CN112043620A - Silk mask - Google Patents
Silk mask Download PDFInfo
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- CN112043620A CN112043620A CN202010886055.2A CN202010886055A CN112043620A CN 112043620 A CN112043620 A CN 112043620A CN 202010886055 A CN202010886055 A CN 202010886055A CN 112043620 A CN112043620 A CN 112043620A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/733—Alginic acid; Salts thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
- A61K8/987—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/42—Micas ; Interstratified clay-mica products
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/85—Products or compounds obtained by fermentation, e.g. yoghurt, beer, wine
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
Abstract
The invention relates to the technical field of cosmetics, in particular to an improved silk mask with high moisture retention, which comprises a silk substrate and a mask essence, wherein the preparation method of the silk substrate comprises the following steps: 1) soaking mulberry silk with sericin content less than 3 wt% in ethanol aqueous solution of lithium bromide for 6-8h to obtain expanded silk; 2) ultrasonically activating the expanded silk and the modified vermiculite in a solvent in the presence of an activating agent and a cross-linking agent to obtain modified expanded silk; 3) and carding and lapping the modified expanded silk to prepare the silk matrix. The silk mask provided by the invention is rich in nutrition, is easy to absorb by skin, and has excellent moisturizing effect.
Description
Technical Field
The invention relates to the technical field of cosmetics, and particularly relates to a silk mask.
Background
The facial mask is a special cosmetic, and is applied on facial skin to form a film to isolate skin from the outside, and the effective components in the facial mask can permeate into skin to moisten skin, increase nutrition, and promote skin skill and metabolism, so that the facial skin is white, soft, comfortable, and youthful. The mask has the functions of nourishing and cleaning skin, is considered as a first aid expert of the skin, and can provide the most sufficient nutrients for the skin in the shortest time to recover the vitality of the skin. The skin care mask is periodically adhered to make the skin more delicate and smooth, and can effectively reduce wrinkles and slow down aging.
The silk mask mainly comprises silk fibers and active silk protein. The silk mask is a bionic dermis, namely a silk film, used for treating scalds in the medical field. Since the fibroin contains 18 amino acids (10 times of pearl powder content) which have great nutritive value for human bodies, the fibroin belongs to a porous substance, has good air permeability and excellent water absorption, is widely used in wound dressings after operations and burn wound dressings in the United states and Japan, is beneficial to wound healing and has no stimulation, and is called as 'artificial skin'.
Nowadays, modern's rhythm of life is faster and faster, and pressure is also bigger and bigger, sleep the not good phenomenon that has become modern often, add people in the air conditioning environment for a long time in addition, in the environment, the skin lack of water is serious, skin is ageing very easily, moisturizing problem to skin also becomes the focus of our research gradually, in addition, though rich abundant nutrient substance on the silk facial mask, skin is limited to these nutrient substance's absorption, the moisturizing effect that leads to these silk facial masks receives the restriction, the moisturizing effect that leads to current facial mask moisturizing can't satisfy our demand.
Disclosure of Invention
The invention aims to overcome the problems in the prior art and provides a silk mask which is rich in nutrition, easy to absorb by skin and excellent in moisturizing effect.
In order to achieve the above object, the invention provides a silk mask, which comprises a silk matrix and a mask essence, and is characterized in that the preparation method of the silk matrix comprises the following steps:
1) soaking mulberry silk with sericin content less than 3 wt% in ethanol aqueous solution of lithium bromide for 6-8h to obtain expanded silk; and
stirring vermiculite in water for 30-90min at 70-90 ℃, adding a silane coupling agent, performing ultrasonic reaction for 2-5h at 70-90 ℃, then preserving heat for 12-24h at 70-90 ℃, and then soaking in acid for activation to obtain modified vermiculite;
2) ultrasonically activating the expanded silk and the modified vermiculite in a solvent in the presence of an activating agent and a cross-linking agent to obtain modified expanded silk;
3) and carding and lapping the modified expanded silk to prepare the silk matrix.
