CN106278093A - Fast hard Waterproof ceramic tile adhesive agent - Google Patents

Fast hard Waterproof ceramic tile adhesive agent Download PDF

Info

Publication number
CN106278093A
CN106278093A CN201610651560.2A CN201610651560A CN106278093A CN 106278093 A CN106278093 A CN 106278093A CN 201610651560 A CN201610651560 A CN 201610651560A CN 106278093 A CN106278093 A CN 106278093A
Authority
CN
China
Prior art keywords
ceramic tile
parts
agent
tile adhesive
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610651560.2A
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Chinese (zh)
Inventor
黄海涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Yawa New Building Material Co Ltd
Original Assignee
Shanghai Yawa New Building Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Yawa New Building Material Co Ltd filed Critical Shanghai Yawa New Building Material Co Ltd
Priority to CN201610651560.2A priority Critical patent/CN106278093A/en
Publication of CN106278093A publication Critical patent/CN106278093A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/145Calcium sulfate hemi-hydrate with a specific crystal form
    • C04B28/146Calcium sulfate hemi-hydrate with a specific crystal form alpha-hemihydrate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00637Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention provides a kind of fast hard Waterproof ceramic tile adhesive agent, including powder and liquor, described powder includes each component of following parts by weight: alumina cement, ordinary portland cement, Gypsum Fibrosum, quartz sand, silicon ash, hydrophober, water reducer, flyash, water-retaining agent, anti-sag agent, redispersable latex powder, water-soluble organic compounds early strength agent part and alkyl-carboxyl class retarder;Described liquor includes each component of following parts by weight: acrylic emulsion, styrene-butadiene emulsion, water, defoamer, preservative.This adhesive is by component ordinary portland cement, alumina cement forms powder with the combination of Gypsum Fibrosum, be combined with acrylic emulsion and styrene-butadiene emulsion formed liquor carry out with the use of, the fast the most waterproof of ceramic tile adhesive can be realized, with be used alone powder as compared with adhesive, plybonding effect and the waterproof effect of the present invention are more preferable.

