CN112107493B - Moisturizing facial mask containing nano magnetic array particles and preparation method thereof - Google Patents
Moisturizing facial mask containing nano magnetic array particles and preparation method thereof Download PDFInfo
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- CN112107493B CN112107493B CN202011067482.4A CN202011067482A CN112107493B CN 112107493 B CN112107493 B CN 112107493B CN 202011067482 A CN202011067482 A CN 202011067482A CN 112107493 B CN112107493 B CN 112107493B
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- 239000002245 particle Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 230000003020 moisturizing effect Effects 0.000 title claims abstract description 15
- 230000001815 facial effect Effects 0.000 title abstract description 16
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 44
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000002002 slurry Substances 0.000 claims abstract description 30
- 239000004917 carbon fiber Substances 0.000 claims abstract description 22
- 239000000758 substrate Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 239000004745 nonwoven fabric Substances 0.000 claims description 23
- 239000003738 black carbon Substances 0.000 claims description 22
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000000725 suspension Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 229910001172 neodymium magnet Inorganic materials 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 12
- 235000011187 glycerol Nutrition 0.000 claims description 8
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 8
- 239000012279 sodium borohydride Substances 0.000 claims description 8
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 7
- 229920002385 Sodium hyaluronate Polymers 0.000 claims description 7
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 7
- 235000019441 ethanol Nutrition 0.000 claims description 7
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 7
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- 239000012466 permeate Substances 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- 229940010747 sodium hyaluronate Drugs 0.000 claims description 7
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 6
- 241000026010 Dendrobium candidum Species 0.000 claims description 6
- 229930195725 Mannitol Natural products 0.000 claims description 6
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 6
- 239000000594 mannitol Substances 0.000 claims description 6
- 235000010355 mannitol Nutrition 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229960000502 poloxamer Drugs 0.000 claims description 6
- 229920001983 poloxamer Polymers 0.000 claims description 6
- 229950008882 polysorbate Drugs 0.000 claims description 6
- 229920000136 polysorbate Polymers 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 6
- 239000000230 xanthan gum Substances 0.000 claims description 6
- 229920001285 xanthan gum Polymers 0.000 claims description 6
- 229940082509 xanthan gum Drugs 0.000 claims description 6
- 235000010493 xanthan gum Nutrition 0.000 claims description 6
- 238000007605 air drying Methods 0.000 claims description 5
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 10
- 235000015097 nutrients Nutrition 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 8
- 230000009286 beneficial effect Effects 0.000 abstract description 6
- 230000001737 promoting effect Effects 0.000 abstract description 6
- 230000008929 regeneration Effects 0.000 abstract description 4
- 238000011069 regeneration method Methods 0.000 abstract description 4
- 206010033675 panniculitis Diseases 0.000 abstract description 3
- 210000004304 subcutaneous tissue Anatomy 0.000 abstract description 3
- 230000005426 magnetic field effect Effects 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 4
- 239000002122 magnetic nanoparticle Substances 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006249 magnetic particle Substances 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000033764 rhythmic process Effects 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N2/00—Magnetotherapy
- A61N2/002—Magnetotherapy in combination with another treatment
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N2/00—Magnetotherapy
- A61N2/06—Magnetotherapy using magnetic fields produced by permanent magnets
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Cosmetics (AREA)
Abstract
The invention relates to a moisturizing facial mask containing nano magnetic array particles and a preparation method thereof. In the preparation process, fe with one-dimensional chain structure is prepared in advance under the action of an external magnetic field 3 O 4 The nano array particles are uniformly and directionally distributed on the carbon fiber mask substrate under the action of an external magnetic field, and finally the mask slurry is injected into the mask substrate. The mask product obtained by the method can fully utilize the uniform magnetic field effect generated by the nano magnetic array particles, promote the repair and regeneration of subcutaneous tissues at the inner side of the skin, and does not need to use extra external magnetic field equipment. Meanwhile, the uniform magnetic field generated by the nano magnetic array particles is beneficial to promoting the permeation of the nutrient components in the mask slurry to the skin, so as to achieve the effect of increasing the uniform absorption of the nutrient components by the skin.
