CN112233910B - 纳米二氧化钒/天然多孔碳电极材料的制备方法 - Google Patents
纳米二氧化钒/天然多孔碳电极材料的制备方法 Download PDFInfo
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- CN112233910B CN112233910B CN202011115821.1A CN202011115821A CN112233910B CN 112233910 B CN112233910 B CN 112233910B CN 202011115821 A CN202011115821 A CN 202011115821A CN 112233910 B CN112233910 B CN 112233910B
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- pure cotton
- cotton felt
- vanadium dioxide
- electrode material
- porous carbon
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- 239000007772 electrode material Substances 0.000 title claims abstract description 30
- 229910021542 Vanadium(IV) oxide Inorganic materials 0.000 title claims abstract description 23
- GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 title claims abstract description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 50
- 229920000742 Cotton Polymers 0.000 claims abstract description 38
- 238000010438 heat treatment Methods 0.000 claims abstract description 28
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000003763 carbonization Methods 0.000 claims abstract description 15
- 238000010000 carbonizing Methods 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 10
- 238000000889 atomisation Methods 0.000 claims abstract description 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 238000007865 diluting Methods 0.000 claims abstract description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- 238000002791 soaking Methods 0.000 claims description 9
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 6
- 238000009656 pre-carbonization Methods 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- -1 vanadyl glycol Chemical compound 0.000 abstract description 3
- 238000001354 calcination Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract 1
- 239000003990 capacitor Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 229920000049 Carbon (fiber) Polymers 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000003575 carbonaceous material Substances 0.000 description 3
- 229920001940 conductive polymer Polymers 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/46—Metal oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inert Electrodes (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
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CN202011115821.1A CN112233910B (zh) | 2020-10-19 | 2020-10-19 | 纳米二氧化钒/天然多孔碳电极材料的制备方法 |
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CN202011115821.1A CN112233910B (zh) | 2020-10-19 | 2020-10-19 | 纳米二氧化钒/天然多孔碳电极材料的制备方法 |
Publications (2)
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CN112233910A CN112233910A (zh) | 2021-01-15 |
CN112233910B true CN112233910B (zh) | 2022-11-01 |
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CN113470981B (zh) * | 2021-05-28 | 2022-08-16 | 湖南大学 | 多孔碳纤维/金属氧化物复合材料及石墨烯基导电油墨的制备方法和在超级电容器中的应用 |
Citations (1)
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CN109216718A (zh) * | 2018-09-12 | 2019-01-15 | 成都先进金属材料产业技术研究院有限公司 | 钒电池用电极及钒电池 |
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US5958361A (en) * | 1993-03-19 | 1999-09-28 | Regents Of The University Of Michigan | Ultrafine metal oxide powders by flame spray pyrolysis |
CN100346000C (zh) * | 2005-11-25 | 2007-10-31 | 湖南师范大学 | 一种五氧化二钒薄膜的制备方法——超声喷雾法 |
CN101572191B (zh) * | 2009-06-05 | 2012-04-25 | 武汉理工大学 | 一种v2o5-有序介孔碳复合材料及其制备方法 |
CN102795968B (zh) * | 2012-09-12 | 2014-07-09 | 西南大学 | 一种乙二醇氧钒的制备方法及由乙二醇氧钒制备m相二氧化钒粉体的方法 |
CN104167303B (zh) * | 2014-07-29 | 2017-03-22 | 上海应用技术学院 | 一种介孔氧化钒/碳复合纳米材料及其制备方法 |
CN105819508B (zh) * | 2016-03-15 | 2018-07-03 | 中国科学院广州能源研究所 | 一种喷雾热解法制备vo2(m)纳米粉体及薄膜的方法 |
CN106450258B (zh) * | 2016-12-02 | 2018-11-13 | 黑龙江科技大学 | 一种氧化钒与硬碳纤维布复合电极材料的制备方法 |
CN107910199A (zh) * | 2017-10-12 | 2018-04-13 | 大连海洋大学 | 一种具有赝电容特性的超级电容器负极材料及其制备方法 |
KR102157512B1 (ko) * | 2018-11-16 | 2020-09-18 | 한국세라믹기술원 | 리그노셀룰로오스 바이오매스를 이용한 구형의 다공성 활성탄 제조방법 및 이를 이용한 슈퍼커패시터의 제조방법 |
CN110047659A (zh) * | 2019-03-28 | 2019-07-23 | 南京理工大学 | 一种生物质基柔性电极材料的制备方法 |
CN110148534A (zh) * | 2019-04-26 | 2019-08-20 | 浙江工业大学 | 一种纳米金属氧化物/碳基柔性电极材料的制备方法 |
CN110571060B (zh) * | 2019-06-24 | 2021-06-11 | 北京科技大学 | 一种二氧化钒/泡沫镍一体化电极的制备方法 |
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Patent Citations (1)
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CN109216718A (zh) * | 2018-09-12 | 2019-01-15 | 成都先进金属材料产业技术研究院有限公司 | 钒电池用电极及钒电池 |
Non-Patent Citations (1)
Title |
---|
A highly active biomass-derived electrode for all vanadium redox flow batteries;Z.H.Zhang等;《Electrochimica Acta》;20170724;第197-205页 * |
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