CN112107493A - Moisturizing mask containing nano magnetic array particles and preparation method thereof - Google Patents
Moisturizing mask containing nano magnetic array particles and preparation method thereof Download PDFInfo
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- CN112107493A CN112107493A CN202011067482.4A CN202011067482A CN112107493A CN 112107493 A CN112107493 A CN 112107493A CN 202011067482 A CN202011067482 A CN 202011067482A CN 112107493 A CN112107493 A CN 112107493A
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- 239000002245 particle Substances 0.000 title claims abstract description 61
- 230000003020 moisturizing effect Effects 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 44
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 44
- 230000001815 facial effect Effects 0.000 claims abstract description 32
- 239000002002 slurry Substances 0.000 claims abstract description 31
- 239000004917 carbon fiber Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 239000003738 black carbon Substances 0.000 claims description 22
- 239000004745 nonwoven fabric Substances 0.000 claims description 22
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000000725 suspension Substances 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000011259 mixed solution Substances 0.000 claims description 12
- 229910001172 neodymium magnet Inorganic materials 0.000 claims description 12
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 8
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 8
- 239000012279 sodium borohydride Substances 0.000 claims description 8
- 229920002385 Sodium hyaluronate Polymers 0.000 claims description 7
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- 229940010747 sodium hyaluronate Drugs 0.000 claims description 7
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 6
- 241001076416 Dendrobium tosaense Species 0.000 claims description 6
- 229930195725 Mannitol Natural products 0.000 claims description 6
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- 238000007605 air drying Methods 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 6
- 230000001939 inductive effect Effects 0.000 claims description 6
- 239000000594 mannitol Substances 0.000 claims description 6
- 235000010355 mannitol Nutrition 0.000 claims description 6
- 229960000502 poloxamer Drugs 0.000 claims description 6
- 229920001983 poloxamer Polymers 0.000 claims description 6
- 229950008882 polysorbate Drugs 0.000 claims description 6
- 229920000136 polysorbate Polymers 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 239000000230 xanthan gum Substances 0.000 claims description 6
- 229920001285 xanthan gum Polymers 0.000 claims description 6
- 229940082509 xanthan gum Drugs 0.000 claims description 6
- 235000010493 xanthan gum Nutrition 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 235000015097 nutrients Nutrition 0.000 abstract description 8
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 7
- 230000008929 regeneration Effects 0.000 abstract description 4
- 238000011069 regeneration method Methods 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 206010033675 panniculitis Diseases 0.000 abstract description 3
- 230000001737 promoting effect Effects 0.000 abstract description 3
- 210000004304 subcutaneous tissue Anatomy 0.000 abstract description 3
- 230000005426 magnetic field effect Effects 0.000 abstract description 2
- 230000035515 penetration Effects 0.000 abstract 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 5
- 239000002122 magnetic nanoparticle Substances 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000006249 magnetic particle Substances 0.000 description 1
- 238000002653 magnetic therapy Methods 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N2/00—Magnetotherapy
- A61N2/002—Magnetotherapy in combination with another treatment
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N2/00—Magnetotherapy
- A61N2/06—Magnetotherapy using magnetic fields produced by permanent magnets
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Health & Medical Sciences (AREA)
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- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
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- Birds (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Radiology & Medical Imaging (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to a moisturizing mask containing nano magnetic array particles and a preparation method thereof. In the preparation process, Fe with a one-dimensional chain structure is prepared in advance under the action of an external magnetic field3O4Nano-array particles ofThen the carbon fiber facial mask slurry is uniformly distributed on the carbon fiber facial mask base material in an oriented array mode under the action of an external magnetic field, and finally the facial mask slurry is injected into the facial mask base material. The obtained facial mask product can fully utilize the uniform magnetic field effect generated by the nano magnetic array particles, promote the repair and regeneration of subcutaneous tissues at the inner side of the skin and does not need to use additional external magnetic field equipment. Meanwhile, the uniform magnetic field generated by the nano magnetic array particles is beneficial to promoting the penetration of the nutrient components in the mask slurry to the skin, so as to achieve the effect of increasing the uniform absorption of the nutrient components by the skin.
Description
Technical Field
The invention relates to the field of facial masks, in particular to a moisturizing facial mask containing nano magnetic array particles and a preparation method thereof.