Description
Technical Field
The invention relates to the field of facial masks, in particular to a moisturizing facial mask containing nano magnetic array particles and a preparation method thereof.
Background
Along with the development of society, the life rhythm of people is faster and faster, and negative reactions of people to fast-paced life and heavy working pressure can be reflected on physical health along with time accumulation, wherein the most intuitive and obvious skin surface is mainly reflected on that the skin surface is dried due to water loss, skin is aged, wrinkles, color spots and the like are generated.
In order to alleviate the negative effects of life and work stress on the body, facial films are the most common method of female skin care. The types of facial masks in the market are various, however, the existing facial masks mostly utilize the direct absorption of the skin to nutrient solution in the facial mask, but the absorption effect is usually low, so that the maintenance effect of the facial mask is not ideal.
It is pointed out that the regeneration and repair of skin tissue can be promoted by providing an external magnetic field through an external magnetic therapeutic instrument. Related products such as corresponding magnetic therapeutic instruments also appear on the market, but the price of the products is relatively high, which is not beneficial to popularization.
The research results also indicate that the magnetic nano particles are directly added into the facial mask, so that the absorption of the skin to the nutrient components in the facial mask slurry can be promoted by utilizing the magnetic nano particles in the facial mask. However, the magnetic nanoparticles are directly added, the magnetic pole direction is disordered, and the generated micro magnetic field is unstable, so that the effect is not ideal.
Therefore, the invention aims to provide a moisturizing mask capable of effectively promoting the absorption of various nutrients and moisture in the mask by skin.
Disclosure of Invention
In order to solve the problem of insufficient absorbability in the existing mask product, the invention provides the moisturizing mask containing the nano magnetic array particles and the preparation method thereof, wherein the moisturizing mask can effectively promote the absorption of various nutrients and moisture in the mask by skin.
The invention comprises the following three steps:
1. preparation of nano magnetic array particles
Sodium borohydride (NaBH) 4 ) Mixing the aqueous solution of iron chloride and the aqueous solution of the iron chloride according to the volume ratio of 1:1, regulating the pH value of the mixed solution to be 12-14 by using sodium hydroxide, then placing the mixed solution into a reaction kettle, applying an external magnetic field along the vertical direction of the reaction kettle, and then carrying out hydrothermal reaction for 15-25h at 160-180 ℃ to obtain Fe with a one-dimensional chain structure 3 O 4 After the reaction, the nano array particles are naturally cooled to room temperature, and then the NdFeB permanent magnet is utilized to lead Fe with one-dimensional chain structure 3 O 4 The nano array particles are separated and collected, and deionized water and anhydrous water are sequentially usedWashing with ethanol for later use.
2. Magnetic field induced one-dimensional chain structure Fe 3 O 4 The nano array particles are arranged on the surface of the carbon fiber mask substrate in a directional array manner
Spreading the carbon fiber mask substrate at the bottom of the container, and applying an external magnetic field outside the bottom of the container; fe of one-dimensional chain structure obtained in the first step 3 O 4 Ultrasonically dispersing nano array particles in ethanol solution to obtain 50-100g/L suspension, injecting the suspension into the container to enable the suspension to be soaked in the tiled carbon fiber mask substrate, standing and air-drying to obtain Fe loaded with one-dimensional chain-like structures in directional array arrangement 3 O 4 Carbon fiber mask base material of nano array particles.
3. Applying mask slurry
And (3) flatly paving the carbon fiber mask substrate obtained in the step two in a grouting mold, then injecting mask slurry into the grouting mold, enabling the mask slurry to permeate into the whole carbon fiber mask substrate, and then taking out the mask.
