CN112137894B - Moisturizing mask and preparation method thereof - Google Patents

Moisturizing mask and preparation method thereof Download PDF

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CN112137894B
CN112137894B CN202011067483.9A CN202011067483A CN112137894B CN 112137894 B CN112137894 B CN 112137894B CN 202011067483 A CN202011067483 A CN 202011067483A CN 112137894 B CN112137894 B CN 112137894B
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mask
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magnetic field
carbon fiber
array
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CN112137894A (en
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张洁
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GUANGDONG BASONNIA BIOTECHNOLOGY Co.,Ltd.
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Guangdong Basonnia Biotechnology Co ltd
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
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    • A—HUMAN NECESSITIES
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    • A61K8/00—Cosmetics or similar toiletry preparations
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
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    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
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    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
    • A—HUMAN NECESSITIES
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    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
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    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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Abstract

The invention relates to a moisturizing mask and a preparation method thereof. In the preparation process, Fe with a one-dimensional chain structure is prepared in advance under the action of an external magnetic field3O4Nano-array particles and white TiO2Mixing black Fe3O4The nano magnetic array particles are coated, then are uniformly and directionally distributed on the white carbon fiber spunlace non-woven fabric in an array mode under the action of an external magnetic field, and finally the facial mask slurry is injected into the facial mask base material. The obtained facial mask product can fully utilize the uniform magnetic field effect generated by the nano magnetic array particles, promote the repair and regeneration of subcutaneous tissues at the inner side of the skin and does not need to use additional external magnetic field equipment. Meanwhile, the uniform magnetic field generated by the nano magnetic array particles is beneficial to promoting the penetration of the nutrient components in the mask slurry to the skin, so as to increase the nutrient components of the skinThe effect of uniform absorption.

Description

Moisturizing mask and preparation method thereof
Technical Field
The invention relates to the field of facial masks, in particular to a facial mask containing TiO2Coated with Fe3O4A moisturizing facial mask containing nanometer magnetic array particles and its preparation method are provided.
Background
With the development of society, the pace of life of people is faster and faster, and the negative reactions of people to fast paced life and heavy working pressure are reflected on the health of people along with the accumulation of time, wherein the most intuitive and obvious is the skin surface, which is mainly reflected in that the skin surface becomes dry due to the loss of moisture, the skin becomes aged, wrinkles, color spots and the like appear.
In order to alleviate the negative effects of life and work pressure on the body, facial masks have become a common method of skin care for most women. The mask products on the market are various, however, most of the existing masks utilize direct absorption of the skin to nutrient solution in the mask, but the absorption effect is generally low, so that the maintenance effect of the mask is not ideal.
Research results indicate that the regeneration and repair of skin tissues can be promoted by providing an external magnetic field through an external magnetic therapy apparatus. Related products such as corresponding magnetic therapeutic apparatuses also appear in the market, but the products are relatively high in price and are not beneficial to popularization.
Research results also indicate that the magnetic nanoparticles in the facial mask can be utilized to promote the absorption of the skin on the nutrient components in the facial mask slurry by directly adding the magnetic nanoparticles into the facial mask. However, the effect is not ideal because the magnetic field generated by directly adding the magnetic nanoparticles is unstable due to disorder of the magnetic pole direction.
Therefore, the invention aims to provide the moisturizing mask which can effectively promote the skin to absorb various nutrient components and moisture in the mask.
Disclosure of Invention
In order to solve the problem of insufficient absorbability in the existing mask products, the invention provides a mask containing TiO, which can effectively promote the skin to absorb various nutrient components and moisture in the mask2Coated with Fe3O4A moisturizing facial mask containing nanometer magnetic array particles and its preparation method are provided.
The invention comprises the following four steps:
preparation of nano magnetic array particle
Reacting sodium borohydride (NaBH)4) The aqueous solution of (A) and the aqueous solution of ferric chloride are mixed in a volume ratio of 1:1, and the pH value of the mixed solution is adjusted to be12-14, then placing the mixed solution in a reaction kettle, applying an external magnetic field along the vertical direction of the reaction kettle, and then carrying out hydrothermal reaction for 15-25h at 160-3O4The nano-array particles are naturally cooled to room temperature after the reaction is finished, and then the one-dimensional chain-shaped structure Fe is treated by using an NdFeB permanent magnet3O4And separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use.
