CN111533545A - 多功能负离子能量片及其制备方法 - Google Patents

多功能负离子能量片及其制备方法 Download PDF

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CN111533545A
CN111533545A CN202010416981.3A CN202010416981A CN111533545A CN 111533545 A CN111533545 A CN 111533545A CN 202010416981 A CN202010416981 A CN 202010416981A CN 111533545 A CN111533545 A CN 111533545A
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邓小武
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Abstract

本发明公开了多功能负离子能量片,由下述重量配比的原材料制成:六环石5‑8份、锗石5‑6份、砭石3‑5份、石英10‑15份、电气石3‑5份、氧化镁1‑2份、氧化锆1‑3份、氧化锌2‑3份、氧化钙1‑2份、氧化锰3‑5份、高岭土4‑5份、硅藻土3‑5份、稀土5‑8份、去离子水20‑25份、碳酸钙2‑3份、氢氧化铝粉3‑5份、硝酸银3‑5份、硝酸钡2‑3份、硝酸铁2‑3份、硝酸镍2‑3份、柠檬酸1‑2份、聚乙烯醇3‑5份、石墨烯分散液15‑20份、氨水10‑13份。

Description

多功能负离子能量片及其制备方法
技术领域
涉及多功能负离子能量片及其制备方法。
背景技术
自然界中存在着一些天然玉石、矿石等能释放一定量的空气负离子、远红外线、磁场,但往往性能单一、功效较差。而且往往数量稀少、价格昂贵、大小和形状也都受到限制,不利于实际应用。
且市面上的大多数涂覆型的负离子产品,在距离涂覆层30CM外就基本检测不到空气负离子。
发明内容
本发明为克服上述情况不足,旨在提供能解决上述问题的技术方案。
多功能负离子能量片,由下述重量配比的原材料制成:六环石5-8份、锗石5-6份、砭石3-5份、石英10-15份、电气石3-5份、氧化镁1-2份、氧化锆1-3份、氧化锌2-3份、氧化钙1-2份、氧化锰3-5份、高岭土4-5份、硅藻土3-5份、稀土5-8份、去离子水20-25份、碳酸钙2-3份、氢氧化铝粉3-5份、硝酸银3-5份、硝酸钡2-3份、硝酸铁2-3份、硝酸镍2-3份、柠檬酸1-2份、聚乙烯醇3-5份、石墨烯分散液15-20份、氨水10-13份。
多功能负离子能量片的制备方法,包括以下步骤:
步骤一:将六环石、锗石、砭石、石英、电气石分别放置于粉碎设备中进行粉碎,粉碎至400目,得到六环石粉、锗石粉、砭石粉、石英粉、电气石粉;
步骤二:将氧化镁、氧化锆、氧化锌、氧化钙、氧化锰放入至混合设备中进行搅拌混合,得到第一混合物料,将第一混合物料水化72小时;
步骤三:将第一混合物料、六环石粉、锗石粉、砭石粉、硅藻土、石英粉、稀土和去离子水一同加入到混合设备中进行搅拌混合至膏状,得到第二混合物料,而后将第二混合物料熟化24小时,再加入适量高岭土搅拌成泥状,而后压制成第一薄层坯料待用;
步骤四:将碳酸钙、氢氧化铝粉、氧化锌加入至混合设备中进行混合,得到混合粉料;
步骤五:将混合粉料加入至少恒温池中,进行反应,恒温池温度控制在50℃,待反应结束后,得到浸泡溶液,恒温池中的浸泡溶液气泡消失后自然降温至30℃;
步骤六:将硝酸银和稀土与浸泡溶液一同加入至搅拌机中搅拌3小时,而后进行中和处理7小时,而后进行清洗过滤,除去浸泡溶液中的酸根离子;
