CN103467055A - Mosaic binding agent integrating two purposes of binding and joint filling - Google Patents

Mosaic binding agent integrating two purposes of binding and joint filling Download PDF

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Publication number
CN103467055A
CN103467055A CN2013104142064A CN201310414206A CN103467055A CN 103467055 A CN103467055 A CN 103467055A CN 2013104142064 A CN2013104142064 A CN 2013104142064A CN 201310414206 A CN201310414206 A CN 201310414206A CN 103467055 A CN103467055 A CN 103467055A
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China
Prior art keywords
mosaic
joint filling
tackiness agent
gypsum
binding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2013104142064A
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Chinese (zh)
Inventor
方楚燕
董峰亮
邓德安
徐英
张泳东
梁至柔
阿那
陆小勇
胡程
陈学静
周碧平
严昌俊
万德刚
丁天华
薛静
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Davco Guangzhou Building Material Co Ltd
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Davco Guangzhou Building Material Co Ltd
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Priority to CN2013104142064A priority Critical patent/CN103467055A/en
Publication of CN103467055A publication Critical patent/CN103467055A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a mosaic binding agent integrating two purposes of binding and joint filling. The mosaic binding agent is prepared from gypsum, quartz powder, cellulose ether, re-dispersible emulsion powder, a retarder, a water reducing agent, bentonite and a mould inhibitor, as well as an inorganic pigment which is added as required by construction. The mosaic binding agent, which is neutral, can solve the problems of oxidization blackening and alkali efflorescence of the glass mosaics resulting from the strong alkalinity of a cement hydration product when the glass mosaics are bound by traditional cement or a traditional cement-based binding agent, achieve simultaneous construction of binding and joint filling without the phenomena of interface separating, hollowing and falling, and has the advantages of being high in whiteness and powerful in binding force, enhancing the decorate grade, simplifying matters with high efficiency, reducing the labor cost and shortening the construction period; in addition, colors can be mixed to achieve a rich-color-difference matching decoration effect, so that the mosaic binding agent has personalization; the mosaic binding agent is applicable to binding and joint filling of tiles and mosaics, and is especially applicable to simultaneous construction of binding and joint filling of glass mosaics.

Description

Paste the two-in-one mosaic tackiness agent of joint filling
Technical field
The present invention relates to a kind of tackiness agent, particularly the two-in-one mosaic tackiness agent of a kind of stickup joint filling, belong to the matrix material technical field in building trade.
Background technology
In ceramic tile market, past attempts is popular large-sized product once, but people find gradually, and the mosaic be combined into by the small size ceramic tile has another kind of aesthetic feeling, and decorative effect is splendid; Due to it, by a piece, sequenced on the leatheroid or grid cloth that sticks on a certain size, so very convenient laying, the part that is widely used in exterior wall or interior wall is decorated, simultaneously, development along with production technology, the mosaic product of various materials emerges in an endless stream, as ceramic mosaic, stone ceramic mosaic graphic, glass Mosaic (comprising hot melt glass and crystal glass), metal mosaic, timber mosaic, shell mosaic, corium mosaic, resin mosaic etc.
When with mosaic, carrying out decoration construction, normally first with white cement, mosaic is affixed to and needs metope or the ground decorated, then with white cement, the gap between the mosaic fritter is filled and led up to i.e. joint filling.This traditional constructional method is because the shrinkability of white cement is large, and poor water retention property often occurs because cohesive force is inadequate that obscission appears in mosaic; In addition because cement is overbased materials, when sticking glass mosaic, metal mosaic or goldleaf mosaic, due to the glass Mosaic of these goldleaf, minute surface, plating, cold spray one class without crossing high-temperature fusion, between the color layers of mosaic material and glass coating, by glue, connect mutually, once run into the easy oxidation blackening of acid and alkali substance, affect decorative effect.In addition, in actual applications, some construction master worker, in order to reduce material cost, also can add some fine sands, does not carry out selected sandstone, and grating is poor, not only affects cohesive force, has also affected decorative effect simultaneously.
