CN112281498A - 一种防紫外线防蚊虫织物及其制备方法 - Google Patents

一种防紫外线防蚊虫织物及其制备方法 Download PDF

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CN112281498A
CN112281498A CN201910659224.6A CN201910659224A CN112281498A CN 112281498 A CN112281498 A CN 112281498A CN 201910659224 A CN201910659224 A CN 201910659224A CN 112281498 A CN112281498 A CN 112281498A
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mosquito
proof
parts
fabric layer
ultraviolet
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吕旭初
阮利强
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Xinxiang Patron Saint Special Fabric Co Ltd
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Xinxiang Patron Saint Special Fabric Co Ltd
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Abstract

本发明公开了一种防紫外线防蚊虫织物及其制备方法，该织物包括叠合的三层织物层，最外层织物层为防紫外线织物层，中间层为防蚊虫织物层，最内层为棉纺织物层，所述防紫外线织物层由60‑80wt%棉、8‑25wt%的聚酯纤维和8‑25wt%的氨纶制成，防蚊虫织物层由95‑99wt%棉和1‑5wt%的氨纶制成，棉纺织物层为100%棉；防蚊虫织物层中粘附有防蚊虫微胶囊，防蚊虫微胶囊的直径为20‑80nm。该织物能够有效的吸收紫外线减少紫外线对皮肤的伤害，又能用气味驱赶蚊虫防止蚊虫叮咬，轻薄透气效果良好，使用寿命长。

Description

一种防紫外线防蚊虫织物及其制备方法
技术领域
本发明属于多功能织物制造领域，具体涉及一种防紫外线防蚊虫织物及其制备方法。
背景技术
太阳光谱中的紫外线不仅使纺织品褪色和脆化，过量照射人体，也可使人体皮肤晒伤老化，产生黑色素和色斑，严重的还会诱发癌变，严重危害人类健康。防止紫外线对人体的危害，已经被越来越多的消费者所重视。为了保护人体避免紫外线的过量辐射，开发防紫外线纺织品是极其必要的。
蚊虫除直接吸血外，还会传播多种疾病，如疟疾，登草热，流行性乙脑等，危害人类健康，因此防止蚊虫传播疾病是全球共同关注的重要公共卫生问题。现有的防蚊虫织物多以拟除虫菊类化合物作为整理剂制备防蚊虫产品们虽然具有良好的防蚊虫效果，但功能较单一，不能满足人们对多功能防蚊虫织物的需求。
中国专利CN108720140A公开了一种防水防紫外线面料，有以下质量百分比的原料制成，彩色棉13～17％、麻纤维12～12％、锦纶25～43％、毛纤维14～18％、氟纶12～15％和铜氨纤维16～24％，该防水防紫外线面料单纯的通过面料的改进，达不到防紫外线的效果。