The vermiculite has the function of heat preservation, and the modified vermiculite is added into the silk matrix, so that heat generated by zeolite can be preserved when the facial mask is applied, the absorption of skin on active substances is further promoted, and the efficacy of the facial mask is improved.
According to the present invention, under the preferred conditions, in step (1), the aqueous ethanolic solution of lithium bromide has a weight concentration of lithium bromide ranging from 15 to 25 wt%.
Preferably, the silane coupling agent is at least one selected from the group consisting of gamma-chloropropyltrimethoxysilane, gamma-chloropropyltriethoxysilane, gamma-chloropropylmethyldimethoxysilane, gamma-chloropropylmethyldiethoxysilane, gamma-mercaptopropyltrimethoxysilane and gamma-mercaptopropyltriethoxysilane.
In the step (2), the activator is at least one selected from the group consisting of diaminodipropylimine, hexamethylenediamine and ethylenediamine.
In step (2), the cross-linking agent is glutaraldehyde.
The high-moisture tencel facial mask comprises a silk substrate and facial mask essence, wherein the facial mask essence comprises the following components in parts by weight: 0.05-0.8 part of graphene aqueous solution, 0.05-0.8 part of skin repair agent, 0.1-0.8 part of resveratrol, 0.3-1.5 parts of transdermal peptide EFG, 0.2-3 parts of allantoin, 0.1-2.8 parts of sodium alginate, 0.3-2.5 parts of plant essential oil, 1-10 parts of hyaluronic acid, 2-15 parts of modified zeolite, 5-20 parts of rice washing water fermentation liquor and 1-20 parts of glycerol.
In the invention, the graphene aqueous solution is compounded with resveratrol and hyaluronic acid, and the transdermal peptide EFG and allantoin are used as auxiliary materials, so that active ingredients can enter the deep layer of the skin, the active ingredients are effectively released, subcutaneous fibrous tissues are activated, in addition, fibroin in the silk matrix can form a compact protein film on the surface layer of the skin, the effect of isolating air oxidation for the skin is achieved, the active ingredients in the facial mask essence are absorbed by the skin to the maximum extent, the absorption efficiency of the skin on the active ingredients is improved, the effect of the active ingredients is exerted to the maximum extent, the damaged cells of the skin are effectively repaired, and the occurrence of fine wrinkles of the skin is reduced; when the skin is in a conjunctiva on the surface layer, the volatilization of the water on the surface layer of the skin is reduced, and a good moisturizing effect is achieved.
According to the invention, in order to further improve the efficacy of the silk mask, the mask essence comprises the following components under the preferable conditions: 0.1-0.5 part of graphene aqueous solution, 0.1-0.6 part of skin repair agent, 0.2-0.5 part of resveratrol, 0.8-1.2 parts of transdermal peptide EFG, 0.6-2.2 parts of allantoin, 0.2-2.3 parts of sodium alginate, 0.5-2 parts of plant essential oil, 3-8 parts of hyaluronic acid, 3-10 parts of modified zeolite, 10-15 parts of rice washing water fermentation liquor and 3-18 parts of glycerol.
According to the present invention, the method for preparing the rice-washing water fermentation broth comprises: washing 1kg of rice with water, soaking in 5L of water, adding 30-50g of pericarpium Citri Tangerinae, fermenting at 30-50 deg.C for 10-30 days, and collecting supernatant.
According to the invention, the graphene can kill bacteria on the surface of the skin, accelerate metabolism of the skin and promote absorption of active ingredients by the skin, if the concentration of the graphene is too low, the graphene cannot achieve an ideal effect, and if the concentration of the graphene is too high, on one hand, the graphene self generates a agglomeration phenomenon, on the other hand, the graphene can adsorb other active ingredients in the mask, so that the efficacy of the mask is reduced, and under the preferable condition, the concentration of the graphene is 5-16 mg/L.