步骤七:将电气石粉、砭石粉、氧化铝、石英粉一同加入到混合设备中进行搅拌混合,而后加入水球研磨3小时后进行超声乳化30分钟,在进行水球研磨3小时,而后陈化24小时后得到釉料坯料待用;
步骤八:将硝酸钡、硝酸铁、硝酸镍加入混合设备中进行混合,而后加入柠檬酸和去离子水进行二次搅拌至完全溶解,得到第三混合物料;
步骤九:将氨水加入到第三混合物料中,通过氨水调节第三混合物料的PH至6-7,而后进行水浴加热至80-90℃,持续搅拌至溶液挥发完全,得到溶胶前驱体;
步骤十:将溶胶前驱体放入干燥设备中,在100-120℃的环境下干燥4天后,以1-2℃/min的速度升温至800℃,保温3h后降温得到镍掺杂钡铁氧体粉体先驱体;
步骤十一:将镍掺杂钡铁氧体粉体先驱体进行球磨处理,而后加入聚乙烯醇与镍掺杂钡铁氧体粉体充分混合后,压制成第二薄层坯料待用;
步骤十二:将第一薄层坯料压制在第二薄层坯料的外层上,而后放入至烧制炉体中,通入0.1-0.5MP压缩空气,以2-3℃/min升温至400℃,保温3小时排胶,而后以200-400℃/h升温至1200-1250℃,接着保温3小时,烧结完成后自然降至常温,得到素胚;
步骤十三:将素胚完全放入石墨烯分散液中超声浸渍1小时,而后取出烘干,喷涂釉料至素胚表面,而后微波低温烧制成型。
作为本发明进一步的方案:所述步骤五中的恒温池为40%溶度磷酸恒温池。
与现有技术相比,本发明的有益效果是:
负离子能量片在使用时候可释放负离子、远红外线、磁场,而与人体摩擦还能产生脉冲超声波。而且价格相比天然玉石便宜且效果更佳,最重要的是通过特定的组合,该多功能负离子能量片所释放的空气负离子的迁移距离比其他涂覆型的负离子产品更远。
负离子能量片在距离釉料层1M外依然能清晰的检测到空气负离子,且检测数值与距离釉料层30CM处检测数值基本一致。
除此之外,在与人体摩擦时产生与天然砭石相近的超声波脉冲数。在保健养生、瓷砖、日用品等领域具有广阔的市场前景和应用价值。
本发明的附加方面和优点将在下面的描述中部分给出,部分将从下面的描述中变得明显,或通过本发明的实践了解到。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
本发明实施例中,本发明公开了多功能负离子能量片,由下述重量配比的原材料制成:六环石5-8份、锗石5-6份、砭石3-5份、石英10-15份、电气石3-5份、氧化镁1-2份、氧化锆1-3份、氧化锌2-3份、氧化钙1-2份、氧化锰3-5份、高岭土4-5份、硅藻土3-5份、稀土5-8份、去离子水20-25份、碳酸钙2-3份、氢氧化铝粉3-5份、硝酸银3-5份、硝酸钡2-3份、硝酸铁2-3份、硝酸镍2-3份、柠檬酸1-2份、聚乙烯醇3-5份、石墨烯分散液15-20份、氨水10-13份。
多功能负离子能量片的制备方法,包括以下步骤:
步骤一:将六环石、锗石、砭石、石英、电气石分别放置于粉碎设备中进行粉碎,粉碎至400目,得到六环石粉、锗石粉、砭石粉、石英粉、电气石粉;
步骤二:将氧化镁、氧化锆、氧化锌、氧化钙、氧化锰放入至混合设备中进行搅拌混合,得到第一混合物料,将第一混合物料水化72小时;
步骤三:将第一混合物料、六环石粉、锗石粉、砭石粉、硅藻土、石英粉、稀土和去离子水一同加入到混合设备中进行搅拌混合至膏状,得到第二混合物料,而后将第二混合物料熟化24小时,再加入适量高岭土搅拌成泥状,而后压制成第一薄层坯料待用;
步骤四:将碳酸钙、氢氧化铝粉、氧化锌加入至混合设备中进行混合,得到混合粉料;
步骤五:将混合粉料加入至少恒温池中,进行反应,恒温池温度控制在50℃,待反应结束后,得到浸泡溶液,恒温池中的浸泡溶液气泡消失后自然降温至30℃;
步骤六:将硝酸银和稀土与浸泡溶液一同加入至搅拌机中搅拌3小时,而后进行中和处理7小时,而后进行清洗过滤,除去浸泡溶液中的酸根离子;