Background
With the development of society, the pace of life of people is faster and faster, and the negative reactions of people to fast paced life and heavy working pressure are reflected on the health of people along with the accumulation of time, wherein the most intuitive and obvious is the skin surface, which is mainly reflected in that the skin surface becomes dry due to the loss of moisture, the skin becomes aged, wrinkles, color spots and the like appear.
In order to alleviate the negative effects of life and work pressure on the body, facial masks have become a common method of skin care for most women. The mask products on the market are various, however, most of the existing masks utilize direct absorption of the skin to nutrient solution in the mask, but the absorption effect is generally low, so that the maintenance effect of the mask is not ideal.
Research results indicate that the regeneration and repair of skin tissues can be promoted by providing an external magnetic field through an external magnetic therapy apparatus. Related products such as corresponding magnetic therapeutic apparatuses also appear in the market, but the products are relatively high in price and are not beneficial to popularization.
Research results also indicate that the magnetic nanoparticles in the facial mask can be utilized to promote the absorption of the skin on the nutrient components in the facial mask slurry by directly adding the magnetic nanoparticles into the facial mask. However, the effect is not ideal because the magnetic field generated by directly adding the magnetic nanoparticles is unstable due to disorder of the magnetic pole direction.
Therefore, the invention aims to provide the moisturizing mask which can effectively promote the skin to absorb various nutrient components and moisture in the mask.
Disclosure of Invention
In order to solve the problem of insufficient absorbability in the existing mask products, the invention provides a moisturizing mask containing nano magnetic array particles and a preparation method thereof, wherein the moisturizing mask can effectively promote the skin to absorb various nutrient components and water in the mask.
The invention comprises the following three steps:
preparation of nano magnetic array particle
Reacting sodium borohydride (NaBH)4) The aqueous solution and the aqueous solution of ferric chloride are mixed according to the volume ratio of 1:1, sodium hydroxide is used for adjusting the pH value of the mixed solution to 12-14, then the mixed solution is placed in a reaction kettle, an external magnetic field is applied along the vertical direction of the reaction kettle, and then hydrothermal reaction is carried out for 15-25h at the temperature of 160-180 ℃, so as to obtain Fe with a one-dimensional chain structure3O4The nano-array particles are naturally cooled to room temperature after the reaction is finished, and then the one-dimensional chain-shaped structure Fe is treated by using an NdFeB permanent magnet3O4And separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use.
Secondly, inducing Fe with one-dimensional chain structure by magnetic field3O4The nano array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Paving the carbon fiber mask base material at the bottom of the container, and applying an external magnetic field outside the bottom of the container; fe with one-dimensional chain structure obtained in the step one3O4Ultrasonically dispersing nano array particles in an ethanol solution to obtain a suspension with the concentration of 50-100g/L, then injecting the suspension into the container to enable the suspension to submerge the tiled carbon fiber mask base material, standing and air-drying to obtain Fe loaded with a one-dimensional chain structure in directional array arrangement3O4A carbon fiber mask substrate of nano-array particles.
Thirdly, applying facial mask slurry
Flatly paving the carbon fiber facial mask base material obtained in the step two in a grouting mold, then injecting facial mask slurry into the grouting mold, enabling the facial mask slurry to penetrate into the whole carbon fiber facial mask base material, and then taking out the facial mask.
Further, in the first step, the sodium borohydride (NaBH)4) The concentration of the aqueous solution of (A) is 20-50g/L, and the concentration of the aqueous solution of ferric chloride is 15-40 g/L.
Further, in the first step, the magnitude of the external magnetic field is 0.2-0.4T, and the external magnetic field is applied by arranging an NdFeB permanent magnet at each of the upper and lower portions of the reaction vessel.
Further, in the second step, the magnitude of the external magnetic field is 0.2-0.4T.
Further, in the second step, the carbon fiber mask base material is a black carbon fiber spunlace non-woven fabric.
Further, in the third step, the composition of the mask slurry comprises the following components in parts by mass in 100 parts by weight:
10-15 parts of glycerin, 0.5-2 parts of sodium hyaluronate, 1-10 parts of poloxamer, 0.05-0.2 part of acetyl tetrapeptide, 0.05-0.2 part of palmitoyl tripeptide, 0.2-1 part of dendrobium officinale extract, 0.02-0.08 part of triethanolamine, 0.3-0.8 part of mannitol, 0.5-1 part of xanthan gum, 0.2-1 part of polysorbate, 0.5-4 parts of propylene glycol, 15.5-23.5 parts of silicone oil-based oily phase and the balance of water.
