CN111728883A - Cleansing oil emulsified to form multi-structure emulsion (W/O/W) and preparation method thereof - Google Patents
Cleansing oil emulsified to form multi-structure emulsion (W/O/W) and preparation method thereof Download PDFInfo
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- CN111728883A CN111728883A CN202010650132.4A CN202010650132A CN111728883A CN 111728883 A CN111728883 A CN 111728883A CN 202010650132 A CN202010650132 A CN 202010650132A CN 111728883 A CN111728883 A CN 111728883A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/066—Multiple emulsions, e.g. water-in-oil-in-water
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
Abstract
The invention discloses cleansing oil emulsified to form multi-structure emulsion (W/O/W) and a preparation method thereof. The makeup remover oil of the multiple structure emulsion (W/O/W) comprises an oil phase, an emulsifier and hydroalcoholic premixed phase, is a homogeneous system formed by premixing polyalcohol, the emulsifier and deionized water, and is prepared by adding the emulsifier and the hydroalcoholic premixed phase into the oil phase. The makeup remover oil emulsified with water to form multiple-structure emulsion (W/O/W) has the advantages that the makeup remover oil has sufficient dissolving capacity for grease, forms multiple emulsified structures through water emulsification, wraps makeup and dirt in an oil phase (intermediate phase) through a double-interface film, forms a special multiple structure due to water emulsification, wraps oil-soluble makeup in the intermediate phase, overcomes the risk that common makeup remover oil is easy to demulsify and causes grease residue and acne, and achieves the purpose of thorough makeup removal and no residue.
Description
Technical Field
The invention relates to the field of makeup remover preparation chemical industry, in particular to makeup remover emulsified to form multiple-structure emulsion (W/O/W) and a preparation method thereof.
Background
In recent years, with the increasing demand for personal images, makeup has become indispensable before going out for every female and some men. With this, there is an increasing need for removing makeup from cosmetics, particularly from make-up products.
At present, the existing makeup removing products can be divided into oil type and water type according to formulation, wherein the makeup removing oil has strong makeup removing power due to the principle that the makeup removing oil is dissolved in oil, and the existing water type makeup removing products have the problems that the makeup removing power is insufficient and the makeup can not be quickly removed for cosmetics with strong oil. Therefore, cleansing oils are still a type of cleansing that many consumers prefer. However, the traditional cleansing oil is thick in texture, not refreshing, slow in emulsification speed, not easy to clean and poor in use feeling.
Disclosure of Invention
The invention mainly aims to provide the makeup removing oil for forming the emulsion with multiple structures in the emulsification process and the preparation method thereof, the makeup removing oil has strong makeup removing force, has fresh skin feeling after use, and can effectively improve the problems stated in the background technology.
In order to achieve the purpose, the invention adopts the technical scheme that:
a makeup remover emulsified to form a multiple structure emulsion (W/O/W) and a preparation method thereof, wherein the makeup remover of the multiple structure emulsion (W/O/W) comprises the following components: the cleansing oil comprises an oil phase, an O/W and W/O type emulsifier phase and a hydroalcoholic premixed phase, wherein the emulsifier and hydroalcoholic premixed phase is a homogeneous system formed by premixing polyol, an emulsifier and deionized water, the mass ratio of the polyol to the emulsifier to the deionized water is 0.1-10:1-20:5-20, the mass ratio of the O/W to the W/O type emulsifier is 1-10:1-10, and the cleansing oil capable of forming a multi-structure emulsion (W/O/W) when meeting water is prepared by adding the emulsifier phase and the hydroalcoholic premixed phase into the oil phase.
Further, the mass percentage of the oil phase in the cleansing oil is 50-90%.
Further, the oil phase is at least one oil selected from the group consisting of vegetable oils and fats and synthetic oils and fats.
Still further, the vegetable fats and oils include corn germ oil, sunflower seed oil, grape seed oil, sweet almond seed oil, shea butter, olive fruit oil, jojoba seed oil, glass chicory seed oil, elderberry oil and sea buckthorn fruit oil, and the synthetic fats and oils include coco-caprylate/caprate, dioctyl carbonate, glycerol tri (ethylhexanoate), isopropyl palmitate, isopropyl myristate, pentaerythritol tetra (ethylhexanoate), C12-15 alcohol benzoate, diisopropyl sebacate, C11-13 alkane, isononyl isononanoate, isohexadecane and cyclopenta dimethyl siloxane.
Further, the polyalcohol is at least one selected from glycerol, butanediol, 1, 2-propylene glycol, 1, 3-propylene glycol, polyethylene glycol-8, dipropylene glycol, 1, 2-pentanediol and 1, 2-hexanediol.
