CN112209690A - Cement-based ceramic tile binder and preparation method thereof - Google Patents
Cement-based ceramic tile binder and preparation method thereof Download PDFInfo
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- CN112209690A CN112209690A CN202011016639.0A CN202011016639A CN112209690A CN 112209690 A CN112209690 A CN 112209690A CN 202011016639 A CN202011016639 A CN 202011016639A CN 112209690 A CN112209690 A CN 112209690A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
- C04B2111/00646—Masonry mortars
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention relates to a cement-based ceramic tile binder and a preparation method thereof, wherein the cement-based ceramic tile binder is mainly prepared from the following components in parts by weight: the cement comprises a sulfur-aluminum cementing material, gypsum, mineral powder, quartz sand, rubber powder, cellulose ether, starch ether, a water reducing agent, fiber, an early strength agent and a retarder. The invention overcomes the defects that the prior cement-based tile glue on the market generally uses silicate cement or special sulpho-alumina cement as a cementing material, has lower early strength, slower strength increasing speed, long curing period and the like, has high adjustability (can adjust construction time, bonding strength and other properties) by matching preferred types and dosage proportions of sulpho-alumina cementing material, gypsum and mineral powder and under the coordination of other auxiliary materials such as fiber, cellulose ether, starch ether, quartz sand, rubber powder, water reducing agent, early strength agent and retarder, and has excellent properties such as high early strength, fast hydration hardening, high bonding strength and the like.
Description
Technical Field
The invention relates to a cement-based ceramic tile binder and a preparation method thereof, which are applied to the field of production of binders for decoration products.
Background
The existing cement-based tile glue on the market generally uses silicate cement or special sulpho-alumina cement as a cementing material, has low early strength, slow strength increasing speed and long solid curing period, and can be constructed again on the basis of about 7 days after construction. This greatly increases the construction period, which is very costly for a long time. Therefore, a simple method is urgently needed for renovating old houses, and high-performance tile glue capable of being directly constructed on the surface of the original tile is needed. Therefore, the cement-based ceramic tile adhesive with early strength, quick hardening, convenience and high efficiency and the preparation method thereof become necessary.
Disclosure of Invention
In order to overcome the defects that the existing cement-based ceramic tile adhesive on the market generally uses silicate cement or special sulpho-alumina cement as a cementing material, and has low early strength, slow strength increasing speed, long solid curing period and the like, the invention provides the cement-based ceramic tile adhesive and the preparation method thereof.
The technical scheme of the invention is as follows:
the cement-based ceramic tile binder is mainly prepared from the following components in parts by weight:
the gypsum is 180-220 mesh anhydrous gypsum,
the mineral powder reaches the performance index of GB/T18046-2008S 95 mineral powder.
The cement-based ceramic tile binder is prepared by matching the preferred type and dosage proportion of the sulpho-aluminum cement, gypsum and mineral powder, and has high adjustability (capable of adjusting construction time, bonding strength and other properties) under the coordination of other auxiliary materials such as fiber, cellulose ether, starch ether, quartz sand, rubber powder, a water reducing agent, an early strength agent and a retarder, and has excellent properties such as high early strength, rapid hydration hardening, high bonding strength and the like.
The cement-based ceramic tile adhesive is based on a sulphoaluminate adhesive (clinker), the setting time and the strength of a cementing material are adjusted by adding gypsum, the water resistance of the cementing material can be improved by adding mineral powder, and the viscosity, the construction property and the water retention of a product can be adjusted by adding cellulose ether. The addition of the starch ether ensures the anti-slip performance of the product. The water reducing agent ensures that the product has better product stirring comfort and product workability on the premise of ensuring water demand. The addition of the rubber powder endows the product with better workability. The film-forming resin formed after the glue powder meets water can increase the cohesive force of the product, improve the tensile strength, enhance the bending strength, reduce the elastic modulus, improve the deformability, and avoid the tests of freeze-thaw cycle, heat aging and the like. The fiber enables the product to have better overall cohesiveness and higher transverse deformation value. The early strength agent can increase the early strength of the product, and the retarder is used for adjusting the construction time of the product. The cement-based tile glue in the market generally directly uses silicate cement or special sulphoaluminate cement as a cementing material, and the special sulphoaluminate cement is prepared from sulphoaluminate cement (clinker), gypsum and an admixture, but the dosage percentage of the sulphoaluminate cement is uncertain, and the selection of the type and the dosage proportion of the gypsum and the admixture are also uncertain, so that the special sulphoaluminate cement in the market is unstable in quality and high in price. The direct use of commercially available finished cement also results in the unadjustable nature of cement-based tile adhesives (construction time, bond strength and other properties are unadjustable).
