CN111686796B - 油砂沥青非临氢减粘改质催化剂及其制备方法和应用 - Google Patents
油砂沥青非临氢减粘改质催化剂及其制备方法和应用 Download PDFInfo
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- CN111686796B CN111686796B CN202010642016.8A CN202010642016A CN111686796B CN 111686796 B CN111686796 B CN 111686796B CN 202010642016 A CN202010642016 A CN 202010642016A CN 111686796 B CN111686796 B CN 111686796B
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- oil sand
- sand asphalt
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- ultrasonic impregnation
- acid
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- 239000010426 asphalt Substances 0.000 title claims abstract description 96
- 239000003027 oil sand Substances 0.000 title claims abstract description 90
- 239000003054 catalyst Substances 0.000 title claims abstract description 52
- 230000004048 modification Effects 0.000 title claims abstract description 38
- 238000012986 modification Methods 0.000 title claims abstract description 38
- 238000005984 hydrogenation reaction Methods 0.000 title abstract description 28
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 75
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 75
- 239000010457 zeolite Substances 0.000 claims abstract description 75
- 238000001035 drying Methods 0.000 claims abstract description 69
- 239000002253 acid Substances 0.000 claims abstract description 55
- 239000000243 solution Substances 0.000 claims abstract description 41
- 230000009467 reduction Effects 0.000 claims abstract description 31
- 239000012266 salt solution Substances 0.000 claims abstract description 28
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 15
- 150000003624 transition metals Chemical class 0.000 claims abstract description 15
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 14
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 14
- 238000005470 impregnation Methods 0.000 claims description 74
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 29
- 239000001257 hydrogen Substances 0.000 claims description 29
- 229910052739 hydrogen Inorganic materials 0.000 claims description 29
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000008367 deionised water Substances 0.000 claims description 13
- 229910021641 deionized water Inorganic materials 0.000 claims description 13
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 12
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims description 12
- 229910001603 clinoptilolite Inorganic materials 0.000 claims description 12
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 7
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 6
- 235000019270 ammonium chloride Nutrition 0.000 claims description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 6
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 6
- 229910017604 nitric acid Inorganic materials 0.000 claims description 6
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 claims description 4
- 229960002089 ferrous chloride Drugs 0.000 claims description 3
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 36
- 238000000034 method Methods 0.000 abstract description 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 18
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 18
- 229910052717 sulfur Inorganic materials 0.000 abstract description 18
- 239000011593 sulfur Substances 0.000 abstract description 18
- 230000008569 process Effects 0.000 abstract description 9
- 239000011159 matrix material Substances 0.000 abstract description 8
- 239000003208 petroleum Substances 0.000 abstract description 7
- 230000008901 benefit Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000005265 energy consumption Methods 0.000 abstract description 4
- 239000003921 oil Substances 0.000 description 18
- 238000001514 detection method Methods 0.000 description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 238000004523 catalytic cracking Methods 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 8
- 238000005457 optimization Methods 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229910001385 heavy metal Inorganic materials 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 238000005336 cracking Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 239000010779 crude oil Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 4
- 239000002358 oil sand bitumen Substances 0.000 description 4
- 230000002572 peristaltic effect Effects 0.000 description 4
- 238000005086 pumping Methods 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 239000006004 Quartz sand Substances 0.000 description 3