步骤七:将电气石粉、砭石粉、氧化铝、石英粉一同加入到混合设备中进行搅拌混合,而后加入水球研磨3小时后进行超声乳化30分钟,在进行水球研磨3小时,而后陈化24小时后得到釉料坯料待用;
步骤八:将硝酸钡、硝酸铁、硝酸镍加入混合设备中进行混合,而后加入柠檬酸和去离子水进行二次搅拌至完全溶解,得到第三混合物料;
步骤九:将氨水加入到第三混合物料中,通过氨水调节第三混合物料的PH至6-7,而后进行水浴加热至80-90℃,持续搅拌至溶液挥发完全,得到溶胶前驱体;
步骤十:将溶胶前驱体放入干燥设备中,在100-120℃的环境下干燥4天后,以1-2℃/min的速度升温至800℃,保温3h后降温得到镍掺杂钡铁氧体粉体先驱体;
步骤十一:将镍掺杂钡铁氧体粉体先驱体进行球磨处理,而后加入聚乙烯醇与镍掺杂钡铁氧体粉体充分混合后,压制成第二薄层坯料待用;
步骤十二:将第一薄层坯料压制在第二薄层坯料的外层上,而后放入至烧制炉体中,通入0.1-0.5MP压缩空气,以2-3℃/min升温至400℃,保温3小时排胶,而后以200-400℃/h升温至1200-1250℃,接着保温3小时,烧结完成后自然降至常温,得到素胚;
步骤十三:将素胚完全放入石墨烯分散液中超声浸渍1小时,而后取出烘干,喷涂釉料至素胚表面,而后微波低温烧制成型。
所述步骤五中的恒温池为40%溶度磷酸恒温池。
【实施例一】
多功能负离子能量片,由下述重量配比的原材料制成:由下述重量配比的原材料制成:六环石5份、锗石5份、砭石3份、石英10份、电气石3份、氧化镁1份、氧化锆3份、氧化锌3份、氧化钙1份、氧化锰3份、高岭土4份、硅藻土3份、稀土8份、去离子水25份、碳酸钙2份、氢氧化铝粉5份、硝酸银3份、硝酸钡2份、硝酸铁2份、硝酸镍3份、柠檬酸2份、聚乙烯醇5份、石墨烯分散液15份、氨水10份。
多功能负离子能量片的制备方法,包括以下步骤:
步骤一:将六环石、锗石、砭石、石英、电气石分别放置于粉碎设备中进行粉碎,粉碎至400目,得到六环石粉、锗石粉、砭石粉、石英粉、电气石粉;
步骤二:将氧化镁、氧化锆、氧化锌、氧化钙、氧化锰放入至混合设备中进行搅拌混合,得到第一混合物料,将第一混合物料水化72小时;
步骤三:将第一混合物料、六环石粉、锗石粉、砭石粉、硅藻土、石英粉、稀土和去离子水一同加入到混合设备中进行搅拌混合至膏状,得到第二混合物料,而后将第二混合物料熟化24小时,再加入适量高岭土搅拌成泥状,而后压制成第一薄层坯料待用;
步骤四:将碳酸钙、氢氧化铝粉、氧化锌加入至混合设备中进行混合,得到混合粉料;
步骤五:将混合粉料加入至少恒温池中,进行反应,恒温池温度控制在50℃,待反应结束后,得到浸泡溶液,恒温池中的浸泡溶液气泡消失后自然降温至30℃;
步骤六:将硝酸银和稀土与浸泡溶液一同加入至搅拌机中搅拌3小时,而后进行中和处理7小时,而后进行清洗过滤,除去浸泡溶液中的酸根离子;
步骤七:将电气石粉、砭石粉、氧化铝、石英粉一同加入到混合设备中进行搅拌混合,而后加入水球研磨3小时后进行超声乳化30分钟,在进行水球研磨3小时,而后陈化24小时后得到釉料坯料待用;
步骤八:将硝酸钡、硝酸铁、硝酸镍加入混合设备中进行混合,而后加入柠檬酸和去离子水进行二次搅拌至完全溶解,得到第三混合物料;
步骤九:将氨水加入到第三混合物料中,通过氨水调节第三混合物料的PH至6-7,而后进行水浴加热至80-90℃,持续搅拌至溶液挥发完全,得到溶胶前驱体;
步骤十:将溶胶前驱体放入干燥设备中,在100-120℃的环境下干燥4天后,以1-2℃/min的速度升温至800℃,保温3h后降温得到镍掺杂钡铁氧体粉体先驱体;
步骤十一:将镍掺杂钡铁氧体粉体先驱体进行球磨处理,而后加入聚乙烯醇与镍掺杂钡铁氧体粉体充分混合后,压制成第二薄层坯料待用;
步骤十二:将第一薄层坯料压制在第二薄层坯料的外层上,而后放入至烧制炉体中,通入0.1-0.5MP压缩空气,以2-3℃/min升温至400℃,保温3小时排胶,而后以200-400℃/h升温至1200-1250℃,接着保温3小时,烧结完成后自然降至常温,得到素胚;