II, TiO2Coated with Fe3O4Preparation of nano magnetic array particles
Taking 5-10g of Fe with one-dimensional chain structure obtained in the step one3O4Magnetically dispersing the nano-array particles in a mixed solution of 80ml of absolute ethyl alcohol and 20ml of tetrabutyl titanate, magnetically ultrasonically dispersing, stirring, heating in a water bath to 40-50 ℃, slowly dropwise adding deionized water to hydrolyze the tetrabutyl titanate, and coating the tetrabutyl titanate on Fe with a one-dimensional chain structure3O4And (3) washing the product on the surface of the nano-array particles by using deionized water for later use.
Magnetic field induced TiO2Coated with Fe3O4The nano magnetic array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Paving the carbon fiber mask base material at the bottom of the container, and applying an external magnetic field outside the bottom of the container; TiO obtained in the second step2Coated with Fe3O4Ultrasonically dispersing nano magnetic array particles in an ethanol solution to obtain a suspension with the concentration of 50-100g/L, then injecting the suspension into the container to enable the suspension to submerge the tiled carbon fiber mask base material, standing and air-drying to obtain TiO loaded with directional array arrangement2Coated with Fe3O4A carbon fiber mask substrate of nano magnetic array particles.
Fourthly, applying facial mask slurry
Flatly paving the carbon fiber facial mask base material obtained in the third step in a grouting mold, then injecting facial mask slurry into the grouting mold, enabling the facial mask slurry to permeate the whole carbon fiber facial mask base material, and then taking out the facial mask.
Further, in the first step, the sodium borohydride (NaBH)4) The concentration of the aqueous solution of (A) is 20-50g/L, and the concentration of the aqueous solution of ferric chloride is 15-40 g/L.
Further, in the first step, the magnitude of the external magnetic field is 0.2-0.4T, and the external magnetic field is applied by arranging an NdFeB permanent magnet at each of the upper and lower portions of the reaction vessel.
Further, in the third step, the magnitude of the external magnetic field is 0.2-0.4T.
Further, in the third step, the carbon fiber mask base material is white carbon fiber spunlace non-woven fabric.
Further, in the fourth step, the composition of the mask slurry comprises the following components in parts by mass in 100 parts by weight:
10-15 parts of glycerin, 0.5-2 parts of sodium hyaluronate, 1-10 parts of poloxamer, 0.05-0.2 part of acetyl tetrapeptide, 0.05-0.2 part of palmitoyl tripeptide, 0.2-1 part of dendrobium officinale extract, 0.02-0.08 part of triethanolamine, 0.3-0.8 part of mannitol, 0.5-1 part of xanthan gum, 0.2-1 part of polysorbate, 0.5-4 parts of propylene glycol, 15.5-23.5 parts of silicone oil-based oily phase and the balance of water.
In the invention, the nano magnetic array particles arranged in a directional array are directly added into the facial mask, so that the uniform magnetic field effect generated by the nano magnetic array particles can be fully utilized, the repair and regeneration of subcutaneous tissues at the inner side of the skin are promoted, and no additional external magnetic field equipment is needed. Meanwhile, the uniform magnetic field generated by the nano magnetic array particles is beneficial to promoting the matching of components such as silicone oil, glycerin, sodium hyaluronate, acetyl tetrapeptide, palmitoyl tripeptide and the like in the mask slurry, so that the activity of the components is enhanced, the permeation of the substances to the skin is further promoted, the absorption of the skin to the nutritional ingredients, particularly the absorption of the glycerin is increased, and the effect of better skin care is achieved.
In the present invention, the added magnetic particles are Fe having a one-dimensional chain structure3O4Nano-array particles prepared by preparing Fe3O4An external magnetic field is applied in a direction during the process of the nanoparticles,so that magnetic Fe3O4The nano particles are easy to be connected into a chain along the direction of the easy magnetization axis thereof for growing, and the obtained Fe with a one-dimensional chain structure3O4Compared with common Fe3O4 nanoparticles, the nano-array particles can provide a more effective micro magnetic field, are more favorable for promoting the repair and regeneration of subcutaneous tissues and are more favorable for promoting the absorption of skin on nutrient components in mask slurry.
In the present invention, Fe having a one-dimensional chain structure is applied to the surface of the carbon fiber mask base material3O4In the process of nano-array particles, a magnetic field with the same degree is applied to the carbon fiber mask base material, so that Fe with a one-dimensional chain structure can be ensured3O4The nano array particles are uniformly and directionally distributed on the carbon fiber mask base material in an array manner, so that a uniform and directional micro magnetic field can be applied to the skin surface of a mask product, and the uniform absorption of the skin on the nutrient components in the mask slurry is facilitated.
