CN111943510A - Method for manufacturing handicraft added with glass color stone - Google Patents
Method for manufacturing handicraft added with glass color stone Download PDFInfo
- Publication number
- CN111943510A CN111943510A CN202010839895.3A CN202010839895A CN111943510A CN 111943510 A CN111943510 A CN 111943510A CN 202010839895 A CN202010839895 A CN 202010839895A CN 111943510 A CN111943510 A CN 111943510A
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- Prior art keywords
- parts
- stone
- glass color
- color stone
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B25/00—Annealing glass products
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Finishing Walls (AREA)
Abstract
The invention relates to the technical field of building materials, in particular to a method for manufacturing a handicraft added with glass color stone; the invention improves the utilization rate of environmental wastes by selecting the construction wastes and can greatly reduce the production cost; the hardness and high temperature resistance of the glass color stone are improved by selecting titanium dioxide and silicon dioxide; the invention improves the glossiness of the glass color stone by selecting fluorite and dolomite.
Description
Technical Field
The invention relates to the technical field of building materials, in particular to a method for manufacturing a handicraft added with glass color stone.
Background
The common paint for the inner and outer walls of the building has a plurality of defects caused by a paint film after being used for a period of time in a severe environment: such as efflorescence, cracking, and falling … …, thereby affecting the aesthetics of the wall and the urban environment; and the existing interior and exterior wall coatings are stone-like coatings, which have poor stone-like effect, lower repairability when repairing buildings and higher construction cost.
Disclosure of Invention
The invention aims to solve the technical problem and provides a method for manufacturing artware added with glass color stone aiming at the technical defects, the invention improves the utilization rate of environmental wastes by selecting construction wastes and can greatly reduce the production cost; the hardness and high temperature resistance of the glass color stone are improved by selecting titanium dioxide and silicon dioxide; the invention improves the glossiness of the glass color stone by selecting fluorite and dolomite.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: the glass color stone is mainly prepared from the following raw materials in parts by weight: 150 parts of construction waste 130-containing materials, 40-60 parts of mica stones, 40-60 parts of silicon dioxide, 35-55 parts of inorganic dyes, 25-35 parts of titanium dioxide, 17-26 parts of fluorite, 15-20 parts of dolomite and 5-10 parts of curing agents.
Further optimizing the technical scheme, the glass color stone is mainly prepared from the following raw materials in parts by weight: 140 parts of building waste, 50 parts of mica stone, 50 parts of silicon dioxide, 45 parts of inorganic dye, 30 parts of titanium dioxide, 22 parts of fluorite, 17 parts of dolomite and 8 parts of curing agent.
Further optimizing the technical scheme, the glass color stone is mainly prepared from the following raw materials in parts by weight: 135 parts of construction waste, 45 parts of mica stone, 55 parts of silicon dioxide, 40 parts of inorganic dye, 27 parts of titanium dioxide, 19 parts of fluorite, 16 parts of dolomite and 6 parts of curing agent.
Further optimizing the technical scheme, the glass color stone is mainly prepared from the following raw materials in parts by weight: 145 parts of construction waste, 55 parts of mica stone, 53 parts of silicon dioxide, 50 parts of inorganic dye, 31 parts of titanium dioxide, 23 parts of fluorite, 15 parts of dolomite and 9 parts of curing agent.
Further optimizing the technical scheme, the construction waste mainly comprises soil, slag soil, scattered mortar and concrete, and broken bricks and concrete blocks produced by chiseling.
Further optimizing the technical scheme, the method comprises the following steps:
(1) sequentially putting the building waste, the micaceous stone, the fluorite and the dolomite in parts by weight into a crusher for crushing, and drying by an electric heating oven at the drying temperature of 170-175 ℃ for 20-30min after crushing is finished, so as to obtain a dried material a;
(2) sequentially taking the material a, the silicon dioxide and the titanium dioxide according to the parts by weight, putting the material a, the silicon dioxide and the titanium dioxide into a smelting furnace for melting treatment at the melting temperature of 2100-2150 ℃, and then clarifying and homogenizing to obtain a molten material b;
(3) sequentially taking the material b, the inorganic dye and the curing agent according to the parts by weight, putting the materials b, the inorganic dye and the curing agent into a stirrer together for stirring treatment, and obtaining a material c after uniformly stirring;
(4) and (3) extruding and molding the material c through an extruder, performing gradient cooling through an annealing kiln at the conveying speed of 3-5m/min under the temperature conditions of 450 ℃, 400 ℃, 350 ℃ and 300 ℃ in sequence, leaving the material c out of the annealing kiln when the material c is cooled to the temperature of 100-120 ℃, cooling to 40-50 ℃ through air cooling, and cutting according to the size to obtain the glass color stone.
Compared with the prior art, the invention has the following advantages: 1. the invention improves the utilization rate of environmental wastes by selecting the construction wastes and can greatly reduce the production cost; 2. the hardness and high temperature resistance of the glass color stone are improved by selecting titanium dioxide and silicon dioxide; 3. the invention improves the glossiness of the glass color stone by selecting fluorite and dolomite.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail below with reference to specific embodiments. It should be understood that the description is intended to be exemplary only, and is not intended to limit the scope of the present invention. Moreover, in the following description, descriptions of well-known structures and techniques are omitted so as to not unnecessarily obscure the concepts of the present invention.