Further, in the first step, the sodium borohydride (NaBH 4 ) The concentration of the aqueous solution of ferric chloride is 20-50g/L, and the concentration of the aqueous solution of ferric chloride is 15-40g/L.
In the first step, the external magnetic field is 0.2-0.4T, and the external magnetic field is applied by arranging an NdFeB permanent magnet at the upper part and the lower part of the reaction kettle respectively.
Further, in the second step, the magnitude of the external magnetic field is 0.2-0.4T.
In the second step, the carbon fiber mask substrate is a black carbon fiber spunlaced nonwoven fabric.
Further, in the third step, the mask slurry comprises the following components in parts by weight in 100 parts by weight:
10-15 parts of glycerin, 0.5-2 parts of sodium hyaluronate, 1-10 parts of poloxamer, 0.05-0.2 part of acetyl tetrapeptide, 0.05-0.2 part of palmitoyl tripeptide, 0.2-1 part of dendrobium candidum extract, 0.02-0.08 part of triethanolamine, 0.3-0.8 part of mannitol, 0.5-1 part of xanthan gum, 0.2-1 part of polysorbate, 0.5-4 parts of propylene glycol, 15.5-23.5 parts of silicone oil-based oily phase and the balance of water.
According to the invention, the nano magnetic array particles arranged in the directional array are directly added into the mask, so that the uniform magnetic field effect generated by the nano magnetic array particles can be fully utilized, the repair and regeneration of subcutaneous tissues inside the skin can be promoted, and no extra external magnetic field equipment is needed. Meanwhile, the uniform magnetic field generated by the nano magnetic array particles is beneficial to promoting the matching of components such as silicone oil, glycerol, sodium hyaluronate, acetyl tetrapeptide, palmitoyl tripeptide and the like in the mask slurry, enhancing the activity of the components, further promoting the permeation of the components to the skin, achieving the effect of increasing the absorption of the nutrients by the skin, particularly the absorption of glycerol, and playing a role in better skin care effect.
In the invention, the added magnetic particles are Fe with one-dimensional chain structure 3 O 4 Nano-array particles prepared by preparing Fe 3 O 4 Applying an external magnetic field directed during the process of the nanoparticles, so that the magnetic Fe 3 O 4 The nano particles are easy to be connected along the direction of the easy magnetization axis to grow in a chain shape, and the obtained Fe with one-dimensional chain-shaped structure 3 O 4 Compared with common Fe3O4 nano particles, the nano array particles can provide more effective micro magnetic fields, are more beneficial to promoting the repair and regeneration of subcutaneous tissues and are more beneficial to promoting the absorption of nutrient components in facial mask slurry.
In the invention, fe with one-dimensional chain structure is applied to the surface of the carbon fiber mask substrate 3 O 4 In the process of nano array particles, a magnetic field with the same degree is applied to the carbon fiber mask substrate, so that Fe with a one-dimensional chain structure can be ensured 3 O 4 The nano array particles are uniformly distributed on the carbon fiber mask substrate in an oriented array manner, so that the uniform and oriented micro magnetic field can be applied to the surface of the facial mask product, which is beneficial to the uniform absorption of the skin to the nutrient components in the facial mask slurry.
Detailed Description
The following examples are illustrative of the invention and are not intended to limit the scope of the invention.
Example 1
The preparation method of the moisturizing mask containing the nano magnetic array particles comprises the following three steps:
1. preparation of nano magnetic array particles
Sodium borohydride (NaBH) at a concentration of 30g/L 4 ) Mixing the aqueous solution of 30g/L ferric chloride with the volume ratio of 1:1, regulating the pH value of the mixed solution to be 14 by sodium hydroxide, then placing the mixed solution in a reaction kettle, applying an external magnetic field with the magnetic field strength of 0.28T along the vertical direction of the reaction kettle by arranging an NdFeB permanent magnet at the upper part and the lower part of the reaction kettle respectively, and then carrying out hydrothermal reaction for 18h at 180 ℃ to obtain Fe with a one-dimensional chain structure 3 O 4 After the reaction, the nano array particles are naturally cooled to room temperature, and then the NdFeB permanent magnet is utilized to lead Fe with one-dimensional chain structure 3 O 4 The nano array particles are separated and collected and washed by deionized water and absolute ethyl alcohol in sequence for standby.