中国专利CN107696608A公开了一种防蚊虫面料，包括基础层，基础层外依次设有支撑层、透气层、驱蚊虫层，各层通过缝合固定，基础层背面设置有衬里织物层，所述衬里织物层包括三层，外层为特氟龙层，夹层为纺织物，内层为特氟龙涂层，该防蚊虫面料具有防水、防油、防污等特点，缺点是制造成本高，面料厚实，不适宜夏季穿着。
中国专利CN102465450A公开了一种防蚊虫面料，整理液含有防虫液、粘合剂、将坯布浸轧在整理液中，水洗、烘干、定型等，制成防蚊虫面料，该面料具有轻薄透气，耐洗涤，防蚊虫时间长等特点，缺点是夏季穿着只能防蚊虫，无法防紫外线，功能单一。
发明内容
为解决上述问题，本发明提供一种防紫外线防蚊虫织物及其制备方法，该织物能够有效的吸收紫外线减少紫外线对皮肤的伤害，又能用气味驱赶蚊虫防止蚊虫叮咬，轻薄透气效果良好，使用寿命长。
本发明的目的是以下述方式实现的：
一种防紫外线防蚊虫织物，包括叠合的三层织物层，最外层织物层为防紫外线织物层，中间层为防蚊虫织物层，最内层为棉纺织物层，所述防紫外线织物层由60-80wt％棉、8-25wt％的聚酯纤维和8-25wt％的氨纶制成，防蚊虫织物层由95-99wt％棉和1-5wt％的氨纶制成，棉纺织物层为100％棉；防蚊虫织物层中粘附有防蚊虫微胶囊，防蚊虫微胶囊的直径为20-80nm。
一种防紫外线防蚊虫织物的制备方法，包括以下步骤，(1)制备防紫外线剂：防紫外线剂由以下重量份的组分组成，苯并三唑及其衍生物20-45份、氧化锌微粒10-35份、氧化钛微粒10-35份、氧化铈微粒10-35份和氧化锆微粒10-35份制成；(2)制备防蚊虫整理剂：防蚊虫整理剂由以下重量份的组分组成，硝酸硫胺素15-25份、干柠檬粉3-7份、薄荷冰片5-10份、薰衣草3-8份、七里香2-6份、艾叶10-18份、藿香8-15份、菖蒲8-15份、夜来香10-18份、樟脑油5-15份、天竺葵6-20份、金银花5-15份、天然除虫菊素23-45份、野菊花提取物15-30份，紫苏叶5-10份；(3)制备防蚊虫微胶囊：微胶囊以部分醚化的密胺树脂初缩体作为壁材，内包防蚊虫整理剂；(4)制备多功能整理液：将防紫外线剂、防蚊虫整理剂、固着剂和溶剂水混合制成多功能整理液，防紫外线剂的浓度为40-60g/L，防蚊虫整理剂的浓度为40-60g/L，固着剂的浓度为20-40g/L；(5)浸轧：防紫外线织物层和防蚊虫织物层分别浸轧在多功能整理液中，二浸二轧，轧液率为70-80％；(6)防蚊虫织物层粘附防蚊虫微胶囊：将防蚊虫微胶囊通过耐水性粘合剂粘附在在防蚊虫织物层的上下表面上；(7)三层织物层的叠合，将防紫外线织物层、防蚊虫织物层和棉纺织物层依次叠合缝制在一起；(8)喷涂，通过高压喷涂方式在防紫外线织物层的外侧喷涂一层多功能整理液；(9)烘干：将烘干机温度设为70-100℃，烘干3-5分钟；(10)烘焙：在120℃下烘焙30s。
步骤(4)中的固着剂为AF6100。
步骤(4)中的耐水性粘合剂为水溶性环氧树脂与聚乙烯醇的混合物，水溶性环氧树脂的质量分数为10-25％。
防紫外线织物层和防蚊虫织物层中均还有棉和氨纶，因为棉的成分高吸湿能力强、透气弥补了氨纶吸湿差，棉的强度高弥补了氨纶强度最差的特点，但是氨纶具有优良的延展性和弹性，使服装具有良好的尺寸稳定性，紧贴人体又能伸缩自如，便于活动，弥补棉的弹性差，氨纶耐光性弥补了棉耐光性差的特点。
苯并三唑为良好的紫外光吸收剂，吸收波长290-360纳米，氧化锌微粒、氧化钛微粒、氧化铈微粒和氧化锆微粒均具有良好的吸收紫外线的功能；防蚊虫整理剂中大部分为天然物质，产生的气味能够有效的驱避蚊虫，防止蚊虫叮咬；织物的最内层为棉纺织物层，与人体皮肤接触，提高舒适感。