According to the present invention, in order to improve the repair ability of the silk mask, it is preferable that the skin repair agent is at least one selected from the group consisting of glycine, alanine, valine, isoleucine, leucine, proline, arginine, aspartic acid, glutamic acid, L-threonine, citric acid, and betaine.
According to the present invention, preferably, the plant essential oil is at least one selected from the group consisting of rose essential oil, camellia essential oil, lemon essential oil, lavender essential oil, calendula oil and geranium essential oil, and the addition of the plant essential oil can be adjusted according to the fragrance of the essential oil and the efficacy of the essential oil, which is not described herein again.
According to the invention, the zeolite in the mask liquid is mixed with water after adsorbing a large amount of alcohol solvent to release heat, and the released heat can heat the mask essence, so that skin pores can be opened while the mask is applied, the absorption of skin to active substances is promoted, and the efficacy of the mask is improved. In order to control the heat release speed of the zeolite, avoid too slow heat release to play a role in heating or too fast heat release, which results in short heating time and damage to skin, the zeolite is preferably modified, and the modification method of the zeolite comprises the following steps:
and carrying out acid treatment on the zeolite powder, and carrying out modification reaction on the zeolite powder and a crown ether reagent under an ultrasonic condition to obtain the modified zeolite.
Further, the modification method of the zeolite comprises the following steps: soaking the zeolite powder in an acid solution for 30-90min, then roasting at the temperature of 300-450 ℃ for 1-5h, and then carrying out ultrasonic reaction on the roasted product and a crown ether reagent at the temperature of 60-100 ℃ for 2-8h to obtain the modified zeolite powder.
More preferably, the zeolite powder has a particle size of 20 to 100 μm, and more preferably 30 to 60 μm.
Further preferably, the crown ether reagent is selected from aza-15-crown-5, aza-18-crown-6, aza-21-crown-7, aza-24-crown-8, diaza-15-crown-5, diaza-18-crown-6, diaza-21-crown-7, diaza-24-crown-8, aminobenzo-15-crown-5, aminobenzo-18-crown-6, aminobenzo-21-crown-7, aminobenzo-24-crown-8, aminoholothia-15-crown-5, aminoholothia-18-crown-6, Aza-21-crown-6, Aza-, At least one of aminobenzothiocrowth ethers.
According to the invention, in the silk mask, the weight ratio of the modified vermiculite to the modified zeolite is 1:1-3 under the preferable conditions.
According to the present invention, the mask essence further comprises an auxiliary agent commonly known to those skilled in the art, such as at least one of a preservative, a thickener, a pH adjuster and a humectant, and further, the preservative is at least one selected from diazolidinyl urea, methylparaben and phenoxyethanol; the pH regulator is triethanolamine; the thickener can be xanthan gum and carbomer; the humectant may be at least one of polyethylene glycol, polypropylene glycol, butylene glycol, propylene glycol, hexylene glycol, xylitol, sorbitol, and the like.
When the silk mask is stored, the silk matrix is soaked in 1-2 times of water, the mask essence is stored separately, and when the silk mask is used, the silk matrix is soaked in the mask essence for 2-3min and then used.
According to the technical scheme, the graphene aqueous solution is compounded with the resveratrol and the hyaluronic acid, and the transdermal peptide EFG and the allantoin are used as auxiliary materials, so that the active ingredients can enter the deep layer of the skin, the active ingredients are effectively released, the subcutaneous fibrous tissue is activated, in addition, the fibroin in the silk matrix can form a compact protein film on the surface layer of the skin, the effect of isolating air oxidation for the skin is achieved, the active ingredients in the facial mask essence are absorbed by the skin to the maximum extent, the absorption efficiency of the skin on the active ingredients is improved, the effect of the active ingredients is exerted to the maximum extent, the damaged cells of the skin are effectively repaired, and the occurrence of fine wrinkles of the skin is reduced; when the skin is in a conjunctiva on the surface layer, the volatilization of the water on the surface layer of the skin is reduced, and a good moisturizing effect is achieved.
