CN108558317A - A kind of building water-proof glue and preparation method thereof - Google Patents
A kind of building water-proof glue and preparation method thereof Download PDFInfo
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- CN108558317A CN108558317A CN201810499047.5A CN201810499047A CN108558317A CN 108558317 A CN108558317 A CN 108558317A CN 201810499047 A CN201810499047 A CN 201810499047A CN 108558317 A CN108558317 A CN 108558317A
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- building water
- proof glue
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- powder
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
Abstract
The invention belongs to building material technical fields more particularly to a kind of building water-proof glue and preparation method thereof, include the raw material components of following parts by weight:20~100 parts of white cement, 30~120 parts of waste stone powder, 5~20 parts of quartz sand, 10~80 parts of polymer dispersion powder, 5~30 parts of hydroxypropyl cellulose, 1~18 part of acrylic emulsion, 4~30 parts of styrene-butadiene emulsion and 5~20 parts of auxiliary agent.A kind of building water-proof glue provided by the invention, it is designed specifically for ceramic tile and marble, has the function of water proof anti-seepage, significantly improves and improve the closely knit performance in ceramic tile and marble bonding, and its tensile strength is good, avoids the hidden danger that ceramic tile or marble fall off.
Description
Technical field
The invention belongs to building material technical fields more particularly to a kind of building water-proof glue and preparation method thereof.
Background technology
Building adhesive on chemical building due to its use environment special, the requirement higher to building adhesive, but it is commercially available
Building adhesive it is different degrees of there are problems that adhesive strength not enough, acid-fast alkali-proof not enough be easy aging.And waterproof effect is good
The bad quality and service life for being directly related to engineering.
For wall is directed in building trade when being bonded ceramic tile or marble, the etch in order to avoid water to wall is led to
Normal way has following several:One is ceramic tile, ceramic tile seam cement or special joint filling material are bonded on the common coat of plaster of wall
Material carries out ditch and stitches operation, it is made to play the role of waterproof.This method is the main construction method of current architectural ornament market, but by
The small contraction distortion of generation is influenced by ambient temperature and humidity in wall, thus causes coat of plaster and ceramic tile adhesive material
Also occurs crack therewith, rainwater easily enters ceramic tile ditch seam crack, passes through the crack etch of ceramic tile adhesive material and coat of plaster
Wall cannot play the role of waterproof.Another is to use waterproof mortar as plaster, then bonds porcelain on it
Brick and ceramic tile ditch stitch operation.This method increases unit construction since the cost of waterproof mortar is significantly larger than common plastering mortar
Cost, construction party is only adopted this method in the keypoint part of building, and most wall construction still follows first
Kind construction method.Another is to use common ceramic tile rubber powder or adhesive, due to these ceramic tile rubber powders or adhesive bonds power
It is low, adhesive force is small, is unable to undergo the cold and hot influence of weather, causes infiltration, hollowing, falls off, seriously threaten personal safety, inhabitation ring
Border has not been suitable for the big vitrified tile of specification, polished bricks, marmorean stickup.
It can be seen that for art technology, there is an urgent need to a kind of superpower adhesive force and coagulabilitys, and can resist
Shake, cracking resistance, weather-proof, water proof anti-seepage is saturating, environment-protecting and non-poisonous building water-proof glue easy for construction.
Invention content
The present invention for the above technical issues, proposes a kind of building water-proof glue and preparation method thereof.
In order to achieve the above object, the technical solution adopted by the present invention is:
A kind of building water-proof glue, includes the raw material components of following parts by weight:20~100 parts of white cement, 30~120
Part waste stone powder, 5~20 parts of quartz sand, 10~80 parts of polymer dispersion powder, 5~30 parts of hydroxypropyl cellulose, 1~
18 parts of acrylic emulsion, 4~30 parts of styrene-butadiene emulsion and 5~20 parts of auxiliary agent.
Preferably, the polymer dispersion powder is vinyl acetate-ethylene copolymer.