Further, the O/W type emulsifier is at least one selected from the group consisting of polyglycerin-10 oleate, sorbitan polyether-30 tetraoleate, polyglycerin-6 dicaprate, polyglycerin-10 dioleate, polyglycerin-10 diisostearate, and polyglycerin-6 oleate.
Further, the W/O type emulsifier is at least one selected from polyglycerol-3 polyricinoleate, sorbitan trioleate, sorbitan sesquioleate, polyglycerol-2 sesquicaprylate, polyglycerol-2 oleate, PEG-20 glycerol triisostearate, PEG-8 diisostearate and sorbitan oleate.
Further, the oil phase of the cleansing oil of the multiple structure emulsion (W/O/W) comprises the following oil in parts by weight: 20-50 parts of sunflower seed oil, 18-40 parts of coconut oil alcohol-caprylate/caprate, 5-20 parts of dioctyl carbonate, 1-20 parts of grape seed oil and 1-20 parts of jojoba seed oil; the emulsifier comprises the following components in parts by weight: 1-20 parts of sorbitol polyether-30 tetraoleate, 1-20 parts of polyglycerol-3 polyricinoleate and 1-20 parts of polyglycerol-6 didecanoate; the polyol comprises the following components in parts by weight: 0.1-10 parts of butanediol, 0.1-10 parts of 1, 2-pentanediol, 0.1-10 parts of 1, 2-hexanediol and 0.1-10 parts of dipropylene glycol.
The preparation method of the cleansing oil emulsified to form the multi-structure emulsion (W/O/W) comprises the following steps:
s1: preparing an emulsifier and hydroalcoholic premixed phase, sequentially adding an O/W and W/O type emulsifier, deionized water and a polyol premixed phase into a stirring container, and fully and uniformly stirring for later use;
s2: preparing an oil phase: sequentially adding the oil phase components into a stirring container, and fully and uniformly stirring for later use;
s3: and adding the premixed phase of the emulsifier and the hydroalcoholic solvent prepared in the step S1 into the oil phase prepared in the step S2, and stirring until the system is transparent, so that the cleansing oil of the multi-structure emulsion (W/O/W) is prepared.
Compared with the prior art, the invention has the following beneficial effects: the cleansing oil of the multiple-structure emulsion (W/O/W) has sufficient dissolving capacity for grease, and because the cleansing oil of the invention forms a special multiple structure by emulsifying in water, oil-soluble color cosmetics are wrapped in a mesophase, so that the risk of oil residue and acne caused by easy demulsification of common cleansing oil is overcome, and the purpose of thorough cleansing without residue is achieved.
Drawings
FIGS. 1 to 3 are photographs of emulsified particles of a sample according to the present invention in a W/O/W multiple structure under a microscope.
Detailed Description
The following detailed description of the preferred embodiments of the present invention is provided to enable those skilled in the art to more readily understand the advantages and features of the present invention, and to clearly and unequivocally define the scope of the present invention.
In this embodiment, a makeup remover for emulsifying to form a multiple-structure emulsion (W/O/W) and a preparation method thereof, the makeup remover for the multiple-structure emulsion (W/O/W) includes the following components: an oil phase, an emulsifier phase, a premixed phase of water and alcohol. The emulsifier phase and the hydroalcoholic premixed phase are prepared by premixing a W/O and O/W type emulsifier, deionized water and polyol and fully and uniformly stirring. The oil phase is prepared by uniformly stirring all the grease. The cleansing oil is prepared by adding W/O and O/W type emulsifiers and a hydroalcoholic premixed phase into an oil phase under stirring.
The oil phase of the invention is selected from at least one of the following fats: corn (ZEA MAYS) germ oil, sunflower (heliothis ANNUUS) seed oil, grape (VITIS VINIFERA) seed oil, sweet almond (PRUNUS amygdalus sdulscis) seed oil, BUTYROSPERMUM PARKII (butysrospermum PARKII) fruit fat, olive (oleea EUROPAEA) fruit oil, jojoba (SIMMONDSIA CHINENSIS) seed oil, witloof (BORAGO OFFICINALIS) seed oil, SAMBUCUS NIGRA (SAMBUCUS NIGRA) oil, sea buckthorn (HIPPOPHAE RHAMNOIDES) fruit oil, coco-octanoate/decanoate, dicaprylyl carbonate, glycerol tri (ethylhexanoate), isopropyl palmitate, isopropyl myristate, pentaerythritol tetra (ethylhexanoate), C12-15 alcohol benzoate, diisopropyl sebacate, C11-13 alkane, isononyl isononanoate, isohexadecane and cyclopentadimethylsiloxane. Preferably, the oil phase of the present invention is a mixture of various oils and fats, and specifically includes sunflower (helioanthhus nnuus) seed oil, coco-caprylate/caprate, dicaprylyl carbonate, grape (VITIS VINIFERA) seed oil, and jojoba (SIMMONDSIA CHINENSIS) seed oil. The oil phase of the invention is prepared from the following oil in proportion: 20-50 parts of sunflower seed oil, 20-40 parts of coconut oil alcohol-caprylate/caprate, 5-20 parts of dioctyl carbonate, 1-20 parts of grape seed oil and 1-20 parts of jojoba seed oil.
