CN112159735A - 一种无残留水基清洗剂及其制备方法 - Google Patents

一种无残留水基清洗剂及其制备方法 Download PDF

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CN112159735A
CN112159735A CN202011052440.3A CN202011052440A CN112159735A CN 112159735 A CN112159735 A CN 112159735A CN 202011052440 A CN202011052440 A CN 202011052440A CN 112159735 A CN112159735 A CN 112159735A
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parts
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residue
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cleaning agent
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窦树君
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Kunshan Nuoquail Material Technology Co ltd
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Abstract

本发明公开了一种无残留水基清洗剂，按质量分数计，包括如下组分：表面活性剂20‑32份、防锈剂3‑9份、防腐剂0.1‑0.2份、渗透剂2‑5份、助剂10‑13.5份和水40‑50份。本发明提供的无残留水基清洗剂不含氢氧化钠(钾)、碳酸钠、碳酸氢钠、磷酸钠等无机碱或盐，容易漂洗并且漂洗后无残留，大大降低了对后续工序的影响。

Description

一种无残留水基清洗剂及其制备方法
技术领域
本发明涉及清洗剂领域，更具体地说是涉及一种无残留水基清洗剂及其制备方法。
背景技术
水基清洗剂广泛用于工业清洗中，对塑胶、光学玻璃镜片、金属制品(铜、铁、铝、钢、锌、合金)等材料表面的拉伸油、切削油、防锈油、润滑油、冲压油等各种油污、污渍、油脂等有很好的清洗效果。并且，水基清洗剂不燃不爆，无毒无害，使用安全，不污染环境。
现有的水基清洗剂主要是一些碱性较强的无机碱或无机盐，如氢氧化钠、碳酸钠、硅酸盐、磷酸盐等。但这类清洗剂由于含有无机碱或无机盐，后续漂洗不容易从金属或者其他硬表面工件表面去除，导致部分无机碱或者无机盐残留于工件表面，从而不利于镀膜、氧化及涂装等后续工序的进行。
因此，如何提供一种无残留水基清洗剂是本领域技术人员亟需解决的技术问题。
发明内容
有鉴于此，本发明针对现有技术中存在的问题提供了一种无残留水基清洗剂，由于其不残留于金属等硬表面，对于工件后处理没有影响，减少了清洗工序，降低了成本。
为了实现上述目的，本发明采用如下技术方案：
一种无残留水基清洗剂，按质量分数计，包括如下组分：表面活性剂20-32份、防锈剂3-9份、防腐剂0.1-0.2份、渗透剂2-5份、助剂10-13.5份和水40-50份。
优选的，包括如下组分：表面活性剂32份、防锈剂6份、防腐剂0.1份、渗透剂5份、助剂13.5份和水43.4份。
优选的，所述表面活性剂由脂肪醇聚氧乙烯醚、异构脂肪醇聚氧乙烯醚、烷基酚聚氧乙烯醚、脂肪酸胺皂和聚氧乙烯脱水山梨醇单油酸酯组成。
例如异构十三醇10EO、异构十三醇5EO、吐温80配合既能增强混合物亲水能力、同时又有很强的亲油能力，从而具有很好的清洗效果。
优选的，所述防锈剂由硼酸、山梨酸、葵二酸、十二碳二元酸、三元羧酸、二聚酸、新葵酸、正辛酸、苯并三氮唑或硅酸钠中的一种或几种组成。
优选的，所述防腐剂由1,2-苯并异噻唑-3-酮、1，3，5-三(2-羟乙基)-六氢三嗪或3-碘-2-丙炔基丁基氨基甲酸酯中的一种或几种组成。
优选的，所述渗透剂由乙醇、乙二醇、二乙二醇、丙三醇或二乙二醇单丁醚中的一种或几种组成。
优选的，所述助剂包括：清洗剂13份、消泡剂0.5份。
优选的，所述清洗助剂由一乙醇胺、二乙醇胺，三乙醇胺、1-异丙醇胺、二环己胺、磷酸酯、醇醚羧酸或烷基糖苷中的一种或几种组成。如三乙醇胺、磷酸酯可增强清洗及防锈性。
优选的，所述消泡剂为二甲基硅油乳液或聚醚消泡剂。如二甲基硅油乳液具有很好的消泡效果。
本发明还公开了上述一种无残留水基清洗剂的制备方法，包括以下步骤：先将清洗助剂溶解于一部分水中，搅拌均匀，然后边搅拌边加入防锈剂，搅拌至混合液透明后加入表面活性剂和渗透剂，冷却后加入防腐剂和消泡剂，最后再加入剩余的水搅拌均匀即可。
与现有技术相比，本发明提供的无残留水基清洗剂不含氢氧化钠(钾)、碳酸钠、碳酸氢钠、磷酸钠等无机碱或盐，容易漂洗并且漂洗后无残留，大大降低了对后续工序的影响。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1
将6质量份三乙醇胺、3质量份一乙醇胺溶解于30质量份的纯水中，搅拌均匀，边搅拌边依次加入4质量份三元酸、2质量份新葵酸、1质量份AEC-9H，搅拌均匀直至混合液透明后加入7质量份MOA-9、7质量份E1306(异构十三醇聚氧乙烯醚)、14质量份OP-10(聚氧乙烯辛基苯酚醚-10)、4质量份6501(椰子油脂肪酸二乙醇酰胺)、5质量份乙醇，冷却后加入0.1质量份1，2-苯并异噻唑-3-酮，0.5质量份聚醚消泡剂T-350，补加16.4质量份纯水搅拌均匀即可。
实施例2
将6质量份二乙醇胺、3质量份异丙醇胺溶解于20质量份的纯水中，搅拌均匀，边搅拌边依次加入1质量份葵二酸、2质量份正辛酸、1质量份AEC-9H、3质量份磷酸酯直至混合液透明，搅拌均匀后加入7质量份MOA-9、7质量份E1306、14质量份OP-10、4质量份6501、5质量份乙二醇，冷却后加入0.1质量份1，2-苯并异噻唑-3-酮，0.5质量份二甲基硅油消泡剂，补加26.4质量份纯水搅拌均匀即可。
实施例3
将6质量份三乙醇胺、3质量份异丙醇胺溶解于20质量份的纯水中，搅拌均匀，边搅拌边依次加入1质量份葵二酸、4质量份硼酸、2质量份三元酸、2质量份正辛酸、1质量份AEC-9H，搅拌均匀直至混合液透明后加入7质量份烷基糖苷、7质量份E1306、14质量份OP-10、4质量份T-80、5质量份二乙二醇，冷却后加入0.5质量份1，3，5-三(2-羟乙基)-六氢三嗪，0.2质量份二甲基硅油消泡剂，补加23.3质量份纯水搅拌均匀即可。
实施例4
将6质量份三乙醇胺、3质量份一乙醇胺溶解于30质量份的纯水中，搅拌均匀，边搅拌边依次加入4质量份三元酸、2质量份新葵酸、1质量份AEC-9H、3质量份磷酸酯直至混合液透明，搅拌均匀后加入7质量份E1306、14质量份OP-10、4质量份T-80、5质量份乙二醇，冷却后加入0.1质量份1，2-苯并异噻唑-3-酮，0.5质量份聚醚消泡剂，补加20.4质量份纯水搅拌均匀即可。
本发明实施例中所用E1306、MOA-9、OP-10、T-80、6501均采购于江苏海安石油化工厂，AEC-9H、烷基糖苷采购于上海发凯化工有限公司，T-350采购于江苏腾达助剂有限公司。
2005年12月，上海某柴油机厂由于技术升级，产品清洁度检测标准提高，如6135柴油机缸体装配前清洁度检测标准由2350毫克提升到1800毫克，质检部门检测总是不达标。使用本发明实施例1制备的无残留水基清洗剂一个月，清洁度检测残留物平均为1320毫克，大大低于该客户清洁度要求，取得较好的效益。
本说明书中各个实施例采用递进的方式描述，每个实施例重点说明的都是与其他实施例的不同之处，各个实施例之间相同相似部分互相参见即可。对于实施例公开的装置而言，由于其与实施例公开的方法相对应，所以描述的比较简单，相关之处参见方法部分说明即可。
对所公开的实施例的上述说明，使本领域专业技术人员能够实现或使用本发明。对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的，本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下，在其它实施例中实现。因此，本发明将不会被限制于本文所示的这些实施例，而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。

