CN111979764A - 丙纶面料亲水剂 - Google Patents
丙纶面料亲水剂 Download PDFInfo
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- CN111979764A CN111979764A CN202010649937.7A CN202010649937A CN111979764A CN 111979764 A CN111979764 A CN 111979764A CN 202010649937 A CN202010649937 A CN 202010649937A CN 111979764 A CN111979764 A CN 111979764A
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- coconut oil
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 12
- -1 Polypropylene Polymers 0.000 title claims abstract description 10
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 10
- 239000004744 fabric Substances 0.000 title claims abstract description 10
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000003756 stirring Methods 0.000 claims abstract description 17
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 14
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 14
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000005642 Oleic acid Substances 0.000 claims abstract description 14
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 14
- 239000003054 catalyst Substances 0.000 claims abstract description 14
- 235000019864 coconut oil Nutrition 0.000 claims abstract description 14
- 239000003240 coconut oil Substances 0.000 claims abstract description 14
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 14
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 14
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 14
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 14
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 14
- 239000008117 stearic acid Substances 0.000 claims abstract description 14
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 235000021313 oleic acid Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000007547 defect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明涉及一种丙纶面料亲水剂,按照重量份数计,它包括(1)油酸35‑50份;(2)硬脂酸30‑45份;(3)椰油酸28‑40份;(4)甲氧基封端聚氧乙烯聚氧丙烯基醚15‑25份;(5)催化剂5‑10份;其制备方法,它包括(1)首先在搅拌装置中依次加入油酸、硬脂酸、甲氧基封端聚氧乙烯聚氧丙烯基醚、椰油酸、催化剂,加热搅拌均匀,温度控制在50‑80℃;(2)然后将搅拌装置抽真空,反应2‑5小时即可。本发明环保,亲水性好,显著提高纤维延伸性和韧性。
Description
技术领域
本发明涉及一种亲水剂,具体涉及一种丙纶亲水剂。
背景技术
亲水剂能使面料表面张力迅速下降,多为长链有机化合物,分子中同时存在亲水基团和亲油基团,亲水剂在生产过程中需要将多种原料进行混合制备,丙纶面料它是由丙烯作原料经聚合、熔体纺丝制得的纤维。
发明内容
发明目的:本发明的目的是为了克服现有技术中的不足,提供一种环保,亲水性好,显著提高纤维延伸性和韧性的丙纶面料亲水剂。
技术方案:为了解决上述技术问题,本发明所述的丙纶面料亲水剂,按照重量份数计,它包括,
(1)油酸 35-50份;
(2)硬脂酸 30-45份;
(3)椰油酸 28-40份;
(4)甲氧基封端聚氧乙烯聚氧丙烯基醚 15-25份;
(5)催化剂 5-10份;
其制备方法,它包括以下步骤,
(1)首先在搅拌装置中依次加入油酸、硬脂酸、甲氧基封端聚氧乙烯聚氧丙烯基醚、椰油酸、催化剂,加热搅拌均匀,温度控制在50-80℃;
(2)然后将搅拌装置抽真空,反应2-5小时即可。
优选地,按照重量份数计,它包括,
(1)油酸 46份;
(2)硬脂酸 38份;
(3)椰油酸 32份;
(4)甲氧基封端聚氧乙烯聚氧丙烯基醚 16份;
(5)催化剂 7份。