夜来香，又名夜香树，叶片心形，边缘披有柔毛，每逢夏秋之间，在叶腋就会绽开一簇簇黄绿色的吊钟形小花，当月上树梢时它即飘出阵阵清香，这种香味，却令蚊子害怕，是驱蚊佳品。
天竺葵花团锦簇，丰满成球，南北各地都能适应。高温时节，摆放室外疏荫环境，天竺葵具有一种特有的气味，这种气味使蚊蝇闻味而逃。
七里香，是一种四季常绿的小灌木，外形呈伞房状，分枝多，叶小亮泽，花白繁密，开花后还能结红色浆果，为陋室增加美感，摸其叶片，会感到浓浓的甜香味，驱蚊效果很好。
柠檬中含有大量柠檬酸，其特有的香味能够驱避蚊虫。
藿香本身是一种具有芳香味的植物，全株都具有香味，其香味驱避蚊虫效果很好。
艾草具有一种特殊的香味，这特殊的香味具有驱蚊虫的功效，所以，古人常在门前挂艾草，一来用于避邪，二来用于赶走蚊虫。
菖蒲可以提取芳香油，有香气，该香气可以驱避蚊虫。
相对于现有技术，本发明的中的织物能够有效的吸收紫外线，防止紫外线对人体皮肤的伤害，通过防蚊虫织物层产生的气味，驱避蚊虫，减少蚊虫的叮咬和伤害，最内层的棉纺织物层能够提高人体皮肤的舒适感。
具体实施方式
实施例1：
一种防紫外线防蚊虫织物，包括叠合的三层织物层，最外层织物层为防紫外线织物层，中间层为防蚊虫织物层，最内层为棉纺织物层，所述防紫外线织物层由60-80wt％棉、8-25wt％的聚酯纤维和8-25wt％的氨纶制成，防蚊虫织物层由95-99wt％棉和1-5wt％的氨纶制成，棉纺织物层为100％棉；防蚊虫织物层中粘附有防蚊虫微胶囊，防蚊虫微胶囊的直径为20-80nm。
一种防紫外线防蚊虫织物的制备方法，包括以下步骤，(1)制备防紫外线剂：防紫外线剂由以下重量份的组分组成，苯并三唑及其衍生物20-45份、氧化锌微粒10-35份、氧化钛微粒10-35份、氧化铈微粒10-35份和氧化锆微粒10-35份制成；(2)制备防蚊虫整理剂：防蚊虫整理剂由以下重量份的组分组成，硝酸硫胺素15-25份、干柠檬粉3-7份、薄荷冰片5-10份、薰衣草3-8份、七里香2-6份、艾叶10-18份、藿香8-15份、菖蒲8-15份、夜来香10-18份、樟脑油5-15份、天竺葵6-20份、金银花5-15份、天然除虫菊素23-45份、野菊花提取物15-30份，紫苏叶5-10份；(3)制备防蚊虫微胶囊：微胶囊以部分醚化的密胺树脂初缩体作为壁材，内包防蚊虫整理剂；(4)制备多功能整理液：将防紫外线剂、防蚊虫整理剂、固着剂和溶剂水混合制成多功能整理液，防紫外线剂的浓度为40-60g/L，防蚊虫整理剂的浓度为40-60g/L，固着剂的浓度为20-40g/L；(5)浸轧：防紫外线织物层和防蚊虫织物层分别浸轧在多功能整理液中，二浸二轧，轧液率为70-80％；(6)防蚊虫织物层粘附防蚊虫微胶囊：将防蚊虫微胶囊通过耐水性粘合剂粘附在在防蚊虫织物层的上下表面上；(7)三层织物层的叠合，将防紫外线织物层、防蚊虫织物层和棉纺织物层依次叠合缝制在一起；(8)喷涂，通过高压喷涂方式在防紫外线织物层的外侧喷涂一层多功能整理液；(9)烘干：将烘干机温度设为70-100℃，烘干3-5分钟；(10)烘焙：在120℃下烘焙30s。制备过程二浸二轧，提高多功能整理液的渗透率，提高防紫外线和防蚊虫的效果，再粘附微胶囊提高防蚊虫的效果，经过长时间穿着，微胶囊破损，防蚊虫剂暴露出来，保持织物的防蚊虫效果，二浸二轧之后在织物的最外层防紫外线层高压喷涂一层多功能整理液，提高使用效果。