Description

Fast hard Waterproof ceramic tile adhesive agent
Technical field
The present invention relates to building material technical field, relate to a kind of fast hard Waterproof ceramic tile adhesive agent.
Background technology
The pulverulent mixture that ceramic tile adhesive is made up of cement, mineral aggregate, organic admixture, during use need to water or Other liquid mixs, for ornament materials such as sticking brick, face brick, floor tiles.In prior art, in particular for inside and outside metope, During the places such as bathroom, owing to environment reason has a strong impact on the adhesive strength between ceramic tile and base material, adhesion strength is caused to reduce, empty Drum, cracking, ceramic tile comes off.
In prior art, CN102503303A discloses a kind of high-strength ceramic tile tackiness agent, although the adhesive of preparation Intensity is high, but its firm time is long, is unsuitable for rapid construction;Material stiffness is big, and pliability is the highest.Disclosed in CN103613347A A kind of Waterproof ceramic tile adhesive material, although it has good water resistance, but still it is long to there is the hardened material time, uncomfortable In rapid construction;Material stiffness is big, and pliability is the highest and intensity is the highest, it is impossible to meet the requirement of high intensity.
Disclosing a kind of rapid hardening high-strength ceramic tile adhesive in CN105503106A, it does not uses liquor so that adhesive glues Knotting strength is the highest, and water proofing property is the most poor, is especially difficult to meet intensity and the waterproof requirement that furring tile is pasted.
Summary of the invention
For defect of the prior art, it is an object of the invention to provide a kind of fast hard Waterproof ceramic tile adhesive agent, it is provided that one It is good that kind has water resistance, has the most elastic or elongation percentage, and the operating time is long, the high-strength ceramic tile adhesive material that setting rate is fast Material.
It is an object of the invention to be achieved through the following technical solutions:
The invention provides a kind of fast hard Waterproof ceramic tile adhesive agent, it is characterised in that include powder and liquor,
Described powder includes each component of following parts by weight: alumina cement 7~15 parts, ordinary portland cement 30~45 parts, stone Cream 2~10 parts, quartz sand 60~65 parts, silicon ash 2~5 parts, hydrophober 1~3 parts, water reducer 0.4~0.7 part, flyash 10~ 15 parts, water-retaining agent 0.2~0.8 part, anti-sag agent 0.1~0.5 part, redispersable latex powder 7~9 parts, water-soluble organic close Thing early strength agent 0.2~1.0 parts and alkyl-carboxyl class retarder 0.05~0.2 part.
Described liquor includes each component of following parts by weight: acrylic emulsion 20~40 parts, styrene-butadiene emulsion 20-30 part, Water 40-60 part, defoamer 0.05~0.3 part, preservative 0.02~0.4 part.
Preferably, described alumina cement includes FONDU aluminate cement;Described ordinary portland cement includes that cement includes that intensity is 42.5 Portland cement.
Preferably, described Gypsum Fibrosum is semi-hydrated gypsum.
Preferably, the particle diameter of described quartz sand is 50-100 mesh.
Preferably, described water-retaining agent is methylhydroxypropylcellulose ether;Described anti-sag agent is starch ether.
Preferably, described redispersable latex powder is acrylic copolymer or Styrene-acrylic copolymer.
Preferably, described early strength agent is calcium formate or lithium carbonate;Described retarder is tartaric acid.
Preferably, described water reducer is sulfonated melamine compound resin;Described hydrophober is that silylation is redispersible hates Pigment end.
Preferably, described defoamer is mineral oil defoaming agent;Described preservative is water paint preservative.
Present invention also offers the preparation method of a kind of fast hard Waterproof ceramic tile adhesive agent, comprise the following steps: prepare respectively Powder and liquor, be mixed in proportion powder and liquor.
The present invention by component ordinary portland cement, the combination of alumina cement and Gypsum Fibrosum and add hydrophober, water reducer etc. Series additive and the combination of emulsion, can realize the fast the most waterproof of ceramic tile adhesive.
The interpolation of the parts by weight of powder component alumina cement of the present invention and Gypsum Fibrosum it is critical that.If component is high Aluminum cement is very few with the addition of Gypsum Fibrosum, then can cause the fastest hard;Addition is too much, then intensity can be caused to decline.Pu Guishui Mud, alumina cement and Gypsum Fibrosum ternary system interaction can produce substantial amounts of entringite, and this can promote adhesive quick-hardening, with Time generating of entringite be beneficial to fill the gap between mortar inside, adhesive can be made finer and close, intensity can be higher.
The interpolation of the parts by weight of liquor part acrylic emulsion of the present invention and styrene-butadiene emulsion it is critical that.If Acrylic emulsion is very few with the addition of styrene-butadiene emulsion, then can cause not having water-proof function;Addition is too much, then can cause product Flexible too high so that it is intensity declines.Acrylic emulsion and styrene-butadiene emulsion interaction can improve its polymer content, can promote Adhesive is cross-linked with each other, can make adhesive have high resistance to impermeability and to chloride, sulfate ion, carbon dioxide or other The corrosion resistance of aggressive substances.
Powder organically combines with emulsion and can improve the adhesion strength with large-size ceramic tile simultaneously, makes large-sized ceramic tile permissible Turn and be posted on different base materials;Under the effect of anti-sag agent, improve workability so that it is more convenient to operate: and have There is good waterproof effect.
Prior art is compared, and the present invention has a following beneficial effect:
1. the present invention is by component ordinary portland cement, and alumina cement forms powder, with acrylic emulsion with the combination of Gypsum Fibrosum With styrene-butadiene emulsion combine the liquor formed carry out with the use of, the fast the most waterproof of ceramic tile adhesive can be realized, and be used alone powder Agent is compared as adhesive, and plybonding effect and the waterproof effect of the present invention are more preferable.
2. the present invention the most also utilizes mineral rubber gel material and the combination at macromolecule polymer dispersion powder end, further Improve its adhesion strength and quick-hardening performance, make the superior adhesion strength that material is provided with on the basal plane that each are different; Under the effect of anti-downslide material, improve workability so that it is more convenient to operate.Retarder delays hydration reaction simultaneously, Significantly improve and improve tile bonding material workability.
3. adhesion strength and the water resistance twenty four hours of adhesive prepared by the present invention just reaches wanting of industry regulation Asking, the adhesive of high intensity improves speed of application, accelerating construction progress.Shop prefabricated module room simultaneously, due to adhesive strength Height, moves Prefabricated block room and is not result in the technical problems such as ceramic tile stripping and ceramic tile come off after sticking brick.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.Following example will assist in the technology of this area Personnel are further appreciated by the present invention, but limit the present invention the most in any form.It should be pointed out that, the ordinary skill to this area For personnel, without departing from the inventive concept of the premise, it is also possible to make some deformation and improvement.These broadly fall into the present invention Protection domain.
Embodiment 1~5
Present embodiments provide a kind of fast hard Waterproof ceramic tile adhesive agent, including each component of the parts by weight shown in table 1.
Its preparation method is:
Mixing apparatus is clean, otherwise, cleans mixing apparatus;
Prepare powder: be initially charged cement and filler;During stirring, add other additive, stir 10-20 minute Above, mix homogeneously;
Prepare liquor: by each component mix homogeneously;
Prepare ceramic tile adhesive: powder and liquor mix homogeneously can be used.
The component of fast hard Waterproof ceramic tile adhesive agent described in watch 1. embodiment 1-5 and parts by weight thereof
Comparative example 1~6
Following comparative example 1~6 is the comparative example of embodiment 1, it is provided that be fast hard moisture-proof adhesive, parts by weight calculate Powder and liquor, be specifically shown in Table 2 and table 3:
Table 2
Table 3
Implementation result
Use this area common detection methods, the performance of above-described embodiment and the resulting composition of comparative example is surveyed Examination, testing result is as shown in table 4 below:
Table 4
The testing result of comparative example 4~6 is identical with comparative example 1~3.
The concrete application approach of the present invention is a lot, and the above is only the preferred embodiment of the present invention.It should be pointed out that, above Embodiment is merely to illustrate the present invention, and is not limited to protection scope of the present invention.Common skill for the art For art personnel, under the premise without departing from the principles of the invention, it is also possible to make some improvement, these improvement also should be regarded as this Bright protection domain.