At present, the wall floor tile production in the whole world and consumption are all in rising trend, and China is ceramic tile big country.The glass Mosaic that developed recently is swift and violent, use traditional product and construction technology, the needs that after first patch block, joint filling can not satisfying the market, first paste mosaic, joint filling construction again, need to prepare respectively to paste and stick with glue agent and joint filling sticks with glue agent, cause complex procedures, long in time limit, construction cost increases; The situations such as brick, the accumulation of salt in the surface soil also easily appear falling in crossed construction.
CN 103011731 A disclose a kind of tile paste and the dual-purpose tackiness agent of joint filling, and its component is cement, filler, redispersable latex powder, ether of cellulose, hardening accelerator, thixotroping lubricant, lignocellulose, hydrophober, anti-accumulation of salt in the surface soil agent, mould inhibitor, dispersion agent.Its disclosed dual-purpose tackiness agent is need to prepare respectively different tackiness agent for stickup and the joint filling of existing ceramic tile, due to stickup, to stick with glue the adhesive products formula that agent uses with joint filling different, batching can cause the repetition in man-hour respectively, the problem of waste material, provide a kind of can the stickup, the tackiness agent that joint filling is dual-purpose, but the components by weight formula from its record, cement accounts for 20-40%, filler accounts for 50-70%, can see, this dual-purpose tackiness agent is still and belongs to cement-based adhesive, as be applied to mosaic, glass Mosaic particularly, the problems such as the aforesaid mosaic caused due to the strong basicity of hydrolysis product of cement is oxidized still likely appear when the stickup of metal mosaic or goldleaf mosaic and joint filling.And the preferred quartz sand of filler, for coarse aggregate can't play decorative effect attractive in appearance as pointing the time.
There are not at present a kind of stickup, gas-filling adhesive to solve aforesaid owing to using traditional cement or cement-based adhesive to cause the problems such as mosaic is oxidized, have no for mosaic yet and paste the stickup of neutrality of special-purpose gypsum base and the report of the two-in-one tackiness agent of joint filling.
Summary of the invention
The object of the present invention is to provide a kind of two-in-one mosaic tackiness agent of gypsum base for mosaic stickup and joint filling, be particularly useful for stickup and the joint filling construction of carrying out glass Mosaic indoor, the two-in-one mosaic tackiness agent of this stickup joint filling can solve the oxidized blackening of glass Mosaic that traditional cement or cement-based adhesive cause due to the strong basicity of hydrolysis product of cement when the sticking glass mosaic, the problem of the accumulation of salt in the surface soil, can realize pasting, joint filling is constructed and not Presence of an interface separation simultaneously, hollowing, situation about coming off, there is whiteness high, bonding force is strong, can improve decoration grade, save trouble efficient, can greatly reduce cost of labor, the advantage of reduction of erection time, also can mix colours as required to obtain and there is the decorative effect that enriches the aberration collocation, there is personalization.
In order to address the above problem, the technical solution adopted in the present invention is as follows: the two-in-one mosaic tackiness agent of a kind of stickup joint filling, reaching the mineral dye that need to add by construction by gypsum, silica powder, ether of cellulose, redispersible latex powder, retardant, water reducer, wilkinite, mould inhibitor forms, it is a kind of neutral mosaic tackiness agent of gypsum base, each component concentration is the kg number containing this component in adhesive products per ton, as follows:
Gypsum 400-750
Silica powder 150-550
Ether of cellulose 1-5
Redispersible latex powder 5-30
Retardant 0.5-5
Water reducer 1-4
Mineral dye 0-30
Wilkinite 25-50
Mould inhibitor 0.5-2.
The component proportion of formula optimization of the present invention is as follows, and each component concentration is the kg number containing this component in adhesive products per ton:
Gypsum 500-700
Silica powder 200-450
Ether of cellulose 2-4.5
Redispersible latex powder 8-25
Retardant 1.5-4
Water reducer 1.2-3.8
Mineral dye 0-25
Wilkinite 32-44
Mould inhibitor 0.5-1.5.
