CN1173524A - Building waterproof adhesive - Google Patents
Building waterproof adhesive Download PDFInfo
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- CN1173524A CN1173524A CN 96120237 CN96120237A CN1173524A CN 1173524 A CN1173524 A CN 1173524A CN 96120237 CN96120237 CN 96120237 CN 96120237 A CN96120237 A CN 96120237A CN 1173524 A CN1173524 A CN 1173524A
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Abstract
A water-proofing pasty adhesive for the building is prepared from used graft copolymer of foam polystyrene, thickening resin, filler, stabilizer, ultraviolet absorbent and solvent, and is suitable for laying marble, granite, ceramic tile, enamelled tile, mosaic, cement floor tile, wooden floor tile and plastic floor tile and preventing leakage of roof and pipeline. Its advantages are in secondary pollution, high adhesion and good water-proof nature.
Description
The invention belongs to the macromolecule adhesive field, relate in particular to a kind of cream pasty state moisture-proof adhesive for building.
Along with expanding economy, the problem of environmental pollution of waste and old polystyrene foamed (EPS) more and more is subject to people's attention, at present domestic having is the bibliographical information that main raw material is made tackiness agent with waste and old polystyrene foamed much, as Chinese patent CN1082587, CN1072439, CN1057285 etc., all introduced with waste and old polystyrene foamed is the tackiness agent of main raw material preparation, but because polystyrene is glassy, matter is crisp, broken at a touch, heat-resisting low, use temperature only is 60-75 ℃, so existing is that the architecture adhesion agent that main raw material prepares all exists shortcomings such as bonding strength is low with waste and old polystyrene foamed, range of application is narrow, be difficult to be used for bonding marble ceramic tile, and be unsuitable for waterproof, moistureproof demanding occasion is used.
The objective of the invention is with waste and old polystyrene foamed is raw material, overcome the crisp shortcoming of its matter, the moisture-proof adhesive of the be widely used in building field of a kind of bonding strength height, acid and alkali-resistance, the variation of heatproof degree, water resistance excellence is provided, can be used for the bonding of various building materials such as various ceramic tiles such as marble and cement, timber, plastic floor, can require to use under the high occasion in waterproof, protection against the tide, and this architecture adhesion agent is turned waste into wealth, raw material is cheap and easy to get, not only product price is lower, and can eliminate environmental pollution.
Consisting of of tackiness agent of the present invention: (by weight):
100 parts of waste and old polystyrene foamed graft copolymers
Tackifying resin 8-24 part
Filler 120-265 part
Stablizer 5-25 part
Uv-absorbing agent 1-5 part
The present invention makes according to adherent adsorption theory and anti-water theory, utilize the low-pole of polystyrene, surface energy is lower, characteristics such as cohesion intensity height, removing wherein, hydrophilic radical forms, crisp to the soft variation of matter for solving EPS from matter, so adopt the EPS graft copolymer, with EPS glue and softening agent, monomers such as rosin prepare the EPS graft copolymer with the chemical graft method, used softening agent is used always, as phthalic ester plasticizer, the preparation method is as follows: the waste polystyrene foam EPS that reclaims is not added cleaning thrown into solvent in proportion (solvent for use is an aromatic hydrocarbon among the present invention, hydrochloric ether, solvent oil, methylethylketone, dimethylbenzene etc.) in the jar (100 gram solvents add the EPS30-45 gram), and rear enclosed adopts oil pump to extract out solvent glue standby from changing (self-dissolving 96 hours) again; In the three-necked bottle that has agitator, condenser, add polystyrene glue, softening agent, (three's ratio is 100 to rosin: 5-20: 1-15), heating is melted, temperature 65-85 ℃, after reaction times 40-60 minute, the sampling denseness reaches the 700-800 degree, can become glue to obtain the graft copolymer component.
In tackiness agent of the present invention, added tackifying resin for improving its bonding strength, as carboxylic styrene butadiene latex, paracril, Gum Rosin, polyvinyl chloride resin, urea-formaldehyde resin.