有益效果:本发明与现有技术相比,其显著优点是:本发明采用油酸、硬脂酸、椰油酸、甲氧基封端聚氧乙烯聚氧丙烯基醚、催化剂,经过加热搅拌,抽真空反应,整体低毒环保,使用稳定可靠,亲水性好,可以显著提高纤维的延伸性和韧性。
具体实施方式
下面结合实施例对本发明作进一步的说明。
实施例1
本发明所述的丙纶面料亲水剂,按照重量份数计,它包括,
(1)油酸 39份;
(2)硬脂酸 32份;
(3)椰油酸 30份;
(4)甲氧基封端聚氧乙烯聚氧丙烯基醚 17份;
(5)催化剂 6份;
其制备方法,它包括以下步骤,
(1)首先在搅拌装置中依次加入油酸、硬脂酸、甲氧基封端聚氧乙烯聚氧丙烯基醚、椰油酸、催化剂,加热搅拌均匀,温度控制在50-80℃;
(2)然后将搅拌装置抽真空,反应2-5小时即可。
实施例2
本发明所述的丙纶面料亲水剂,按照重量份数计,它包括,
(1)油酸 48份;
(2)硬脂酸 40份;
(3)椰油酸 33份;
(4)甲氧基封端聚氧乙烯聚氧丙烯基醚 20份;
(5)催化剂 8份;
其制备方法,它包括以下步骤,
(1)首先在搅拌装置中依次加入油酸、硬脂酸、甲氧基封端聚氧乙烯聚氧丙烯基醚、椰油酸、催化剂,加热搅拌均匀,温度控制在50-80℃;
(2)然后将搅拌装置抽真空,反应2-5小时即可。
本发明采用油酸、硬脂酸、椰油酸、甲氧基封端聚氧乙烯聚氧丙烯基醚、催化剂,经过加热搅拌,抽真空反应,整体低毒环保,使用稳定可靠,亲水性好,可以显著提高纤维的延伸性和韧性。
本发明提供了一种思路及方法,具体实现该技术方案的方法和途径很多,以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围,本实施例中未明确的各组成部分均可用现有技术加以实现。
Claims (2)
1.丙纶面料亲水剂,其特征在于:按照重量份数计,它包括,
(1)油酸 35-50份;
(2)硬脂酸 30-45份;
(3)椰油酸 28-40份;
(4)甲氧基封端聚氧乙烯聚氧丙烯基醚 15-25份;
(5)催化剂 5-10份;
其制备方法,它包括以下步骤,
(1)首先在搅拌装置中依次加入油酸、硬脂酸、甲氧基封端聚氧乙烯聚氧丙烯基醚、椰油酸、催化剂,加热搅拌均匀,温度控制在50-80℃;
(2)然后将搅拌装置抽真空,反应2-5小时即可。
2.根据权利要求1所述的丙纶面料亲水剂,其特征在于:按照重量份数计,它包括,
(1)油酸 46份;
(2)硬脂酸 38份;
(3)椰油酸 32份;
(4)甲氧基封端聚氧乙烯聚氧丙烯基醚 16份;
(5)催化剂 7份。
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4169062A (en) * | 1977-05-12 | 1979-09-25 | Southern Sizing Co. | Random copolymers of polyoxyethylene polyoxypropylene glycol monoester, process of making the same and textile fiber containing the same |
CN101994251A (zh) * | 2009-08-11 | 2011-03-30 | 中国石化集团洛阳石油化工工程公司 | 一种乳化液型涤纶工业丝用油剂 |
CN105274846A (zh) * | 2015-11-19 | 2016-01-27 | 上海多纶化工有限公司 | 聚丙烯纤维用纺丝拉伸油剂 |
CN105399941A (zh) * | 2015-12-10 | 2016-03-16 | 浙江皇马科技股份有限公司 | 一种多元醇聚醚脂肪酸酯的制备方法 |
CN106480736A (zh) * | 2016-09-27 | 2017-03-08 | 浙江四通化纤股份有限公司 | 丙纶超柔软地毯丝纺丝油剂及制备方法 |
CN108166256A (zh) * | 2016-12-07 | 2018-06-15 | 浙江四通化纤股份有限公司 | 超柔软丙纶地毯纱的制备方法 |
-
2020
- 2020-07-08 CN CN202010649937.7A patent/CN111979764A/zh active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4169062A (en) * | 1977-05-12 | 1979-09-25 | Southern Sizing Co. | Random copolymers of polyoxyethylene polyoxypropylene glycol monoester, process of making the same and textile fiber containing the same |
CN101994251A (zh) * | 2009-08-11 | 2011-03-30 | 中国石化集团洛阳石油化工工程公司 | 一种乳化液型涤纶工业丝用油剂 |
CN105274846A (zh) * | 2015-11-19 | 2016-01-27 | 上海多纶化工有限公司 | 聚丙烯纤维用纺丝拉伸油剂 |
CN105399941A (zh) * | 2015-12-10 | 2016-03-16 | 浙江皇马科技股份有限公司 | 一种多元醇聚醚脂肪酸酯的制备方法 |
CN106480736A (zh) * | 2016-09-27 | 2017-03-08 | 浙江四通化纤股份有限公司 | 丙纶超柔软地毯丝纺丝油剂及制备方法 |
CN108166256A (zh) * | 2016-12-07 | 2018-06-15 | 浙江四通化纤股份有限公司 | 超柔软丙纶地毯纱的制备方法 |
Non-Patent Citations (1)
Title |
---|
裘炳毅, 中国轻工业出版社 * |
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