CN111926333A - 一种处理热浸镀废板用复合缓蚀剂的制备方法 - Google Patents
一种处理热浸镀废板用复合缓蚀剂的制备方法 Download PDFInfo
- Publication number
- CN111926333A CN111926333A CN202010793540.5A CN202010793540A CN111926333A CN 111926333 A CN111926333 A CN 111926333A CN 202010793540 A CN202010793540 A CN 202010793540A CN 111926333 A CN111926333 A CN 111926333A
- Authority
- CN
- China
- Prior art keywords
- mixed solution
- solution
- corrosion inhibitor
- graphene
- composite corrosion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000007797 corrosion Effects 0.000 title claims abstract description 60
- 238000005260 corrosion Methods 0.000 title claims abstract description 60
- 239000003112 inhibitor Substances 0.000 title claims abstract description 52
- 239000002131 composite material Substances 0.000 title claims abstract description 46
- 239000002699 waste material Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 76
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 57
- 239000000843 powder Substances 0.000 claims abstract description 33
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 30
- 239000010959 steel Substances 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 27
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000012153 distilled water Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000654 additive Substances 0.000 claims abstract description 11
- 230000000996 additive effect Effects 0.000 claims abstract description 11
- 238000004064 recycling Methods 0.000 claims abstract description 10
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N azepane Chemical compound C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims description 70
- 239000011259 mixed solution Substances 0.000 claims description 53
- 229910001335 Galvanized steel Inorganic materials 0.000 claims description 25
- 239000008397 galvanized steel Substances 0.000 claims description 25
- 238000002156 mixing Methods 0.000 claims description 21
- 238000010438 heat treatment Methods 0.000 claims description 20
- 229910002804 graphite Inorganic materials 0.000 claims description 19
- 239000010439 graphite Substances 0.000 claims description 19
- 239000012286 potassium permanganate Substances 0.000 claims description 15
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 238000009210 therapy by ultrasound Methods 0.000 claims description 12
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 9
- 229910017604 nitric acid Inorganic materials 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 8
- 229920001732 Lignosulfonate Polymers 0.000 claims description 7
- 238000007865 diluting Methods 0.000 claims description 7
- 235000019357 lignosulphonate Nutrition 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000011084 recovery Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 239000003153 chemical reaction reagent Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000005530 etching Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000004108 freeze drying Methods 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- 238000004321 preservation Methods 0.000 claims description 5
- 238000003786 synthesis reaction Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 230000002194 synthesizing effect Effects 0.000 claims description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 238000007747 plating Methods 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 238000003618 dip coating Methods 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 235000011149 sulphuric acid Nutrition 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 23
- 229910052742 iron Inorganic materials 0.000 abstract description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract description 2
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 abstract 2
- 238000002791 soaking Methods 0.000 abstract 1
- 239000011701 zinc Substances 0.000 description 12
- 229910052725 zinc Inorganic materials 0.000 description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 7