Filler described in the tackiness agent of the present invention is a 250-325 order marble flour, 300-325 order Fly-ash, 250-400 order SULPHUR POWDER, 200-300 height of eye aluminium cement, 200-300 order terra alba, 150-450 order smolmitza, 150-450 order light burnt powder, 325 order kaolin, 400-600 order talcum powder, zinc oxide, the borax powder, magnesium oxide, the mixture of two or more in the colophonium powder, smolmitza, light burnt powder is as adhesion promotor, terra alba, high-alumina cement is done to solidify alkaline-resisting dose, SULPHUR POWDER is made acidproof auxiliary agent, kaolin is used to improve anti-doing and wets, alkaline-resisting, resistance to deterioration, the talcum powder used as stabilizers, lubricating auxiliary agent.
For improving the stability of product, added stablizer in the tackiness agent of the present invention, as zinc oxide calcium stearate, aluminum stearate, carbon black silver powder, titanium dioxide etc.
For improving the resistance to deterioration of product, in tackiness agent of the present invention, also added UV light absorber, as 2 (3,5-di-tert-butyl-3-hydroxy phenyl)-5-chlorobenzotriazoles.
The manufacturing of tackiness agent be will be as mentioned before the graft copolymer component of preparation and tackifying resin, filler, stablizer and UV light absorber put into and carry out mixing in the concrete mixer, then the blended sizing material enters and grinds dispersion in the three-roll grinder, promptly makes buildings waterproof tackiness agent of the present invention to reaching the 250-350 order.
Building water-proof tackiness agent provided by the invention has the following advantages:
1). the water resistance excellence: soak 100h do not have peel off, cracking phenomena, shearing resistance＞0.8MPa;
2). acid resistance: soak 62h with the nitric acid liquid of saturated 44-55% and do not have dry linting, peel off, bubble;
3). alkali resistance: soak 86h with saturated sodium hydroxide solution, no dry linting, peel off, bubble;
4). the heatproof degree changes: placing 7h for 100 ℃ does not have and peels off;
5). bonding strength height: reach state specified standards, ultimate compression strength＞5MPa, shearing resistance 1.2MPa;
6). of many uses: as to can be used for the firm stickup of marble that swimming pool, kitchen, vault, toilet, bathing pool and interior and exterior wall decorate, grouan, ceramic tile, ornamental brick, mosaic, cement system floor tile, floorboards of wood brick, plastic floor brick etc., also can be widely used in roof leakage, damp proofing of ground, pipeline antiseepage etc.;
7). solved " white pollution " problem, and do not caused secondary pollution, the cost of gained tackiness agent is low, and per ton cost 2500-3500 unit only is 1/8 of domestic other similar tackiness agent;
8). product adopts the pasty state packing, and storage period is long, 6 months storage periods of general caking agent, and this tackiness agent was 8-12 individual month;
9). low-consuming: this tackiness agent proportion is lighter than body of cement, with 4 kilograms of smart cement flours, with only 1 kilogram in this glue; Consumption is smooth relevant with ground, and during adhesive linkage 1.5-2mm, general glue consumption is every square metre of about 1.5-2 kilogram;
10). easy to use: this tackiness agent is a single-component, and the composition that replaces solidifying agent is arranged in the adhesive formulation, as terra alba, high-alumina cement, need not to add solidifying agent, saving of work and time when therefore using.
Embodiment 1:
Having agitator, add polystyrene glue 100 grams in the three-necked bottle of condenser, dibutyl phthalate 15 grams, rosin 7 grams, make the graft copolymer component described in the by specification, get prepared graft copolymer base-material 100 grams again, 250 order marble flours, 120 grams, 300 order Fly-ashes, 60 grams, 250 order SULPHUR POWDER, 37 grams, zinc oxide 10 grams, borax 5 grams, carboxylic styrene butadiene latex 8 grams, zinc oxide calcium stearate 10 grams, 2 (3,5-di-tert-butyl-3-hydroxy phenyl)-5-chlorobenzotriazole 2 grams, as described in specification sheets, make buildings waterproof tackiness agent of the present invention, can be used for marmorean strong bond etc.Embodiment 2:
Get dioctyl phthalate (DOP) 5 grams, rosin 15 grams and 100 gram EPS glues and make graft copolymer 100 grams, again with 325 order Fly-ashes, 100 grams, 200 order terra albas, 30 grams, 450 order smolmitza, 25 grams, 325 order kaolin, 27 grams, magnesium oxide 10 grams, Gum Rosin 24 grams, titanium dioxide 5 grams, 2 (3,5-di-tert-butyl-3-hydroxy phenyl)-5-chlorobenzotriazole 5 grams, make buildings waterproof tackiness agent of the present invention, can be used for bonding ceramic tile etc.Embodiment 3:
The preparation of EPS glue is as embodiment 1, get 100 glues, 300 order light burnt powders, 50 grams, borax 70 grams, polyvinyl chloride resin 16 grams, aluminum stearate 24 grams, 2 (3,5-di-tert-butyl-3-hydroxy phenyl)-5-chlorobenzotriazole 1 gram, make buildings waterproof tackiness agent of the present invention, can be used for bonding plastics floor tile etc.