2. Magnetic field induced one-dimensional chain structure Fe 3 O 4 The nano array particles are arranged on the surface of the carbon fiber mask substrate in a directional array manner
The black carbon fiber spunlaced non-woven fabric is flatly paved at the bottom of the container, and an external magnetic field with the magnetic field strength of 0.28T is applied to the outer side of the bottom of the container; fe of one-dimensional chain structure obtained in the first step 3 O 4 Dispersing nano array particles in ethanol solution by ultrasonic to obtain suspension with the concentration of 80g/L, injecting the suspension into the container to enable the suspension to be soaked in tiled black carbon fiber spun-laced non-woven fabric, standing and air-drying to obtain Fe loaded with one-dimensional chain-like structures arranged in a directional array 3 O 4 Black carbon fiber spun-laced nonwoven fabric of nano array particles.
3. Applying mask slurry
Flatly paving the black carbon fiber spun-laced non-woven fabric obtained in the second step in a grouting mold, then injecting the mask slurry into the grouting mold to enable the mask slurry to permeate into the whole black carbon fiber spun-laced non-woven fabric, and then taking out the mask.
The mask slurry comprises the following components in parts by weight:
12 parts of glycerin, 0.5 part of sodium hyaluronate, 5 parts of poloxamer, 0.05 part of acetyl tetrapeptide, 0.2 part of palmitoyl tripeptide, 0.5 part of dendrobium candidum extract, 0.04 part of triethanolamine, 0.8 part of mannitol, 0.5 part of xanthan gum, 0.5 part of polysorbate, 2 parts of propylene glycol, 18.8 parts of silicone oil-based oily phase and the balance of water.
Example 2
The preparation method of the moisturizing mask containing the nano magnetic array particles comprises the following three steps:
1. preparation of nano magnetic array particles
Sodium borohydride (NaBH) at a concentration of 40g/L 4 ) Mixing the aqueous solution of 35g/L ferric chloride with the volume ratio of 1:1, regulating the pH value of the mixed solution to be 13 by sodium hydroxide, then placing the mixed solution in a reaction kettle, applying an external magnetic field with the magnetic field strength of 0.35T along the vertical direction of the reaction kettle by arranging an NdFeB permanent magnet at the upper part and the lower part of the reaction kettle respectively, and then carrying out hydrothermal reaction for 22h at 180 ℃ to obtain Fe with a one-dimensional chain structure 3 O 4 After the reaction, the nano array particles are naturally cooled to room temperature, and then the NdFeB permanent magnet is utilized to lead Fe with one-dimensional chain structure 3 O 4 The nano array particles are separated and collected and washed by deionized water and absolute ethyl alcohol in sequence for standby.
2. Magnetic field induced one-dimensional chain structure Fe 3 O 4 The nano array particles are arranged on the surface of the carbon fiber mask substrate in a directional array manner
The black carbon fiber spunlaced non-woven fabric is flatly paved at the bottom of the container, and an external magnetic field with the magnetic field strength of 0.35T is applied to the outer side of the bottom of the container; fe of one-dimensional chain structure obtained in the first step 3 O 4 The nano array particles are dispersed in ethanol solution by ultrasonic to obtain suspension with the concentration of 80g/L, and then the suspension is injected into the containerThe suspension liquid is enabled to permeate through the tiled black carbon fiber spunlaced non-woven fabric, then the non-woven fabric is stood and air-dried, and Fe with a one-dimensional chain structure which is arranged in a directional array is obtained 3 O 4 Black carbon fiber spun-laced nonwoven fabric of nano array particles.