Example 1
The glass color stone is mainly prepared from the following raw materials in parts by weight: 140 parts of building waste, 50 parts of mica stone, 50 parts of silicon dioxide, 45 parts of inorganic dye, 30 parts of titanium dioxide, 22 parts of fluorite, 17 parts of dolomite and 8 parts of curing agent.
Example 2
The glass color stone is mainly prepared from the following raw materials in parts by weight: 135 parts of construction waste, 45 parts of mica stone, 55 parts of silicon dioxide, 40 parts of inorganic dye, 27 parts of titanium dioxide, 19 parts of fluorite, 16 parts of dolomite and 6 parts of curing agent.
Example 3
The glass color stone is mainly prepared from the following raw materials in parts by weight: 145 parts of construction waste, 55 parts of mica stone, 53 parts of silicon dioxide, 50 parts of inorganic dye, 31 parts of titanium dioxide, 23 parts of fluorite, 15 parts of dolomite and 9 parts of curing agent.
TABLE 1
TABLE 2
TABLE 3
Appearance rating/rating | Change in appearance of the surface of the test specimen |
A | Without change |
B | Slight to moderate discoloration |
C | Severe discoloration or very slight loss of light |
D | Slight loss of gloss or the appearance of very slight corrosion products |
E | Severe loss of light or corrosion products or pitting of the sample with a thin layer on a local surface |
F | With corrosion products or pitting corrosion, one of which is distributed over the entire test surface |
G | With a thick layer of corrosion products or pitting over the entire surface and with deep pitting |
H | With very thick corrosion product layers or pitting over the entire surface and with deep pitting |
I | Occurrence of corrosion of base metal |
TABLE 4
Corrosion rating/grade | Area of defect/%) |
10 | Defect free |
9 | ≤0.1 |
8 | >0.1-0.25 |
7 | >0.25-0.5 |
6 | >0.5-1.0 |
5 | >1.0-2.5 |
4 | >2.5-5 |
3 | >5-10 |
2 | >10-25 |
1 | >25-30 |
0 | >50 |
In summary, it can be seen that the embodiment 1 of the present invention is the best embodiment, and the obtained vitreous color stone has strong corrosion resistance, good temperature change adaptability, improved utilization rate of environmental waste, simple processing, low production cost, and easy molding.
It is to be understood that the above-described embodiments of the present invention are merely illustrative of or explaining the principles of the invention and are not to be construed as limiting the invention. Therefore, any modification, equivalent replacement, improvement and the like made without departing from the spirit and scope of the present invention should be included in the protection scope of the present invention. Further, it is intended that the appended claims cover all such variations and modifications as fall within the scope and boundaries of the appended claims or the equivalents of such scope and boundaries.
Claims (6)
1. The artware added with the glass color stone is characterized in that: the glass color stone is mainly prepared from the following raw materials in parts by weight: 150 parts of construction waste 130-containing materials, 40-60 parts of mica stones, 40-60 parts of silicon dioxide, 35-55 parts of inorganic dyes, 25-35 parts of titanium dioxide, 17-26 parts of fluorite, 15-20 parts of dolomite and 5-10 parts of curing agents.
2. The artwork added with glass color stone as claimed in claim 1, wherein: the glass color stone is mainly prepared from the following raw materials in parts by weight: 140 parts of building waste, 50 parts of mica stone, 50 parts of silicon dioxide, 45 parts of inorganic dye, 30 parts of titanium dioxide, 22 parts of fluorite, 17 parts of dolomite and 8 parts of curing agent.
3. The artwork added with glass color stone as claimed in claim 1, wherein: the glass color stone is mainly prepared from the following raw materials in parts by weight: 135 parts of construction waste, 45 parts of mica stone, 55 parts of silicon dioxide, 40 parts of inorganic dye, 27 parts of titanium dioxide, 19 parts of fluorite, 16 parts of dolomite and 6 parts of curing agent.
4. The artwork added with glass color stone as claimed in claim 1, wherein: the glass color stone is mainly prepared from the following raw materials in parts by weight: 145 parts of construction waste, 55 parts of mica stone, 53 parts of silicon dioxide, 50 parts of inorganic dye, 31 parts of titanium dioxide, 23 parts of fluorite, 15 parts of dolomite and 9 parts of curing agent.
5. The granite-imitated glass-colored stone of any one of claims 1 to 4, which is characterized in that: the construction waste mainly comprises soil, slag soil, scattered mortar and concrete, and broken bricks and concrete blocks produced by chiseling.