In the present invention, white TiO is used2Mixing black Fe3O4The nano magnetic array particles are coated, so that the nano magnetic array particles are white-like, and can be used in a white mask product. At the same time, TiO on the surface2Also has skin whitening effect.
Detailed Description
The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
Example 1
The preparation method of the moisturizing mask comprises the following four steps:
preparation of nano magnetic array particle
Sodium borohydride (NaBH) at a concentration of 30g/L4) Mixing the aqueous solution of (1) and an aqueous solution of ferric chloride with the concentration of 30g/L according to the volume ratio of 1:1, adjusting the pH value of the mixed solution to be 14 by using sodium hydroxide, then placing the mixed solution into a reaction kettle, applying an external magnetic field with the magnetic field intensity of 0.28T along the vertical direction of the reaction kettle by arranging NdFeB permanent magnets at the upper part and the lower part of the reaction kettle respectively, and then carrying out hydrothermal reaction for 18 hours at the temperature of 180 ℃ to obtain the productFe of chain-like structure3O4The nano-array particles are naturally cooled to room temperature after the reaction is finished, and then the one-dimensional chain-shaped structure Fe is treated by using an NdFeB permanent magnet3O4And separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use.
II, TiO2Coated with Fe3O4Preparation of nano magnetic array particles
Taking 10g of Fe with one-dimensional chain structure obtained in the step one3O4Magnetically dispersing the nano-array particles in a mixed solution of 80ml of absolute ethyl alcohol and 20ml of tetrabutyl titanate, magnetically ultrasonically dispersing, stirring, heating in a water bath to 50 ℃, slowly dropwise adding deionized water to hydrolyze the tetrabutyl titanate, and coating the tetrabutyl titanate on Fe with a one-dimensional chain structure3O4And (3) washing the product on the surface of the nano-array particles by using deionized water for later use.
Magnetic field induced TiO2Coated with Fe3O4The nano magnetic array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Spreading the white carbon fiber spunlace non-woven fabric on the bottom of the container, and applying an external magnetic field with the magnetic field intensity of 0.28T to the outer side of the bottom of the container; TiO obtained in the second step2Coated with Fe3O4Ultrasonically dispersing nano magnetic array particles in an ethanol solution to obtain a suspension with the concentration of 80g/L, then injecting the suspension into the container to enable the suspension to submerge the tiled carbon fiber mask base material, standing and air-drying to obtain TiO loaded with directional array arrangement2Coated with Fe3O4A carbon fiber mask substrate of nano magnetic array particles.
Fourthly, applying facial mask slurry
Flatly paving the carbon fiber facial mask base material obtained in the third step in a grouting mold, then injecting facial mask slurry into the grouting mold, enabling the facial mask slurry to permeate the whole carbon fiber facial mask base material, and then taking out the facial mask.
The facial mask slurry comprises the following components in parts by mass in 100 parts by weight:
12 parts of glycerin, 0.5 part of sodium hyaluronate, 5 parts of poloxamer, 0.05 part of acetyl tetrapeptide, 0.2 part of palmitoyl tripeptide, 0.5 part of dendrobium officinale extract, 0.04 part of triethanolamine, 0.8 part of mannitol, 0.5 part of xanthan gum, 0.5 part of polysorbate, 2 parts of propylene glycol, 18.8 parts of silicone oil-based oily phase and the balance of water.
Example 2
The preparation method of the moisturizing mask comprises the following four steps:
preparation of nano magnetic array particle
Sodium borohydride (NaBH) with concentration of 40g/L4) The aqueous solution and the aqueous solution of ferric chloride with the concentration of 35g/L are mixed according to the volume ratio of 1:1, the pH value of the mixed solution is adjusted to 13 by sodium hydroxide, then the mixed solution is placed in a reaction kettle, an NdFeB permanent magnet is respectively arranged at the upper part and the lower part of the reaction kettle, an external magnetic field with the magnetic field intensity of 0.35T is applied along the vertical direction of the reaction kettle, and then the hydrothermal reaction is carried out for 22 hours at the temperature of 180 ℃, so that the Fe with the one-dimensional chain structure is obtained3O4The nano-array particles are naturally cooled to room temperature after the reaction is finished, and then the one-dimensional chain-shaped structure Fe is treated by using an NdFeB permanent magnet3O4And separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use.