In the invention, the nano magnetic array particles arranged in a directional array are directly added into the facial mask, so that the uniform magnetic field effect generated by the nano magnetic array particles can be fully utilized, the repair and regeneration of subcutaneous tissues at the inner side of the skin are promoted, and no additional external magnetic field equipment is needed. Meanwhile, the uniform magnetic field generated by the nano magnetic array particles is beneficial to promoting the matching of components such as silicone oil, glycerin, sodium hyaluronate, acetyl tetrapeptide, palmitoyl tripeptide and the like in the mask slurry, so that the activity of the components is enhanced, the permeation of the substances to the skin is further promoted, the absorption of the skin to the nutritional ingredients, particularly the absorption of the glycerin is increased, and the effect of better skin care is achieved.
In the present invention, the added magnetic particles are Fe having a one-dimensional chain structure3O4Nano-array particles prepared by preparing Fe3O4Applying an external magnetic field oriented during the process of the nanoparticles so that the magnetic Fe3O4The nano particles are easy to be connected into a chain along the direction of the easy magnetization axis thereof for growing, and the obtained Fe with a one-dimensional chain structure3O4Compared with common Fe3O4 nanoparticles, the nano-array particles can provide more effective micro magnetic field, are more favorable for promoting the repair and regeneration of subcutaneous tissues and are more favorable for promotingAbsorption of nutrients from the mask slurry by the skin.
In the present invention, Fe having a one-dimensional chain structure is applied to the surface of the carbon fiber mask base material3O4In the process of nano-array particles, a magnetic field with the same degree is applied to the carbon fiber mask base material, so that Fe with a one-dimensional chain structure can be ensured3O4The nano array particles are uniformly and directionally distributed on the carbon fiber mask base material in an array manner, so that a uniform and directional micro magnetic field can be applied to the skin surface of a mask product, and the uniform absorption of the skin on the nutrient components in the mask slurry is facilitated.
Detailed Description
The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
Example 1
A moisturizing mask containing nano magnetic array particles comprises the following three steps:
preparation of nano magnetic array particle
Sodium borohydride (NaBH) at a concentration of 30g/L4) The aqueous solution and the aqueous solution of ferric chloride with the concentration of 30g/L are mixed according to the volume ratio of 1:1, the pH value of the mixed solution is adjusted to 14 by sodium hydroxide, then the mixed solution is placed in a reaction kettle, an NdFeB permanent magnet is respectively arranged at the upper part and the lower part of the reaction kettle, an external magnetic field with the magnetic field intensity of 0.28T is applied along the vertical direction of the reaction kettle, and then the hydrothermal reaction is carried out for 18 hours at the temperature of 180 ℃, so that the Fe with the one-dimensional chain structure is obtained3O4The nano-array particles are naturally cooled to room temperature after the reaction is finished, and then the one-dimensional chain-shaped structure Fe is treated by using an NdFeB permanent magnet3O4And separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use.
Secondly, inducing Fe with one-dimensional chain structure by magnetic field3O4The nano array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Spreading black carbon fiber spunlace nonwoven fabric on the bottom of the container, and applying an external magnet with a magnetic field intensity of 0.28T to the outer side of the bottom of the containerA field; fe with one-dimensional chain structure obtained in the step one3O4Ultrasonically dispersing nano array particles in an ethanol solution to obtain a suspension with the concentration of 80g/L, then injecting the suspension into the container to enable the suspension to be over the flat black carbon fiber spunlace non-woven fabric, standing and air-drying to obtain Fe loaded with a one-dimensional chain structure in directional array arrangement3O4The black carbon fiber spunlace non-woven fabric of the nano-array particles.
Thirdly, applying facial mask slurry
Flatly paving the black carbon fiber spunlace non-woven fabric obtained in the step two in a grouting mold, then injecting the mask slurry into the grouting mold, enabling the mask slurry to penetrate into the whole black carbon fiber spunlace non-woven fabric, and then taking out the mask.
The facial mask slurry comprises the following components in parts by mass in 100 parts by weight:
12 parts of glycerin, 0.5 part of sodium hyaluronate, 5 parts of poloxamer, 0.05 part of acetyl tetrapeptide, 0.2 part of palmitoyl tripeptide, 0.5 part of dendrobium officinale extract, 0.04 part of triethanolamine, 0.8 part of mannitol, 0.5 part of xanthan gum, 0.5 part of polysorbate, 2 parts of propylene glycol, 18.8 parts of silicone oil-based oily phase and the balance of water.