6. The method for manufacturing the artware added with the glass color stone as claimed in claim 1, wherein: the method comprises the following steps:
(1) sequentially putting the building waste, the micaceous stone, the fluorite and the dolomite in parts by weight into a crusher for crushing, and drying by an electric heating oven at the drying temperature of 170-175 ℃ for 20-30min after crushing is finished, so as to obtain a dried material a;
(2) sequentially taking the material a, the silicon dioxide and the titanium dioxide according to the parts by weight, putting the material a, the silicon dioxide and the titanium dioxide into a smelting furnace for melting treatment at the melting temperature of 2100-2150 ℃, and then clarifying and homogenizing to obtain a molten material b;
(3) sequentially taking the material b, the inorganic dye and the curing agent according to the parts by weight, putting the materials b, the inorganic dye and the curing agent into a stirrer together for stirring treatment, and obtaining a material c after uniformly stirring;
(4) and (3) extruding and molding the material c through an extruder, performing gradient cooling through an annealing kiln at the conveying speed of 3-5m/min under the temperature conditions of 450 ℃, 400 ℃, 350 ℃ and 300 ℃ in sequence, leaving the material c out of the annealing kiln when the material c is cooled to the temperature of 100-120 ℃, cooling to 40-50 ℃ through air cooling, and cutting according to the size to obtain the glass color stone.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202010839895.3A CN111943510A (en) | 2020-08-19 | 2020-08-19 | Method for manufacturing handicraft added with glass color stone |
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CN202010839895.3A CN111943510A (en) | 2020-08-19 | 2020-08-19 | Method for manufacturing handicraft added with glass color stone |
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Family
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CN202010839895.3A Pending CN111943510A (en) | 2020-08-19 | 2020-08-19 | Method for manufacturing handicraft added with glass color stone |
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU1788950C (en) * | 1989-12-29 | 1993-01-15 | Производственное Объединение "Силикат" | Glass for glass-crystalline material |
CN1915878A (en) * | 2006-09-05 | 2007-02-21 | 山东建筑大学材料科学研究所 | Method for producing color glass ceramic by using sludge of concrete |
CN102219380A (en) * | 2011-05-03 | 2011-10-19 | 北京中伦基业科技发展有限公司 | Method for producing glass-ceramics plate by using construction waste |
KR20120043588A (en) * | 2010-10-26 | 2012-05-04 | 한국세라믹기술원 | Method for manufacturing soda-lime color glass using refused coal ore and color glass manufactured by the same |
CN104163614A (en) * | 2013-05-20 | 2014-11-26 | 深圳市科耐乐新材料有限公司 | Method for manufacturing stone-simulating decorative plate without sintering |
CN106277770A (en) * | 2016-07-06 | 2017-01-04 | 吴海屏 | Utilize the method that granite waste material produces glass |
CN107117821A (en) * | 2017-06-30 | 2017-09-01 | 合肥利裕泰玻璃制品有限公司 | A kind of high strength micro-crystalline glass and preparation method thereof |
CN108298814A (en) * | 2018-02-08 | 2018-07-20 | 合肥利裕泰玻璃制品有限公司 | A kind of novel building glass and preparation method thereof |
CN110937811A (en) * | 2019-12-13 | 2020-03-31 | 中郡庄艺(泉州)新材料有限公司 | Microcrystalline glass using stone powder as raw material and preparation method thereof |
CN111087171A (en) * | 2019-11-22 | 2020-05-01 | 石家庄泰图建材有限公司 | Glass color sheet and preparation method thereof |
-
2020
- 2020-08-19 CN CN202010839895.3A patent/CN111943510A/en active Pending
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU1788950C (en) * | 1989-12-29 | 1993-01-15 | Производственное Объединение "Силикат" | Glass for glass-crystalline material |
CN1915878A (en) * | 2006-09-05 | 2007-02-21 | 山东建筑大学材料科学研究所 | Method for producing color glass ceramic by using sludge of concrete |
KR20120043588A (en) * | 2010-10-26 | 2012-05-04 | 한국세라믹기술원 | Method for manufacturing soda-lime color glass using refused coal ore and color glass manufactured by the same |
CN102219380A (en) * | 2011-05-03 | 2011-10-19 | 北京中伦基业科技发展有限公司 | Method for producing glass-ceramics plate by using construction waste |
CN104163614A (en) * | 2013-05-20 | 2014-11-26 | 深圳市科耐乐新材料有限公司 | Method for manufacturing stone-simulating decorative plate without sintering |
CN106277770A (en) * | 2016-07-06 | 2017-01-04 | 吴海屏 | Utilize the method that granite waste material produces glass |
CN107117821A (en) * | 2017-06-30 | 2017-09-01 | 合肥利裕泰玻璃制品有限公司 | A kind of high strength micro-crystalline glass and preparation method thereof |
CN108298814A (en) * | 2018-02-08 | 2018-07-20 | 合肥利裕泰玻璃制品有限公司 | A kind of novel building glass and preparation method thereof |
CN111087171A (en) * | 2019-11-22 | 2020-05-01 | 石家庄泰图建材有限公司 | Glass color sheet and preparation method thereof |
CN110937811A (en) * | 2019-12-13 | 2020-03-31 | 中郡庄艺(泉州)新材料有限公司 | Microcrystalline glass using stone powder as raw material and preparation method thereof |
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