CN106517796A - Method of preparing glass ceramics from granite waste residue - Google Patents
Method of preparing glass ceramics from granite waste residue Download PDFInfo
- Publication number
- CN106517796A CN106517796A CN201611068004.9A CN201611068004A CN106517796A CN 106517796 A CN106517796 A CN 106517796A CN 201611068004 A CN201611068004 A CN 201611068004A CN 106517796 A CN106517796 A CN 106517796A
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- CN
- China
- Prior art keywords
- granite waste
- devitrified glass
- temperature
- glass
- waste residues
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention relates to the technical field of functional materials, in particular to a method of preparing glass ceramics from granite waste residue. The method of preparing the glass ceramics from the granite waste residue includes the following steps that quartz sand, basic magnesium carbonate, aluminum hydroxide and ZrO2 are mixed uniformly, put into a corundum crucible and kept at the temperature for 2 h in a silicon molybdenum rod electric furnace at the temperature of 1600 DEG C, then molten glass is poured onto a preheated steel plate to carry out casting molding, the molded molten glass is fast placed in an annealing furnace at the temperature of 680 DEG C to carry out annealing so as to obtain uniform and transparent basic glass, and then glass ceramics are obtained through the nucleating and crystallization processes. The four-point bending strength of the glass ceramics are 67.35 MPa, and four point bending strength of a sample is gradually improved along with rising of crystallization temperature, and the crystal phase structure is uniform and presents columnar and felt-shaped compact assemblages which are arrayed in a stacked mode.
Description
Technical field
The present invention relates to technical field of function materials, and in particular to a kind of method that granite waste residues prepare devitrified glass.
Background technology
Devitrified glass is that the parent glass of Jing specific components design passes through nucleation and composite made by crystallization process, together
Traditional ceramic phase ratio, devitrified glass have many good performances:As thermal coefficient of expansion is adjustable, it is high mechanical strength, good
Chemical resistance and heat stability.It is by adjusting composition and changing heat treating regime, it is possible to obtain transparent, translucent or not
Transparent product, energy industrialization large-scale production, is widely used in chemical industry, Aero-Space, building decoration, electronics and power engineering
In field.
At present, to R2O-MgO-Al2 O3-SiO2The research of microcrystalline glass in series is more with fluoride as Nucleating Agent, and fluoride
The environment that is added to bring very big harm, should not life-time service. granite is a kind of natural raw mineral materials, is widely used in
The interior and exterior finishes of building, with increase of the people to granite demand, in recovery process, substantial amounts of waste material is also with surprising
Speed increases, and the numerous imbalances for not only causing ecological environment are also a kind of wasting of resources, in the face of such severe environmental problem,
Mine tailing is all produced by each field in the approach for trying to explore commercial production and environmental harmony, industry in 2010 and information portion
Devitrified glass technology is incorporated《Metal tailings comprehensive utilization ad hoc planning (2010 ~ 2015 years)》Emphasis tackling key problem technology.
The content of the invention
It is contemplated that proposing a kind of method that granite waste residues prepare devitrified glass.
Technical program of the present invention lies in：
The method that granite waste residues prepare devitrified glass, comprises the steps：
By quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mix homogeneously is put in crucible, and is incubated in silicon molybdenum rod furnace
Vitreous humour is poured on into cast molding on the steel plate of preheating afterwards, is placed in annealing furnace and is annealed, obtain the parent glass of homogeneous transparent, so
Devitrified glass is obtained through coring and crystallization process afterwards.
Described quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.2：55.8：33.0：6.0.
Described quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.0：55.8：33.2：6.0.
Described quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.5：55.5：33.5：5.5.
Described quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.0：55.5：33.2：6.3.
Described crucible is corundum crucible.
The temperature of described silicon molybdenum rod furnace is 1500 ~ 1600 DEG C, and temperature retention time is 2 ~ 2.5h.
The temperature of described annealing furnace is 680 ~ 700 DEG C, and annealing time is 30 ~ 45min.
The method have technical effect that：
Devitrified glass four point bending strength of the present invention be 67.35MPa, with crystallization temperature rising sample four point bending strength by
Cumulative big, its crystal phase structure uniformly and is presented column felted densification aggregation and is staggered.
Specific embodiment
The method that granite waste residues prepare devitrified glass, comprises the steps：
Embodiment 1
By quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mix homogeneously is put in crucible, and is incubated in silicon molybdenum rod furnace
Vitreous humour is poured on into cast molding on the steel plate of preheating afterwards, is placed in annealing furnace and is annealed, obtain the parent glass of homogeneous transparent, so
Devitrified glass is obtained through coring and crystallization process afterwards.
Wherein, described quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.2：55.8：33.0：
6.0.Described crucible is corundum crucible.The temperature of described silicon molybdenum rod furnace be 1500 ~ 1600 DEG C, temperature retention time be 2 ~
2.5h.The temperature of described annealing furnace is 680 ~ 700 DEG C, and annealing time is 30 ~ 45min.