Detailed Description
The endpoints of the ranges and any values disclosed herein are not limited to the precise range or value, and such ranges or values should be understood to encompass values close to those ranges or values. For ranges of values, between the endpoints of each of the ranges and the individual points, and between the individual points may be combined with each other to give one or more new ranges of values, and these ranges of values should be considered as specifically disclosed herein.
The present invention will be described in detail below by way of examples.
In the following examples, the preparation method of the rice washing water comprises: washing 1kg of rice with water, soaking in 5L of water, adding 40g of pericarpium Citri Tangerinae, fermenting at 45 deg.C for 30 days, and collecting supernatant.
The concentration of the graphene aqueous solution is 10 mg/L.
Example 1
The high-moisture tencel facial mask comprises a silk substrate and facial mask essence, wherein the facial mask essence comprises the following components in parts by weight: 0.2 part by weight of graphene aqueous solution, 0.5 part by weight of glycine, 0.3 part by weight of resveratrol, 1 part by weight of transdermal peptide EFG, 1.5 parts by weight of allantoin, 2.1 parts by weight of sodium alginate, 1.5 parts by weight of rose essential oil, 5 parts by weight of hyaluronic acid, 8 parts by weight of modified zeolite, 12 parts by weight of rice washing water fermentation liquor, 15 parts by weight of glycerol, 0.05 part by weight of methylparaben, 0.3 part by weight of polyethylene glycol, 0.5 part by weight of polypropylene glycol and 5 parts by weight of carbomer.
The preparation method of the silk mask comprises the following steps:
(1) preparing facial mask essence:
soaking zeolite powder (with particle size of 30-50 μm) in 1mol/L hydrochloric acid solution for 60min, centrifuging, washing, drying, calcining acidified zeolite powder at 400 deg.C for 2h, and ultrasonically reacting the calcined product with amino holothia-18-crown ether-6 at 90 deg.C for 5h to obtain modified zeolite powder;
ultrasonically dispersing graphene water solution, glycine, resveratrol, transdermal peptide EFG, allantoin, sodium alginate, rose essential oil, hyaluronic acid, modified zeolite, rice washing water fermentation liquor, glycerol, methyl hydroxybenzoate, polyethylene glycol, polypropylene glycol and carbomer uniformly, and then adding a pH regulator to adjust the pH to be neutral to obtain mask essence;
(2) preparing a silk matrix:
1) soaking mulberry silk with sericin content less than 3 wt% in lithium bromide ethanol water solution (lithium bromide 20 wt%, ethanol 25 wt%, water 55 wt%) for 8h to obtain expanded silk; and
stirring vermiculite in water for 75min at 80 ℃, adding gamma-chloropropyl methyl diethoxy silane, performing ultrasonic reaction for 4h at 80 ℃, keeping the ultrasonic power at 400W, then preserving the heat at 80 ℃ for 20h, and then soaking in 1mol/L hydrochloric acid solution for 60min to obtain modified vermiculite;
2) uniformly mixing 10mL of ethylenediamine and 3mL of glutaraldehyde in 100mL of water to obtain a mixed solution; ultrasonically activating the expanded silk and the modified vermiculite (the weight ratio of vermiculite to the expanded silk is 1:50) in a mixed solution for 2.5 hours at 750 ℃ with the ultrasonic power of 500W to obtain the modified expanded silk;
3) and carding and lapping the modified expanded silk to prepare the silk matrix.