Preferably, further comprising the zeolite powder that parts by weight are 0.5~10 part.
Preferably, the auxiliary agent includes 1~10 part of swelling agent, 3~15 parts of anti-crack fiber, 0.5~3 part of defoaming
One or more of agent, 2~10 parts of plasticizer, 0.3~3 part of stabilizer and 0.5~5 part ultraviolet absorber combine.
Preferably, the swelling agent is aluminum sulfate, aluminium oxide, alum or calcium silicates;The anti-crack fiber is day
Right paper pulp is that raw material passes through polypropylene made of working process by lignocellulosic material made of milled processed or with polypropylene
Fiber.
Preferably, the antifoaming agent is that hydrophobic silica, polyol hydrophobic type or alicyclic organic are polyhydroxylated
Close object.
Preferably, the plasticizer is polyether polyols alcohols or phthalic ester plasticizer, including:O-phthalic
Sour dinonyl, phthalic acid two (2- ethyl hexyls) ester, n-butyl phthalate, diisooctyl phthalate, neighbour
Phthalic acid diisobutyl ester, di-n-octyl phthalate, polyethylene glycol, poly- tetrahydrochysene are barked glycol, polypropylene glycol, the O-phthalic of muttering
One or more of sour di-isooctyl, repefral and diamyl phthalate mix, the plasticizer
Molecular weight is 200~5000.
Preferably, the stabilizer is one kind in zinc oxide calcium stearate, aluminum stearate, carbon black silver powder and titanium dioxide
Or several combinations;The ultraviolet absorber is 2 (3,5- di-tert-butyl -3- hydroxy phenyls) -5- chlorobenzotriazoles.
A kind of preparation method of above-mentioned building water-proof glue, includes the following steps:
Step 1:It takes white cement, waste stone powder, quartz sand, polymer dispersion powder, hydroxypropyl cellulose, anti-crack fiber, disappear
Double-planet power mixer high-speed stirred is added in infusion, stabilizer and ultraviolet absorber, and vacuum degree is under 0.085~0.099Mpa
Dehydration 1~2 hour, rotating speed are 800~1200rpm, and mixture A is prepared;
Step 2:Aqueous acrylic emulsion and styrene-butadiene emulsion are placed in container in advance, then will be in the mixture A slowly
It is added, stirring at low speed dispersion;Rotating speed is 350~450 revs/min when dispersion, and jitter time is 1.5~2.5h, is prepared mixed
Close object B;
Step 3:Plasticizer and swelling agent are added into mixture B, is stirred in the case where vacuum degree is 0.085~0.099Mpa
30~45min, rotating speed are 300~800rpm, and building water-proof glue is prepared.
Preferably, the raw material in the step 1 is also added with zeolite powder.
A kind of purposes of above-mentioned building water-proof glue, the building water-proof glue are used for ceramic tile and marmorean bonding.
Compared with prior art, the advantages and positive effects of the present invention are:
1, a kind of building water-proof glue provided by the invention, designs specifically for ceramic tile and marble, has anti-
The impervious function of water significantly improves and improves the closely knit performance in ceramic tile and marble bonding, and its tensile strength is good, keeps away
The hidden danger that ceramic tile or marble fall off is exempted from;
2, a kind of building water-proof glue provided by the invention, construction process requirement is low, and film forming speed is fast, carry out ceramic tile and
High temperature trickling, cold cracking phenomenon will not occur after marmorean bonding construction;It can construct under normal temperature condition, substantially improve work
The work situation of people, reduces labor intensity;
3, the preparation method of a kind of building water-proof glue provided by the invention, each step reasonable design, easy to implement, raw material
It is easy to get, and cheap, preparation method is simple, and construction method is easy, and high-speed stirred can effectively be avoided to cause lotion broken
Breast.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
The every other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects
It encloses.
A kind of building water-proof glue, includes the raw material components of following parts by weight:20~100 parts of white cement, 30~120
Part waste stone powder, 5~20 parts of quartz sand, 10~80 parts of polymer dispersion powder, 5~30 parts of hydroxypropyl cellulose, 1~
18 parts of acrylic emulsion, 4~30 parts of styrene-butadiene emulsion and 5~20 parts of auxiliary agent.