所述步骤(4)中的固着剂为AF6100。
所述步骤(4)中的耐水性粘合剂为水溶性环氧树脂与聚乙烯醇的混合物，水溶性环氧树脂的质量分数为10-25％。
实施例2
一种防紫外线防蚊虫织物，包括叠合的三层织物层，最外层织物层为防紫外线织物层，中间层为防蚊虫织物层，最内层为棉纺织物层，所述防紫外线织物层由70.9wt％棉、17.5wt％的聚酯纤维和11.6wt％的氨纶制成，防蚊虫织物层由96.8wt％棉和3.2wt％的氨纶制成，棉纺织物层为100％棉；防蚊虫织物层中粘附有防蚊虫微胶囊，防蚊虫微胶囊的直径为30nm。
一种防紫外线防蚊虫织物的制备方法，包括以下步骤，(1)制备防紫外线剂：防紫外线剂由以下重量份的组分组成，苯并三唑及其衍生物40份、氧化锌微粒15份、氧化钛微粒15份、氧化铈微粒15份和氧化锆微粒15份制成；(2)制备防蚊虫整理剂：防蚊虫整理剂由以下重量份的组分组成，硝酸硫胺素20份、干柠檬粉7份、薄荷冰片6份、薰衣草7份、七里香2份、艾叶12份、藿香14份、菖蒲9份、夜来香16份、樟脑油7份、天竺葵20份、金银花12份、天然除虫菊素30份、野菊花提取物18份，紫苏叶9份；(3)制备防蚊虫微胶囊：微胶囊以部分醚化的密胺树脂初缩体作为壁材，内包防蚊虫整理剂；(4)制备多功能整理液：将防紫外线剂、防蚊虫整理剂、固着剂和溶剂水混合制成多功能整理液，防紫外线剂的浓度为50g/L，防蚊虫整理剂的浓度为55g/L，固着剂的浓度为30g/L；(5)浸轧：防紫外线织物层和防蚊虫织物层分别浸轧在多功能整理液中，二浸二轧，轧液率为70-80％；(6)防蚊虫织物层粘附防蚊虫微胶囊：将防蚊虫微胶囊通过耐水性粘合剂粘附在在防蚊虫织物层的上下表面上；(7)三层织物层的叠合，将防紫外线织物层、防蚊虫织物层和棉纺织物层依次叠合缝制在一起；(8)喷涂，通过高压喷涂方式在防紫外线织物层的外侧喷涂一层多功能整理液；(9)烘干：将烘干机温度设为70-100℃，烘干3-5分钟；(10)烘焙：在120℃下烘焙30s。
所述步骤(4)中的固着剂为AF6100。
所述步骤(4)中的耐水性粘合剂为水溶性环氧树脂与聚乙烯醇的混合物，水溶性环氧树脂的质量分数为15％。
实施例3
一种防紫外线防蚊虫织物，包括叠合的三层织物层，最外层织物层为防紫外线织物层，中间层为防蚊虫织物层，最内层为棉纺织物层，所述防紫外线织物层由78.3wt％棉、11.7wt％的聚酯纤维和10wt％的氨纶制成，防蚊虫织物层由97.3wt％棉和2.7wt％的氨纶制成，棉纺织物层为100％棉；防蚊虫织物层中粘附有防蚊虫微胶囊，防蚊虫微胶囊的直径为50nm。
一种防紫外线防蚊虫织物的制备方法，包括以下步骤，(1)制备防紫外线剂：防紫外线剂由以下重量份的组分组成，苯并三唑及其衍生物35份、氧化锌微粒18份、氧化钛微粒15份、氧化铈微粒15份和氧化锆微粒20份制成；(2)制备防蚊虫整理剂：防蚊虫整理剂由以下重量份的组分组成，硝酸硫胺素18份、干柠檬粉5份、薄荷冰片10份、薰衣草6份、七里香6份、艾叶18份、藿香12份、菖蒲13份、夜来香12份、樟脑油15份、天竺葵6份、金银花15份、天然除虫菊素38份、野菊花提取物25份，紫苏叶10份；(3)制备防蚊虫微胶囊：微胶囊以部分醚化的密胺树脂初缩体作为壁材，内包防蚊虫整理剂；(4)制备多功能整理液：将防紫外线剂、防蚊虫整理剂、固着剂和溶剂水混合制成多功能整理液，防紫外线剂的浓度为40g/L，防蚊虫整理剂的浓度为60g/L，固着剂的浓度为25g/L；(5)浸轧：防紫外线织物层和防蚊虫织物层分别浸轧在多功能整理液中，二浸二轧，轧液率为70-80％；(6)防蚊虫织物层粘附防蚊虫微胶囊：将防蚊虫微胶囊通过耐水性粘合剂粘附在在防蚊虫织物层的上下表面上；(7)三层织物层的叠合，将防紫外线织物层、防蚊虫织物层和棉纺织物层依次叠合缝制在一起；(8)喷涂，通过高压喷涂方式在防紫外线织物层的外侧喷涂一层多功能整理液；(9)烘干：将烘干机温度设为70-100℃，烘干3-5分钟；(10)烘焙：在120℃下烘焙30s。