II, TiO2Coated with Fe3O4Preparation of nano magnetic array particles
Taking 8g of Fe with a one-dimensional chain structure obtained in the step one3O4Magnetically dispersing the nano-array particles in a mixed solution of 80ml of absolute ethyl alcohol and 20ml of tetrabutyl titanate, magnetically ultrasonically dispersing, stirring, heating in a water bath to 45 ℃, slowly dropwise adding deionized water to hydrolyze the tetrabutyl titanate, and coating the tetrabutyl titanate on Fe with a one-dimensional chain structure3O4And (3) washing the product on the surface of the nano-array particles by using deionized water for later use.
Magnetic field induced TiO2Coated with Fe3O4The nano magnetic array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Laying white carbon fiber spunlace non-woven fabric in a containerThe bottom of the container, and an external magnetic field with the magnetic field intensity of 0.35T is applied to the outer side of the bottom of the container; TiO obtained in the second step2Coated with Fe3O4Ultrasonically dispersing nano magnetic array particles in an ethanol solution to obtain a suspension with the concentration of 75g/L, then injecting the suspension into the container to enable the suspension to submerge the tiled carbon fiber mask base material, standing and air-drying to obtain TiO loaded with directional array arrangement2Coated with Fe3O4A carbon fiber mask substrate of nano magnetic array particles.
Fourthly, applying facial mask slurry
And D, flatly leveling the white carbon fiber spunlace non-woven fabric obtained in the step two, paving the flat white carbon fiber spunlace non-woven fabric in a grouting mold, then injecting the mask slurry into the grouting mold, so that the mask slurry permeates into the whole white carbon fiber spunlace non-woven fabric, and then taking out the mask.
The facial mask slurry comprises the following components in parts by mass in 100 parts by weight:
15 parts of glycerin, 0.5 part of sodium hyaluronate, 3 parts of poloxamer, 0.05 part of acetyl tetrapeptide, 0.05 part of palmitoyl tripeptide, 0.4 part of dendrobium officinale extract, 0.02 part of triethanolamine, 0.3 part of mannitol, 1 part of xanthan gum, 0.8 part of polysorbate, 2 parts of propylene glycol, 21.5 parts of silicone oil-based oily phase and the balance of water.
Example 3
The preparation method of the moisturizing mask comprises the following four steps:
preparation of nano magnetic array particle
Sodium borohydride (NaBH) with a concentration of 50g/L4) The aqueous solution and the aqueous solution of ferric chloride with the concentration of 40g/L are mixed according to the volume ratio of 1:1, the pH value of the mixed solution is adjusted to 14 by sodium hydroxide, then the mixed solution is placed in a reaction kettle, an NdFeB permanent magnet is respectively arranged at the upper part and the lower part of the reaction kettle, an external magnetic field with the magnetic field intensity of 0.4T is applied along the vertical direction of the reaction kettle, and then the hydrothermal reaction is carried out for 25 hours at the temperature of 180 ℃, so that Fe with a one-dimensional chain structure is obtained3O4The nano-array particles are naturally cooled to room temperature after the reaction is finished, and thenUsing NdFeB permanent magnet to convert one-dimensional chain-shaped structure Fe3O4And separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use.
II, TiO2Coated with Fe3O4Preparation of nano magnetic array particles
Taking 10g of Fe with one-dimensional chain structure obtained in the step one3O4Magnetically dispersing the nano-array particles in a mixed solution of 80ml of absolute ethyl alcohol and 20ml of tetrabutyl titanate, magnetically ultrasonically dispersing, stirring, heating in a water bath to 50 ℃, slowly dropwise adding deionized water to hydrolyze the tetrabutyl titanate, and coating the tetrabutyl titanate on Fe with a one-dimensional chain structure3O4And (3) washing the product on the surface of the nano-array particles by using deionized water for later use.
Magnetic field induced TiO2Coated with Fe3O4The nano magnetic array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Spreading the white carbon fiber spunlace non-woven fabric on the bottom of the container, and applying an external magnetic field with the magnetic field intensity of 0.4T to the outer side of the bottom of the container; TiO obtained in the second step2Coated with Fe3O4Ultrasonically dispersing nano magnetic array particles in an ethanol solution to obtain a suspension with the concentration of 70g/L, then injecting the suspension into the container to enable the suspension to submerge the tiled carbon fiber mask base material, standing and air-drying to obtain TiO loaded with directional array arrangement2Coated with Fe3O4A carbon fiber mask substrate of nano magnetic array particles.
