职业的特殊性，如部队、消防等人员的负荷量远远超过常人，经常会出现一些下肢损伤，主要表现在足弓韧带过度拉伸、足部的跟骨痛、前脚掌痛等症状。这是由于前掌和后跟部位的峰值压力过大，足部神经受到严重压迫所致。针对这种情况，需要对防护鞋垫做出改进，现在的使用的鞋垫种类比较多，有弹性的发泡材料EVA、TPU材质、布料、还有皮制等多种，然而这些鞋垫对足部的防护力度明显不足。
发明内容
为了克服上述缺陷，本发明提供了一种改变弹性体的物理性质，增强催化性、稳定性等化学性质，使力学性也得到改善的防护纳米弹性鞋垫。
本发明解决其技术问题所采用的技术方案是：一种防护纳米弹性鞋垫制备方法，包括如下步骤：
S1、塑炼：取天然橡胶投入开炼机塑炼，所述开炼机的辊筒温度为40-50℃；
S2、混炼：取一定配比量的丁腈橡胶加入到开炼机内与天然橡胶混炼；
S3、香料配比：取20-40份盐酸洗必泰粉，16-20份纳米二氧化硅，14-18份沸石粉，24-30份电气石粉，5-15份甲壳胺粉混合成香料粉；
S4、搅拌：向开炼机内加入上述配比量的香料搅拌均匀，辊筒温度70-80℃，辊距2-3mm；
S5、助剂配比：向开炼机内依次加入配比量的增塑剂、碳酸钙、炭黑、氧化锌、十八碳烷酸、促进剂、防老剂、发孔剂以及硫磺；
S6、混炼：将上述开炼机内的混合物进行混炼50-60分钟形成混炼胶；
S7、延压：将混炼胶在压延机上制成胶片；
S8、硫化：将胶片通过挤出机压出到模具中进行硫化，硫化温度110℃，硫化时间1.2h；
S9、出片：从模具中取出，用切片机按要求厚度进行切片。
在本发明一个较佳实施例中，盐酸洗必泰粉、纳米二氧化硅、沸石粉、电气石粉、甲壳胺粉的粒径为10-20nm。
在本发明一个较佳实施例中，增塑剂为邻苯二甲酸二辛酯；所述防老剂为2，2，4-三甲基-1，2-二氢化喹啉；所述发孔剂为N，N-二亚硝基五亚甲基四胺；所述促进剂为2，2’-二硫代二苯并噻唑。
本发明的有益效果是：采用上述结构后，借助橡胶材料弹性优良的特性，将纳米改性材料介入，改变基质单一材料的结构参数，改变弹性体的物理性质，增强催化性、稳定性等化学性质，使力学性也得到改善；高比表面积的纳米材料表面存在大量的残键，其表面能对气体和细菌有强烈的吸附作用，可使细菌的细胞膜或细胞原生质活性酶得到破坏，从而使细菌死亡；并可与鞋内的异臭分子或者任何形式的水分子、氧分子、氮分子结合，发生化学反应，改变异臭分子的性质，使异臭分子消失及依附微粒而消失下沉。
附图说明
图1是本发明制备工艺流程示意图。
具体实施方式
下面结合附图对本发明的较佳实施例进行详细阐述，以使本发明的优点和特征能更易于被本领域技术人员理解，从而对本发明的保护范围做出更为清楚明确的界定。
如图1所示一种防护纳米弹性鞋垫制备方法，包括如下步骤：
S1、塑炼：取天然橡胶投入开炼机塑炼，所述开炼机的辊筒温度为40-50℃；
S2、混炼：取一定配比量的丁腈橡胶加入到开炼机内与天然橡胶混炼；
S3、香料配比：取20-40份盐酸洗必泰粉，16-20份纳米二氧化硅，14-18份沸石粉，24-30份电气石粉，5-15份甲壳胺粉混合成香料粉；
S4、搅拌：向开炼机内加入上述配比量的香料搅拌均匀，辊筒温度70-80℃，辊距2-3mm；
S5、助剂配比：向开炼机内依次加入配比量的增塑剂、碳酸钙、炭黑、氧化锌、十八碳烷酸、促进剂、防老剂、发孔剂以及硫磺；
S6、混炼：将上述开炼机内的混合物进行混炼50-60分钟形成混炼胶；
S7、延压：将混炼胶在压延机上制成胶片；
S8、硫化：将胶片通过挤出机压出到模具中进行硫化，硫化温度110℃，硫化时间1.2h；
S9、出片：从模具中取出，用切片机按要求厚度进行切片。
盐酸洗必泰粉、纳米二氧化硅、沸石粉、电气石粉、甲壳胺粉的粒径为10-20nm。
增塑剂为邻苯二甲酸二辛酯；所述防老剂为2，2，4-三甲基-1，2-二氢化喹啉；所述发孔剂为N，N-二亚硝基五亚甲基四胺；所述促进剂为2，2’-二硫代二苯并噻唑。