Example 2
A moisturizing mask containing nano magnetic array particles comprises the following three steps:
preparation of nano magnetic array particle
Sodium borohydride (NaBH) with concentration of 40g/L4) The aqueous solution and the aqueous solution of ferric chloride with the concentration of 35g/L are mixed according to the volume ratio of 1:1, the pH value of the mixed solution is adjusted to 13 by sodium hydroxide, then the mixed solution is placed in a reaction kettle, an NdFeB permanent magnet is respectively arranged at the upper part and the lower part of the reaction kettle, an external magnetic field with the magnetic field intensity of 0.35T is applied along the vertical direction of the reaction kettle, and then the hydrothermal reaction is carried out for 22 hours at the temperature of 180 ℃, so that the Fe with the one-dimensional chain structure is obtained3O4The nano array particles are naturally cooled to room temperature after the reaction is finished, and then a one-dimensional chain is formed by utilizing an NdFeB permanent magnetStructural Fe3O4And separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use.
Secondly, inducing Fe with one-dimensional chain structure by magnetic field3O4The nano array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Flatly paving the black carbon fiber spunlace non-woven fabric at the bottom of the container, and applying an external magnetic field with the magnetic field intensity of 0.35T to the outer side of the bottom of the container; fe with one-dimensional chain structure obtained in the step one3O4Ultrasonically dispersing nano array particles in an ethanol solution to obtain a suspension with the concentration of 80g/L, then injecting the suspension into the container to enable the suspension to be over the flat black carbon fiber spunlace non-woven fabric, standing and air-drying to obtain Fe loaded with a one-dimensional chain structure in directional array arrangement3O4The black carbon fiber spunlace non-woven fabric of the nano-array particles.
Thirdly, applying facial mask slurry
Flatly paving the black carbon fiber spunlace non-woven fabric obtained in the step two in a grouting mold, then injecting the mask slurry into the grouting mold, enabling the mask slurry to penetrate into the whole black carbon fiber spunlace non-woven fabric, and then taking out the mask.
The facial mask slurry comprises the following components in parts by mass in 100 parts by weight:
15 parts of glycerin, 0.5 part of sodium hyaluronate, 3 parts of poloxamer, 0.05 part of acetyl tetrapeptide, 0.05 part of palmitoyl tripeptide, 0.4 part of dendrobium officinale extract, 0.02 part of triethanolamine, 0.3 part of mannitol, 1 part of xanthan gum, 0.8 part of polysorbate, 2 parts of propylene glycol, 21.5 parts of silicone oil-based oily phase and the balance of water.
Example 3
A moisturizing mask containing nano magnetic array particles comprises the following three steps:
preparation of nano magnetic array particle
Sodium borohydride (NaBH) with a concentration of 50g/L4) And an aqueous solution of ferric chloride having a concentration of 40g/L in a volume of 1:1Mixing, adjusting the pH value of the mixed solution to 14 by using sodium hydroxide, then placing the mixed solution into a reaction kettle, respectively arranging NdFeB permanent magnets at the upper part and the lower part of the reaction kettle to apply an external magnetic field with the magnetic field intensity of 0.4T along the vertical direction of the reaction kettle, and then carrying out hydrothermal reaction for 25 hours at 180 ℃ to obtain Fe with a one-dimensional chain structure3O4The nano-array particles are naturally cooled to room temperature after the reaction is finished, and then the one-dimensional chain-shaped structure Fe is treated by using an NdFeB permanent magnet3O4And separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use.
Secondly, inducing Fe with one-dimensional chain structure by magnetic field3O4The nano array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Flatly paving the black carbon fiber spunlace non-woven fabric at the bottom of the container, and applying an external magnetic field with the magnetic field intensity of 0.4T to the outer side of the bottom of the container; fe with one-dimensional chain structure obtained in the step one3O4Ultrasonically dispersing nano array particles in an ethanol solution to obtain a suspension with the concentration of 70g/L, then injecting the suspension into the container to enable the suspension to submerge the tiled black carbon fiber spunlace non-woven fabric, standing and air-drying to obtain Fe loaded with one-dimensional chain-shaped structures in directional array arrangement3O4The black carbon fiber spunlace non-woven fabric of the nano-array particles.