Embodiment 2
By quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mix homogeneously is put in crucible, and is incubated in silicon molybdenum rod furnace
Vitreous humour is poured on into cast molding on the steel plate of preheating afterwards, is placed in annealing furnace and is annealed, obtain the parent glass of homogeneous transparent, so
Devitrified glass is obtained through coring and crystallization process afterwards.
Described quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.0：55.8：33.2：6.0.
Described crucible is corundum crucible.The temperature of described silicon molybdenum rod furnace is 1500 ~ 1600 DEG C, and temperature retention time is 2 ~ 2.5h.Institute
The temperature of the annealing furnace stated is 680 ~ 700 DEG C, and annealing time is 30 ~ 45min.
Embodiment 3
By quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mix homogeneously is put in crucible, and is incubated in silicon molybdenum rod furnace
Vitreous humour is poured on into cast molding on the steel plate of preheating afterwards, is placed in annealing furnace and is annealed, obtain the parent glass of homogeneous transparent, so
Devitrified glass is obtained through coring and crystallization process afterwards.
Wherein, described quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.5：55.5：33.5：
5.5.Described crucible is corundum crucible.The temperature of described silicon molybdenum rod furnace be 1500 ~ 1600 DEG C, temperature retention time be 2 ~
2.5h.The temperature of described annealing furnace is 680 ~ 700 DEG C, and annealing time is 30 ~ 45min.
Embodiment 4
By quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mix homogeneously is put in crucible, and is incubated in silicon molybdenum rod furnace
Vitreous humour is poured on into cast molding on the steel plate of preheating afterwards, is placed in annealing furnace and is annealed, obtain the parent glass of homogeneous transparent, so
Devitrified glass is obtained through coring and crystallization process afterwards.
Wherein, described quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.0：55.5：33.2：
6.3.Described crucible is corundum crucible.The temperature of described silicon molybdenum rod furnace be 1500 ~ 1600 DEG C, temperature retention time be 2 ~
2.5h.The temperature of described annealing furnace is 680 ~ 700 DEG C, and annealing time is 30 ~ 45min.
Claims (8)
1. the method that granite waste residues prepare devitrified glass, it is characterised in that：Comprise the steps：
By quartz sand and basic magnesium carbonate, aluminium hydroxide, ZrO2Mix homogeneously is put in crucible, and is incubated in silicon molybdenum rod furnace
Vitreous humour is poured on into cast molding on the steel plate of preheating afterwards, is placed in annealing furnace and is annealed, obtain the parent glass of homogeneous transparent, so
Devitrified glass is obtained through coring and crystallization process afterwards.
2. the method that granite waste residues according to claim 1 prepare devitrified glass, it is characterised in that：Described quartz sand
With basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.2：55.8：33.0：6.0.
3. the method that granite waste residues according to claim 1 prepare devitrified glass, it is characterised in that：Described quartz sand
With basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.0：55.8：33.2：6.0.
4. the method that granite waste residues according to claim 1 prepare devitrified glass, it is characterised in that：Described quartz sand
With basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.5：55.5：33.5：5.5.
5. the method that granite waste residues according to claim 1 prepare devitrified glass, it is characterised in that：Described quartz sand
With basic magnesium carbonate, aluminium hydroxide, ZrO2Mixed proportion be 5.0：55.5：33.2：6.3.
6. the method that granite waste residues according to claim 1 prepare devitrified glass, it is characterised in that：Described crucible is
Corundum crucible.
7. the method that granite waste residues according to claim 1 prepare devitrified glass, it is characterised in that：Described Si-Mo rod
The temperature of electric furnace is 1500 ~ 1600 DEG C, and temperature retention time is 2 ~ 2.5h.
8. the method that granite waste residues according to claim 1 prepare devitrified glass, it is characterised in that：Described annealing furnace
Temperature be 680 ~ 700 DEG C, annealing time be 30 ~ 45min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611068004.9A CN106517796A (en) | 2016-11-29 | 2016-11-29 | Method of preparing glass ceramics from granite waste residue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611068004.9A CN106517796A (en) | 2016-11-29 | 2016-11-29 | Method of preparing glass ceramics from granite waste residue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106517796A true CN106517796A (en) | 2017-03-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611068004.9A Pending CN106517796A (en) | 2016-11-29 | 2016-11-29 | Method of preparing glass ceramics from granite waste residue |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20190330113A1 (en) * | 2018-04-26 | 2019-10-31 | MagneStone Limited | Synthetic stone |
| CN115094493A (en) * | 2022-06-28 | 2022-09-23 | 无锡乐普金属科技有限公司 | Nickel plating process for stainless steel |
-
2016
- 2016-11-29 CN CN201611068004.9A patent/CN106517796A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20190330113A1 (en) * | 2018-04-26 | 2019-10-31 | MagneStone Limited | Synthetic stone |
| US10858290B2 (en) * | 2018-04-26 | 2020-12-08 | MagneStone Limited | Synthetic stone |
| CN115094493A (en) * | 2022-06-28 | 2022-09-23 | 无锡乐普金属科技有限公司 | Nickel plating process for stainless steel |
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Legal Events
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| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170322 |