The above-mentioned building water-proof glue formula component compatibility provided for the embodiment is reasonable, effectively for ceramic tile and greatly
The bonding use of reason stone designs, and substantially increases the closely knit and waterproof impervious characteristic that ceramic tile and marble bond.
Specifically, wherein utilizing white cement, waste stone powder, quartz sand and polymer dispersion powder to organically combine improves its adherency
Power makes building water-proof glue be provided with the superior adhesive property on each different basal plane.Acrylic emulsion and butylbenzene breast
The further compatibility of liquid improves polymer content, further makes white cement, waste stone powder, quartz sand and polymer dispersion powder mutual
Crosslinking, make marine glue have high resistance to impervious, high water proofing property and to chloride, sulfate ion, carbon dioxide or other invade
The corrosion resistance of corrosion substance.The hydroxypropyl cellulose of further compatibility, improves the filming performance of polymer dispersion powder,
During use, polymer dispersion powder can preferably form a film, and it is existing to avoid occurring between ceramic tile or marble and joint face hollowing
As;Polymer dispersion powder provided by the invention has higher pressure resistance in use by the mutual cooperation of each component
Degree, adhesive strength and water resistance.
In an alternative embodiment, the polymer dispersion powder is vinyl acetate-ethylene copolymer.
In an alternative embodiment, further comprise the zeolite powder that parts by weight are 0.5~10 part.18, zeolite powder
The dosage for decreasing white cement is added, improves the adhesive strength of polymer dispersion powder.
In an alternative embodiment, the auxiliary agent includes 1~10 part of swelling agent, 3~15 parts of anti-crack fiber, 0.5~3
Antifoaming agent, 2~10 parts of plasticizer, 0.3~3 part of stabilizer and one kind or several in 0.5~5 part of ultraviolet absorber of part
Kind combination.It is preferred that each mutual compatibility of auxiliary agent type, improves workability, keep its operation more convenient.And carry out ceramic tile or
When marmorean bonding, for effectively being filled between gap, reduce porosity significantly improve and improve ceramic tile and
The compactness and waterproof impervious characteristic of marble bonding.
In an alternative embodiment, the swelling agent is aluminum sulfate, aluminium oxide, alum or calcium silicates;The cracking resistance
Fiber is natural pulp by lignocellulosic material made of milled processed or is that raw material is formed by working process with polypropylene
Polypropylene fibre.Under the action of swelling agent and anti-crack fiber, binding material generates certain volume expansion, avoids material
Miniature deformation caused by shrinking makes it have the function for the strain cracking for resisting material, improves the tensile strength of binding material,
Avoid the hidden danger that ceramic tile or marble fall off.
In an alternative embodiment, the antifoaming agent is hydrophobic silica, polyol hydrophobic type or alicyclic organic
Polyol.
In an alternative embodiment, the plasticizer be polyether polyols alcohols or phthalic ester plasticizer, including:
Diisononyl phthalate, phthalic acid two (2- ethyl hexyls) ester, n-butyl phthalate, phthalic acid two are different
Last of the ten Heavenly stems ester, diisobutyl phthalate, di-n-octyl phthalate, polyethylene glycol, poly- tetrahydrochysene bark mutter glycol, polypropylene glycol,
One or more of diisooctyl phthalate, repefral and diamyl phthalate mix, described
The molecular weight of plasticizer is 200~5000.
In an alternative embodiment, the stabilizer is zinc oxide calcium stearate, aluminum stearate, carbon black silver powder and titanium dioxide
One or more of combination;The ultraviolet absorber is 2 (3,5- di-tert-butyl -3- hydroxy phenyls) -5- chlorobenzotriazoles.