Thirdly, applying facial mask slurry
Flatly paving the black carbon fiber spunlace non-woven fabric obtained in the step two in a grouting mold, then injecting the mask slurry into the grouting mold, enabling the mask slurry to penetrate into the whole black carbon fiber spunlace non-woven fabric, and then taking out the mask.
The facial mask slurry comprises the following components in parts by mass in 100 parts by weight:
10 parts of glycerin, 2 parts of sodium hyaluronate, 6 parts of poloxamer, 0.2 part of acetyl tetrapeptide, 0.1 part of palmitoyl tripeptide, 1 part of dendrobium officinale extract, 0.0 part of triethanolamine, 0.3 part of mannitol, 0.5 part of xanthan gum, 0.2 part of polysorbate, 0.5 part of propylene glycol, 23.5 parts of silicone oil-based oily phase and the balance of water.
Example 4
A moisturizing mask containing nano magnetic array particles comprises the following three steps:
preparation of nano magnetic array particle
Sodium borohydride (NaBH) at a concentration of 25g/L4) The aqueous solution and the aqueous solution of ferric chloride with the concentration of 20g/L are mixed according to the volume ratio of 1:1, the pH value of the mixed solution is adjusted to 12 by sodium hydroxide, then the mixed solution is placed in a reaction kettle, an NdFeB permanent magnet is respectively arranged at the upper part and the lower part of the reaction kettle, an external magnetic field with the magnetic field intensity of 0.25T is applied along the vertical direction of the reaction kettle, and then the hydrothermal reaction is carried out for 15 hours at 160 ℃, so that the Fe with the one-dimensional chain structure is obtained3O4The nano-array particles are naturally cooled to room temperature after the reaction is finished, and then the one-dimensional chain-shaped structure Fe is treated by using an NdFeB permanent magnet3O4And separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use.
Secondly, inducing Fe with one-dimensional chain structure by magnetic field3O4The nano array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Flatly paving the black carbon fiber spunlace non-woven fabric at the bottom of the container, and applying an external magnetic field with the magnetic field intensity of 0.25T to the outer side of the bottom of the container; fe with one-dimensional chain structure obtained in the step one3O4Ultrasonically dispersing nano array particles in an ethanol solution to obtain a suspension with the concentration of 50g/L, then injecting the suspension into the container to enable the suspension to submerge the tiled black carbon fiber spunlace non-woven fabric, standing and air-drying to obtain Fe loaded with one-dimensional chain-shaped structures in directional array arrangement3O4The black carbon fiber spunlace non-woven fabric of the nano-array particles.
Thirdly, applying facial mask slurry
Flatly paving the black carbon fiber spunlace non-woven fabric obtained in the step two in a grouting mold, then injecting the mask slurry into the grouting mold, enabling the mask slurry to penetrate into the whole black carbon fiber spunlace non-woven fabric, and then taking out the mask.
The facial mask slurry comprises the following components in parts by mass in 100 parts by weight:
12 parts of glycerin, 0.5 part of sodium hyaluronate, 5 parts of poloxamer, 0.05 part of acetyl tetrapeptide, 0.2 part of palmitoyl tripeptide, 1 part of dendrobium officinale extract, 0.0 part of triethanolamine, 0.3 part of mannitol, 0.5 part of xanthan gum, 0.2 part of polysorbate, 0.5 part of propylene glycol, 23.5 parts of silicone oil-based oily phase and the balance of water.
Claims (7)
1. A preparation method of a moisturizing mask containing nano magnetic array particles comprises the following steps:
preparation of nano magnetic array particle
Reacting sodium borohydride (NaBH)4) The aqueous solution and the aqueous solution of ferric chloride are mixed according to the volume ratio of 1:1, sodium hydroxide is used for adjusting the pH value of the mixed solution to 12-14, then the mixed solution is placed in a reaction kettle, an external magnetic field is applied along the vertical direction of the reaction kettle, and then hydrothermal reaction is carried out for 15-25h at the temperature of 160-180 ℃, so as to obtain Fe with a one-dimensional chain structure3O4The nano-array particles are naturally cooled to room temperature after the reaction is finished, and then the one-dimensional chain-shaped structure Fe is treated by using an NdFeB permanent magnet3O4And separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use.