The O/W type emulsifier is at least one selected from polyglycerol-10 oleate, sorbitan polyether-30 tetraoleate, polyglycerol-6 dicaprate, polyglycerol-10 dioleate, polyglycerol-10 diisostearate and polyglycerol-6 oleate.
The W/O type emulsifier is at least one selected from polyglycerol-3 polyricinoleate, sorbitan trioleate, sorbitan sesquioleate, polyglycerol-2 sesquicaprylate, polyglycerol-2 oleate, PEG-20 glycerol triisostearate, PEG-8 diisostearate and sorbitan oleate.
The emulsifier of the invention is a mixture of sorbitol polyether-30 tetraoleate, polyglycerol-3 ricinoleate and polyglycerol-6 didecanoate.
The present invention will be described in detail with reference to specific examples below:
example 1:
the makeup remover oil forming a multi-structure emulsion (W/O/W) in water in the embodiment comprises the following raw materials in percentage by mass: 73 parts of oil phase, 3 parts of butanediol, 10 parts of O/W type emulsifier, 10 parts of W/O type emulsifier and 7 parts of deionized water.
The oil phase of this example is a mixture of the following fats: the oil is prepared from sunflower (Helianthus ANNUUS) seed oil, coconut oil alcohol-caprylate/caprate, dioctyl carbonate, grape (VITIS VINIFERA) seed oil, and jojoba (Simmondsiachinensis) seed oil, wherein the oil is mixture of sorbitan polyether-30 tetraoleate, polyglycerol-3 ricinoleate, and polyglycerol-6 dicaprate, and the proportion of the emulsifiers can be adjusted according to requirement.
Weighing the emulsifier, the deionized water and the butanediol according to the formula ratio, premixing, fully and uniformly stirring, adding into the mixture of the grease, and stirring until the system is uniform and transparent, thus preparing the cleansing oil of the embodiment.
Example 2:
the makeup remover oil forming a multi-structure emulsion (W/O/W) in water in the embodiment comprises the following raw materials in percentage by mass: 50 parts of oil phase, 10 parts of a mixture of butanediol and 1, 2-hexanediol, 15 parts of O/W type emulsifier, 10 parts of W/O type emulsifier and 15 parts of deionized water.
The oil phase composition of this example was the same as in example 1, and the amount of each oil or fat added to the oil phase was adjusted as needed. The emulsifier components of this example were the same as in example 1, and the amount of each emulsifier added was adjusted as needed.
The method of preparing the cleansing oil according to this example was performed with reference to example 1.
Example 3:
the makeup remover oil forming a multi-structure emulsion (W/O/W) in water in the embodiment comprises the following raw materials in percentage by mass: 70 parts of grease, 10 parts of 1, 2-pentanediol, 10 parts of O/W type emulsifier, 5 parts of W/O type emulsifier and 5 parts of deionized water.
The oil phase composition of this example was the same as in example 1, and the amount of each oil or fat added to the oil phase was adjusted as needed. The emulsifier components of this example were the same as in example 1, and the amount of each emulsifier added was adjusted as needed.
The method of preparing the cleansing oil according to this example was performed with reference to example 1.
Example 4:
the makeup remover oil forming a multi-structure emulsion (W/O/W) in water in the embodiment comprises the following raw materials in percentage by mass: 80 parts of grease, 2 parts of 1, 2-pentanediol, 8 parts of O/W type emulsifier, 7 parts of W/O type emulsifier and 3 parts of water.
The oil phase composition of this example was the same as in example 1, and the amount of each oil or fat added to the oil phase was adjusted as needed. The components of the emulsifier in this example were the same as in example 1, and the amount of each emulsifier added was adjusted as needed.
The method of preparing the cleansing oil according to this example was performed with reference to example 1.
The cleansing oil prepared in each embodiment of the invention is subjected to stability test, sensitive muscle group patch test, group evaluation test and microscope experiment.