3. Applying mask slurry
Flatly paving the black carbon fiber spun-laced non-woven fabric obtained in the second step in a grouting mold, then injecting the mask slurry into the grouting mold to enable the mask slurry to permeate into the whole black carbon fiber spun-laced non-woven fabric, and then taking out the mask.
The mask slurry comprises the following components in parts by weight:
15 parts of glycerin, 0.5 part of sodium hyaluronate, 3 parts of poloxamer, 0.05 part of acetyl tetrapeptide, 0.05 part of palmitoyl tripeptide, 0.4 part of dendrobium candidum extract, 0.02 part of triethanolamine, 0.3 part of mannitol, 1 part of xanthan gum, 0.8 part of polysorbate, 2 parts of propylene glycol, 21.5 parts of silicone oil-based oily phase and the balance of water.
Example 3
The preparation method of the moisturizing mask containing the nano magnetic array particles comprises the following three steps:
1. preparation of nano magnetic array particles
Sodium borohydride (NaBH) at a concentration of 50g/L 4 ) Mixing the aqueous solution of the ferric chloride with the concentration of 40g/L according to the volume ratio of 1:1, regulating the pH value of the mixed solution to be 14 by sodium hydroxide, then placing the mixed solution in a reaction kettle, applying an external magnetic field with the magnetic field strength of 0.4T along the vertical direction of the reaction kettle by arranging an NdFeB permanent magnet at the upper part and the lower part of the reaction kettle respectively, and then carrying out hydrothermal reaction for 25h at 180 ℃ to obtain the Fe with a one-dimensional chain-shaped structure 3 O 4 After the reaction, the nano array particles are naturally cooled to room temperature, and then the NdFeB permanent magnet is utilized to lead Fe with one-dimensional chain structure 3 O 4 The nano array particles are separated and collected and washed by deionized water and absolute ethyl alcohol in sequence for standby.
2. Magnetic field induced one-dimensional chain structure Fe 3 O 4 The nano array particles are arranged on the surface of the carbon fiber mask substrate in a directional array manner
Spreading the black carbon fiber spunlaced non-woven fabric on the bottom of a container, and applying an external magnetic field with the magnetic field strength of 0.4T on the outer side of the bottom of the container; fe of one-dimensional chain structure obtained in the first step 3 O 4 Dispersing nano array particles in ethanol solution by ultrasonic to obtain a suspension with the concentration of 70g/L, injecting the suspension into the container to enable the suspension to be soaked in tiled black carbon fiber spun-laced non-woven fabrics, standing and air-drying to obtain Fe loaded with one-dimensional chain-like structures in directional array arrangement 3 O 4 Black carbon fiber spun-laced nonwoven fabric of nano array particles.
3. Applying mask slurry
Flatly paving the black carbon fiber spun-laced non-woven fabric obtained in the second step in a grouting mold, then injecting the mask slurry into the grouting mold to enable the mask slurry to permeate into the whole black carbon fiber spun-laced non-woven fabric, and then taking out the mask.
The mask slurry comprises the following components in parts by weight:
10 parts of glycerin, 2 parts of sodium hyaluronate, 6 parts of poloxamer, 0.2 part of acetyl tetrapeptide, 0.1 part of palmitoyl tripeptide, 1 part of dendrobium candidum extract, 0.0 part of triethanolamine, 0.3 part of mannitol, 0.5 part of xanthan gum, 0.2 part of polysorbate, 0.5 part of propylene glycol, 23.5 parts of silicone oil-based oily phase and the balance of water.