The present embodiment also provides a kind of preparation method of above-mentioned building water-proof glue, includes the following steps:
Step 1:It takes white cement, waste stone powder, quartz sand, polymer dispersion powder, hydroxypropyl cellulose, anti-crack fiber, disappear
Double-planet power mixer high-speed stirred is added in infusion, stabilizer and ultraviolet absorber, and vacuum degree is under 0.085~0.099Mpa
Dehydration 1~2 hour, rotating speed are 800~1200rpm, and mixture A is prepared;
Step 2:Aqueous acrylic emulsion and styrene-butadiene emulsion are placed in container in advance, then will be in the mixture A slowly
It is added, stirring at low speed dispersion;Rotating speed is 350~450 revs/min when dispersion, and jitter time is 1.5~2.5h, is prepared mixed
Close object B;
Step 3:Plasticizer and swelling agent are added into mixture B, is stirred in the case where vacuum degree is 0.085~0.099Mpa
30~45min, rotating speed are 300~800rpm, and building water-proof glue is prepared.
In an alternative embodiment, the raw material in the step 1 is also added with zeolite powder.
The present embodiment also provides a kind of purposes of above-mentioned building water-proof glue, and the building water-proof glue is for ceramic tile and greatly
The bonding of reason stone.
A kind of building water-proof glue and preparation method thereof that the embodiment of the present invention is provided is introduced in detail in order to become apparent from,
It is described below in conjunction with specific embodiment.
Embodiment 1:
A kind of building water-proof glue, it is characterised in that:Include the raw material components of following parts by weight:20 parts of white cement,
120 parts of waste stone powder, 5 parts of quartz sand, 80 parts of vinyl acetate-ethylene copolymer, 5 parts of hydroxypropyl cellulose, 18
The acrylic emulsion, 4 parts of styrene-butadiene emulsion and 20 parts of auxiliary agent of part.
The auxiliary agent include 1 part of aluminium oxide, 15 parts of lignocellulosic material, 0.5 part of polyol hydrophobic type,
2 parts of diisononyl phthalate, 3 parts of phthalic acid two (2- ethyl hexyls) ester, 1 part of phthalic acid two are just pungent
Ester, 2 parts of polyethylene glycol, 2 parts of poly- tetrahydrochysene are barked glycol, 0.3 part of zinc oxide calcium stearate and the 2 of 5 parts (the special fourths of 3,5- bis- of muttering
Base -3- hydroxy phenyls) -5- chlorobenzotriazoles.
A kind of preparation method of building water-proof glue, includes the following steps:
Step 1:White cement, waste stone powder, quartz sand, vinyl acetate-ethylene copolymerization are taken according to above-mentioned parts by weight
Object, hydroxypropyl cellulose, lignocellulosic material, polyol hydrophobic type, zinc oxide calcium stearate and 2 (the special fourths of 3,5- bis-
Base -3- hydroxy phenyls) -5- chlorobenzotriazoles be added double-planet power mixer high-speed stirred, vacuum degree be 0.085~
It is dehydrated 1~2 hour under 0.099Mpa, rotating speed is 800~1200rpm, and mixture A is prepared;
Step 2:Aqueous acrylic emulsion and styrene-butadiene emulsion are placed in container in advance, then will be in the mixture A slowly
It is added, stirring at low speed dispersion;Rotating speed is 350~450 revs/min when dispersion, and jitter time is 1.5~2.5h, is prepared mixed
Close object B;
Step 3:Diisononyl phthalate, phthalic acid two (2- ethyl hexyls) ester, neighbour are added into mixture B
Phthalic acid di-n-octyl, polyethylene glycol, poly- tetrahydrochysene are barked glycol and the aluminium oxide of muttering, in the case where vacuum degree is 0.085~0.099Mpa
30~45min is stirred, rotating speed is 300~800rpm, and building water-proof glue is prepared.
A kind of purposes of above-mentioned building water-proof glue, the building water-proof glue are used for ceramic tile and marmorean bonding.
