CN111943637A - Method for manufacturing artificial stone added with glass color stone - Google Patents

Method for manufacturing artificial stone added with glass color stone Download PDF

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Publication number
CN111943637A
CN111943637A CN202010839896.8A CN202010839896A CN111943637A CN 111943637 A CN111943637 A CN 111943637A CN 202010839896 A CN202010839896 A CN 202010839896A CN 111943637 A CN111943637 A CN 111943637A
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Prior art keywords
parts
stone
artificial stone
weight
fluorite
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CN202010839896.8A
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Chinese (zh)
Inventor
罗晓龙
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Shijiazhuang Taitu Ecological Technology Co Ltd
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Shijiazhuang Taitu Ecological Technology Co Ltd
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Priority to CN202010839896.8A priority Critical patent/CN111943637A/en
Publication of CN111943637A publication Critical patent/CN111943637A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B32/00Artificial stone not provided for in other groups of this subclass
    • C04B32/005Artificial stone obtained by melting at least part of the composition, e.g. metal
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Structural Engineering (AREA)
  • Finishing Walls (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to the technical field of artificial stones, in particular to a method for manufacturing an artificial stone added with glass color stone; the invention improves the utilization rate of environmental wastes by selecting the construction wastes and the straw powder, and can greatly reduce the production cost; the corrosion resistance and the waterproof performance of the artificial stone are improved by selecting the epoxy resin; the invention improves the luster of the artificial stone by selecting the fluorite and the dolomite.

