CN106630641A - Environment-friendly glass ceramic decorative material with high flexural property - Google Patents
Environment-friendly glass ceramic decorative material with high flexural property Download PDFInfo
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- CN106630641A CN106630641A CN201611225702.5A CN201611225702A CN106630641A CN 106630641 A CN106630641 A CN 106630641A CN 201611225702 A CN201611225702 A CN 201611225702A CN 106630641 A CN106630641 A CN 106630641A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B25/00—Annealing glass products
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B32/00—Thermal after-treatment of glass products not provided for in groups C03B19/00, C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
- C03B32/02—Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0063—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing waste materials, e.g. slags
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ceramic Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Glass Compositions (AREA)
Abstract
The invention provides an environment-friendly glass ceramic decorative material with high flexural property and a preparation method of the environment-friendly glass ceramic decorative material. The environment-friendly glass ceramic decorative material is high in mechanical strength and hardness and good in heat resistance, flexural property, corrosion resistance and wear resistance, various pipes and boards can be prepared from the material, and the material can be widely applied to architectural wear-resistant and corrosion-resistant materials and architectural decorative materials.
Description
Technical field
The invention belongs to the strong devitrified glass environment friendly decorative material in environment friendly decorative material field, more particularly to fracture resistance.
Background technology
Devitrified glass is a kind of new material that comprehensive glass and ceramic technology grow up, and is that microcrystal is mutually equal with glass
The material of even distribution, its physicochemical property concentrated glass, ceramics and lithotome triple advantages, such as high mechanical strength, it is heat-resisting,
Wear-resisting, antioxygenic property is good, excellent electrical properties, the coefficient of expansion is adjustable, heat endurance is good etc., and better than lithotome and ceramics,
Can be used for building curtain wall and indoor high-grade decoration, be the new material of the 21 century with development prospect.
Devitrified glass can grind stone etc. as main production raw material with ore, industrial tailings, metallurgical slag, flyash, coal, and
It is pollution-free during producing, product "dead" pollution itself, therefore be otherwise known as environment-friendly products or green material, traditional mode of production
Devitrified glass top layer and its internal layer Jing be commonly present a large amount of manufacturability pores, and fracture resistance is not strong, limits crystallite glass
The application of glass.
The content of the invention
The object of the invention is exactly have the defect of technology to make up oneself, there is provided a kind of strong devitrified glass environmental protection of fracture resistance
Ornament materials and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of strong devitrified glass environment friendly decorative material of fracture resistance, it is made up of the raw material of following weight parts:
Gangue 25-30 parts, quartz sand 20-30 parts, flyash 15-20 parts, silica 1 0-15 parts, calcium carbonate 10-15 parts,
Alabaster 10-15 parts, zinc oxide 6-8 parts, potassium oxide 3-4 parts, boron oxide 2-3 parts, sodium tetraborate 0.15-0.3 parts, vanadic anhydride
0.15-0.3 parts；
Its preparation method is：
(1) raw material of above-mentioned weight portion is mixed to join in glass-melting furnace, is melted uniformly at a high temperature of 1520-1620 DEG C
Vitreum；
(2) above-mentioned vitreum is direct plungeed into water, then cold quenching is ground into 20-25um powder into glass particle, is dried, and put down
It is laid on refractory material horizontal plane, laid thickness is 20-24mm；
(3) above-mentioned laid good glass particle is placed in resistance furnace together with refractory material, temperature schedule:At room temperature with 5-8
DEG C/min ramps to 1220-1360 DEG C, it is incubated 3-3.5h；
(4) anneal:Glass after above-mentioned crystallization is made annealing treatment with the annealing cooling rate of 4-5 DEG C/min, when temperature drop
During as 280-320 DEG C, then naturally cool to room temperature；
(5) size as requested cuts into plate, grinding and polishing, deburring.
It is an advantage of the invention that:
The devitrified glass environment friendly decorative material high mechanical strength of present invention production, hardness is big, with good heat resistance, fold resistance
Energy, corrosion resistance and wearability, product can be made into all kinds of tubing, sheet material, can be widely applied to architectural wear resistant corrosion resistant material
Material, building and ornament materials.