Embodiment 2:
A kind of building water-proof glue, it is characterised in that:Include the raw material components of following parts by weight:30 parts of white cement,
100 parts of waste stone powder, 8 parts of quartz sand, 65 parts of vinyl acetate-ethylene copolymer, 10 parts of hydroxypropyl cellulose, 8
The zeolite powder, 3 parts of acrylic emulsion, 26 parts of styrene-butadiene emulsion and 8 parts of auxiliary agent of part.
The auxiliary agent include 2 parts of aluminium oxide, 12 parts of polypropylene fibre, 1 part of alicyclic organic polyol, 2 parts
Diisononyl phthalate, 2 parts of phthalic acid two (2- ethyl hexyls) ester, 2 parts of n-butyl phthalate, 2
Diisooctyl phthalate, 1.2 parts of titanium dioxide and the 2 of 3 parts (3,5- di-tert-butyl -3- hydroxy phenyls) -5- chlorobenzenes of part
And one or more of triazole combines.
A kind of preparation method of building water-proof glue, includes the following steps:
Step 1:White cement, waste stone powder, quartz sand, vinyl acetate-ethylene copolymerization are taken according to above-mentioned parts by weight
Object, hydroxypropyl cellulose, alicyclic organic polyol, zeolite powder, polypropylene fibre, titanium dioxide and 2 (3,5- di-tert-butyls-
3- hydroxy phenyls) -5- chlorobenzotriazoles addition double-planet power mixer high-speed stirred, vacuum degree is 0.085~0.099Mpa
Lower dehydration 1~2 hour, rotating speed is 800~1200rpm, and mixture A is prepared;
Step 2:Aqueous acrylic emulsion and styrene-butadiene emulsion are placed in container in advance, then will be in the mixture A slowly
It is added, stirring at low speed dispersion;Rotating speed is 350~450 revs/min when dispersion, and jitter time is 1.5~2.5h, is prepared mixed
Close object B;
Step 3:Aluminium oxide, diisononyl phthalate, (the 2- ethyls of phthalic acid two are added into mixture B
Oneself) ester, n-butyl phthalate and diisooctyl phthalate, are stirred in the case where vacuum degree is 0.085~0.099Mpa
30~45min, rotating speed are 300~800rpm, and building water-proof glue is prepared.
A kind of purposes of above-mentioned building water-proof glue, the building water-proof glue are used for ceramic tile and marmorean bonding.
Embodiment 3:
A kind of building water-proof glue, it is characterised in that:Include the raw material components of following parts by weight:60 parts of white cement,
80 parts of waste stone powder, 10 parts of quartz sand, 55 parts of vinyl acetate-ethylene copolymer, 18 parts of hydroxypropyl cellulose, 6
The zeolite powder, 12 parts of acrylic emulsion, 22 parts of styrene-butadiene emulsion and 14 parts of auxiliary agent of part.
The auxiliary agent includes 5 parts of aluminium oxide, 11 parts of polypropylene fibre, 2 parts of hydrophobic silica, 1 part of adjacent benzene
Dioctyl phthalate dinonyl, 1 part of phthalic acid two (2- ethyl hexyls) ester, 1 part of n-butyl phthalate, 1 part of neighbour
Phthalic acid diisodecyl ester, 1 part of diisobutyl phthalate, 1 part of di-n-octyl phthalate, 2 parts of stearic acid
One or more of aluminium and the 2 of 3 parts (3,5- di-tert-butyl -3- hydroxy phenyls) -5- chlorobenzotriazoles combine.