- 238000010795 Steam Flooding Methods 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 238000010793 Steam injection (oil industry) Methods 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- CQBLUJRVOKGWCF-UHFFFAOYSA-N [O].[AlH3] Chemical compound [O].[AlH3] CQBLUJRVOKGWCF-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000000852 hydrogen donor Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- -1 salt compounds Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/592—Compositions used in combination with generated heat, e.g. by steam injection
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C3/00—Working-up pitch, asphalt, bitumen
- C10C3/002—Working-up pitch, asphalt, bitumen by thermal means
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C3/00—Working-up pitch, asphalt, bitumen
- C10C3/02—Working-up pitch, asphalt, bitumen by chemical means reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
项目 | 粘度/(Pa·s) | 减粘率/% |
油砂沥青 | 35.4 | - |
实施例13 | 26.1 | 26.27 |
实施例14 | 25.5 | 27.97 |
实施例15 | 19.6 | 44.63 |
项目 | 饱和分/% | 芳香分/% | 胶质/% | 沥青质/% |
油砂沥青 | 28.01 | 38.52 | 24.96 | 8.51 |
实施例13 | 25.80 | 40.36 | 21.94 | 11.89 |
实施例14 | 23.20 | 40.87 | 23.62 | 12.30 |
实施例15 | 23.21 | 41.78 | 23.61 | 11.40 |
对比例1 | 23.73 | 40.65 | 23.21 | 12.41 |
对比例2 | 25.47 | 39.61 | 21.91 | 13.01 |
对比例3 | 24.22 | 39.67 | 22.56 | 13.55 |
Claims (1)
Priority Applications (1)
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CN202010642016.8A CN111686796B (zh) | 2020-07-06 | 2020-07-06 | 油砂沥青非临氢减粘改质催化剂及其制备方法和应用 |
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CN202010642016.8A CN111686796B (zh) | 2020-07-06 | 2020-07-06 | 油砂沥青非临氢减粘改质催化剂及其制备方法和应用 |
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CN111686796A CN111686796A (zh) | 2020-09-22 |
CN111686796B true CN111686796B (zh) | 2023-11-10 |
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CN202010642016.8A Active CN111686796B (zh) | 2020-07-06 | 2020-07-06 | 油砂沥青非临氢减粘改质催化剂及其制备方法和应用 |
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03249947A (ja) * | 1990-02-26 | 1991-11-07 | Sekiyu Sangyo Kasseika Center | 炭化水素油の接触分解用触媒組成物ならびにそれを用いる接触分解法 |
CN1729275A (zh) * | 2002-12-20 | 2006-02-01 | 艾尼股份公司 | 重质原料例如重质原油和蒸馏渣油转化的方法 |
CN101301621A (zh) * | 2008-06-24 | 2008-11-12 | 同济大学 | 煤焦油沥青轻质化制油裂化催化剂制备和应用方法 |
CN101322945A (zh) * | 2008-08-01 | 2008-12-17 | 中国海洋石油总公司 | 一种含硫凝析油改质催化剂的制备方法及用途 |
CN101597511A (zh) * | 2008-06-04 | 2009-12-09 | 中国石油天然气股份有限公司 | 一种超重原油改质处理的工艺方法 |
CN102899078A (zh) * | 2011-07-29 | 2013-01-30 | 中国石油化工股份有限公司 | 一种生产丙烯的催化裂化方法 |
CN105772070A (zh) * | 2016-02-23 | 2016-07-20 | 新疆恒晟能源科技有限公司 | 一种用于汽油非临氢改质的催化剂及其制备方法 |
CN107541249A (zh) * | 2017-07-01 | 2018-01-05 | 上海英保能源化工科技有限公司 | 一种劣质重油轻质化组合工艺 |
CN108587668A (zh) * | 2018-03-29 | 2018-09-28 | 南京大学连云港高新技术研究院 | 一种劣质重油废塑料裂解脱硫减粘生产轻质油气的方法 |
CN108587675A (zh) * | 2018-03-29 | 2018-09-28 | 南京大学连云港高新技术研究院 | 一种重油减粘的方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060272983A1 (en) * | 2005-06-07 | 2006-12-07 | Droughton Charlotte R | Processing unconventional and opportunity crude oils using zeolites |
CA2630075C (en) * | 2008-04-28 | 2013-12-31 | Imperial Oil Resources Limited | Process for extraction of bitumen from oilsands |
-
2020
- 2020-07-06 CN CN202010642016.8A patent/CN111686796B/zh active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03249947A (ja) * | 1990-02-26 | 1991-11-07 | Sekiyu Sangyo Kasseika Center | 炭化水素油の接触分解用触媒組成物ならびにそれを用いる接触分解法 |
CN1729275A (zh) * | 2002-12-20 | 2006-02-01 | 艾尼股份公司 | 重质原料例如重质原油和蒸馏渣油转化的方法 |
CN101597511A (zh) * | 2008-06-04 | 2009-12-09 | 中国石油天然气股份有限公司 | 一种超重原油改质处理的工艺方法 |
CN101301621A (zh) * | 2008-06-24 | 2008-11-12 | 同济大学 | 煤焦油沥青轻质化制油裂化催化剂制备和应用方法 |
CN101322945A (zh) * | 2008-08-01 | 2008-12-17 | 中国海洋石油总公司 | 一种含硫凝析油改质催化剂的制备方法及用途 |
CN102899078A (zh) * | 2011-07-29 | 2013-01-30 | 中国石油化工股份有限公司 | 一种生产丙烯的催化裂化方法 |
CN105772070A (zh) * | 2016-02-23 | 2016-07-20 | 新疆恒晟能源科技有限公司 | 一种用于汽油非临氢改质的催化剂及其制备方法 |
CN107541249A (zh) * | 2017-07-01 | 2018-01-05 | 上海英保能源化工科技有限公司 | 一种劣质重油轻质化组合工艺 |
CN108587668A (zh) * | 2018-03-29 | 2018-09-28 | 南京大学连云港高新技术研究院 | 一种劣质重油废塑料裂解脱硫减粘生产轻质油气的方法 |
CN108587675A (zh) * | 2018-03-29 | 2018-09-28 | 南京大学连云港高新技术研究院 | 一种重油减粘的方法 |
Non-Patent Citations (2)
Title |
---|
Upgrading vacuum distillation residue of oil refinery using microwave irradiation;Zarrin Nasri;《Chemical Engineering & Processing: Process Intensification》;20191009;第146卷;第1-15页 * |
古阶祥 著.沸石的催化性能.《沸石》.中国建筑工业出版社,1980,第42,44页. * |
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