The stability tests included high temperature, low temperature and cold thermal cycling tests. Namely, the cleansing oil of the invention is respectively placed at 45 ℃, 25 ℃ and 4 ℃ for 8 weeks, and the appearance of the product is regularly observed whether abnormal phenomena such as turbidity, layering and the like occur. And observing whether the appearance of the product is abnormal or not after the product is subjected to cold and hot circulation for 3 times at the cold and hot circulation temperature of-18 ℃/25 ℃.
The sensitive muscle patch test is to screen 33 sensitive muscle subjects through a sensitive muscle screening questionnaire and a lactic acid stabbing pain questionnaire, and finally 33 subjects complete the test, wherein 7 men and 26 women are 7 and the age is 19-55 years old. The spot tester with the test substance and the control spot tester are applied to the curved side of the forearm of a sensitive muscle subject, and are lightly pressed with the palm to be uniformly applied to the skin for 24 hours. The skin reactions were observed according to the standard of table 2 30min (after disappearance of the indentation), 24h and 48h after removal of the test article plaque test device, respectively, and the observation results were recorded.
The qualified spot test device with the area not more than 50mm2 and the depth of about 1mm is selected. The test article is placed in a spot tester cell in an amount of about 0.020g to about 0.025 g. The spot tester and the control spot tester with the test substance are applied to the curved side of the forearm of the subject, and are lightly pressed with the palm to be uniformly applied to the skin for 24 hours. Skin reactions were observed at 30min (after disappearance of the indentation), 24h and 48h after removal of the test article plaque test apparatus, respectively, according to the criteria of table 1, and the observation results were recorded. The scoring criteria for the patch test are shown in table 1:
TABLE 1 skin closed Patch test skin response grading Standard
The test method for evaluating the crowd of the cleansing oil comprises the following steps: selecting 18-45 years old volunteers who make up at least 3 times per week, and taking 30 cases in total. The test period is four weeks, the test is used every day, and the use method comprises the following steps: the face cleansing oil with the size of the first yuan of coins is taken by dry hands, the whole face is massaged for no more than one minute in a circling way, water is added for emulsification, the circling and massage are carried out for 0.5 to 1 minute, the action is gentle, and the face cleansing oil is washed clean by warm water.
The cleansing oil disclosed by the invention is used for evaluating two indexes of makeup removing ability and skin feeling after use, and a grading system is adopted for evaluating each index.
The specific grading criteria for cleansing power are:
level 1: the color cosmetics and dirt are clean and quick in the using process.
And 2, stage: the color cosmetics and dirt cleaning power is common in the using process.
And 3, level: the color cosmetics and dirt cleaning ability is poor in the using process.
The skin feel after use was specifically graded as:
level 1: after the skin care product is used, the skin has no adverse reaction, is not dried, and is fresh and moist.
And 2, stage: after the skin care product is used, the skin has no adverse reaction, and cannot be dry and wet.
And 3, level: after the skin care product is used, the skin does not have adverse reaction, and the feeling of the skin care product is greasy or very dry.
The results of the population evaluation of the cleansing oils of examples 1 to 4 of the present invention are shown in Table 2.
Table 2 evaluation results of cleansing power and skin feel after use of the cleansing oils of examples 1 to 4
The results of the stability tests performed on the cleansing oils of examples 1 to 4 of the present invention are shown in Table 3.
Table 3 examples 1-4 stability test results
Therefore, the cleansing oil of each embodiment of the invention has stable system, heat resistance of 45 ℃, cold resistance of-18 ℃ and stable and abnormal cold and heat circulation.
Through the spot-on test of sensitive skin crowds of the cleansing oil of the embodiments 1 to 4, the result score grades are all 0 grade, which shows that the cleansing oil has extremely low irritation and no adverse reaction exists in the sensitive skin crowds subjected to the residual test.
Through the crowd evaluation test of the cleansing oil of the embodiments 1 to 4, the test subjects generally believe that the cleansing oil of the invention has good spreadability, fresh and non-greasy skin after use, high cleansing speed and emulsification speed, easy washing and excellent cleansing power.
The microscopic experiment refers to sucking 3ml of cleansing oil with a suction tube, dropping into a 500ml beaker with deionized water at one time, standing for 5min, taking the last emulsion, sampling to make a tablet, observing under a microscope (model: LC-202DB) and taking photographs, which are shown in figures 1 to 3.