Claims (10)

1. a fast hard Waterproof ceramic tile adhesive agent, it is characterised in that include powder and liquor,
Described powder includes each component of following parts by weight: alumina cement 7~15 parts, ordinary portland cement 30~45 parts, Gypsum Fibrosum 2~ 10 parts, quartz sand 60~65 parts, silicon ash 2~5 parts, hydrophober 1~3 parts, water reducer 0.4~0.7 part, flyash 10~15 parts, Water-retaining agent 0.2~0.8 part, anti-sag agent 0.1~0.5 part, redispersable latex powder 7~9 parts, water-soluble organic compounds are the most by force Agent 0.2~1.0 parts and alkyl-carboxyl class retarder 0.05~0.2 part;
Described liquor includes each component of following parts by weight: acrylic emulsion 20~40 parts, styrene-butadiene emulsion 20-30 part, water 40- 60 parts, defoamer 0.05~0.3 part, preservative 0.02~0.4 part.
2. fast hard Waterproof ceramic tile adhesive agent as claimed in claim 1, it is characterised in that described alumina cement includes FONDU aluminum Acid salt cement;Described ordinary portland cement includes that cement includes the Portland cement that intensity is 42.5.
3. fast hard Waterproof ceramic tile adhesive agent as claimed in claim 1, it is characterised in that described Gypsum Fibrosum is semi-hydrated gypsum.
4. fast hard Waterproof ceramic tile adhesive agent as claimed in claim 1, it is characterised in that the particle diameter of described quartz sand is 50-100 Mesh.
5. fast hard Waterproof ceramic tile adhesive agent as claimed in claim 1, it is characterised in that described water-retaining agent is that methylhydroxypropyl is fine Dimension element ether;Described anti-sag agent is starch ether.
6. fast hard Waterproof ceramic tile adhesive agent as claimed in claim 1, it is characterised in that described redispersable latex powder is propylene Acid copolymer or Styrene-acrylic copolymer.
7. fast hard Waterproof ceramic tile adhesive agent as claimed in claim 1, it is characterised in that described early strength agent is calcium formate or carbon Acid lithium;Described retarder is tartaric acid.
8. fast hard Waterproof ceramic tile adhesive agent as claimed in claim 1, it is characterised in that described water reducer is sulfonated melamine Formaldehyde resin;Described hydrophober is silylation redispersible hydrophobic powder.
9. fast hard Waterproof ceramic tile adhesive agent as claimed in claim 1, it is characterised in that described defoamer is mineral oils froth breaking Agent;Described preservative is water paint preservative.
10. the preparation method of a fast hard Waterproof ceramic tile adhesive agent as claimed in claim 1, it is characterised in that include following Step: prepare powder and liquor respectively, is mixed in proportion powder and liquor.
CN201610651560.2A 2016-08-10 2016-08-10 Fast hard Waterproof ceramic tile adhesive agent Pending CN106278093A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610651560.2A CN106278093A (en) 2016-08-10 2016-08-10 Fast hard Waterproof ceramic tile adhesive agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Publications (1)