Example 4
The preparation method of the moisturizing mask containing the nano magnetic array particles comprises the following three steps:
1. preparation of nano magnetic array particles
Sodium borohydride (NaBH) at a concentration of 25g/L 4 ) Mixing the aqueous solution of iron chloride with the concentration of 20g/L according to the volume ratio of 1:1, regulating the pH value of the mixed solution to be 12 by sodium hydroxide, then placing the mixed solution in a reaction kettle, and applying a NdFeB permanent magnet along the vertical direction of the reaction kettle by arranging a NdFeB permanent magnet at the upper part and the lower part of the reaction kettle respectivelyAn external magnetic field with the magnetic field strength of 0.25T is carried out for 15h by hydrothermal reaction at 160 ℃ to obtain Fe with a one-dimensional chain structure 3 O 4 After the reaction, the nano array particles are naturally cooled to room temperature, and then the NdFeB permanent magnet is utilized to lead Fe with one-dimensional chain structure 3 O 4 The nano array particles are separated and collected and washed by deionized water and absolute ethyl alcohol in sequence for standby.
2. Magnetic field induced one-dimensional chain structure Fe 3 O 4 The nano array particles are arranged on the surface of the carbon fiber mask substrate in a directional array manner
The black carbon fiber spunlaced non-woven fabric is flatly paved at the bottom of the container, and an external magnetic field with the magnetic field strength of 0.25T is applied to the outer side of the bottom of the container; fe of one-dimensional chain structure obtained in the first step 3 O 4 Dispersing nano array particles in ethanol solution by ultrasonic to obtain a suspension with the concentration of 50g/L, injecting the suspension into the container to enable the suspension to be soaked in tiled black carbon fiber spun-laced non-woven fabrics, standing and air-drying to obtain Fe loaded with one-dimensional chain-like structures in directional array arrangement 3 O 4 Black carbon fiber spun-laced nonwoven fabric of nano array particles.
3. Applying mask slurry
Flatly paving the black carbon fiber spun-laced non-woven fabric obtained in the second step in a grouting mold, then injecting the mask slurry into the grouting mold to enable the mask slurry to permeate into the whole black carbon fiber spun-laced non-woven fabric, and then taking out the mask.
The mask slurry comprises the following components in parts by weight:
12 parts of glycerin, 0.5 part of sodium hyaluronate, 5 parts of poloxamer, 0.05 part of acetyl tetrapeptide, 0.2 part of palmitoyl tripeptide, 1 part of dendrobium candidum extract, 0.0 part of triethanolamine, 0.3 part of mannitol, 0.5 part of xanthan gum, 0.2 part of polysorbate, 0.5 part of propylene glycol, 23.5 parts of silicone oil-based oily phase and the balance of water.
Claims (7)
1. A preparation method of a moisturizing mask containing nano magnetic array particles comprises the following steps:
1. preparation of nano magnetic array particles
Sodium borohydride (NaBH) 4 ) Mixing the aqueous solution of iron chloride and the aqueous solution of the iron chloride according to the volume ratio of 1:1, regulating the pH value of the mixed solution to be 12-14 by using sodium hydroxide, then placing the mixed solution into a reaction kettle, applying an external magnetic field along the vertical direction of the reaction kettle, and then carrying out hydrothermal reaction for 15-25h at 160-180 ℃ to obtain Fe with a one-dimensional chain structure 3 O 4 After the reaction, the nano array particles are naturally cooled to room temperature, and then the NdFeB permanent magnet is utilized to lead Fe with one-dimensional chain structure 3 O 4 The nano array particles are separated and collected and washed by deionized water and absolute ethyl alcohol in sequence for standby;
2. magnetic field induced one-dimensional chain structure Fe 3 O 4 The nano array particles are arranged on the surface of the carbon fiber mask substrate in a directional array manner
Spreading the carbon fiber mask substrate at the bottom of the container, and applying an external magnetic field outside the bottom of the container; fe of one-dimensional chain structure obtained in the first step 3 O 4 Ultrasonically dispersing nano array particles in ethanol solution to obtain 50-100g/L suspension, injecting the suspension into the container to enable the suspension to be soaked in the tiled carbon fiber mask substrate, standing and air-drying to obtain Fe loaded with one-dimensional chain-like structures in directional array arrangement 3 O 4 Carbon fiber mask base material of nano array particles;
3. applying mask slurry
And (3) flatly paving the carbon fiber mask substrate obtained in the step two in a grouting mold, then injecting mask slurry into the grouting mold, enabling the mask slurry to permeate into the whole carbon fiber mask substrate, and then taking out the mask.