所述步骤(4)中的固着剂为AF6100。
所述步骤(4)中的耐水性粘合剂为水溶性环氧树脂与聚乙烯醇的混合物，水溶性环氧树脂的质量分数为18％。
实施例4
一种防紫外线防蚊虫织物，包括叠合的三层织物层，最外层织物层为防紫外线织物层，中间层为防蚊虫织物层，最内层为棉纺织物层，所述防紫外线织物层由80wt％棉、8wt％的聚酯纤维和12wt％的氨纶制成，防蚊虫织物层由99wt％棉和1wt％的氨纶制成，棉纺织物层为100％棉；防蚊虫织物层中粘附有防蚊虫微胶囊，防蚊虫微胶囊的直径为20nm。
一种防紫外线防蚊虫织物的制备方法，包括以下步骤，(1)制备防紫外线剂：防紫外线剂由以下重量份的组分组成，苯并三唑及其衍生物45份、氧化锌微粒12份、氧化钛微粒17份、氧化铈微粒24份和氧化锆微粒19份制成；(2)制备防蚊虫整理剂：防蚊虫整理剂由以下重量份的组分组成，硝酸硫胺素25份、干柠檬粉4份、薄荷冰片5份、薰衣草4份、七里香3份、艾叶10份、藿香15份、菖蒲10份、夜来香14份、樟脑油5份、天竺葵15份、金银花5份、天然除虫菊素45份、野菊花提取物15份，紫苏叶7份；(3)制备防蚊虫微胶囊：微胶囊以部分醚化的密胺树脂初缩体作为壁材，内包防蚊虫整理剂；(4)制备多功能整理液：将防紫外线剂、防蚊虫整理剂、固着剂和溶剂水混合制成多功能整理液，防紫外线剂的浓度为55g/L，防蚊虫整理剂的浓度为48g/L，固着剂的浓度为26g/L；(5)浸轧：防紫外线织物层和防蚊虫织物层分别浸轧在多功能整理液中，二浸二轧，轧液率为70-80％；(6)防蚊虫织物层粘附防蚊虫微胶囊：将防蚊虫微胶囊通过耐水性粘合剂粘附在在防蚊虫织物层的上下表面上；(7)三层织物层的叠合，将防紫外线织物层、防蚊虫织物层和棉纺织物层依次叠合缝制在一起；(8)喷涂，通过高压喷涂方式在防紫外线织物层的外侧喷涂一层多功能整理液；(9)烘干：将烘干机温度设为70-100℃，烘干3-5分钟；(10)烘焙：在120℃下烘焙30s。
所述步骤(4)中的固着剂为AF6100。
所述步骤(4)中的耐水性粘合剂为水溶性环氧树脂与聚乙烯醇的混合物，水溶性环氧树脂的质量分数为25％。
实施例5
一种防紫外线防蚊虫织物，包括叠合的三层织物层，最外层织物层为防紫外线织物层，中间层为防蚊虫织物层，最内层为棉纺织物层，所述防紫外线织物层由60wt％棉、25wt％的聚酯纤维和15wt％的氨纶制成，防蚊虫织物层由95wt％棉和5wt％的氨纶制成，棉纺织物层为100％棉；防蚊虫织物层中粘附有防蚊虫微胶囊，防蚊虫微胶囊的直径为80nm。
一种防紫外线防蚊虫织物的制备方法，包括以下步骤，(1)制备防紫外线剂：防紫外线剂由以下重量份的组分组成，苯并三唑及其衍生物30份、氧化锌微粒35份、氧化钛微粒10份、氧化铈微粒10份和氧化锆微粒35份制成；(2)制备防蚊虫整理剂：防蚊虫整理剂由以下重量份的组分组成，硝酸硫胺素22份、干柠檬粉3份、薄荷冰片7份、薰衣草8份、七里香4份、艾叶14份、藿香10份、菖蒲8份、夜来香18份、樟脑油13份、天竺葵18份、金银花10份、天然除虫菊素23份、野菊花提取物