Example 2
The high-moisture tencel facial mask comprises a silk substrate and facial mask essence, wherein the facial mask essence comprises the following components in parts by weight: 0.1 part by weight of graphene water solution, 0.6 part by weight of isoleucine, 0.5 part by weight of resveratrol, 0.8 part by weight of transdermal peptide EFG, 2.2 parts by weight of allantoin, 0.2 part by weight of sodium alginate, 2 parts by weight of calendula oil, 3 parts by weight of hyaluronic acid, 10 parts by weight of modified zeolite, 5 parts by weight of rice washing water fermentation liquor, 3 parts by weight of glycerol, 0.05 part by weight of methylparaben, 0.3 part by weight of polyethylene glycol, 0.5 part by weight of polypropylene glycol and 5 parts by weight of carbomer.
The preparation method of the silk mask is the same as that of example 1.
Example 3
The high-moisture tencel facial mask comprises a silk substrate and facial mask essence, wherein the facial mask essence comprises the following components in parts by weight: 0.5 part by weight of graphene aqueous solution, 0.1 part by weight of valine, 0.2 part by weight of resveratrol, 01.2 parts by weight of transdermal peptide EFG, 0.6 part by weight of allantoin, 2.3 parts by weight of sodium alginate, 0.5 part by weight of calendula oil, 8 parts by weight of hyaluronic acid, 3 parts by weight of modified zeolite, 1 part by weight of rice washing water fermentation liquor, 18 parts by weight of glycerol, 0.05 part by weight of methyl hydroxybenzoate, 0.3 part by weight of polyethylene glycol, 0.5 part by weight of polypropylene glycol and 5 parts by weight of carbomer.
The preparation method of the silk mask is the same as that of example 1.
Example 4
The high-moisture tencel facial mask comprises a silk substrate and facial mask essence, wherein the facial mask essence comprises the following components in parts by weight: 0.05 part of graphene aqueous solution, 0.05 part of proline, 0.1 part of resveratrol, 0.3 part of transdermal peptide EFG, 0.2 part of allantoin, 2.8 parts of sodium alginate, 0.3 part of camellia essential oil, 10 parts of hyaluronic acid, 2 parts of modified zeolite, 5 parts of rice washing water fermentation liquor, 1 part of glycerol, 0.05 part of methyl hydroxybenzoate, 0.3 part of polyethylene glycol, 0.5 part of polypropylene glycol and 5 parts of carbomer.
The preparation method of the silk mask is the same as that of example 1.
Example 5
The high-moisture tencel facial mask comprises a silk substrate and facial mask essence, wherein the facial mask essence comprises the following components in parts by weight: 0.8 part of graphene aqueous solution, 0.8 part of aspartic acid, 0.8 part of resveratrol, 1.5 parts of transdermal peptide EFG, 3 parts of allantoin, 0.1 part of sodium alginate, 2.5 parts of camellia essential oil, 1 part of hyaluronic acid, 15 parts of modified zeolite, 1 part of rice washing water fermentation liquor, 20 parts of glycerol, 0.05 part of methylparaben, 0.3 part of polyethylene glycol, 0.5 part of polypropylene glycol and 5 parts of carbomer.
The preparation method of the silk mask is the same as that of example 1.
Example 6
The process of example 1 was followed except that: the modification method of the zeolite comprises the following steps: soaking zeolite powder (with particle size of 30-50 μm) in 1mol/L hydrochloric acid solution for 60min, centrifuging, washing, drying, calcining the acidified zeolite powder at 300-450 deg.C for 1-5h, and performing ultrasonic reaction on the calcined product at 60-100 deg.C for 2-8h to obtain the modified zeolite powder.
Example 7
The procedure of example 1 was followed except that the zeolite was not modified.
Example 8
The process of example 1 was followed except that no zeolite was added.
Example 9
The procedure of example 1 was followed except that the vermiculite was modified by the following method:
soaking vermiculite in 1mol/L hydrochloric acid solution at 80 deg.C for 60min to obtain modified vermiculite.
Example 10
The procedure of example 1 was followed except that vermiculite was not modified.
Example 11
The procedure of example 1 was followed except that vermiculite was not added.
