CN112280263B - 一种木质素基可生物降解高分子复合材料薄膜及其制备方法 - Google Patents
一种木质素基可生物降解高分子复合材料薄膜及其制备方法 Download PDFInfo
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- CN112280263B CN112280263B CN202011156182.3A CN202011156182A CN112280263B CN 112280263 B CN112280263 B CN 112280263B CN 202011156182 A CN202011156182 A CN 202011156182A CN 112280263 B CN112280263 B CN 112280263B
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- lignin
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- biodegradable polymer
- caprolactone
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- 229920005610 lignin Polymers 0.000 title claims abstract description 127
- 239000002131 composite material Substances 0.000 title claims abstract description 57
- 229920002988 biodegradable polymer Polymers 0.000 title claims abstract description 24
- 239000004621 biodegradable polymer Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000002861 polymer material Substances 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims description 30
- 239000002245 particle Substances 0.000 claims description 26
- 239000002243 precursor Substances 0.000 claims description 22
- 229920001610 polycaprolactone Polymers 0.000 claims description 21
- 238000000071 blow moulding Methods 0.000 claims description 19
- 238000007664 blowing Methods 0.000 claims description 15
- 229920002961 polybutylene succinate Polymers 0.000 claims description 15
- 239000004631 polybutylene succinate Substances 0.000 claims description 15
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 12
- 239000004626 polylactic acid Substances 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 11
- 239000004632 polycaprolactone Substances 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- -1 polybutylene succinate Polymers 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical compound O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims 1
- 230000005855 radiation Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract 1
- 230000004048 modification Effects 0.000 description 12
- 238000012986 modification Methods 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 238000001125 extrusion Methods 0.000 description 8
- 238000005469 granulation Methods 0.000 description 8
- 230000003179 granulation Effects 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229920006237 degradable polymer Polymers 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000005476 size effect Effects 0.000 description 2
- AXKZIDYFAMKWSA-UHFFFAOYSA-N 1,6-dioxacyclododecane-7,12-dione Chemical compound O=C1CCCCC(=O)OCCCCO1 AXKZIDYFAMKWSA-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 229920000331 Polyhydroxybutyrate Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000005015 poly(hydroxybutyrate) Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2497/00—Characterised by the use of lignin-containing materials
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- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
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CN113278265A (zh) * | 2021-06-25 | 2021-08-20 | 华东理工大学 | 一种可降解的木质素基复合农用地膜及制备方法 |
CN113956588B (zh) * | 2021-12-02 | 2022-12-13 | 湖南湘鹤集团电缆科技股份有限公司 | 抗老化阻燃pvc材料及用于电线或电缆制备方法、用途 |
CN114133680B (zh) * | 2021-12-02 | 2023-04-18 | 湖南湘鹤集团电缆科技股份有限公司 | 一种pvc材料及其用于电线或电缆的制备方法、用途 |
CN113969047A (zh) * | 2021-12-16 | 2022-01-25 | 怀化学院 | 一种抗老化阻燃聚乳酸材料及其制备方法 |
CN114316287B (zh) * | 2021-12-17 | 2023-06-30 | 南京先进生物材料与过程装备研究院有限公司 | 一种含木质素聚酯多元醇的制备方法 |
CN114133508B (zh) * | 2022-01-14 | 2023-10-31 | 南京先进生物材料与过程装备研究院有限公司 | 一种高性能木质素基聚氨酯及其制备方法 |
Citations (6)
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JPH04275301A (ja) * | 1991-02-28 | 1992-09-30 | Daicel Chem Ind Ltd | 酢酸セルロースの低分子量化方法、ラクトン変性酢酸セルロースおよびその製造方法 |
US5321065A (en) * | 1990-01-23 | 1994-06-14 | Pierre Bono | Degradable plastics film including lignin as active vegetable filler |
JP2001019702A (ja) * | 1999-07-05 | 2001-01-23 | Daicel Chem Ind Ltd | 環状エステル変性セルロース誘導体の製造方法 |
CN109504052A (zh) * | 2018-12-13 | 2019-03-22 | 湖南绿燊环保科技有限公司 | 用于改性聚乳酸的生物质增韧剂及其制备方法、改性聚乳酸及其制备方法 |
CN111500037A (zh) * | 2020-06-03 | 2020-08-07 | 泉州陶纪塑胶有限公司 | 一种高密度竹粉改性聚乳酸生物降解塑料及其制备方法 |
CN112812348A (zh) * | 2021-02-26 | 2021-05-18 | 江南大学 | 一种高耐热抗紫外聚乳酸/纳米木质素复合膜及制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2014116672A1 (en) * | 2013-01-22 | 2014-07-31 | Carnegie Mellon University | Lignin-containing polymers and compositions including lignin-containing polymers |
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2020
- 2020-10-26 CN CN202011156182.3A patent/CN112280263B/zh active Active
Patent Citations (6)
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US5321065A (en) * | 1990-01-23 | 1994-06-14 | Pierre Bono | Degradable plastics film including lignin as active vegetable filler |
JPH04275301A (ja) * | 1991-02-28 | 1992-09-30 | Daicel Chem Ind Ltd | 酢酸セルロースの低分子量化方法、ラクトン変性酢酸セルロースおよびその製造方法 |
JP2001019702A (ja) * | 1999-07-05 | 2001-01-23 | Daicel Chem Ind Ltd | 環状エステル変性セルロース誘導体の製造方法 |
CN109504052A (zh) * | 2018-12-13 | 2019-03-22 | 湖南绿燊环保科技有限公司 | 用于改性聚乳酸的生物质增韧剂及其制备方法、改性聚乳酸及其制备方法 |
CN111500037A (zh) * | 2020-06-03 | 2020-08-07 | 泉州陶纪塑胶有限公司 | 一种高密度竹粉改性聚乳酸生物降解塑料及其制备方法 |
CN112812348A (zh) * | 2021-02-26 | 2021-05-18 | 江南大学 | 一种高耐热抗紫外聚乳酸/纳米木质素复合膜及制备方法 |
Non-Patent Citations (6)
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Grafting polycaprolactone onto alkaline lignin for improved compatibility and processability;Jing Tian;《International Journal of Biological Macromolecules》;20190909(第141期);第919-926页 * |
开环聚合接枝改性木质素;秦国富;《化学进展》;20200902;第32卷(第10期);第1547-1556页 * |
木质素基生物降解高分子材料的研究进展;王毕魁;《邵阳学院学报(自然科学版)》;20200229;第17卷(第1期);第76页 * |
木质素改性聚醋酸乙烯酯/聚丁二酸丁二醇酯复合材料的性能;舒友;《精细化工中间体》;20190228;第49卷(第1期);第34-37页 * |
木质素马来酸酯的制备研究;舒友;《精细化工中间体》;20190430;第49卷(第2期);第36-39页 * |
生物可降解的聚己内酯-g-木质素薄膜的制备与性能研究;王静雅;《华东理工大学学报(自然科学版)》;20200831;第46卷(第4期);第472-479页 * |
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