27份，紫苏叶5份；(3)制备防蚊虫微胶囊：微胶囊以部分醚化的密胺树脂初缩体作为壁材，内包防蚊虫整理剂；(4)制备多功能整理液：将防紫外线剂、防蚊虫整理剂、固着剂和溶剂水混合制成多功能整理液，防紫外线剂的浓度为53g/L，防蚊虫整理剂的浓度为46g/L，固着剂的浓度为35g/L；(5)浸轧：防紫外线织物层和防蚊虫织物层分别浸轧在多功能整理液中，二浸二轧，轧液率为70-80％；(6)防蚊虫织物层粘附防蚊虫微胶囊：将防蚊虫微胶囊通过耐水性粘合剂粘附在在防蚊虫织物层的上下表面上；(7)三层织物层的叠合，将防紫外线织物层、防蚊虫织物层和棉纺织物层依次叠合缝制在一起；(8)喷涂，通过高压喷涂方式在防紫外线织物层的外侧喷涂一层多功能整理液；(9)烘干：将烘干机温度设为70-100℃，烘干3-5分钟；(10)烘焙：在120℃下烘焙30s。
所述步骤(4)中的固着剂为AF6100。
所述步骤(4)中的耐水性粘合剂为水溶性环氧树脂与聚乙烯醇的混合物，水溶性环氧树脂的质量分数为12％。
实施例6
一种防紫外线防蚊虫织物，包括叠合的三层织物层，最外层织物层为防紫外线织物层，中间层为防蚊虫织物层，最内层为棉纺织物层，所述防紫外线织物层由75.8wt％棉、14.4wt％的聚酯纤维和9.8wt％的氨纶制成，防蚊虫织物层由98.4wt％棉和1.6wt％的氨纶制成，棉纺织物层为100％棉；防蚊虫织物层中粘附有防蚊虫微胶囊，防蚊虫微胶囊的直径为40nm。
一种防紫外线防蚊虫织物的制备方法，包括以下步骤，(1)制备防紫外线剂：防紫外线剂由以下重量份的组分组成，苯并三唑及其衍生物20份、氧化锌微粒10份、氧化钛微粒35份、氧化铈微粒35份和氧化锆微粒10份制成；(2)制备防蚊虫整理剂：防蚊虫整理剂由以下重量份的组分组成，硝酸硫胺素15份、干柠檬粉6份、薄荷冰片8份、薰衣草3份、七里香5份、艾叶16份、藿香8份、菖蒲15份、夜来香10份、樟脑油10份、天竺葵10份、金银花7份、天然除虫菊素28份、野菊花提取物30份，紫苏叶6份；(3)制备防蚊虫微胶囊：微胶囊以部分醚化的密胺树脂初缩体作为壁材，内包防蚊虫整理剂；(4)制备多功能整理液：将防紫外线剂、防蚊虫整理剂、固着剂和溶剂水混合制成多功能整理液，防紫外线剂的浓度为45g/L，防蚊虫整理剂的浓度为55g/L，固着剂的浓度为38g/L；(5)浸轧：防紫外线织物层和防蚊虫织物层分别浸轧在多功能整理液中，二浸二轧，轧液率为70-80％；(6)防蚊虫织物层粘附防蚊虫微胶囊：将防蚊虫微胶囊通过耐水性粘合剂粘附在在防蚊虫织物层的上下表面上；(7)三层织物层的叠合，将防紫外线织物层、防蚊虫织物层和棉纺织物层依次叠合缝制在一起；(8)喷涂，通过高压喷涂方式在防紫外线织物层的外侧喷涂一层多功能整理液；(9)烘干：将烘干机温度设为70-100℃，烘干3-5分钟；(10)烘焙：在120℃下烘焙30s。
所述步骤(4)中的固着剂为AF6100。
所述步骤(4)中的耐水性粘合剂为水溶性环氧树脂与聚乙烯醇的混合物，水溶性环氧树脂的质量分数为25％。
将上述实施例制成的织物进行抗紫外线性能测试，采用BS EN13758-1:2002服装面料抗太阳紫外线测试方法，测量其紫外线防护系数(UPF)和UVA的透过率值，具体测试数据见表1。
表1实施例2-6织物的紫外线防护系数(UPF)和UVA的透过率值
Figure BDA0002137897130000081
将上述实施例制成的织物进行防蚊虫测试，采用GB/T 30126-2013防蚊虫纺织品测试标准，通过人员驱避测试方法，测量驱避率，具体测试数据见表2，表3为驱避率防蚊等级参照表。