Described gypsum is one or both in dehydrated gyp-, semi-hydrated gypsum, dihydrate gypsum; The whiteness of described gypsum is the 85-95 degree; While adopting dehydrated gyp-and semi-hydrated gypsum, the preferable amount ratio is dehydrated gyp-: semi-hydrated gypsum=2:1.
Described silica powder particle diameter is the 200-400 order, and whiteness is the 85-90 degree.
Described ether of cellulose is to be hydroxypropyl methyl cellulose ether or the hydroxyethyl ether cellulose that viscosity is 500-7000 mPas.
Described redispersible latex powder is ethylene-vinyl acetate copolymer or copolymer in cinnamic acrylic ester.
Described retardant is one or both in Trisodium Citrate, Sunmorl N 60S, boric acid.
Described water reducer is one or both in polycarboxylic acid salt's water reducer, polysulfonate class water reducer, thionamic acid class water reducer.
Described wilkinite is sodium bentonite or calcium-base bentonite.
Described mould inhibitor is benzimidazoles mould inhibitor or benzothiazoles mould inhibitor.
The two-in-one mosaic tackiness agent of stickup joint filling of the present invention adopts the following methods preparation: first according to proportion speed weighing gypsum, silica powder, ether of cellulose, redispersible latex powder, retardant, water reducer, mineral dye, wilkinite, mould inhibitor, hand operated mixing mixes in advance, put into again the cement mortar mixer of the planetary cement mortar mixer of JC/T681-2005 or other applicable models, stirring at low speed, stir 10-20 minute, until mix, can the tackiness agent powder.
The present invention is as follows with respect to the beneficial effect of prior art:
(1) the present invention be directed to the technical problem that glass Mosaic adopts cement or cement-based adhesive to exist, select the gypsum place of cement as main gelling material: the gypsum main component is calcium sulfate, it is a kind of air-setting inorganic coagulation material of neutrality, using the main raw of gypsum as the glass Mosaic tackiness agent, when application, tackiness agent pH value is 7, be neutral, therefore, adopt this neutral tackiness agent to paste mosaic, not there will be the alkaline matter after similar traditional hydrated cementitious to cause the problems such as mosaic oxidation blackening, the accumulation of salt in the surface soil;
(2) gypsum is a kind of white powder material, whiteness is generally more than 85 degree, than general white cement (whiteness is at the 75-85 degree) height, it is main volume that tackiness agent of the present invention be take the gypsum of whiteness 85-95, coordinate the high whiteness of the whiteness scope of employing high-quality at 85-90 simultaneously, the high silica powder of grating is as inert filler, in combined formulation, other components can make the final tackiness agent whiteness obtained high, for pasting mosaic, especially for use in glass Mosaic, metal mosaic etc. this type of will embody the mosaic material of its beautiful decorative effect the time, adopt mosaic tackiness agent of the present invention can obtain bright background color, reach the purpose that sets off the color of mosaic material own, obtain more excellent decorative effect, further improved the decoration grade of mosaic,
(3) tackiness agent of the present invention is applicable to mosaic stickup, joint filling are carried out simultaneously, there do not is incompatible between material and interfacial separation that produce, thereby mosaic hollowing, dropping situations occur, and save trouble and efficiently, greatly reduce cost of labor, reduction of erection time;
(4) the ether of cellulose effect in the present invention's formula is the water-retentivity that improves tackiness agent, thereby improves operable time and set time, to be more suitable for the applied environment on engineering or building site, improves sag resistance, thereby prevents that mosaic from gliding, and bonding force is strong;
(5) user also can be according to formula of the present invention, according to demand or the collocation of mosaic color, adds required mineral dye, and tackiness agent is deployed into to required color, improves decorative effect, has more personalization.