Description

Method for manufacturing artificial stone added with glass color stone
Technical Field
The invention relates to the technical field of artificial stones, in particular to a method for manufacturing an artificial stone added with glass color stone.
Background
The artificial stone product has the advantages of no toxicity, no radioactivity, flame retardance, no oil adhesion, no dirt seepage, antibiosis, mildew resistance, wear resistance, impact resistance, easy maintenance, seamless splicing, arbitrary shape and the like, and is gradually a new favorite in the market of decoration and building materials. However, the shrinkage of the existing artificial stone product is high, and the corrosion resistance and the temperature resistance are poor, so that the existing artificial stone product can only be used as an indoor building decoration material, but can not be used as an outdoor building decoration material, and the popularization and the application of the artificial stone product are severely restricted.
Disclosure of Invention
The invention aims to solve the technical problem and provides a method for manufacturing the artificial stone added with the glass color stone aiming at the technical defects, the invention improves the utilization rate of environmental wastes by selecting the construction wastes and the straw powder, and can greatly reduce the production cost; the corrosion resistance and the waterproof performance of the artificial stone are improved by selecting the epoxy resin; the invention improves the luster of the artificial stone by selecting the fluorite and the dolomite.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: the artificial stone is mainly prepared from the following raw materials in parts by weight: 120-150 parts of building waste, 60-90 parts of mica stone, 40-70 parts of inorganic pigment, 15-30 parts of epoxy resin, 10-20 parts of straw powder, 5-15 parts of fluorite, 5-15 parts of dolomite, 5-10 parts of an anti-fouling agent and 5-10 parts of a curing agent.
Further optimizing the technical scheme, the artificial stone is mainly prepared from the following raw materials in parts by weight: 130 parts of building waste, 75 parts of mica stone, 55 parts of inorganic pigment, 20 parts of epoxy resin, 15 parts of straw powder, 10 parts of fluorite, 10 parts of dolomite, 8 parts of an anti-fouling agent and 7 parts of a curing agent.
Further optimizing the technical scheme, the artificial stone is mainly prepared from the following raw materials in parts by weight: 140 parts of building waste, 60 parts of mica stone, 65 parts of inorganic pigment, 25 parts of epoxy resin, 12 parts of straw powder, 13 parts of fluorite, 12 parts of dolomite, 6 parts of an anti-fouling agent and 5 parts of a curing agent.
Further optimizing the technical scheme, the artificial stone is mainly prepared from the following raw materials in parts by weight: 120 parts of building waste, 80 parts of mica stone, 60 parts of inorganic pigment, 18 parts of epoxy resin, 16 parts of straw powder, 11 parts of fluorite, 13 parts of dolomite, 7 parts of an anti-fouling agent and 6 parts of a curing agent.
Further optimizing the technical scheme, the construction waste mainly comprises soil, slag soil, scattered mortar and concrete, and broken bricks and concrete blocks produced by chiseling.
Further optimizing the technical scheme, the method comprises the following steps:
(1) sequentially putting the building waste, the micaceous stone, the fluorite and the dolomite in parts by weight into a crusher for crushing, and after crushing is finished, drying by an electric heating drying oven at 185 ℃ for 25-35min at 180 ℃ to obtain a dried material a;
(2) sequentially taking the materials a according to the parts by weight, putting the materials a into a smelting furnace for melting treatment, wherein the melting temperature is 2250-2350 ℃, and then clarifying and homogenizing to obtain molten materials b;
(3) sequentially putting the material b, the inorganic pigment, the epoxy resin, the straw powder, the anti-fouling agent and the curing agent in parts by weight into a stirrer for stirring treatment, and uniformly stirring to obtain a material c;
(4) and (3) extruding and molding the material c through an extruder, then performing gradient cooling through an annealing kiln, wherein the conveying speed is 4-6m/min, the temperature conditions are 500 ℃, 450 ℃, 400 ℃, 350 ℃ and 300 ℃ in sequence, when the material c is cooled to 100 ℃ and 120 ℃, the material c leaves the annealing kiln, then cooling to 40-50 ℃ through air cooling, and then cutting according to the size to obtain the artificial stone.
Compared with the prior art, the invention has the following advantages: 1. the invention improves the utilization rate of environmental wastes by selecting the construction wastes and the straw powder, and can greatly reduce the production cost; 2. the corrosion resistance and the waterproof performance of the artificial stone are improved by selecting the epoxy resin; 3. the invention improves the luster of the artificial stone by selecting the fluorite and the dolomite.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail below with reference to specific embodiments. It should be understood that the description is intended to be exemplary only, and is not intended to limit the scope of the present invention. Moreover, in the following description, descriptions of well-known structures and techniques are omitted so as to not unnecessarily obscure the concepts of the present invention.
Example 1
The glass color sheet is mainly prepared from the following raw materials in parts by weight: 60 parts of mica stone, 50 parts of soda ash, 45 parts of inorganic dye, 35 parts of filler, 20 parts of barium sulfate, 15 parts of fluorite and 10 parts of dolomite.
Example 2
The glass color sheet is mainly prepared from the following raw materials in parts by weight: 75 parts of mica stone, 60 parts of soda ash, 50 parts of inorganic dye, 30 parts of filler, 18 parts of barium sulfate, 13 parts of fluorite and 12 parts of dolomite.
Example 3
The glass color sheet is mainly prepared from the following raw materials in parts by weight: 80 parts of mica stone, 50 parts of soda ash, 40 parts of inorganic dye, 35 parts of filler, 20 parts of barium sulfate, 15 parts of fluorite and 9 parts of dolomite.
TABLE 1
Figure RE-GDA0002714229080000031
TABLE 2
Figure RE-GDA0002714229080000032
TABLE 3
Figure RE-GDA0002714229080000033
Figure RE-GDA0002714229080000041
TABLE 4
Corrosion rating/grade Area of defect/%)
10 Defect free
9 ≤0.1
8 >0.1-0.25
7 >0.25-0.5
6 >0.5-1.0
5 >1.0-2.5
4 >2.5-5
3 >5-10
2 >10-25
1 >25-30
0 >50
In summary, it can be seen that the embodiment 1 of the present invention is the best embodiment, and the artificial stone prepared by the method has strong corrosion resistance, good temperature change adaptation capability, simple processing, low production cost, and easy molding.
It is to be understood that the above-described embodiments of the present invention are merely illustrative of or explaining the principles of the invention and are not to be construed as limiting the invention. Therefore, any modification, equivalent replacement, improvement and the like made without departing from the spirit and scope of the present invention should be included in the protection scope of the present invention. Further, it is intended that the appended claims cover all such variations and modifications as fall within the scope and boundaries of the appended claims or the equivalents of such scope and boundaries.