Publication Number Publication Date
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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107129242A (en) * 2017-06-06 2017-09-05 肥西县碧涛建材有限公司 A kind of ceramic tile adhesive and preparation method thereof
CN107417218A (en) * 2017-06-22 2017-12-01 合肥易美特建材有限公司 A kind of water-proof high-intensity ceramic tile adhesive and preparation method thereof
CN107418312A (en) * 2017-05-27 2017-12-01 青岛东方雨虹建筑材料有限公司 A kind of hydrophobic type polymer cement waterproof paint and preparation method thereof
CN107663053A (en) * 2017-10-24 2018-02-06 河北晨阳工贸集团有限公司 A kind of soft and graceful soft rock is attached to the construction technology in the decoration of flooring
CN108516777A (en) * 2018-04-20 2018-09-11 广东美涂士建材股份有限公司 A kind of quick-dry type Polymer cement materials and preparation method thereof
CN108558317A (en) * 2018-05-23 2018-09-21 陈谓清 A kind of building water-proof glue and preparation method thereof
CN108675734A (en) * 2018-08-03 2018-10-19 浙江忠信新型建材股份有限公司 A kind of high-performance hard ceramic tile adhesive soon
CN108751882A (en) * 2018-07-10 2018-11-06 广东美涂士建材股份有限公司 A kind of quick-dry type bi-component water-proof ceramic tile gum and preparation method thereof
CN109206113A (en) * 2018-10-11 2019-01-15 成都宏基建材股份有限公司 A kind of gypsum base vitreous tile adhesive and preparation method thereof
CN109336537A (en) * 2018-11-27 2019-02-15 中国矿业大学(北京) A kind of ceramic tile adhesive and preparation method thereof
CN110510970A (en) * 2019-08-28 2019-11-29 贵州福泉蓝图住宅产业化有限公司 A kind of gypsum base Ceramic Tiles adhesive and preparation method thereof
CN111171637A (en) * 2020-03-20 2020-05-19 广州维施克建材有限公司 Waterproof coating formula and preparation method thereof
CN111848059A (en) * 2020-02-27 2020-10-30 杭州左工建材有限公司 Water-control moisture-proof mortar for basement
CN112209690A (en) * 2020-09-24 2021-01-12 上海三棵树防水技术有限公司 Cement-based ceramic tile binder and preparation method thereof
CN113307588A (en) * 2021-06-25 2021-08-27 广州市凯聚新材料有限公司 Paste-like flexible ceramic tile binder and preparation method thereof
CN113603434A (en) * 2021-09-10 2021-11-05 四川蜀羊防水材料有限公司 Waterproof tile glue and preparation method thereof
CN113998971A (en) * 2021-10-21 2022-02-01 贵州开磷磷石膏综合利用有限公司 High-strength waterproof gypsum-based tile adhesive for wall
CN114477927A (en) * 2022-01-26 2022-05-13 广州市凯聚新材料有限公司 Ceramic tile bonding mortar material with waterproof function and tool used in cooperation with ceramic tile bonding mortar material
CN115893939A (en) * 2022-11-08 2023-04-04 佛山市鲸砼科技有限公司 Fast-hardening heat-resistant high-performance bi-component ceramic tile back glue
CN117447169A (en) * 2023-12-26 2024-01-26 唐山盾石干粉建材有限责任公司 Ceramic large plate bonding mortar and preparation method thereof