步骤十三:将素胚完全放入石墨烯分散液中超声浸渍1小时,而后取出烘干,喷涂釉料至素胚表面,而后微波低温烧制成型。
【实施例二】
多功能负离子能量片,由下述重量配比的原材料制成:六环石8份、锗石6份、砭石5份、石15份、电气石5份、氧化镁2份、氧化锆1份、氧化锌2份、氧化钙1份、氧化锰5份、高岭土5份、硅藻土5份、稀土8份、去离子水25份、碳酸钙2份、氢氧化铝粉3份、硝酸银3份、硝酸钡2份、硝酸铁3份、硝酸镍3份、柠檬酸2份、聚乙烯醇3份、石墨烯分散液18份、氨水10份。
多功能负离子能量片的制备方法,包括以下步骤:
步骤一:将六环石、锗石、砭石、石英、电气石分别放置于粉碎设备中进行粉碎,粉碎至400目,得到六环石粉、锗石粉、砭石粉、石英粉、电气石粉;
步骤二:将氧化镁、氧化锆、氧化锌、氧化钙、氧化锰放入至混合设备中进行搅拌混合,得到第一混合物料,将第一混合物料水化72小时;
步骤三:将第一混合物料、六环石粉、锗石粉、砭石粉、硅藻土、石英粉、稀土和去离子水一同加入到混合设备中进行搅拌混合至膏状,得到第二混合物料,而后将第二混合物料熟化24小时,再加入适量高岭土搅拌成泥状,而后压制成第一薄层坯料待用;
步骤四:将碳酸钙、氢氧化铝粉、氧化锌加入至混合设备中进行混合,得到混合粉料;
步骤五:将混合粉料加入至少恒温池中,进行反应,恒温池温度控制在50℃,待反应结束后,得到浸泡溶液,恒温池中的浸泡溶液气泡消失后自然降温至30℃;
步骤六:将硝酸银和稀土与浸泡溶液一同加入至搅拌机中搅拌3小时,而后进行中和处理7小时,而后进行清洗过滤,除去浸泡溶液中的酸根离子;
步骤七:将电气石粉、砭石粉、氧化铝、石英粉一同加入到混合设备中进行搅拌混合,而后加入水球研磨3小时后进行超声乳化30分钟,在进行水球研磨3小时,而后陈化24小时后得到釉料坯料待用;
步骤八:将硝酸钡、硝酸铁、硝酸镍加入混合设备中进行混合,而后加入柠檬酸和去离子水进行二次搅拌至完全溶解,得到第三混合物料;
步骤九:将氨水加入到第三混合物料中,通过氨水调节第三混合物料的PH至6-7,而后进行水浴加热至80-90℃,持续搅拌至溶液挥发完全,得到溶胶前驱体;
步骤十:将溶胶前驱体放入干燥设备中,在100-120℃的环境下干燥4天后,以1-2℃/min的速度升温至800℃,保温3h后降温得到镍掺杂钡铁氧体粉体先驱体;
步骤十一:将镍掺杂钡铁氧体粉体先驱体进行球磨处理,而后加入聚乙烯醇与镍掺杂钡铁氧体粉体充分混合后,压制成第二薄层坯料待用;
步骤十二:将第一薄层坯料压制在第二薄层坯料的外层上,而后放入至烧制炉体中,通入0.1-0.5MP压缩空气,以2-3℃/min升温至400℃,保温3小时排胶,而后以200-400℃/h升温至1200-1250℃,接着保温3小时,烧结完成后自然降至常温,得到素胚;
步骤十三:将素胚完全放入石墨烯分散液中超声浸渍1小时,而后取出烘干,喷涂釉料至素胚表面,而后微波低温烧制成型。
对于本领域技术人员而言,显然本发明不限于上述示范性实施例的细节,而且在不背离本发明的精神或基本特征的情况下,能够以其他的具体形式实现本发明。因此,无论从哪一点来看,均应将实施例看作是示范性的,而且是非限制性的,本发明的范围由所附权利要求而不是上述说明限定,因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。

Claims (5)

1.多功能负离子能量片,其特征在于,由下述重量配比的原材料制成:六环石5-8份、锗石5-6份、砭石3-5份、石英10-15份、电气石3-5份、氧化镁1-2份、氧化锆1-3份、氧化锌2-3份、氧化钙1-2份、氧化锰3-5份、高岭土4-5份、硅藻土3-5份、稀土5-8份、去离子水20-25份、碳酸钙2-3份、氢氧化铝粉3-5份、硝酸银3-5份、硝酸钡2-3份、硝酸铁2-3份、硝酸镍2-3份、柠檬酸1-2份、聚乙烯醇3-5份、石墨烯分散液15-20份、氨水10-13份。