Adopt the prepared buildings waterproof tackiness agent of above embodiment, be compared as follows table with the every performance of inferior porcelain powder YJ-1 caking agent:
| Buildings waterproof tackiness agent of the present invention | Inferior porcelain powder YJ-1 caking agent | |
| The decorative cover drying property | Can be used for the bonding of desiccated surface | Bonding again after needing to spray water |
| Construction temperature | Do not limit | ＞5 ℃, best 25 ℃ |
| Storage temperature | Do not limit | ＞0 ℃, the free from dampness place |
| Resistance to acids and bases | Acidproof alkaline-resisting again | Alkaline-resisting not acidproof |
| The scope of application | Can be used for multiple base materials such as marble | Can not be used for marble |
Claims (5)
1. a building water-proof tackiness agent is characterized in that, it contains (by weight):
100 parts of waste and old polystyrene foamed graft copolymers
Tackifying resin 8-24 part
Filler 120-265 part
Stablizer 5-25 part
Uv-absorbing agent 1-5 part
2. according to the described tackiness agent of claim 1, it is characterized in that described tackifying resin is carboxylic styrene butadiene latex, paracril, Gum Rosin, polyvinyl chloride resin, urea-formaldehyde resin.
3. according to the described tackiness agent of claim 1, it is characterized in that described filler is two or more the mixture in 250-325 order marble flour, 300-325 order Fly-ash, 250-400 order SULPHUR POWDER, 200-300 height of eye aluminium cement, 200-300 order terra alba, 150-450 order smolmitza, 150-450 order light burnt powder, 325 order kaolin, 400-600 order talcum powder, zinc oxide, borax powder, magnesium oxide, the colophonium powder.
4. according to the described tackiness agent of claim 1, it is characterized in that described stablizer is a kind of in zinc oxide calcium stearate, aluminum stearate, carbon black silver powder, the titanium dioxide.
5. according to the described tackiness agent of claim 1, it is characterized in that described UV light absorber is 2 (3,5-di-tert-butyl-3-hydroxy phenyl)-5-chlorobenzotriazoles.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96120237A CN1074036C (en) | 1996-10-24 | 1996-10-24 | Building waterproof adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96120237A CN1074036C (en) | 1996-10-24 | 1996-10-24 | Building waterproof adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1173524A true CN1173524A (en) | 1998-02-18 |
| CN1074036C CN1074036C (en) | 2001-10-31 |
Family
ID=5126208
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96120237A Expired - Fee Related CN1074036C (en) | 1996-10-24 | 1996-10-24 | Building waterproof adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1074036C (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215130B (en) * | 2008-01-14 | 2010-11-03 | 常州市宇乔建材科技有限公司 | Modified facing brick binding agent and preparation method thereof |
| CN101735525B (en) * | 2009-12-07 | 2011-06-22 | 陆颂荫 | Leak preventive |
| CN103289459A (en) * | 2013-06-04 | 2013-09-11 | 苏州艾特斯环保材料有限公司 | Bismaleimide-containing waterproof acid and alkali resistant paint |
| CN103467055A (en) * | 2013-09-12 | 2013-12-25 | 德高（广州）建材有限公司 | Mosaic binding agent integrating two purposes of binding and joint filling |
| CN103482930A (en) * | 2013-09-12 | 2014-01-01 | 德高（广州）建材有限公司 | Sticking waterproof three-in-one mosaic adhesive filling joints |