The two-in-one mosaic tackiness agent of stickup joint filling of the present invention is suitable for stickup and the joint filling of ceramic tile, mosaic, is particularly useful for glass Mosaic in indoor stickup and joint filling.Basic construction requirement during construction, construction process are as follows:
(1) all basal planes structurally must be firm, and drying is clean and without movement, oils, grease, paraffin and other fouling productss; The paint basal plane must expose the clean basal plane more than at least 75%;
(2) prepare and paste the two-in-one mosaic tackiness agent of joint filling powder according to formula of the present invention and preparation method, add the clear water that accounts for powder quality 30%-40%, be stirred well to even without the caking paste by electric blender by tackiness agent and water;
(3) the two-in-one tackiness agent of stickup joint filling after stirring is after standing 5-10 minute, then stirs a little 1-2 minute, can use;
(4) will paste the two-in-one tackiness agent slurry of joint filling with suitable notched scraper and scrape and be put on metope, and note adjusting planeness;
(5) with rubber flap, the two-in-one tackiness agent slurry of the stickup joint filling be stirred is evenly criticized and smeared in the mosaic back side, the extruding gap makes gap full;
(6) rub the pressure mosaic on working face, guarantee that mosaic and tackiness agent have better stickup and hollowing does not occur under mosaic;
(7) with rubber flap, the two-in-one tackiness agent slurry of the stickup joint filling be stirred is evenly criticized and smeared in the mosaic surface, must be pressed into slurry fully in gap, must not leave a blank;
(8) use with gap and become 45 °the action at oblique angle scrapes off unnecessary slurry, carefully avoids the slurry in gap is taken out of;
(9) after joint filling work completes, at once with wet cloth or the sponge of wringing out, that the mosaic removing surface is clean.
Embodiment
Below by embodiment, the present invention is described in further details, these embodiment only are used for illustrating the present invention, do not limit the scope of the invention.
embodiment 1prepare the two-in-one mosaic tackiness agent of stickup joint filling of the present invention by following formula:
(1) press the following material of proportion speed weighing: the dehydrated gyp-500kg of whiteness 95, whiteness 90 particle diameters are 200 purpose quartz
Powder 450kg, the hydroxypropyl methyl cellulose ether 2kg that viscosity is 1200mPas, ethylene-vinyl acetate copolymer 12kg, Trisodium Citrate retardant 1.5kg, polycarboxylate high performance dehydragent 2kg, sodium bentonite 32kg, benzothiazoles mould inhibitor 0.5kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into the planetary cement mortar mixer of JC/T681-2005
Stirring at low speed, stir 15 minutes, until mix.
Tackiness agent powder to above-mentioned preparation carries out the performance index detection, as shown in the table:
Sequence number Interventions Requested Measure unit Assay
1 Outward appearance / Homogeneous, dry powder, without caking
2 PH value / 7.3
3 Operable time h 1.5
4 Presetting period min 90
5 Final setting time min 240
6 The stretching adhesive strength MPa 0.62
7 Open assembly time, 10min stretching adhesive strength MPa 0.58
8 Ultimate compression strength MPa 16.5
During construction, the tackiness agent powder of above-mentioned preparation is mixed with the clear water that accounts for powder quality 30%,, after standing 10 minutes then stir a little 2 minutes without the caking paste to even by electric blender, for construction.
embodiment 2adopt the two-in-one mosaic tackiness agent of following formula preparation stickup joint filling of the present invention:
(1) press the following material of proportion speed weighing: the dihydrate gypsum 700kg of whiteness 88, whiteness 85 particle diameters are 250 purpose silica powder 200kg, the hydroxyethyl ether cellulose 4.5kg that viscosity is 2500mPas, cinnamic acrylic ester type redispersible latex powder 25kg, Sunmorl N 60S retardant 4kg, polycarboxylate dehydragent 3.8kg, mineral dye 25kg, sodium bentonite 36.9kg, benzoglyoxaline mould inhibitor 0.8kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into cement mortar mixer, stirring at low speed, stir 10 minutes, until mix.