制备工艺流程：将天然橡胶投入开炼机进行塑炼，开炼机的辊筒温度30-40℃，20min后将一定配比的丁腈橡胶加入到开炼机内与天然橡胶进行混炼，辊筒温度45-50℃；之后向开炼机内加入由盐酸洗必泰、纳米二氧化硅、沸石粉、电气石等材料配比制成的香料，并搅拌均匀，辊筒温度50-70℃；辊距1-2mm时，依次加入配方量的增塑剂、碳酸钙、炭黑、氧化锌等材料进行混炼40-50分钟形成混炼胶；将混炼胶在压延机上制成胶片，然后通过挤出机压出到模具中进行硫化，硫化温度100℃硫化时间1h，之后从模具中取出，用切片机按要求厚度进行切片。
需要强调的是：以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书及附图内容所作的等效结构或等效流程变换，或直接或间接运用在其他相关的技术领域，均同理包括在本发明的专利保护范围内。
Claims (3)
1.一种防护纳米弹性鞋垫制备方法，其特征在于：包括如下步骤：
S1、塑炼：取天然橡胶投入开炼机塑炼，所述开炼机的辊筒温度为40-50℃；
S2、混炼：取一定配比量的丁腈橡胶加入到开炼机内与天然橡胶混炼；
S3、香料配比：取20-40份盐酸洗必泰粉，16-20份纳米二氧化硅，14-18份沸石粉，24-30份电气石粉，5-15份甲壳胺粉混合成香料粉；
S4、搅拌：向开炼机内加入上述配比量的香料搅拌均匀，辊筒温度70-80℃，辊距2-3mm；
S5、助剂配比：向开炼机内依次加入配比量的增塑剂、碳酸钙、炭黑、氧化锌、十八碳烷酸、促进剂、防老剂、发孔剂以及硫磺；
S6、混炼：将上述开炼机内的混合物进行混炼50-60分钟形成混炼胶；
S7、延压：将混炼胶在压延机上制成胶片；
S8、硫化：将胶片通过挤出机压出到模具中进行硫化，硫化温度110℃，硫化时间1.2h；
S9、出片：从模具中取出，用切片机按要求厚度进行切片。
2.根据权利要求1所述一种防护纳米弹性鞋垫制备方法，其特征在于：所述盐酸洗必泰粉、纳米二氧化硅、沸石粉、电气石粉、甲壳胺粉的粒径为10-20nm。
3.根据权利要求1所述一种防护纳米弹性鞋垫制备方法，其特征在于：所述增塑剂为邻苯二甲酸二辛酯；所述防老剂为2，2，4-三甲基-1，2-二氢化喹啉；所述发孔剂为N，N-二亚硝基五亚甲基四胺；所述促进剂为2，2’-二硫代二苯并噻唑。
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102432930A (zh) * | 2011-10-26 | 2012-05-02 | 金猴集团威海鞋业有限公司 | 纳米陶瓷材料橡胶微孔鞋底 |
| CN102504355A (zh) * | 2011-10-26 | 2012-06-20 | 金猴集团威海鞋业有限公司 | 一种弹性抗菌除臭鞋材 |
-
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102432930A (zh) * | 2011-10-26 | 2012-05-02 | 金猴集团威海鞋业有限公司 | 纳米陶瓷材料橡胶微孔鞋底 |
| CN102504355A (zh) * | 2011-10-26 | 2012-06-20 | 金猴集团威海鞋业有限公司 | 一种弹性抗菌除臭鞋材 |
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|---|---|---|---|---|
| CN115466502A (zh) * | 2022-05-16 | 2022-12-13 | 上海年与轻科技(集团)有限公司 | 一种石墨烯导电鞋垫材料及其制备方法 |
| CN115466502B (zh) * | 2022-05-16 | 2023-11-10 | 上海年与轻科技(集团)有限公司 | 一种石墨烯导电鞋垫材料及其制备方法 |
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