A kind of preparation method of building water-proof glue, includes the following steps:
Step 1:It takes white cement, waste stone powder, quartz sand, vinyl acetate-ethylene copolymer, hydroxypropyl cellulose, gather
Tacryl, zeolite powder, hydrophobic silica, aluminum stearate and 2 (3,5- di-tert-butyl -3- hydroxy phenyls) -5- chlorobenzenes and three
Double-planet power mixer high-speed stirred is added in azoles, and vacuum degree is to be dehydrated 1~2 hour under 0.085~0.099Mpa, and rotating speed is
Mixture A is prepared in 800~1200rpm;
Step 2:Aqueous acrylic emulsion and styrene-butadiene emulsion are placed in container in advance, then will be in the mixture A slowly
It is added, stirring at low speed dispersion;Rotating speed is 350~450 revs/min when dispersion, and jitter time is 1.5~2.5h, is prepared mixed
Close object B;
Step 3:Aluminium oxide, diisononyl phthalate, (the 2- ethyls of phthalic acid two are added into mixture B
Oneself) ester, n-butyl phthalate, diisooctyl phthalate, diisobutyl phthalate and phthalic acid two
N-octyl stirs 30~45min in the case where vacuum degree is 0.085~0.099Mpa, and rotating speed is 300~800rpm, is prepared and builds
It builds and uses marine glue.
A kind of purposes of above-mentioned building water-proof glue, the building water-proof glue are used for ceramic tile and marmorean bonding.
Embodiment 4:
A kind of building water-proof glue, it is characterised in that:Include the raw material components of following parts by weight:40 parts of white cement,
100 parts of waste stone powder, 10 parts of quartz sand, 75 parts of vinyl acetate-ethylene copolymer, 10 parts of hydroxypropyl cellulose,
10 parts of zeolite powder, 3 parts of acrylic emulsion, 26 parts of styrene-butadiene emulsion and 15 parts of auxiliary agent.
The auxiliary agent include 8 parts calcium silicates, 6 parts lignocellulosic material dimension, 2.5 parts hydrophobic silica, 1 part
Diisooctyl phthalate, 2 parts of repefral, 1 part of diamyl phthalate, 2.8 parts of titanium dioxide
With the combination of one or more of 1.5 parts 2 (3,5- di-tert-butyl -3- hydroxy phenyls) -5- chlorobenzotriazoles.
A kind of preparation method of building water-proof glue, includes the following steps:
Step 1:White cement, waste stone powder, quartz sand, vinyl acetate-ethylene copolymerization are taken according to above-mentioned parts by weight
Object, hydroxypropyl cellulose, lignocellulosic material dimension, zeolite powder, hydrophobic silica, titanium dioxide and 2 (3,5- di-tert-butyls -3-
Hydroxy phenyl) -5- chlorobenzotriazoles addition double-planet power mixer high-speed stirred, vacuum degree is under 0.085~0.099Mpa
Dehydration 1~2 hour, rotating speed are 800~1200rpm, and mixture A is prepared;
Step 2:Aqueous acrylic emulsion and styrene-butadiene emulsion are placed in container in advance, then will be in the mixture A slowly
It is added, stirring at low speed dispersion;Rotating speed is 350~450 revs/min when dispersion, and jitter time is 1.5~2.5h, is prepared mixed
Close object B;
Step 3:Calcium silicates, diisooctyl phthalate, repefral and neighbour are added into mixture B
Phthalic acid diamyl ester, 30~45min is stirred in the case where vacuum degree is 0.085~0.099Mpa, and rotating speed is 300~800rpm, system
It is standby to obtain building water-proof glue.
A kind of purposes of above-mentioned building water-proof glue, the building water-proof glue are used for ceramic tile and marmorean bonding.
Embodiment 5:
A kind of building water-proof glue, it is characterised in that:Include the raw material components of following parts by weight:100 parts of white cement,
30 parts of waste stone powder, 20 parts of quartz sand, 10 parts of vinyl acetate-ethylene copolymer, 30 parts of hydroxypropyl cellulose, 1
The acrylic emulsion, 30 parts of styrene-butadiene emulsion and 5 parts of auxiliary agent of part.
The auxiliary agent includes 10 parts of alum, 3 parts of polypropylene fibre, 3 parts of alicyclic organic polyol, 2
Polypropylene glycol, 3 parts of carbon black silver powder and the 2 of 0.5 part (3,5- di-tert-butyl -3- hydroxy phenyls) -5- chlorobenzotriazoles of part.