The average tensile bonding strength of the cement-based ceramic tile adhesive in 6 hours can reach 1.44MPa, which is higher than the tensile bonding strength of JC/T547-2017 standard CF ceramic tile adhesive in 6 hours of 0.5MPa, and is also much higher than the requirement of C2 cement-based ceramic tile adhesive in 28 days of tensile bonding strength of 1.0MPa, and the early strength is high. The cement-based ceramic tile binder can be used for additional construction after 3-4 hours, so that the maintenance time and the construction period can be greatly shortened, and the time cost can be effectively saved.
Hydration and hardening are chemical and physical reaction processes of cement, namely a chemical reaction process after cement is stirred by adding water and a process from plasticity (flowability and deformability) to hardening (solid state) of the cement. Hydration sets quickly, i.e. the time for the cement to change from a plastic state to a set state is short.
The faster the cement hydration reaction, the earlier the cement hardening time, the higher the early strength obtained and the higher the bond strength. The early strength of the cement-based binder prepared by the invention is very high, and can be fed back to the binding strength, the original strength can reach 3.2Mpa (see the data of table 1, example 3) according to the test of JC/T547-2017, while the maximum strength of the standard cement-based binder is designed to be C2, and the original strength is not lower than 1.0 Mpa.
In addition, the adhesive can be directly coated on the surface of the original ceramic tile glue and smooth glass/metal and then directly used for tiling, and the adhesive strength is high. The cement-based adhesives on the market are generally only used for tiling on wall and floor surfaces. The cement-based ceramic tile binder has excellent performance, can greatly save labor, shortens construction period, and is convenient and quick to use. And the dosage proportion of the sulfur-aluminum cementing material, the gypsum, the mineral powder and other additives is adjusted, so that the cement-based ceramic tile adhesive can be applied to the surfaces of different substrates and different occasions, and has a large use elastic space.
Compared with the existing commercially available cement-based ceramic tile adhesive, the cement-based ceramic tile adhesive has the excellent performances of high adjustability (the construction time, the bonding strength and other performances can be adjusted), high early strength, high hydration hardening speed, high bonding strength, wide application range, low shrinkage and the like. The shrinkage rate of the cement-based ceramic tile binder is less than or equal to 0.04 percent and is superior to that of a commercially available contrast sample. The specific mechanism is as follows: the anhydrous calcium sulfate in the sulphoaluminate cement (clinker) and a proper amount of anhydrous gypsum are subjected to hydration reaction to form ettringite, the ettringite has expansibility, on the basis, the shrinkage rate is lower, and the portland cement does not have the characteristics, but the sulphoaluminate cement sold in the market contains anhydrous calcium sulfate but does not necessarily contain anhydrous gypsum, the shrinkage rate of a finished product is 0.09-0.1%, the shrinkage rate of the product is less than or equal to 0.04%, and the shrinkage rate is lower than that of the finished product.
The quartz sand is 70-140 meshes of quartz sand.
The quartz sand with the optimized mesh number has good accumulation effect and high strength.
The rubber powder is vinyl acetate/ethylene copolymerized rubber powder.
The preferred type of rubber powder is mature in technology and easy to emulsify and disperse in water.
The starch ether is carboxymethyl starch.
The preferred class of starch ethers is viscosity-type stable and not susceptible to hydrolysis.
The fiber is a polyphenylene fiber with the length of 5-7 mm.
The preferred type of fiber further enhances the bonding strength of the present cement-based ceramic tile binder.
The water reducing agent is a polycarboxylic acid type high-efficiency water reducing agent.
The water reducing effect of the preferable water reducing agent is more remarkable and efficient.
The early strength agent is lithium carbonate or aluminum sulfate.
The preferred class of early strength agents enhances the early strength of the binder.
The retarder is DL-tartaric acid.
The retarder of the preferred category can increase the operation time of the cement-based ceramic tile binder.
The preparation method of the cement-based ceramic tile binder comprises the following steps of:
1) mixing the cellulose ether, the starch ether, the water reducing agent, the fiber, the early strength agent and the retarder in parts by weight into a master batch;
2) starting a stirring blade of a mixer but not starting a fly cutter to enable the rotating speed of the stirring blade to be 100-140 revolutions per minute, firstly adding the quartz sand into the mixer, then sequentially adding the sulpho-alumina cement, the gypsum, the master batch obtained in the step 1), the mineral powder and the rubber powder, and stirring for 1-3 minutes; then, adjusting the stirring blade to a rotation speed of 220-; and finally, starting a fly cutter in the mixer while keeping the stirring blade rotating, so that the rotating speed of the fly cutter is 2800-3200 revolutions per minute, and stirring for 1-3 minutes to uniformly mix the mixture, thereby obtaining the cement-based ceramic tile adhesive.