The foregoing shows and describes the general principles and broad features of the present invention and advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (9)
1. The makeup remover oil is characterized in that the makeup remover oil of the multiple structure emulsion (W/O/W) comprises the following components: an oil phase, an emulsifier phase and a hydroalcoholic premix phase;
the makeup removing oil for the multiple structure emulsion (W/O/W) is prepared by fully premixing two types of emulsifiers and a hydroalcoholic premixed phase and then adding the two types of emulsifiers into an oil phase at one time, wherein the two types of emulsifiers comprise a W/O type emulsifier and an O/W type emulsifier, the makeup removing oil for forming the multiple structure emulsion (W/O/W) when meeting water is prepared by uniformly premixing an emulsifier phase and the hydroalcoholic premixed phase and then adding the emulsifier phase and the hydroalcoholic premixed phase into the oil phase, and a double structure with two interface films of O/W and W/O is formed in the process of emulsifying the makeup removing oil when meeting water.
2. The cleansing oil emulsified to form a multi-structured emulsion (W/O/W) according to claim 1, wherein the oil phase is present in the cleansing oil in an amount of 50 to 90% by weight.
3. The cleansing oil emulsified to form a multiple structured emulsion (W/O/W) according to claim 2, wherein the oil phase is at least one oil selected from the group consisting of vegetable oils and fats and synthetic oils.
4. The cleansing oil emulsified to form a multiple structured emulsion (W/O/W) according to claim 3, wherein said vegetable oils comprise corn germ oil, sunflower seed oil, grape seed oil, sweet almond seed oil, shea butter, olive fruit oil, jojoba seed oil, glass chicory seed oil, Sambucus nigra oil and sea buckthorn fruit oil, and said synthetic oils comprise coco-caprylate/caprate, dioctyl carbonate, tri (ethylhexanoate), ethylhexyl palmitate, isopropyl myristate, pentaerythritol tetra (ethylhexanoate), C12-15 alcohol benzoate, diisopropyl sebacate, C11-13 alkane, isononyl isononanoate, isohexadecane and cyclopenta dimethyl siloxane.
5. The cleansing oil emulsified to form a multiple structured emulsion (W/O/W) according to claim 1 wherein the polyhydric alcohol is at least one selected from the group consisting of glycerin, butylene glycol, 1, 2-propanediol, 1, 3-propanediol, polyethylene glycol-8, dipropylene glycol, 1, 2-pentanediol, and 1, 2-hexanediol.
6. The makeup remover emulsified to form a multiple structure emulsion (W/O/W) according to claim 1, wherein said O/W type emulsifier is at least one selected from the group consisting of polyglycerin-10 oleate, sorbitan polyether-30 tetraoleate, polyglycerin-6 didecanoate, polyglycerin-10 dioleate, polyglycerin-10 diisostearate, and polyglycerin-6 oleate.
7. The makeup remover emulsified to form a multiple structure emulsion (W/O/W) according to claim 1, wherein said W/O type emulsifier is at least one selected from polyglycerin-3 polyricinoleate, sorbitan trioleate, sorbitan sesquioleate, polyglycerin-2 sesquicaprylate, polyglycerin-2 oleate, PEG-20 glyceryl triisostearate, PEG-8 diisostearate, sorbitan oleate.
8. The cleansing oil emulsified to form a multiple structured emulsion (W/O/W) according to any one of claims 1 to 7, wherein the oil phase comprises the following parts by weight of fats and oils: 20-50 parts of sunflower seed oil, 18-40 parts of coconut oil alcohol-caprylate/caprate, 5-20 parts of dioctyl carbonate, 1-20 parts of grape seed oil and 1-20 parts of jojoba seed oil; the emulsifier comprises the following components in parts by weight: 1-20 parts of sorbitol polyether-30 tetraoleate, 1-20 parts of polyglycerol-3 polyricinoleate and 1-20 parts of polyglycerol-6 didecanoate; the polyol comprises the following components in parts by weight: 0.1-10 parts of butanediol, 0.1-10 parts of 1, 2-pentanediol, 0.1-10 parts of 1, 2-hexanediol and 0.1-10 parts of dipropylene glycol.
9. Method for preparing a makeup remover according to any one of claims 1 to 8 emulsified to form a multiple structured emulsion (W/O/W), characterized in that it comprises the following steps:
s1: preparing an emulsifier and hydroalcoholic premixed phase: sequentially adding an O/W emulsifier, a W/O emulsifier, deionized water and polyol into a stirring container, and fully and uniformly stirring for later use;
s2: preparing an oil phase: sequentially adding the oil phase components into a stirring container, and fully and uniformly stirring for later use;
s3: and adding the premixed phase of the emulsifier and the hydroalcoholic solvent prepared in the step S1 into the oil phase prepared in the step S2, and stirring until the system is transparent, so that the cleansing oil of the multi-structure emulsion (W/O/W) is prepared.
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