Fourthly, applying facial mask slurry
And D, flatly leveling the white carbon fiber spunlace non-woven fabric obtained in the step two, paving the flat white carbon fiber spunlace non-woven fabric in a grouting mold, then injecting the mask slurry into the grouting mold, so that the mask slurry permeates into the whole white carbon fiber spunlace non-woven fabric, and then taking out the mask.
The facial mask slurry comprises the following components in parts by mass in 100 parts by weight:
10 parts of glycerin, 2 parts of sodium hyaluronate, 6 parts of poloxamer, 0.2 part of acetyl tetrapeptide, 0.1 part of palmitoyl tripeptide, 1 part of dendrobium officinale extract, 0.0 part of triethanolamine, 0.3 part of mannitol, 0.5 part of xanthan gum, 0.2 part of polysorbate, 0.5 part of propylene glycol, 23.5 parts of silicone oil-based oily phase and the balance of water.
Example 4
The preparation method of the moisturizing mask comprises the following four steps:
preparation of nano magnetic array particle
Sodium borohydride (NaBH) at a concentration of 25g/L4) The aqueous solution and the aqueous solution of ferric chloride with the concentration of 20g/L are mixed according to the volume ratio of 1:1, the pH value of the mixed solution is adjusted to 12 by sodium hydroxide, then the mixed solution is placed in a reaction kettle, an NdFeB permanent magnet is respectively arranged at the upper part and the lower part of the reaction kettle, an external magnetic field with the magnetic field intensity of 0.25T is applied along the vertical direction of the reaction kettle, and then the hydrothermal reaction is carried out for 15 hours at 160 ℃, so that the Fe with the one-dimensional chain structure is obtained3O4The nano-array particles are naturally cooled to room temperature after the reaction is finished, and then the one-dimensional chain-shaped structure Fe is treated by using an NdFeB permanent magnet3O4And separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use.
II, TiO2Coated with Fe3O4Preparation of nano magnetic array particles
Taking 5g of Fe with one-dimensional chain structure obtained in the step one3O4Magnetically dispersing the nano-array particles in a mixed solution of 80ml of absolute ethyl alcohol and 20ml of tetrabutyl titanate, magnetically ultrasonically dispersing, stirring, heating in a water bath to 40 ℃, slowly dropwise adding deionized water to hydrolyze the tetrabutyl titanate, and coating the tetrabutyl titanate on Fe with a one-dimensional chain structure3O4And (3) washing the product on the surface of the nano-array particles by using deionized water for later use.
Magnetic field induced TiO2Coated with Fe3O4The nano magnetic array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Spreading the white carbon fiber spunlace non-woven fabric on the bottom of the container, and applying an external magnetic field with the magnetic field intensity of 0.25T to the outer side of the bottom of the container; will be obtained in the second stepTo TiO 22Coated with Fe3O4Ultrasonically dispersing nano magnetic array particles in an ethanol solution to obtain a suspension with the concentration of 50g/L, then injecting the suspension into the container to enable the suspension to submerge the tiled carbon fiber mask base material, standing and air-drying to obtain TiO loaded with directional array arrangement2Coated with Fe3O4A carbon fiber mask substrate of nano magnetic array particles.
Fourthly, applying facial mask slurry
And D, flatly leveling the white carbon fiber spunlace non-woven fabric obtained in the step two, paving the flat white carbon fiber spunlace non-woven fabric in a grouting mold, then injecting the mask slurry into the grouting mold, so that the mask slurry permeates into the whole white carbon fiber spunlace non-woven fabric, and then taking out the mask.
The facial mask slurry comprises the following components in parts by mass in 100 parts by weight:
12 parts of glycerin, 0.5 part of sodium hyaluronate, 5 parts of poloxamer, 0.05 part of acetyl tetrapeptide, 0.2 part of palmitoyl tripeptide, 1 part of dendrobium officinale extract, 0.0 part of triethanolamine, 0.3 part of mannitol, 0.5 part of xanthan gum, 0.2 part of polysorbate, 0.5 part of propylene glycol, 23.5 parts of silicone oil-based oily phase and the balance of water.