During construction, the tackiness agent powder of above-mentioned preparation is mixed with the clear water that accounts for powder quality 40%,, after standing 5 minutes then stir a little 1 minute without the caking paste to even by electric blender, for construction.
embodiment 3adopt the two-in-one mosaic tackiness agent of following formula preparation stickup joint filling of the present invention:
(1) press the following material of proportion speed weighing: the semi-hydrated gypsum 200kg of whiteness 90, the dehydrated gyp-400kg of whiteness 90, whiteness 85, particle diameter is 350 purpose silica powder 330kg, the hydroxypropyl methyl cellulose ether 3kg that viscosity is 5000mPas, ethylene-vinyl acetate copolymer 8kg, boric acid retardant 1.5kg, polysulfonate water reducer 1.2kg, mineral dye: red iron oxide 10.8kg, calcium-base bentonite 44kg, benzimidazoles mould inhibitor 1.5kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into the planetary cement mortar mixer of JC/T681-2005, stirring at low speed, stir 12 minutes, until mix.
embodiment 4adopt the two-in-one mosaic tackiness agent of following formula preparation stickup joint filling of the present invention:
(1) press the following material of proportion speed weighing: the dehydrated gyp-400kg of whiteness 95, whiteness 85 particle diameters are 180 purpose silica powder 550kg, the hydroxyethyl ether cellulose 5kg that viscosity is 500mPas, cinnamic acrylic ester type redispersible latex powder 5kg, citric acid retardant 0.5kg, sulfamate water reducer 4kg, mineral dye 9.5kg, calcium-base bentonite 25kg, benzothiazoles mould inhibitor 1kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into the cement mortar mixer stirring at low speed 20 minutes, until mix.
embodiment 5adopt the two-in-one mosaic tackiness agent of following formula preparation stickup joint filling of the present invention:
(1) press the following material of proportion speed weighing: the dihydrate gypsum 750kg of whiteness 85, whiteness 90 particle diameters are 400 purpose silica powder 150kg, the hydroxypropyl methyl cellulose ether 1kg that viscosity is 7000mPas, ethylene-vinyl acetate copolymer 30kg, citric acid retardant 2.5kg, Sunmorl N 60S retardant 2.5kg, ammonia carboxylic acid high-performance water reducing agent 1kg, mineral dye 11kg, sodium bentonite 50kg, benzothiazoles mould inhibitor 2kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into the cement mortar mixer stirring at low speed 18 minutes, until mix.

Claims (10)

1. paste the two-in-one mosaic tackiness agent of joint filling for one kind, it is characterized in that: the neutral gum stick that is a kind of gypsum base, reaching the mineral dye that need to add by construction by gypsum, silica powder, ether of cellulose, redispersible latex powder, retardant, water reducer, wilkinite, mould inhibitor forms, each component concentration is the kg number containing this component in adhesive products per ton, as follows:
Gypsum 400-750
Silica powder 150-550
Ether of cellulose 1-5
Redispersible latex powder 5-30
Retardant 0.5-5
Water reducer 1-4
Mineral dye 0-30
Wilkinite 25-50
Mould inhibitor 0.5-2.
2. the two-in-one mosaic tackiness agent of stickup joint filling according to claim 1, it is characterized in that: the neutral gum stick that is a kind of gypsum base, reaching the mineral dye that need to add by construction by gypsum, silica powder, ether of cellulose, redispersible latex powder, retardant, water reducer, wilkinite, mould inhibitor forms, each component concentration is the kg number containing this component in adhesive products per ton, as follows:
Gypsum 500-700
Silica powder 200-450
Ether of cellulose 2-4.5
Redispersible latex powder 8-25
Retardant 1.5-4
Water reducer 1.2-3.8
Mineral dye 0-25
Wilkinite 32-44
Mould inhibitor 0.5-1.5.
3. the two-in-one mosaic tackiness agent of stickup joint filling according to claim 1 and 2, it is characterized in that: described gypsum is one or both in dehydrated gyp-, semi-hydrated gypsum, dihydrate gypsum; The whiteness of described gypsum is the 85-95 degree.