A kind of preparation method of building water-proof glue, includes the following steps:
Step 1:White cement, waste stone powder, quartz sand, vinyl acetate-ethylene copolymerization are taken according to above-mentioned parts by weight
Object, hydroxypropyl cellulose, polypropylene fibre, alicyclic organic polyol, carbon black silver powder and 2 (3,5- di-tert-butyl -3- hydroxyls
Phenyl) -5- chlorobenzotriazoles addition double-planet power mixer high-speed stirred, vacuum degree is to be dehydrated 1 under 0.085~0.099Mpa
~2 hours, rotating speed was 800~1200rpm, and mixture A is prepared;
Step 2:Aqueous acrylic emulsion and styrene-butadiene emulsion are placed in container in advance, then will be in the mixture A slowly
It is added, stirring at low speed dispersion;Rotating speed is 350~450 revs/min when dispersion, and jitter time is 1.5~2.5h, is prepared mixed
Close object B;
Step 3:Alum and polypropylene glycol are added into mixture B, in the case where vacuum degree is 0.085~0.099Mpa
30~45min is stirred, rotating speed is 300~800rpm, and building water-proof glue is prepared.
A kind of purposes of above-mentioned building water-proof glue, the building water-proof glue are used for ceramic tile and marmorean bonding.
Performance detection is tested:
Surface drying time, sag, the compression shear strength for the building water-proof glue that the present invention is prepared for Examples 1 to 5
And the caking property to tile substrate, it is tested according to following standard and method.
Surface drying time, sag, GB/T 13477-2002《Building sealant test method》
Compression shear strength, JC/T 547-2005《Ceramic wall and floor bricks adhesive》
Tile bonding is glued in ceramic tile surface, and conserves conserved 28 days under 28 days or standard conditions at the standard conditions
It is dried after soaked 7 days again and carries out pulling peel test, observe the bond failure situation of the adhesive tape and ceramic tile surface pulled open.If it is
Cohesional failure and tile substrate destruction are determined as that cementability is good;It is judged to not being bonded if it is interfacial failure, it is broken further according to interface
The area of bonding is gone bad to determine bonding percentage.
The results are shown in Table 1 for specific experiment:
Building water-proof colloidality energy test experience result prepared by 1 Examples 1 to 5 of table
Simultaneously for all technical of Examples 1 to 5 according to item detection shown in table 2, wherein Examples 1 to 5
Testing result is as shown in table 2.
The technical indicator testing result of 2 Examples 1 to 5 of table
From the data in table 2, it can be seen that following content:
1, the building water-proof glue that Examples 1 to 5 is provided stretches gluing original intensity (28d) index and is much higher than national row
It is extremely strong to characterize the building water-proof gluing knot power that Examples 1 to 5 is provided for industry standard;
2, the building water-proof glue that Examples 1 to 5 is provided is higher than country in immersion post-tensioning gluing intensity (28d) index
Professional standard, characterize building water-proof glue that Examples 1 to 5 is provided for a long time by the etch of rainwater after, present invention building
It will not be reduced with the cohesive force of marine glue and ceramic tile, it is ensured that the stability of tile bonding;
3, the building water-proof glue 20min that Examples 1 to 5 is provided hangs post-tensioning gluing intensity (28d) index and is higher than
National sector standard characterizes building water-proof glue that Examples 1 to 5 is provided in tile paste work progress, ceramic tile paving
After patch adjustment, the cohesive force for the building water-proof glue that Examples 1 to 5 is provided will not reduce, it is ensured that tile bonding performance is not
Become.
To sum up, building water-proof gluing knotting strength of the invention is high, and the adaptive faculty of environment is strong, is building and personal safety
Provide guarantee.
Claims (10)
1. a kind of building water-proof glue, it is characterised in that:Include the raw material components of following parts by weight:20~100 parts of plain boiled water
Mud, 30~120 parts of waste stone powder, 5~20 parts of quartz sand, 10~80 parts of polymer dispersion powder, 5~30 parts of hydroxypropyl
Cellulose, 1~18 part of acrylic emulsion, 4~30 parts of styrene-butadiene emulsion and 5~20 parts of auxiliary agent.