Claims (7)

1. A preparation method of a moisturizing mask comprises the following steps:
preparation of nano magnetic array particle
Reacting sodium borohydride (NaBH)4) The aqueous solution and the aqueous solution of ferric chloride are mixed according to the volume ratio of 1:1, sodium hydroxide is used for adjusting the pH value of the mixed solution to 12-14, then the mixed solution is placed in a reaction kettle, an external magnetic field is applied along the vertical direction of the reaction kettle, and then hydrothermal reaction is carried out for 15-25h at the temperature of 160-180 ℃, so as to obtain Fe with a one-dimensional chain structure3O4The nano-array particles are naturally cooled to room temperature after the reaction is finished, and then the one-dimensional chain-shaped structure Fe is treated by using an NdFeB permanent magnet3O4Separating and collecting the nano array particles, and washing with deionized water and absolute ethyl alcohol in sequence for later use;
II, TiO2Coated with Fe3O4Preparation of nano magnetic array particles
Taking 5-10g of Fe with one-dimensional chain structure obtained in the step one3O4Magnetically dispersing the nano-array particles in a mixed solution of 80ml of absolute ethyl alcohol and 20ml of tetrabutyl titanate, magnetically ultrasonically dispersing, stirring, heating in a water bath to 40-50 ℃, slowly dropwise adding deionized water to hydrolyze the tetrabutyl titanate, and coating the tetrabutyl titanate on Fe with a one-dimensional chain structure3O4Washing the product on the surface of the nano-array particles by using deionized water for later use;
magnetic field induced TiO2Coated with Fe3O4The nano magnetic array particles are directionally arrayed and arranged on the surface of the carbon fiber mask base material
Paving the carbon fiber mask base material at the bottom of the container, and applying an external magnetic field outside the bottom of the container; TiO obtained in the second step2Coated with Fe3O4Ultrasonically dispersing nano magnetic array particles in an ethanol solution to obtain a suspension with the concentration of 50-100g/L, then injecting the suspension into the container to enable the suspension to submerge the tiled carbon fiber mask base material, standing and air-drying to obtain TiO loaded with directional array arrangement2Coated with Fe3O4A carbon fiber mask substrate of nano magnetic array particles;
fourthly, applying facial mask slurry
Flatly paving the carbon fiber facial mask base material obtained in the third step in a grouting mold, then injecting facial mask slurry into the grouting mold, enabling the facial mask slurry to permeate the whole carbon fiber facial mask base material, and then taking out the facial mask.
2. The method for preparing a moisturizing mask as claimed in claim 1, wherein in the first step, the sodium borohydride (NaBH)4) The concentration of the aqueous solution of (A) is 20-50g/L, and the concentration of the aqueous solution of ferric chloride is 15-40 g/L.
3. The method for preparing a hydrating and moisturizing mask as claimed in claim 2, wherein in the first step, the magnitude of the external magnetic field is 0.2-0.4T, and the external magnetic field is applied by disposing a NdFeB permanent magnet on each of the upper and lower portions of the reaction kettle.
4. The method for preparing the moisturizing mask as claimed in claim 3, wherein in the third step, the magnitude of the external magnetic field is 0.2-0.4T.
5. The preparation method of the moisturizing mask as claimed in claim 4, wherein in the third step, the carbon fiber mask substrate is a white carbon fiber spunlace nonwoven fabric.
6. The preparation method of the moisturizing mask as claimed in claim 5, wherein in the fourth step, the mask slurry comprises 100 parts by weight of the following components in parts by mass: 10-15 parts of glycerin, 0.5-2 parts of sodium hyaluronate, 1-10 parts of poloxamer, 0.05-0.2 part of acetyl tetrapeptide, 0.05-0.2 part of palmitoyl tripeptide, 0.2-1 part of dendrobium officinale extract, 0.02-0.08 part of triethanolamine, 0.3-0.8 part of mannitol, 0.5-1 part of xanthan gum, 0.2-1 part of polysorbate, 0.5-4 parts of propylene glycol, 15.5-23.5 parts of silicone oil-based oily phase and the balance of water.
7. A hydrating and moisturizing mask characterized by being prepared by the preparation method of any one of claims 1 to 6.
CN202011067483.9A 2020-10-06 2020-10-06 Moisturizing mask and preparation method thereof Active CN112137894B (en)

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EP2055295A3 (en) * 2007-10-30 2009-07-08 Dermophisiologique s.r.l. Cosmetic composition based on a magnetic or magnetisable material, the preparation thereof and use thereof for cleansing the epidermis
CN104274374A (en) * 2014-09-28 2015-01-14 黄科冯 Method for preparing magnetic mud mask and powder mask
CN107669564A (en) * 2017-11-21 2018-02-09 江少卿 It is a kind of that there is reparative regeneration, replenishing water and preserving moisture, the skin care compositions of anti-aging

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