- 230000005764 inhibitory process Effects 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 238000009616 inductively coupled plasma Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- -1 thiobenzothiazole Chemical compound 0.000 description 2
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- MEUIIHOXOWVKNP-UHFFFAOYSA-N phosphanylformic acid Chemical compound OC(P)=O MEUIIHOXOWVKNP-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/44—Compositions for etching metallic material from a metallic material substrate of different composition
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
- C23F1/14—Aqueous compositions
- C23F1/16—Acidic compositions
- C23F1/30—Acidic compositions for etching other metallic material
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
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CN202010793540.5A CN111926333B (zh) | 2020-08-10 | 2020-08-10 | 一种处理热浸镀废板用复合缓蚀剂的制备方法 |
Applications Claiming Priority (1)
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CN202010793540.5A CN111926333B (zh) | 2020-08-10 | 2020-08-10 | 一种处理热浸镀废板用复合缓蚀剂的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN111926333A true CN111926333A (zh) | 2020-11-13 |
CN111926333B CN111926333B (zh) | 2022-06-24 |
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CN202010793540.5A Active CN111926333B (zh) | 2020-08-10 | 2020-08-10 | 一种处理热浸镀废板用复合缓蚀剂的制备方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113278974A (zh) * | 2021-05-20 | 2021-08-20 | 惠博新型材料有限公司 | 一种用于回收废镀锌钢板的耐盐酸高压反应装置 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102677072A (zh) * | 2012-05-03 | 2012-09-19 | 中国石油大学(华东) | 一种热浸镀钢材的绿色缓蚀清洗剂配方及应用 |
CN102807209A (zh) * | 2012-08-02 | 2012-12-05 | 清华大学 | 一种石墨烯量子点的制备方法 |
CN104231703A (zh) * | 2014-08-06 | 2014-12-24 | 中国海洋大学 | 一种石墨烯复合防腐涂层的制备方法 |
WO2016045035A1 (zh) * | 2014-09-25 | 2016-03-31 | 深圳粤网节能技术服务有限公司 | 石墨烯的制备方法 |
CN106904603A (zh) * | 2017-03-03 | 2017-06-30 | 青岛农业大学 | 一种基于石墨烯卷的缓蚀剂微胶囊及其制备方法 |
CN108659671A (zh) * | 2018-05-14 | 2018-10-16 | 中科广化(重庆)新材料研究院有限公司 | 一种木质素/石墨烯基复合防腐涂层及其制备方法与应用 |
-
2020
- 2020-08-10 CN CN202010793540.5A patent/CN111926333B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102677072A (zh) * | 2012-05-03 | 2012-09-19 | 中国石油大学(华东) | 一种热浸镀钢材的绿色缓蚀清洗剂配方及应用 |
CN102807209A (zh) * | 2012-08-02 | 2012-12-05 | 清华大学 | 一种石墨烯量子点的制备方法 |
CN104231703A (zh) * | 2014-08-06 | 2014-12-24 | 中国海洋大学 | 一种石墨烯复合防腐涂层的制备方法 |
WO2016045035A1 (zh) * | 2014-09-25 | 2016-03-31 | 深圳粤网节能技术服务有限公司 | 石墨烯的制备方法 |
CN106904603A (zh) * | 2017-03-03 | 2017-06-30 | 青岛农业大学 | 一种基于石墨烯卷的缓蚀剂微胶囊及其制备方法 |
CN108659671A (zh) * | 2018-05-14 | 2018-10-16 | 中科广化(重庆)新材料研究院有限公司 | 一种木质素/石墨烯基复合防腐涂层及其制备方法与应用 |
Non-Patent Citations (4)
Title |
---|
CAIO PAIVA POUSA SOARES ET AL: ""Solvothermal Reduction of Graphite Oxide Using Alcohols"", 《MATERIALS RESEARCH》 * |
寇杰: "《油田水处理》", 31 January 2018, 中国石油大学出版社 * |
崔玉民: "《绿色环保功能涂料》", 31 January 2019, 中国书籍出版社 * |
崔维汉: "《中国防腐蚀工程师实用技术大全 第1册》", 31 January 2001, 山西科学技术出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113278974A (zh) * | 2021-05-20 | 2021-08-20 | 惠博新型材料有限公司 | 一种用于回收废镀锌钢板的耐盐酸高压反应装置 |
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CN111926333B (zh) | 2022-06-24 |
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Address after: 251700 Sun Wu Jie Dao Diao Ma Yang Cun (yuan Cun primary school), Huimin County, Binzhou City, Shandong Province Patentee after: Huibo New Materials Co.,Ltd. Address before: 251700 Sun Wu Jie Dao Diao Ma Yang Cun (yuan Cun primary school), Huimin County, Binzhou City, Shandong Province Patentee before: HUIBO NEW MATERIALS CO.,LTD. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method of composite corrosion inhibitor for treating hot-dip plated waste plates Effective date of registration: 20231229 Granted publication date: 20220624 Pledgee: Shandong Huimin Rural Commercial Bank Co.,Ltd. Pledgor: Huibo New Materials Co.,Ltd. Registration number: Y2023980075694 |