| CN103555269A (en) * | 2013-10-29 | 2014-02-05 | 桂林理工大学 | Seamless splicing glue for artificial stone slabs |
| CN103555224A (en) * | 2013-10-23 | 2014-02-05 | 湖州中辰建设有限公司 | Leakage-proof sealant for construction machinery |
| CN104591606A (en) * | 2013-10-30 | 2015-05-06 | 吕大龙 | Production method for novel nanometer bonding powder |
| CN104884691A (en) * | 2013-01-08 | 2015-09-02 | 加拿大圣戈班爱德福思有限公司 | Glass mat for roofing products |
| CN104944878A (en) * | 2015-05-28 | 2015-09-30 | 南京先声合成材料有限公司 | Waterproof adhesive for construction |
| CN108558317A (en) * | 2018-05-23 | 2018-09-21 | 陈谓清 | A kind of building water-proof glue and preparation method thereof |
| CN110343480A (en) * | 2019-07-26 | 2019-10-18 | 王佳胶带科技(南通)有限公司 | A kind of adhesive waterproof tape and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1073192A (en) * | 1991-12-11 | 1993-06-16 | 周武军 | A kind of method of synthetic polystyrene adhesive |
| CN1088602A (en) * | 1992-12-25 | 1994-06-29 | 郭静峰 | Utilize waste and old polystyrol to make the method for tackiness agent |
-
1996
- 1996-10-24 CN CN96120237A patent/CN1074036C/en not_active Expired - Fee Related
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215130B (en) * | 2008-01-14 | 2010-11-03 | 常州市宇乔建材科技有限公司 | Modified facing brick binding agent and preparation method thereof |
| CN101735525B (en) * | 2009-12-07 | 2011-06-22 | 陆颂荫 | Leak preventive |
| US10227477B2 (en) | 2013-01-08 | 2019-03-12 | Saint-Gobain Adfors Canada, Ltd. | Glass mat for roofing products |
| US9617734B2 (en) | 2013-01-08 | 2017-04-11 | Saint-Gobain Adfors Canada, Ltd. | Glass mat for roofing products |
| CN104884691A (en) * | 2013-01-08 | 2015-09-02 | 加拿大圣戈班爱德福思有限公司 | Glass mat for roofing products |
| CN103289459A (en) * | 2013-06-04 | 2013-09-11 | 苏州艾特斯环保材料有限公司 | Bismaleimide-containing waterproof acid and alkali resistant paint |
| CN103467055A (en) * | 2013-09-12 | 2013-12-25 | 德高（广州）建材有限公司 | Mosaic binding agent integrating two purposes of binding and joint filling |
| CN103482930A (en) * | 2013-09-12 | 2014-01-01 | 德高（广州）建材有限公司 | Sticking waterproof three-in-one mosaic adhesive filling joints |
| WO2015035840A1 (en) * | 2013-09-12 | 2015-03-19 | 德高（广州）建材有限公司 | Three-in-one mosaic adhesive for pasting, seam-filling and water-resisting |
| CN103555224B (en) * | 2013-10-23 | 2015-10-21 | 新昌县羽林街道东陈机械厂 | A kind of building machinery leakproof seal glue |
| CN103555224A (en) * | 2013-10-23 | 2014-02-05 | 湖州中辰建设有限公司 | Leakage-proof sealant for construction machinery |
| CN103555269B (en) * | 2013-10-29 | 2015-12-30 | 桂林理工大学 | The seamless spliced glue of a kind of artificial slabstone |
| CN103555269A (en) * | 2013-10-29 | 2014-02-05 | 桂林理工大学 | Seamless splicing glue for artificial stone slabs |
| CN104591606A (en) * | 2013-10-30 | 2015-05-06 | 吕大龙 | Production method for novel nanometer bonding powder |
| CN104944878A (en) * | 2015-05-28 | 2015-09-30 | 南京先声合成材料有限公司 | Waterproof adhesive for construction |
| CN108558317A (en) * | 2018-05-23 | 2018-09-21 | 陈谓清 | A kind of building water-proof glue and preparation method thereof |
| CN110343480A (en) * | 2019-07-26 | 2019-10-18 | 王佳胶带科技(南通)有限公司 | A kind of adhesive waterproof tape and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1074036C (en) | 2001-10-31 |
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