Example 12
The procedure of example 1 was followed except that the swollen silk and modified vermiculite were directly subjected to ultrasonication without using ethylenediamine and glutaraldehyde.
Comparative example 1
The process of example 1 was followed except that zeolite and vermiculite were not included.
Test example
130 healthy female volunteers of 20-35 years old without allergic history were selected and divided into 13 groups of 10 persons each, and the mask samples prepared in examples 1-12 and comparative example 1 were tested, respectively. All subjects had signed an informed consent.
The silk mask is used: firstly, soaking a silk matrix in facial mask essence for 2-3min, then spraying a small amount of toning lotion on the face to keep the face moist, then applying the soaked silk matrix on the skin, and removing the facial mask after 10-20 min.
In the test, the left forearm of the subject was used as the test site, the mask sample was applied 1 time a day, gently massaged with a finger until complete absorption, and the skin reaction after 24 hours was observed using the right forearm itself as a blank control.
As a result: after detection, the product has good smell and stability, all subjects have no abnormal phenomena such as erythema and the like, and the result is still free of any reaction after continuous observation for 3-4 days, which indicates that the moisturizing mask prepared by the technical scheme is safe.
(1) The temperature of the silk mask applied to the face for 0min, 5min, 10 mm and 15min was recorded at room temperature of 25 ℃, the test was repeated 5 times each time, and the average value was obtained, and the experimental results are shown in table 1.
TABLE 1
| 0min/℃ | 5min/℃ | 10min/℃ | 15min/℃ | |
| Example 1 | 25.5 | 35.1 | 39.5 | 37.9 |
| Example 2 | 25.4 | 33.8 | 38.6 | 37.1 |
| Example 3 | 24.8 | 33.5 | 38.5 | 36.9 |
| Example 4 | 25.1 | 34.2 | 38.1 | 36.8 |
| Example 5 | 25.8 | 34.6 | 38.4 | 36.5 |
| Example 6 | 24.5 | 33.6 | 37.9 | 36.1 |
| Example 7 | 24.3 | 33.1 | 36.8 | 35.3 |
| Example 8 | 25.2 | 32.9 | 34.9 | 34.1 |
| Example 9 | 25.1 | 34.9 | 38.7 | 36.2 |
| Example 10 | 25.0 | 34.7 | 38.2 | 35.7 |
| Example 11 | 25.0 | 34.8 | 37.2 | 34.1 |
| Example 12 | 25.1 | 34.8 | 37.1 | 36.5 |
| Comparative example 1 | 25.3 | 34.2 | 36.7 | 34.9 |
During testing, the inner area of the left forearm of a subject is used as a tested part, the tested part is cleaned by clean water before testing and is stabilized for 30min before testing, the testing temperature is 20-25 ℃, the relative humidity is 50-60%, after the inner sides of the left forearm and the right forearm are respectively coated with a mask sample for 15min, the mask is taken down, the percentage content of moisture of each part at 0, 60 and 120min is measured by an intelligent moisture tester, the testing is repeated for 5 times every time, the average value is obtained, and the experimental result is shown in table 2.
TABLE 2
| 0min/％ | 60min/％ | 120min/％ | 240min/％ | |
| Example 1 | 69.5 | 69.3 | 67.6 | 63.9 |
| Example 2 | 69.3 | 69.1 | 68.3 | 62.1 |
| Example 3 | 68.5 | 68.1 | 67.2 | 61.5 |
| Example 4 | 68.3 | 67.2 | 65.2 | 59.6 |
| Example 5 | 68.1 | 67.6 | 65.7 | 57.5 |
| Example 6 | 67.2 | 65.3 | 63.2 | 52.8 |
| Example 7 | 66.3 | 63.8 | 61.7 | 51.9 |
| Example 8 | 62.9 | 62.7 | 61.9 | 52.0 |
| Example 9 | 68.0 | 65.7 | 61.9 | 52.1 |
| Example 10 | 67.5 | 64.6 | 60.7 | 51.5 |
| Example 11 | 63.6 | 62.1 | 58.7 | 56.7 |
| Example 12 | 65.9 | 63.6 | 61.0 | 52.6 |
| Comparative example 1 | 54.5 | 51.1 | 50.8 | 50.1 |
The preferred embodiments of the present invention have been described above in detail, but the present invention is not limited thereto. Within the scope of the technical idea of the invention, many simple modifications can be made to the technical solution of the invention, including combinations of various technical features in any other suitable way, and these simple modifications and combinations should also be regarded as the disclosure of the invention, and all fall within the scope of the invention.