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107418312B (en) * 2017-05-27 2019-08-27 青岛东方雨虹建筑材料有限公司 A kind of hydrophobic type polymer cement waterproof paint and preparation method thereof
CN107418312A (en) * 2017-05-27 2017-12-01 青岛东方雨虹建筑材料有限公司 A kind of hydrophobic type polymer cement waterproof paint and preparation method thereof
CN107129242A (en) * 2017-06-06 2017-09-05 肥西县碧涛建材有限公司 A kind of ceramic tile adhesive and preparation method thereof
CN107417218A (en) * 2017-06-22 2017-12-01 合肥易美特建材有限公司 A kind of water-proof high-intensity ceramic tile adhesive and preparation method thereof
CN107663053A (en) * 2017-10-24 2018-02-06 河北晨阳工贸集团有限公司 A kind of soft and graceful soft rock is attached to the construction technology in the decoration of flooring
CN107663053B (en) * 2017-10-24 2020-07-31 河北晨阳工贸集团有限公司 Construction process for pasting soft and beautiful soft stone in indoor floor decoration
CN108516777A (en) * 2018-04-20 2018-09-11 广东美涂士建材股份有限公司 A kind of quick-dry type Polymer cement materials and preparation method thereof
CN108558317A (en) * 2018-05-23 2018-09-21 陈谓清 A kind of building water-proof glue and preparation method thereof
CN108751882A (en) * 2018-07-10 2018-11-06 广东美涂士建材股份有限公司 A kind of quick-dry type bi-component water-proof ceramic tile gum and preparation method thereof
CN108675734A (en) * 2018-08-03 2018-10-19 浙江忠信新型建材股份有限公司 A kind of high-performance hard ceramic tile adhesive soon
CN109206113A (en) * 2018-10-11 2019-01-15 成都宏基建材股份有限公司 A kind of gypsum base vitreous tile adhesive and preparation method thereof
CN109336537A (en) * 2018-11-27 2019-02-15 中国矿业大学(北京) A kind of ceramic tile adhesive and preparation method thereof
CN110510970A (en) * 2019-08-28 2019-11-29 贵州福泉蓝图住宅产业化有限公司 A kind of gypsum base Ceramic Tiles adhesive and preparation method thereof
CN111848059A (en) * 2020-02-27 2020-10-30 杭州左工建材有限公司 Water-control moisture-proof mortar for basement
CN111171637A (en) * 2020-03-20 2020-05-19 广州维施克建材有限公司 Waterproof coating formula and preparation method thereof
CN112209690A (en) * 2020-09-24 2021-01-12 上海三棵树防水技术有限公司 Cement-based ceramic tile binder and preparation method thereof
CN113307588A (en) * 2021-06-25 2021-08-27 广州市凯聚新材料有限公司 Paste-like flexible ceramic tile binder and preparation method thereof
CN113307588B (en) * 2021-06-25 2021-12-07 广州市凯聚新材料有限公司 Paste-like flexible ceramic tile binder and preparation method thereof
CN113603434A (en) * 2021-09-10 2021-11-05 四川蜀羊防水材料有限公司 Waterproof tile glue and preparation method thereof
CN113998971A (en) * 2021-10-21 2022-02-01 贵州开磷磷石膏综合利用有限公司 High-strength waterproof gypsum-based tile adhesive for wall
CN114477927A (en) * 2022-01-26 2022-05-13 广州市凯聚新材料有限公司 Ceramic tile bonding mortar material with waterproof function and tool used in cooperation with ceramic tile bonding mortar material
CN115893939A (en) * 2022-11-08 2023-04-04 佛山市鲸砼科技有限公司 Fast-hardening heat-resistant high-performance bi-component ceramic tile back glue
CN117447169A (en) * 2023-12-26 2024-01-26 唐山盾石干粉建材有限责任公司 Ceramic large plate bonding mortar and preparation method thereof
CN117447169B (en) * 2023-12-26 2024-04-12 唐山盾石干粉建材有限责任公司 Ceramic large plate bonding mortar and preparation method thereof

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Application publication date: 20170104