The preparation method of the cement-based ceramic tile binder has the advantages that the components of the cement-based ceramic tile binder are mixed more uniformly and the quality is more stable due to the parameters such as the feeding sequence, the stirring speed and the stirring time. The sectional type speed-increasing stirring mixing method during mixing ensures that the cement-based ceramic tile adhesive is not layered and has more stable performance. Wherein, the fly cutter is a blade which independently rotates at a high speed except for a stirring blade in the mixer.
Compared with the prior art, the method has the following advantages:
1) the cement-based ceramic tile binder disclosed by the application is prepared by matching the sulfur-aluminum cementing material, gypsum and mineral powder in a preferred type and dosage ratio, and under the coordination of other auxiliary materials such as fibers, cellulose ether, starch ether, quartz sand, rubber powder, a water reducing agent, an early strength agent and a retarder, the adjustability is high (the construction time, the bonding strength and other properties can be adjusted), and the cement-based ceramic tile binder has excellent properties such as high early strength, rapid hydration hardening, high bonding strength and the like;
2) the preparation method of the cement-based ceramic tile binder has the advantages that the charging sequence, the stirring speed and the stirring time are increased, and the sectional type speed-up stirring and mixing method enables the components to be mixed more uniformly and the overall performance to be more stable.
Detailed Description
The technical solution of the present invention will be described in detail with reference to examples.
Example 1
The cement-based ceramic tile binder is mainly prepared from the following components in parts by weight:
the gypsum is 200-mesh anhydrous gypsum,
the mineral powder reaches the performance index of GB/T18046-2008S 95 mineral powder.
Preferably, the quartz sand is 100 mesh quartz sand.
Preferably, the rubber powder is vinyl acetate/ethylene copolymer rubber powder.
Preferably, the starch ether is carboxymethyl starch.
Preferably, the fibers are polyphenylene fibers having a length of 6 mm.
Preferably, the water reducing agent is a polycarboxylic acid type high-efficiency water reducing agent.
Preferably, the early strength agent is lithium carbonate.
Preferably, the retarder is DL-tartaric acid.
The preparation method of the cement-based ceramic tile binder comprises the following steps of:
1) mixing the cellulose ether, the starch ether, the water reducing agent, the fiber, the early strength agent and the retarder in parts by weight into a master batch;
2) starting a stirring blade of a mixer but not starting a fly cutter to enable the rotating speed of the stirring blade to be 120 revolutions per minute, firstly adding the quartz sand into the mixer, then sequentially adding the sulpho-alumina cement, the gypsum, the master batch obtained in the step 1), the mineral powder and the rubber powder, and stirring for 2 minutes; then, adjusting the stirring blades to the rotating speed of 240 revolutions per minute, and stirring for 3 minutes; and finally, starting a fly cutter in the mixer while keeping the stirring blades rotating, so that the rotating speed of the fly cutter is 3000 r/min, stirring for 1 min, and uniformly mixing the mixture to obtain the cement-based ceramic tile binder.
Example 2
The cement-based ceramic tile binder is mainly prepared from the following components in parts by weight:
the gypsum is anhydrous gypsum with the purpose of 180 meshes,
the mineral powder reaches the performance index of GB/T18046-2008S 95 mineral powder.
Preferably, the quartz sand is 70 mesh quartz sand.
Preferably, the rubber powder is vinyl acetate/ethylene copolymer rubber powder.
Preferably, the starch ether is carboxymethyl starch.
Preferably, the fibers are polyphenylene fibers having a length of 7 mm.
Preferably, the water reducing agent is a polycarboxylic acid type high-efficiency water reducing agent.
Preferably, the early strength agent is aluminum sulfate.
Preferably, the retarder is DL-tartaric acid.
