CN112250311B - 一种低介电玻璃纤维组合物、低介电玻璃纤维及其制备方法 - Google Patents
一种低介电玻璃纤维组合物、低介电玻璃纤维及其制备方法 Download PDFInfo
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- CN112250311B CN112250311B CN202011155859.1A CN202011155859A CN112250311B CN 112250311 B CN112250311 B CN 112250311B CN 202011155859 A CN202011155859 A CN 202011155859A CN 112250311 B CN112250311 B CN 112250311B
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- glass fiber
- dielectric glass
- low dielectric
- low
- tio
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- 239000003365 glass fiber Substances 0.000 title claims abstract description 132
- 239000000203 mixture Substances 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims description 14
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims abstract description 26
- 229910004298 SiO 2 Inorganic materials 0.000 claims abstract description 24
- 229910010413 TiO 2 Inorganic materials 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims description 30
- 238000002844 melting Methods 0.000 claims description 24
- 230000008018 melting Effects 0.000 claims description 24
- 239000006060 molten glass Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 abstract description 14
- 238000005260 corrosion Methods 0.000 abstract description 9
- 230000007797 corrosion Effects 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 239000011521 glass Substances 0.000 description 26
- 239000000463 material Substances 0.000 description 24
- 238000005491 wire drawing Methods 0.000 description 18
- 239000000292 calcium oxide Substances 0.000 description 16
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 16
- 238000001514 detection method Methods 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000005303 weighing Methods 0.000 description 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 239000011449 brick Substances 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 5
- 239000011819 refractory material Substances 0.000 description 5
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000009776 industrial production Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000008395 clarifying agent Substances 0.000 description 2
- 239000010431 corundum Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 229910000629 Rh alloy Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- JUVGUSVNTPYZJL-UHFFFAOYSA-N chromium zirconium Chemical compound [Cr].[Zr] JUVGUSVNTPYZJL-UHFFFAOYSA-N 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000010365 information processing Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000008054 signal transmission Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/01—Manufacture of glass fibres or filaments
- C03B37/02—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor
- C03B37/025—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor from reheated softened tubes, rods, fibres or filaments, e.g. drawing fibres from preforms
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Glass Compositions (AREA)
Abstract
Description
纤维基本性能 | 检测标准 | 对比例1 | 对比例2 | 对比例3 |
密度(g/cm<sup>3</sup>) | ISO1183-1:2012 | 2.27 | 2.28 | 2.29 |
弹性模量(GPa) | 声波法 | 66.7 | 67.1 | 66.9 |
纤维直径(μm) | GB/T 7690.5 | 6 | 5 | 5 |
拉伸强度(MPa) | ASTM D2343 | 1815 | 1917 | 1922 |
热膨胀系数(10<sup>-6</sup>/K) | ASTM D696 | 3.23 | 3.38 | 3.29 |
导热系数(W/m·k,900℃) | ASTM D5470 | 0.33328 | 0.3219 | 0.3277 |
折射率(%) | ASTM D1648 | 1.45 | 1.46 | 1.49 |
介电常数ε(1GHz) | 同轴空气线法 | 5.91 | 5.88 | 6.39 |
酸后质量保留率(%) | 10%硫酸96℃,96h | 40.9 | 42.6 | 45.7 |
Claims (7)
Priority Applications (1)
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CN202011155859.1A CN112250311B (zh) | 2020-10-26 | 2020-10-26 | 一种低介电玻璃纤维组合物、低介电玻璃纤维及其制备方法 |
Applications Claiming Priority (1)
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CN202011155859.1A CN112250311B (zh) | 2020-10-26 | 2020-10-26 | 一种低介电玻璃纤维组合物、低介电玻璃纤维及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN112250311A CN112250311A (zh) | 2021-01-22 |
CN112250311B true CN112250311B (zh) | 2023-03-24 |
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CN202011155859.1A Active CN112250311B (zh) | 2020-10-26 | 2020-10-26 | 一种低介电玻璃纤维组合物、低介电玻璃纤维及其制备方法 |
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Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113135666B (zh) * | 2020-11-18 | 2021-11-19 | 南京玻璃纤维研究设计院有限公司 | 低介电玻璃纤维及制备方法、玻璃纤维制品、复合材料及应用 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2825084B1 (fr) * | 2001-05-23 | 2003-07-18 | Saint Gobain Vetrotex | Fils de verre aptes a renforcer des matieres organiques et/ou inorganiques, procede de fabrication de fils de verre, composition utilisee |
JP2004107112A (ja) * | 2002-09-17 | 2004-04-08 | Nippon Electric Glass Co Ltd | 低誘電率低誘電正接ガラス繊維 |
CN1903767A (zh) * | 2006-08-07 | 2007-01-31 | 珠海功控玻璃纤维有限公司 | 用于制备低介电常数电子玻璃纤维的玻璃组合物 |
WO2010011701A2 (en) * | 2008-07-25 | 2010-01-28 | Dielectric Solutions, Llc | Glass fiber composition and printed circuit board made from the glass fiber composition |
CN103992039B (zh) * | 2014-05-30 | 2015-07-15 | 重庆国际复合材料有限公司 | 一种低介电常数玻璃纤维 |
CN104556710B (zh) * | 2015-02-03 | 2017-09-26 | 重庆国际复合材料有限公司 | 一种异形玻璃纤维及其制备方法 |
CN104909578B (zh) * | 2015-05-28 | 2017-06-16 | 重庆国际复合材料有限公司 | 一种玻璃纤维 |
CN106830692A (zh) * | 2017-02-04 | 2017-06-13 | 王飞 | 一种高强度高模量低介电常数玻璃纤维 |
-
2020
- 2020-10-26 CN CN202011155859.1A patent/CN112250311B/zh active Active
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Inventor after: Song Pengze Inventor after: Li Gang Inventor before: Song Mingze Inventor before: Li Gang |
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Inventor after: Song Pengze Inventor after: Gao Zengguo Inventor after: Li Gang Inventor after: Zhang Zhili Inventor after: Bai Changzheng Inventor after: Liu Fawei Inventor after: Wang Hongzhi Inventor before: Song Pengze Inventor before: Li Gang |
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Address after: No. 105, Binhai Road South, Yingkou District, China (Liaoning) Pilot Free Trade Zone, Xicheng District, Yingkou, Liaoning Province, 115000 Patentee after: LIAONING XINHONGYUAN ENVIRONMENTAL PROTECTION MATERIAL Co.,Ltd. Address before: 115000 Liaoning Province, Yingkou City West District No. 101 West Street wise Patentee before: LIAONING XINHONGYUAN ENVIRONMENTAL PROTECTION MATERIAL Co.,Ltd. |
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