Specific embodiment
Embodiment 1：A kind of strong devitrified glass environment friendly decorative material of fracture resistance, it is by the raw material group of following weight parts
Into:
25 parts of gangue, 20 parts of quartz sand, 15 parts of flyash, 0 part of silica 1,10 parts of calcium carbonate, 10 parts of alabaster, zinc oxide 6
Part, 3 parts of potassium oxide, 2 parts of boron oxide, 0.15 part of sodium tetraborate, 0.15 part of vanadic anhydride；
Its preparation method is：
(1) raw material of above-mentioned weight portion is mixed to join in glass-melting furnace, uniformly glass is melted at a high temperature of 1520 DEG C
Glass body；
(2) above-mentioned vitreum is direct plungeed into water, then cold quenching is ground into 20um powder into glass particle, is dried, and be laid in
On refractory material horizontal plane, laid thickness is 20mm；
(3) above-mentioned laid good glass particle is placed in resistance furnace together with refractory material, temperature schedule:At room temperature with 5
DEG C/min ramps to 1220 DEG C, it is incubated 3h；
(4) anneal:Glass after above-mentioned crystallization is made annealing treatment with the annealing cooling rate of 4 DEG C/min, when temperature is down to
When 280 DEG C, then naturally cool to room temperature；
(5) size as requested cuts into plate, grinding and polishing, deburring.
Embodiment 2：A kind of strong devitrified glass environment friendly decorative material of fracture resistance, it is by the raw material group of following weight parts
Into:
30 parts of gangue, 30 parts of quartz sand, 20 parts of flyash, 5 parts of silica 1,15 parts of calcium carbonate, 15 parts of alabaster, zinc oxide 8
Part, 4 parts of potassium oxide, 3 parts of boron oxide, 0.3 part of sodium tetraborate, 0.3 part of vanadic anhydride；
Its preparation method is：
(1) raw material of above-mentioned weight portion is mixed to join in glass-melting furnace, uniformly glass is melted at a high temperature of 1620 DEG C
Glass body；
(2) above-mentioned vitreum is direct plungeed into water, then cold quenching is ground into 25um powder into glass particle, is dried, and be laid in
On refractory material horizontal plane, laid thickness is 24mm；
(3) above-mentioned laid good glass particle is placed in resistance furnace together with refractory material, temperature schedule:At room temperature with 8
DEG C/min ramps to 1360 DEG C, it is incubated 3.5h；
(4) anneal:Glass after above-mentioned crystallization is made annealing treatment with the annealing cooling rate of 5 DEG C/min, when temperature is down to
When 320 DEG C, then naturally cool to room temperature；
(5) size as requested cuts into plate, grinding and polishing, deburring.
Embodiment 3：A kind of strong devitrified glass environment friendly decorative material of fracture resistance, it is by the raw material group of following weight parts
Into:
28 parts of gangue, 25 parts of quartz sand, 18 parts of flyash, 2 parts of silica 1,12 parts of calcium carbonate, 12 parts of alabaster, zinc oxide 7
Part, 4 parts of potassium oxide, 3 parts of boron oxide, 0.15 part of sodium tetraborate, 0.3 part of vanadic anhydride；
Its preparation method is：
(1) raw material of above-mentioned weight portion is mixed to join in glass-melting furnace, uniformly glass is melted at a high temperature of 1580 DEG C
Glass body；
(2) above-mentioned vitreum is direct plungeed into water, then cold quenching is ground into 25um powder into glass particle, is dried, and be laid in
On refractory material horizontal plane, laid thickness is 20mm；
(3) above-mentioned laid good glass particle is placed in resistance furnace together with refractory material, temperature schedule:At room temperature with 6
DEG C/min ramps to 1290 DEG C, it is incubated 3h；
(4) anneal:Glass after above-mentioned crystallization is made annealing treatment with the annealing cooling rate of 5 DEG C/min, when temperature is down to
When 320 DEG C, then naturally cool to room temperature；
(5) size as requested cuts into plate, grinding and polishing, deburring.