The preparation method of the cement-based ceramic tile binder comprises the following steps of:
1) mixing the cellulose ether, the starch ether, the water reducing agent, the fiber, the early strength agent and the retarder in parts by weight into a master batch;
2) starting a stirring blade of a mixer but not starting a fly cutter to enable the rotating speed of the stirring blade to be 100 revolutions per minute, firstly adding the quartz sand into the mixer, then sequentially adding the sulpho-alumina cement, the gypsum, the master batch obtained in the step 1), the mineral powder and the rubber powder, and stirring for 3 minutes; then, adjusting the stirring blades to the rotating speed of 220 revolutions per minute, and stirring for 4 minutes; and finally, starting a fly cutter in the mixer while keeping the stirring blades rotating, so that the rotating speed of the fly cutter is 2800 rpm, stirring for 2 minutes, and uniformly mixing the mixture to obtain the cement-based ceramic tile binder.
Example 3
The cement-based ceramic tile binder is mainly prepared from the following components in parts by weight:
the gypsum is the anhydrous gypsum with the purpose of 220 meshes,
the mineral powder reaches the performance index of GB/T18046-2008S 95 mineral powder.
Preferably, the quartz sand is 140 mesh quartz sand.
Preferably, the rubber powder is vinyl acetate/ethylene copolymer rubber powder.
Preferably, the starch ether is carboxymethyl starch.
Preferably, the fibers are polyphenylene fibers having a length of 5 mm.
Preferably, the water reducing agent is a polycarboxylic acid type high-efficiency water reducing agent.
Preferably, the early strength agent is lithium carbonate.
Preferably, the retarder is DL-tartaric acid.
The preparation method of the cement-based ceramic tile binder comprises the following steps of:
1) mixing the cellulose ether, the starch ether, the water reducing agent, the fiber, the early strength agent and the retarder in parts by weight into a master batch;
2) starting a stirring blade of a mixer but not starting a fly cutter to enable the rotating speed of the stirring blade to be 140 revolutions per minute, firstly adding the quartz sand into the mixer, then sequentially adding the sulpho-alumina cement, the gypsum, the master batch obtained in the step 1), the mineral powder and the rubber powder, and stirring for 1 minute; then, adjusting the stirring blades to the rotating speed of 260 revolutions per minute, and stirring for 2 minutes; and finally, starting a fly cutter in the mixer while keeping the stirring blade rotating, so that the rotating speed of the fly cutter is 3200 revolutions per minute, stirring for 3 minutes, and uniformly mixing the mixture to obtain the cement-based ceramic tile binder.
Equipment and raw material sources are as follows:
a mixer: the stirring blades being arranged on a central rotating shaft and the fly-cutter being arranged on the inner wall, e.g. Mottack MR-150
The detection device comprises: reference JC/T547-2017
The sulfur-aluminum cementing material: tangshan polar bear building materials Co.Ltd 725
Gypsum: anhydrous anhydrite (200 mesh), Shahehengtai division of coal and Electricity group in North Anhui province
Mineral powder: shanghai Si pray building materials Co., Ltd, S95 grade mineral powder
Quartz sand: quartz sand limited 30-140 mesh, ying Yang county
Rubber powder: acksonobel specialty Chemicals (Shanghai) Inc., MP2050
Cellulose ether: north cellulose Ltd, TP30011C
Starch ether: evereibei (China) Co., Ltd., Netherlands, FP6
Water reducing agent: MELFLUX2651F, a product of BASF (China) chemical industry
Fiber: polyphenylene fibers (6 mm length), Jiacheng fibers of Taian City
Early strength agent: jiangxi Li industries, Ltd, battery grade, purity 99.9%
Retarder: DL-tartaric acid, Henan Saison chemical products Ltd, food grade
Experimental data:
comparison sample: the building material and the early-strength ceramic tile glue are well developed.
First, strength performance test
The detection method comprises the following steps: refer to JC/T547-2017 cement-based adhesive test section.
Table 1 strength properties test results
Compared with the technical standard of a cement-based binder CF in the JC/T547-2017 ceramic tile adhesive, the product has higher strength, quick hardening and early strength in 6 hours and airing time. The original strength, the tensile bonding strength of soaking, heat aging, freeze-thaw cycling and the like are much higher than the standard. The cement-based tile glue with fast hardening, early strength and high performance is shown.
Second, other Performance tests
The detection method comprises the following steps: the setting time and shrinkage rate test is carried out according to JG/JT70-2009, the tile surface bonding test is referred to JC/T547-2017, and after surface construction, a moving drawing tester is used for bonding test.