表2实施例2-6织物的防蚊虫驱避率值和评级
序号 驱避率R(％) 防蚊等级 洗涤50次后的驱避率 防蚊等级
实施例2 97 A 73 A
实施例3 95 A 65 B
实施例4 93 A 68 B
实施例5 95 A 75 A
实施例6 91 A 62 B
表3为驱避率防蚊等级
防蚊评级 驱避率R(％) 驱避效果
A级 ＞70 具有极强的驱避效果
B级 50-70 具有良好的驱避效果
C级 30-50 具有驱避效果
从上述实验可以看出，本申请中的防紫外线防蚊虫织物层防紫外线效果好，远远超出标注的设定值，防蚊虫效果良好，而且耐洗涤，气味持久，长时间的使用和清洗后，微胶囊破损，防蚊虫剂释放出来，依然具有良好的防蚊虫驱避效果。
以上所述的仅是本发明的优选实施方式，应当指出，对于本领域的技术人员来说，在不脱离本发明整体构思前提下，还可以作出若干改变和改进，这些也应该视为本发明的保护范围。

Claims (4)

1.一种防紫外线防蚊虫织物，其特征在于：包括叠合的三层织物层，最外层织物层为防紫外线织物层，中间层为防蚊虫织物层，最内层为棉纺织物层，所述防紫外线织物层由60-80wt%棉、8-25wt%的聚酯纤维和8-25wt%的氨纶制成，防蚊虫织物层由95-99wt%棉和1-5wt%的氨纶制成，棉纺织物层为100%棉；防蚊虫织物层中粘附有防蚊虫微胶囊，防蚊虫微胶囊的直径为20-80nm。
2.一种如权利要求1所述的防紫外线防蚊虫织物的制备方法，其特征在于：包括以下步骤，（1）制备防紫外线剂：防紫外线剂由以下重量份的组分组成，苯并三唑及其衍生物20-45份、氧化锌微粒10-35份、氧化钛微粒10-35份、氧化铈微粒10-35份和氧化锆微粒10-35份:；（2）制备防蚊虫整理剂：防蚊虫整理剂由以下重量份的组分组成，硝酸硫胺素15-25份、干柠檬粉3-7份、薄荷冰片5-10份、薰衣草3-8份、七里香2-6份、艾叶10-18份、藿香8-15份、菖蒲8-15份、夜来香10-18份、樟脑油5-15份、天竺葵6-20份、金银花5-15份、天然除虫菊素23-45份、野菊花提取物15-30份，紫苏叶5-10份；（3）制备防蚊虫微胶囊：微胶囊以部分醚化的密胺树脂初缩体作为壁材，内包步骤（2）中的防蚊虫整理剂；（4）制备多功能整理液：将防紫外线剂、防蚊虫整理剂、固着剂和溶剂水混合制成多功能整理液，防紫外线剂的浓度为40-60g/L，防蚊虫整理剂的浓度为40-60g/L，固着剂的浓度为20-40g/L；（5）浸轧：防紫外线织物层和防蚊虫织物层分别浸轧在多功能整理液中，二浸二轧，每次的轧液率为70-80%；（6）防蚊虫织物层粘附防蚊虫微胶囊：将防蚊虫微胶囊通过耐水性粘合剂粘附在防蚊虫织物层的上下表面上；（7）三层织物层的叠合，将防紫外线织物层、防蚊虫织物层和棉纺织物层依次叠合缝制在一起；（8）喷涂，通过高压喷涂方式在防紫外线织物层的外侧喷涂一层多功能整理液；（9）烘干：将烘干机温度设为70-100℃，烘干3-5分钟；（10）烘焙：在120℃下烘焙30s。
3.如权利要求2所述的防紫外线防蚊虫织物的制备方法，其特征在于：所述步骤（4）中的固着剂为AF6100。
4.如权利要求2所述的防紫外线防蚊虫织物的制备方法，其特征在于：所述步骤（6）中的耐水性粘合剂为水溶性环氧树脂与聚乙烯醇的混合物，水溶性环氧树脂的质量分数为10-25%。
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