Claims (10)

1.一种无残留水基清洗剂，其特征在于，按质量分数计，包括如下组分：表面活性剂20-32份、防锈剂3-9份、防腐剂0.1-0.2份、渗透剂2-5份、助剂10-13.5份和水40-50份。
2.根据权利要求1所述的一种无残留水基清洗剂，其特征在于，包括如下组分：表面活性剂32份、防锈剂6份、防腐剂0.1份、渗透剂5份、助剂13.5份和水43.4份。
3.根据权利要求1所述的一种无残留水基清洗剂，其特征在于，所述表面活性剂由脂肪醇聚氧乙烯醚、异构脂肪醇聚氧乙烯醚、烷基酚聚氧乙烯醚、脂肪酸胺皂和聚氧乙烯脱水山梨醇单油酸酯组成。这个是表面活性剂的一种。
4.根据权利要求1所述的一种无残留水基清洗剂，其特征在于，所述防锈剂由硼酸、山梨酸、葵二酸、十二碳二元酸、三元羧酸、二聚酸、新葵酸、正辛酸、苯并三氮唑或硅酸钠中的一种或几种组成。
5.根据权利要求1所述的一种无残留水基清洗剂，其特征在于，所述防腐剂由1,2-苯并异噻唑-3-酮、1，3，5-三(2-羟乙基)-六氢三嗪或3-碘-2-丙炔基丁基氨基甲酸酯中的一种或几种组成。
6.根据权利要求1所述的一种无残留水基清洗剂，其特征在于，所述渗透剂由乙醇、乙二醇、二乙二醇、丙三醇或二乙二醇单丁醚中的一种或几种组成。
7.根据权利要求1所述的一种无残留水基清洗剂，其特征在于，所述助剂包括：清洗剂13份、消泡剂0.5份。
8.根据权利要求7所述的一种无残留水基清洗剂，其特征在于，所述清洗剂由一乙醇胺、二乙醇胺，三乙醇胺、1-异丙醇胺、二环己胺、醇醚羧酸或烷基糖苷中的一种或几种组成。
9.根据权利要求8所述的一种无残留水基清洗剂，其特征在于，所述消泡剂为二甲基硅油乳液或聚醚消泡剂。
10.根据权利要求9所述的一种无残留水基清洗剂的制备方法，其特征在于，包括以下步骤：先将清洗助剂溶解于一部分水中，搅拌均匀，然后边搅拌边加入防锈剂，搅拌至混合液透明后加入表面活性剂和渗透剂，冷却后加入防腐剂和消泡剂，最后再加入剩余的水搅拌均匀即可。
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