2. The method of claim 1, wherein in the first step, the sodium borohydride (NaBH 4 ) The concentration of the aqueous solution of ferric chloride is 20-50g/L, and the concentration of the aqueous solution of ferric chloride is 15-40g +.L。
3. The method for preparing a moisturizing mask containing nano-magnetic array particles according to claim 2, wherein in the first step, the external magnetic field is 0.2-0.4T, and the external magnetic field is applied by arranging an NdFeB permanent magnet at the upper part and the lower part of the reaction kettle respectively.
4. The method of claim 3, wherein in the second step, the external magnetic field has a magnitude of 0.2-0.4T.
5. The method of claim 4, wherein in the second step, the carbon fiber mask substrate is a black carbon fiber spun-laced nonwoven fabric.
6. The method for preparing a moisturizing mask containing nano magnetic array particles according to claim 5, wherein in the third step, the mask slurry comprises the following components in parts by weight as 100 parts: 10-15 parts of glycerin, 0.5-2 parts of sodium hyaluronate, 1-10 parts of poloxamer, 0.05-0.2 part of acetyl tetrapeptide, 0.05-0.2 part of palmitoyl tripeptide, 0.2-1 part of dendrobium candidum extract, 0.02-0.08 part of triethanolamine, 0.3-0.8 part of mannitol, 0.5-1 part of xanthan gum, 0.2-1 part of polysorbate, 0.5-4 parts of propylene glycol, 15.5-23.5 parts of silicone oil-based oily phase and the balance of water.
7. A moisturizing mask containing nano-magnetic array particles, characterized by being prepared by the preparation method of any one of claims 1-6.
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| CN104666099A (en) * | 2015-03-13 | 2015-06-03 | 雅弗生物实验室有限公司(加拿大) | Carbon fiber skin-beautifying membrane substrate and preparation method thereof |
| CN111467281A (en) * | 2020-05-29 | 2020-07-31 | 蒋艳伟 | Anti-allergy moisturizing facial mask prepared from active polypeptide and hyaluronic acid and preparation method of anti-allergy moisturizing facial mask |
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| ITMI20072098A1 (en) * | 2007-10-30 | 2009-04-30 | Dermophisiologique S R L | A COSMETIC COMPOSITION BASED ON A MAGNETIC OR MAGNETIZABLE MATERIAL, ITS PREPARATION AND ITS USE FOR CLEANING THE EPIDERMIDAL |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104666099A (en) * | 2015-03-13 | 2015-06-03 | 雅弗生物实验室有限公司(加拿大) | Carbon fiber skin-beautifying membrane substrate and preparation method thereof |
| CN111467281A (en) * | 2020-05-29 | 2020-07-31 | 蒋艳伟 | Anti-allergy moisturizing facial mask prepared from active polypeptide and hyaluronic acid and preparation method of anti-allergy moisturizing facial mask |
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| Assessment of the moisturizing properties of a magnetic mask containing iron oxide particles;Paula Montoya，etal.;《Journal of cosmetic dermatology》;20191231;第835-842页 * |
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Effective date of registration: 20231101 Address after: A307-308, Building 2, No. 452, 6th Street, Baiyang Street, Qiantang District, Hangzhou City, Zhejiang Province, 310000 Patentee after: Lefu Biotechnology (Hangzhou) Co.,Ltd. Address before: Room 309, 3 / F, No.2 building, Qianwan bonded port area, Qingdao area, China (Shandong) pilot Free Trade Zone, Qingdao, Shandong Province Patentee before: Qingdao zizhiyan cosmetics technology Co.,Ltd. |