Secondly, inducing Fe with one-dimensional chain structure by magnetic field3O4The nano array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Paving the carbon fiber mask base material at the bottom of the container, and applying an external magnetic field outside the bottom of the container; fe with one-dimensional chain structure obtained in the step one3O4Ultrasonically dispersing nano array particles in an ethanol solution to obtain a suspension with the concentration of 50-100g/L, then injecting the suspension into the container to enable the suspension to submerge the tiled carbon fiber mask base material, standing and air-drying to obtain Fe loaded with a one-dimensional chain structure in directional array arrangement3O4Carbon of nano-array particlesA fibrous mask substrate.
Thirdly, applying facial mask slurry
Flatly paving the carbon fiber facial mask base material obtained in the step two in a grouting mold, then injecting facial mask slurry into the grouting mold, enabling the facial mask slurry to penetrate into the whole carbon fiber facial mask base material, and then taking out the facial mask.
2. The method for preparing a moisturizing mask containing nano-magnetic array particles as claimed in claim 1, wherein in the first step, the sodium borohydride (NaBH)4) The concentration of the aqueous solution of (A) is 20-50g/L, and the concentration of the aqueous solution of ferric chloride is 15-40 g/L.
3. The method for preparing a moisturizing mask containing nano-magnetic array particles as claimed in claim 2, wherein in the first step, the magnitude of the external magnetic field is 0.2-0.4T, and the external magnetic field is applied by disposing an NdFeB permanent magnet on each of the upper and lower portions of the reaction kettle.
4. The method for preparing a moisturizing mask containing nano-magnetic array particles as claimed in claim 3, wherein in the second step, the magnitude of the external magnetic field is 0.2-0.4T.
5. The method for preparing the moisturizing mask containing nano-magnetic array particles as claimed in claim 4, wherein in the second step, the carbon fiber mask substrate is a black carbon fiber spunlace nonwoven fabric.
6. The preparation method of the moisturizing mask containing the nano magnetic array particles as claimed in claim 5, wherein in the third step, the mask slurry comprises 100 parts by weight of the following components in parts by mass: 10-15 parts of glycerin, 0.5-2 parts of sodium hyaluronate, 1-10 parts of poloxamer, 0.05-0.2 part of acetyl tetrapeptide, 0.05-0.2 part of palmitoyl tripeptide, 0.2-1 part of dendrobium officinale extract, 0.02-0.08 part of triethanolamine, 0.3-0.8 part of mannitol, 0.5-1 part of xanthan gum, 0.2-1 part of polysorbate, 0.5-4 parts of propylene glycol, 15.5-23.5 parts of silicone oil-based oily phase and the balance of water.
7. A moisturizing mask containing nano magnetic array particles, which is characterized by being prepared by the preparation method of any one of claims 1 to 6.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090110704A1 (en) * | 2007-10-30 | 2009-04-30 | Dermophisiologique S.R.L. | Cosmetic composition based on a magnetic or magnetisable material, the preparation thereof and use thereof for cleansing the epidermis |
| CN104666099A (en) * | 2015-03-13 | 2015-06-03 | 雅弗生物实验室有限公司(加拿大) | Carbon fiber skin-beautifying membrane substrate and preparation method thereof |
| CN111467281A (en) * | 2020-05-29 | 2020-07-31 | 蒋艳伟 | Anti-allergy moisturizing facial mask prepared from active polypeptide and hyaluronic acid and preparation method of anti-allergy moisturizing facial mask |
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2020
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| US20090110704A1 (en) * | 2007-10-30 | 2009-04-30 | Dermophisiologique S.R.L. | Cosmetic composition based on a magnetic or magnetisable material, the preparation thereof and use thereof for cleansing the epidermis |
| CN104666099A (en) * | 2015-03-13 | 2015-06-03 | 雅弗生物实验室有限公司(加拿大) | Carbon fiber skin-beautifying membrane substrate and preparation method thereof |
| CN111467281A (en) * | 2020-05-29 | 2020-07-31 | 蒋艳伟 | Anti-allergy moisturizing facial mask prepared from active polypeptide and hyaluronic acid and preparation method of anti-allergy moisturizing facial mask |
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Effective date of registration: 20231101 Address after: A307-308, Building 2, No. 452, 6th Street, Baiyang Street, Qiantang District, Hangzhou City, Zhejiang Province, 310000 Patentee after: Lefu Biotechnology (Hangzhou) Co.,Ltd. Address before: Room 309, 3 / F, No.2 building, Qianwan bonded port area, Qingdao area, China (Shandong) pilot Free Trade Zone, Qingdao, Shandong Province Patentee before: Qingdao zizhiyan cosmetics technology Co.,Ltd. |