Claims (6)

1. The utility model provides an artificial stone with glass color stone which characterized in that: the artificial stone is mainly prepared from the following raw materials in parts by weight: 120-150 parts of building waste, 60-90 parts of mica stone, 40-70 parts of inorganic pigment, 15-30 parts of epoxy resin, 10-20 parts of straw powder, 5-15 parts of fluorite, 5-15 parts of dolomite, 5-10 parts of an anti-fouling agent and 5-10 parts of a curing agent.
2. The vitreous color stone artificial stone according to claim 1, wherein: the artificial stone is mainly prepared from the following raw materials in parts by weight: 130 parts of building waste, 75 parts of mica stone, 55 parts of inorganic pigment, 20 parts of epoxy resin, 15 parts of straw powder, 10 parts of fluorite, 10 parts of dolomite, 8 parts of an anti-fouling agent and 7 parts of a curing agent.
3. The vitreous color stone artificial stone according to claim 1, wherein: the artificial stone is mainly prepared from the following raw materials in parts by weight: 140 parts of building waste, 60 parts of mica stone, 65 parts of inorganic pigment, 25 parts of epoxy resin, 12 parts of straw powder, 13 parts of fluorite, 12 parts of dolomite, 6 parts of an anti-fouling agent and 5 parts of a curing agent.
4. The vitreous color stone artificial stone according to claim 1, wherein: the artificial stone is mainly prepared from the following raw materials in parts by weight: 120 parts of building waste, 80 parts of mica stone, 60 parts of inorganic pigment, 18 parts of epoxy resin, 16 parts of straw powder, 11 parts of fluorite, 13 parts of dolomite, 7 parts of an anti-fouling agent and 6 parts of a curing agent.
5. An artificial stone added with vitreous color stone according to any one of claims 1 to 4, characterized in that: the construction waste mainly comprises soil, slag soil, scattered mortar and concrete, and broken bricks and concrete blocks produced by chiseling.
6. The method for manufacturing a vitreous color stone artificial stone according to any one of claims 1 to 4, wherein: the method comprises the following steps:
(1) sequentially putting the building waste, the micaceous stone, the fluorite and the dolomite in parts by weight into a crusher for crushing, and after crushing is finished, drying by an electric heating drying oven at 185 ℃ for 25-35min at 180 ℃ to obtain a dried material a;
(2) sequentially taking the materials a according to the parts by weight, putting the materials a into a smelting furnace for melting treatment, wherein the melting temperature is 2250-2350 ℃, and then clarifying and homogenizing to obtain molten materials b;
(3) sequentially putting the material b, the inorganic pigment, the epoxy resin, the straw powder, the anti-fouling agent and the curing agent in parts by weight into a stirrer for stirring treatment, and uniformly stirring to obtain a material c;
(4) and (3) extruding and molding the material c through an extruder, then performing gradient cooling through an annealing kiln, wherein the conveying speed is 4-6m/min, the temperature conditions are 500 ℃, 450 ℃, 400 ℃, 350 ℃ and 300 ℃ in sequence, when the material c is cooled to 100 ℃ and 120 ℃, the material c leaves the annealing kiln, then cooling to 40-50 ℃ through air cooling, and then cutting according to the size to obtain the artificial stone.
CN202010839896.8A 2020-08-19 2020-08-19 Method for manufacturing artificial stone added with glass color stone Withdrawn CN111943637A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102838321A (en) * 2012-09-08 2012-12-26 青岛绿帆再生建材有限公司 Construction waste recycled artificial marble and preparation method thereof
CN104556823A (en) * 2015-01-12 2015-04-29 卓培琨 Energy-saving high-performance artificial stone and preparation method thereof
KR20170123837A (en) * 2016-04-29 2017-11-09 (주)아이에스세라텍 Light weight artificial stone having high intensity and the manufacturing method thereof using stone sludge and bentonite
CN107902954A (en) * 2017-11-13 2018-04-13 枣庄市博源人造石有限公司 A kind of artificial stone and preparation method thereof
CN111087171A (en) * 2019-11-22 2020-05-01 石家庄泰图建材有限公司 Glass color sheet and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102838321A (en) * 2012-09-08 2012-12-26 青岛绿帆再生建材有限公司 Construction waste recycled artificial marble and preparation method thereof
CN104556823A (en) * 2015-01-12 2015-04-29 卓培琨 Energy-saving high-performance artificial stone and preparation method thereof
KR20170123837A (en) * 2016-04-29 2017-11-09 (주)아이에스세라텍 Light weight artificial stone having high intensity and the manufacturing method thereof using stone sludge and bentonite
CN107902954A (en) * 2017-11-13 2018-04-13 枣庄市博源人造石有限公司 A kind of artificial stone and preparation method thereof
CN111087171A (en) * 2019-11-22 2020-05-01 石家庄泰图建材有限公司 Glass color sheet and preparation method thereof

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