2.根据权利要求1所述的多功能负离子能量片,其特征在于,由下述重量配比的原材料制成:六环石5份、锗石5份、砭石3份、石英10份、电气石3份、氧化镁1份、氧化锆3份、氧化锌3份、氧化钙1份、氧化锰3份、高岭土4份、硅藻土3份、稀土8份、去离子水25份、碳酸钙2份、氢氧化铝粉5份、硝酸银3份、硝酸钡2份、硝酸铁2份、硝酸镍3份、柠檬酸2份、聚乙烯醇5份、石墨烯分散液15份、氨水10份。
3.根据权利要求1所述的多功能负离子能量片,其特征在于,由下述重量配比的原材料制成:六环石8份、锗石6份、砭石5份、石15份、电气石5份、氧化镁2份、氧化锆1份、氧化锌2份、氧化钙1份、氧化锰5份、高岭土5份、硅藻土5份、稀土8份、去离子水25份、碳酸钙2份、氢氧化铝粉3份、硝酸银3份、硝酸钡2份、硝酸铁3份、硝酸镍3份、柠檬酸2份、聚乙烯醇3份、石墨烯分散液18份、氨水10份。
4.多功能负离子能量片的制备方法,根据权利要求1-3任一项所述的多功能负离子能量片,其特征在于,包括以下步骤:
步骤一:将六环石、锗石、砭石、石英、电气石分别放置于粉碎设备中进行粉碎,粉碎至400目,得到六环石粉、锗石粉、砭石粉、石英粉、电气石粉;
步骤二:将氧化镁、氧化锆、氧化锌、氧化钙、氧化锰放入至混合设备中进行搅拌混合,得到第一混合物料,将第一混合物料水化72小时;
步骤三:将第一混合物料、六环石粉、锗石粉、砭石粉、硅藻土、石英粉、稀土和去离子水一同加入到混合设备中进行搅拌混合至膏状,得到第二混合物料,而后将第二混合物料熟化24小时,再加入适量高岭土搅拌成泥状,而后压制成第一薄层坯料待用;
步骤四:将碳酸钙、氢氧化铝粉、氧化锌加入至混合设备中进行混合,得到混合粉料;
步骤五:将混合粉料加入至少恒温池中,进行反应,恒温池温度控制在50℃,待反应结束后,得到浸泡溶液,恒温池中的浸泡溶液气泡消失后自然降温至30℃;
步骤六:将硝酸银和稀土与浸泡溶液一同加入至搅拌机中搅拌3小时,而后进行中和处理7小时,而后进行清洗过滤,除去浸泡溶液中的酸根离子;
步骤七:将电气石粉、砭石粉、氧化铝、石英粉一同加入到混合设备中进行搅拌混合,而后加入水球研磨3小时后进行超声乳化30分钟,在进行水球研磨3小时,而后陈化24小时后得到釉料坯料待用;
步骤八:将硝酸钡、硝酸铁、硝酸镍加入混合设备中进行混合,而后加入柠檬酸和去离子水进行二次搅拌至完全溶解,得到第三混合物料;
步骤九:将氨水加入到第三混合物料中,通过氨水调节第三混合物料的PH至6-7,而后进行水浴加热至80-90℃,持续搅拌至溶液挥发完全,得到溶胶前驱体;
步骤十:将溶胶前驱体放入干燥设备中,在100-120℃的环境下干燥4天后,以1-2℃/min的速度升温至800℃,保温3h后降温得到镍掺杂钡铁氧体粉体先驱体;
步骤十一:将镍掺杂钡铁氧体粉体先驱体进行球磨处理,而后加入聚乙烯醇与镍掺杂钡铁氧体粉体充分混合后,压制成第二薄层坯料待用;
步骤十二:将第一薄层坯料压制在第二薄层坯料的外层上,而后放入至烧制炉体中,通入0.1-0.5MP压缩空气,以2-3℃/min升温至400℃,保温3小时排胶,而后以200-400℃/h升温至1200-1250℃,接着保温3小时,烧结完成后自然降至常温,得到素胚;
步骤十三:将素胚完全放入石墨烯分散液中超声浸渍1小时,而后取出烘干,喷涂釉料至素胚表面,而后微波低温烧制成型。
5.根据权利要求4所述的多功能负离子能量片的制备方法,其特征在于,所述步骤五中的恒温池为40%溶度磷酸恒温池。
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