Table 2 results of other performance tests
| Test items | Control sample | Cement-based ceramic tile binder |
| Initial setting time (minutes) of the binder | 180 | 30 |
| Final setting time of binder (minutes) | 360 | 60 |
| Shrinkage (%) of binder | ≥0.067 | ≤0.04 |
| Tile surface adhesion test 6 hours Strength (Mpa) | / | 1.32 |
| Tile surface adhesion test 28 days original strength (Mpa) | 0.51 | 2.13 |
As can be seen from the above table, the product of the present invention has fast hydration and hardening, shorter initial setting time and final setting time than those of the comparative sample, and smaller shrinkage than those of the comparative sample. The test of directly coating the surface of the original ceramic tile shows that the product has excellent strength and is a comparative sample.
Therefore, the product has the advantages of higher strength, quick hardening, early strength, quick hydration hardening, low shrinkage rate, capability of being directly smeared on the surface of the original ceramic tile glue, and the like.
The cement-based ceramic tile adhesive and the preparation method thereof according to the present invention are not limited to the above-mentioned embodiments, and any modification or replacement according to the principle of the present invention should be within the protection scope of the present invention.
Claims (9)
1. The cement-based ceramic tile binder is characterized in that: the adhesive is mainly prepared from the following components in parts by weight:
the gypsum is 180-220 mesh anhydrous gypsum,
the mineral powder reaches the performance index of GB/T18046-2008S 95 mineral powder.
2. The cement-based ceramic tile binder of claim 1, wherein: the quartz sand is 70-140 meshes of quartz sand.
3. The cement-based ceramic tile binder of claim 1, wherein: the rubber powder is vinyl acetate/ethylene copolymerized rubber powder.
4. The cement-based ceramic tile binder of claim 1, wherein: the starch ether is carboxymethyl starch.
5. The cement-based ceramic tile binder of claim 1, wherein: the fiber is a polyphenylene fiber with the length of 5-7 mm.
6. The cement-based ceramic tile binder of claim 1, wherein: the water reducing agent is a polycarboxylic acid type high-efficiency water reducing agent.
7. The cement-based ceramic tile binder of claim 1, wherein: the early strength agent is lithium carbonate or aluminum sulfate.
8. The cement-based ceramic tile binder of claim 1, wherein: the retarder is DL-tartaric acid.
9. The method for preparing cement-based ceramic tile binder according to any one of claims 1-8, wherein: comprises the following steps which are carried out in sequence:
1) mixing the cellulose ether, the starch ether, the water reducing agent, the fiber, the early strength agent and the retarder in parts by weight into a master batch;
2) starting a stirring blade of a mixer but not starting a fly cutter to enable the rotating speed of the stirring blade to be 100-140 revolutions per minute, firstly adding the quartz sand into the mixer, then sequentially adding the sulpho-alumina cement, the gypsum, the master batch obtained in the step 1), the mineral powder and the rubber powder, and stirring for 1-3 minutes; then, adjusting the stirring blade to a rotation speed of 220-; and finally, starting a fly cutter in the mixer while keeping the stirring blade rotating, so that the rotating speed of the fly cutter is 2800-3200 revolutions per minute, and stirring for 1-3 minutes to uniformly mix the mixture, thereby obtaining the cement-based ceramic tile adhesive.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113372034A (en) * | 2021-07-06 | 2021-09-10 | 河南三棵树新材料科技有限公司 | Aggregate for preparing cement-based ceramic binder and preparation method thereof |
| CN113860842A (en) * | 2021-10-28 | 2021-12-31 | 河北三棵树涂料有限公司 | Inorganic single-component polymer tile back glue and preparation method thereof |
| CN114368936A (en) * | 2021-12-30 | 2022-04-19 | 福建省三棵树新材料有限公司 | Preparation method of cement-based ceramic binder with good conductivity |
| CN116332614A (en) * | 2023-03-29 | 2023-06-27 | 三棵树(上海)新材料研究有限公司 | Cement-based ceramic binder for winter construction and preparation method thereof |
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| CN113372034A (en) * | 2021-07-06 | 2021-09-10 | 河南三棵树新材料科技有限公司 | Aggregate for preparing cement-based ceramic binder and preparation method thereof |
| CN113860842A (en) * | 2021-10-28 | 2021-12-31 | 河北三棵树涂料有限公司 | Inorganic single-component polymer tile back glue and preparation method thereof |
| CN114368936A (en) * | 2021-12-30 | 2022-04-19 | 福建省三棵树新材料有限公司 | Preparation method of cement-based ceramic binder with good conductivity |
| CN116332614A (en) * | 2023-03-29 | 2023-06-27 | 三棵树(上海)新材料研究有限公司 | Cement-based ceramic binder for winter construction and preparation method thereof |
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