Claims (10)
1. The silk mask comprises a silk substrate and mask essence, and is characterized in that the preparation method of the silk substrate comprises the following steps:
1) soaking mulberry silk with sericin content less than 3 wt% in ethanol aqueous solution of lithium bromide for 6-8h to obtain expanded silk;
2) ultrasonically activating the expanded silk and the modified vermiculite in a solvent in the presence of an activating agent and a cross-linking agent to obtain modified expanded silk;
3) and carding and lapping the modified expanded silk to prepare the silk matrix.
2. The silk mask pack of claim 1, wherein in step (1), the aqueous solution of lithium bromide in ethanol has a concentration of lithium bromide ranging from 15 to 25 wt%.
3. The silk mask according to claim 1 or 2, wherein the modified vermiculite is prepared by the following steps: stirring vermiculite in water for 30-90min at 70-90 ℃, adding a silane coupling agent, performing ultrasonic reaction for 2-5h at 70-90 ℃, then preserving heat for 12-24h at 70-90 ℃, and then soaking in acid for activation to obtain the modified vermiculite.
4. The silk mask according to any one of claims 1 to 3, wherein the activator is selected from at least one of diamino dipropyl imine, hexamethylene diamine and ethylene diamine; and/or
The cross-linking agent is glutaraldehyde.
5. The silk mask according to any one of claims 1 to 4, wherein the weight ratio of the modified vermiculite to the expanded silk is 1: 30-100.
6. The silk mask pack according to any one of claims 1 to 5, wherein the mask essence comprises, by weight: 0.05-0.8 part of graphene aqueous solution, 0.05-0.8 part of skin repair agent, 0.1-0.8 part of resveratrol, 0.3-1.5 parts of transdermal peptide EFG, 0.2-3 parts of allantoin, 0.1-2.8 parts of sodium alginate, 0.3-2.5 parts of plant essential oil, 1-10 parts of hyaluronic acid, 2-15 parts of modified zeolite, 1-5 parts of rice washing water fermentation liquor and 1-20 parts of glycerol.
7. The silk mask pack according to any one of claims 1 to 6, wherein the mask pack essence comprises: 0.1-0.5 part of graphene aqueous solution, 0.1-0.6 part of skin repair agent, 0.2-0.5 part of resveratrol, 0.8-1.2 parts of transdermal peptide EFG, 0.6-2.2 parts of allantoin, 0.2-2.3 parts of sodium alginate, 0.5-2 parts of plant essential oil, 3-8 parts of hyaluronic acid, 3-10 parts of modified zeolite, 1-5 parts of rice washing water fermentation liquor and 3-18 parts of glycerol.
8. The silk mask pack according to any one of claims 1 to 7, wherein the graphene is present at a concentration of 5 to 16 mg/L; and/or
The skin repair agent is at least one selected from the group consisting of glycine, alanine, valine, isoleucine, leucine, proline, arginine, aspartic acid, glutamic acid, L-threonine, citric acid, and betaine.
9. The silk mask of any of claims 1 to 8, wherein the plant essential oil is selected from at least one of rose essential oil, camellia essential oil, lemon essential oil, lavender essential oil, calendula essential oil and geranium essential oil.
10. The silk mask according to any one of claims 6 to 9, wherein the weight ratio of the modified vermiculite to the modified zeolite is 1: 1-3.
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