Claims (4)
1. the strong devitrified glass environment friendly decorative material of a kind of fracture resistance, it is characterised in that：It is by the raw material group of following weight parts
Into:
Gangue 25-30 parts, quartz sand 20-30 parts, flyash 15-20 parts, silica 1 0-15 parts, calcium carbonate 10-15 parts,
Alabaster 10-15 parts, zinc oxide 6-8 parts, potassium oxide 3-4 parts, boron oxide 2-3 parts, sodium tetraborate 0.15-0.3 parts, vanadic anhydride
0.15-0.3 parts.
2. the strong devitrified glass environment friendly decorative material of a kind of fracture resistance as claimed in claim 1, it is characterised in that：Its preparation
Method is：
(1) raw material of above-mentioned weight portion is mixed to join in glass-melting furnace, is melted uniformly at a high temperature of 1520-1620 DEG C
Vitreum；
(2) above-mentioned vitreum is direct plungeed into water, then cold quenching is ground into 20-25um powder into glass particle, is dried, and put down
It is laid on refractory material horizontal plane, laid thickness is 20-24mm；
(3) above-mentioned laid good glass particle is placed in resistance furnace together with refractory material, temperature schedule:At room temperature with 5-8
DEG C/min ramps to 1220-1360 DEG C, it is incubated 3-3.5h；
(4) anneal:Glass after above-mentioned crystallization is made annealing treatment with the annealing cooling rate of 4-5 DEG C/min, when temperature drop
During as 280-320 DEG C, then naturally cool to room temperature；
(5) size as requested cuts into plate, grinding and polishing, deburring.
3. the strong devitrified glass environment friendly decorative material of a kind of fracture resistance as claimed in claim 1, it is characterised in that：It is by under
State the raw material composition of weight portion:
25 parts of gangue, 20 parts of quartz sand, 15 parts of flyash, 0 part of silica 1,10 parts of calcium carbonate, 10 parts of alabaster, zinc oxide 6
Part, 3 parts of potassium oxide, 2 parts of boron oxide, 0.15 part of sodium tetraborate, 0.15 part of vanadic anhydride.
4. the strong devitrified glass environment friendly decorative material of a kind of fracture resistance as claimed in claim 3, it is characterised in that：Its preparation
Method is：
(1) raw material of above-mentioned weight portion is mixed to join in glass-melting furnace, uniformly glass is melted at a high temperature of 1520 DEG C
Glass body；
(2) above-mentioned vitreum is direct plungeed into water, then cold quenching is ground into 20um powder into glass particle, is dried, and be laid in
On refractory material horizontal plane, laid thickness is 20mm；
(3) above-mentioned laid good glass particle is placed in resistance furnace together with refractory material, temperature schedule:At room temperature with 5
DEG C/min ramps to 1220 DEG C, it is incubated 3h；
(4) anneal:Glass after above-mentioned crystallization is made annealing treatment with the annealing cooling rate of 4 DEG C/min, when temperature is down to
When 280 DEG C, then naturally cool to room temperature；
(5) size as requested cuts into plate, grinding and polishing, deburring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611225702.5A CN106630641A (en) | 2016-12-27 | 2016-12-27 | Environment-friendly glass ceramic decorative material with high flexural property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611225702.5A CN106630641A (en) | 2016-12-27 | 2016-12-27 | Environment-friendly glass ceramic decorative material with high flexural property |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106630641A true CN106630641A (en) | 2017-05-10 |
Family
ID=58831815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611225702.5A Pending CN106630641A (en) | 2016-12-27 | 2016-12-27 | Environment-friendly glass ceramic decorative material with high flexural property |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106630641A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111003943A (en) * | 2019-12-17 | 2020-04-14 | 安徽凤阳玻璃有限公司 | High-strength tensile plate glass and preparation method thereof |
-
2016
- 2016-12-27 CN CN201611225702.5A patent/CN106630641A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111003943A (en) * | 2019-12-17 | 2020-04-14 | 安徽凤阳玻璃有限公司 | High-strength tensile plate glass and preparation method thereof |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170510 |