4. the two-in-one mosaic tackiness agent of stickup joint filling according to claim 1 and 2, it is characterized in that: described silica powder particle diameter is the 200-400 order, whiteness is the 85-90 degree.
5. the two-in-one mosaic tackiness agent of stickup joint filling according to claim 1 and 2, it is characterized in that: described ether of cellulose is hydroxypropyl methyl cellulose ether or the hydroxyethyl ether cellulose that viscosity is 500-7000 mPas.
6. the two-in-one mosaic tackiness agent of stickup joint filling according to claim 1 and 2, it is characterized in that: described redispersible latex powder is ethylene-vinyl acetate copolymer or copolymer in cinnamic acrylic ester.
7. the two-in-one mosaic tackiness agent of stickup joint filling according to claim 1 and 2, it is characterized in that: described retardant is one or both in Trisodium Citrate, Sunmorl N 60S, boric acid.
8. the two-in-one mosaic tackiness agent of stickup joint filling according to claim 1 and 2 is characterized in that: described water reducer is one or both in polycarboxylic acid salt's water reducer, polysulfonate class water reducer, thionamic acid class water reducer.
9. the two-in-one mosaic tackiness agent of stickup joint filling according to claim 1 and 2, it is characterized in that: described wilkinite is sodium bentonite or calcium-base bentonite.
10. the two-in-one mosaic tackiness agent of stickup joint filling according to claim 1 and 2, it is characterized in that: described mould inhibitor is benzimidazoles mould inhibitor or benzothiazoles mould inhibitor.
CN2013104142064A 2013-09-12 2013-09-12 Mosaic binding agent integrating two purposes of binding and joint filling Pending CN103467055A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105367031A (en) * 2015-11-18 2016-03-02 广德县常丰竹木业制品有限公司 Waterproof bamboo wood sheet material caulking compound and preparation method thereof
CN105384396A (en) * 2015-11-04 2016-03-09 广州协堡建材有限公司 Mosaic tile sticking and jointing integrated binder mosaic tile glue and preparing method thereof
CN108359395A (en) * 2018-02-27 2018-08-03 合肥尚涵装饰工程有限公司 A kind of one pack system waterproof cracking resistance wall and floor tile gap filler and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1173524A (en) * 1996-10-24 1998-02-18 宋锡贵 Building waterproof adhesive
CN1287146A (en) * 1999-09-03 2001-03-14 徐永生 Adhesive for building decoration
CN102180646A (en) * 2011-01-31 2011-09-14 北京东方雨虹防水技术股份有限公司 Non-base-return color ceramic tile joint mixture
CN102503302A (en) * 2011-10-27 2012-06-20 北京东方雨虹防水技术股份有限公司 High-strength ceramic tile tackiness agent
CN102838337A (en) * 2012-09-04 2012-12-26 同济大学 Desulfurized gypsum based functional mortar for coating and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1173524A (en) * 1996-10-24 1998-02-18 宋锡贵 Building waterproof adhesive
CN1287146A (en) * 1999-09-03 2001-03-14 徐永生 Adhesive for building decoration
CN102180646A (en) * 2011-01-31 2011-09-14 北京东方雨虹防水技术股份有限公司 Non-base-return color ceramic tile joint mixture
CN102503302A (en) * 2011-10-27 2012-06-20 北京东方雨虹防水技术股份有限公司 High-strength ceramic tile tackiness agent
CN102838337A (en) * 2012-09-04 2012-12-26 同济大学 Desulfurized gypsum based functional mortar for coating and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105384396A (en) * 2015-11-04 2016-03-09 广州协堡建材有限公司 Mosaic tile sticking and jointing integrated binder mosaic tile glue and preparing method thereof
CN105367031A (en) * 2015-11-18 2016-03-02 广德县常丰竹木业制品有限公司 Waterproof bamboo wood sheet material caulking compound and preparation method thereof
CN108359395A (en) * 2018-02-27 2018-08-03 合肥尚涵装饰工程有限公司 A kind of one pack system waterproof cracking resistance wall and floor tile gap filler and preparation method thereof

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Application publication date: 20131225