2. building water-proof glue according to claim 1, it is characterised in that:Further comprise parts by weight be 0.5~
10 parts of zeolite powder.
3. building water-proof glue according to claim 1, it is characterised in that:The auxiliary agent include 1~10 part swelling agent,
3~15 parts of anti-crack fiber, 0.5~3 part of antifoaming agent, 2~10 parts of plasticizer, 0.3~3 part of stabilizer and 0.5~5 part
The combination of one or more of ultraviolet absorber.
4. building water-proof glue according to claim 3, it is characterised in that:The swelling agent is aluminum sulfate, aluminium oxide, sulphur
Sour aluminium potassium or calcium silicates;The anti-crack fiber is natural pulp by lignocellulosic material made of milled processed or uses polypropylene
It is that raw material passes through polypropylene fibre made of working process.
5. building water-proof glue according to claim 3, it is characterised in that:The antifoaming agent is hydrophobic silica, more
Hydroxy compounds hydrophobic type or alicyclic organic polyol.
6. building water-proof glue according to claim 3, it is characterised in that:The plasticizer is polyether polyols alcohols or neighbour
Phthalic easter plastizer, including:Diisononyl phthalate, phthalic acid two (2- ethyl hexyls) ester, O-phthalic
Sour di-n-butyl, diisooctyl phthalate, diisobutyl phthalate, di-n-octyl phthalate, polyethylene glycol,
Poly- tetrahydrochysene is barked glycol, polypropylene glycol, diisooctyl phthalate, repefral and the diamyl phthalate of muttering
One or more of mixing, the molecular weight of the plasticizer be 200~5000.
7. building water-proof glue according to claim 3, it is characterised in that:The stabilizer be zinc oxide calcium stearate,
One or more of aluminum stearate, carbon black silver powder and titanium dioxide combine;The ultraviolet absorber is 2 (3,5- di-tert-butyls -3-
Hydroxy phenyl) -5- chlorobenzotriazoles.
8. a kind of preparation method of claim 1~7 any one of them building water-proof glue, it is characterised in that:Including following
Step:
Step 1:Take white cement, waste stone powder, quartz sand, polymer dispersion powder, hydroxypropyl cellulose, anti-crack fiber, defoaming
Double-planet power mixer high-speed stirred is added in agent, stabilizer and ultraviolet absorber, and vacuum degree is to be taken off under 0.085~0.099Mpa
Water 1~2 hour, rotating speed are 800~1200rpm, and mixture A is prepared;
Step 2:Aqueous acrylic emulsion and styrene-butadiene emulsion are placed in container in advance, then will slowly be added in the mixture A
Enter, stirring at low speed dispersion;Rotating speed is 350~450 revs/min when dispersion, and jitter time is 1.5~2.5h, and mixing is prepared
Object B;
Step 3:Plasticizer and swelling agent are added into the mixture B, is stirred in the case where vacuum degree is 0.085~0.099Mpa
30~45min, rotating speed are 300~800rpm, and building water-proof glue is prepared.
9. the preparation method of building water-proof glue according to claim 8, it is characterised in that:Raw material in the step 1
Also it is added with zeolite powder.
10. a kind of purposes of claim 1~7 any one of them building water-proof glue, it is characterised in that:It is described for building anti-
Glue is used for ceramic tile and marmorean bonding.
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Publication number | Priority date | Publication date | Assignee | Title |
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CN111423158A (en) * | 2020-04-18 | 2020-07-17 | 长沙汇泉环境科技有限公司 | Ceramic tile repairing agent and preparation method thereof |
CN111925749A (en) * | 2020-08-14 | 2020-11-13 | 湖北德龙彩画装饰有限公司 | Adhesive special for outer wall canvas |
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CN111925749B (en) * | 2020-08-14 | 2021-09-21 | 湖北德龙彩画装饰有限公司 | Adhesive special for outer wall canvas |
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