CN111529431A - Composition with make-up maintaining and oil controlling effects and cosmetic - Google Patents
Composition with make-up maintaining and oil controlling effects and cosmetic Download PDFInfo
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- CN111529431A CN111529431A CN202010397237.3A CN202010397237A CN111529431A CN 111529431 A CN111529431 A CN 111529431A CN 202010397237 A CN202010397237 A CN 202010397237A CN 111529431 A CN111529431 A CN 111529431A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/008—Preparations for oily skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
Abstract
The invention discloses a composition with a make-up maintaining and oil controlling effect and a cosmetic. The composition disclosed by the invention can effectively improve the migration resistance of a foundation product, directionally absorb and flocculate solidified sebum, has a good oil control effect, can effectively reduce the influence of the sebum secreted by the skin on the makeup, and enables the skin to keep natural and lasting makeup. The composition with the make-up maintaining and oil controlling effects comprises the following components in parts by weight: 0.8-2.5 parts of polydimethylsiloxane-polyol copolymer, 4-11 parts of film-forming agent, 1-8 parts of functional powder and 14-33 parts of volatile silicone oil; the functional powder is a mixture of synthetic fluorophlogopite, hydroxyapatite and zinc oxide; the film forming agent is a combination of polymethylsilsesquioxane and trimethylsiloxysilicate. Belongs to the technical field of cosmetics.
Description
Technical Field
The invention relates to a composition with a make-up maintaining and oil controlling effect and a cosmetic, and belongs to the technical field of cosmetics.
Background
In modern society, almost every woman uses make-up products to beautify the image of the individual and improve the quality of the individual before going out or participating in important activities. However, as the time after makeup is extended, makeup is difficult to maintain as it is, and makeup removal, oil-staining, toner aggregation, and the like are likely to occur. The reason is that the oil naturally secreted by the skin of the human body can dissolve certain components in the color cosmetic product, so that the makeup removal phenomenon occurs; and excessive secreted grease can cause the face to become oily and shiny, which affects the aesthetic feeling.
Most foundation products currently on the market suffer from the following drawbacks: the makeup effect is not lasting, the makeup is easy to remove, the condition of makeup or removal is often caused by oil on the face or sweat, and particularly the condition of oily skin is more obvious; ② the oil control effect is not ideal, the face is easy to generate sticky feeling due to the reduction of air permeability after the skin is oiled, and the makeup is easy to become dark after being wetted by sebum. The foundation products with lasting makeup effect in the market at present are mainly added with oil-soluble film forming agents to realize water resistance, but cannot solve the problem of makeup removal caused by facial sebum secretion; the oil control function is realized by adding porous functional powder, such as porous silica, porous polymethyl methacrylate and the like, but the oil control function does not have the function of solidifying sebum, and the oil and fat secreted by skin cannot be solidified after being absorbed, so that the durability of the makeup is influenced.
Therefore, there is a need to develop a product that can simultaneously achieve good make-up retention and oil control effects to meet the needs of consumers.
Disclosure of Invention
The invention aims to provide a composition with good make-up holding and oil control effects, which creatively utilizes the polydimethylsiloxane, the polyalcohol copolymer, the film forming agent, the functional powder and the volatile silicone oil to carry out reasonable proportioning, effectively improves the anti-migration performance of foundation products, directionally absorbs and flocculates and solidifies sebum, has good oil control effect, can effectively reduce the influence of the sebum secreted by the skin on the make-up, and enables the skin to keep natural and lasting make-up.
In order to achieve the purpose, the invention adopts the following specific technical scheme:
a composition with a make-up maintaining and oil controlling effect comprises the following components in parts by weight: 0.8-2.5 parts of polydimethylsiloxane-polyol copolymer, 4-11 parts of film-forming agent, 1-8 parts of functional powder and 14-33 parts of volatile silicone oil;
the functional powder is a mixture of synthetic fluorophlogopite, hydroxyapatite and zinc oxide;
the film forming agent is a combination of polymethylsilsesquioxane and trimethylsiloxysilicate.
Further, the polydimethylsiloxane-polyol copolymer is any one or combination of PEG/PPG-18/18 polydimethylsiloxane, PEG/PPG-19/19 polydimethylsiloxane and PEG/PPG-20/20 polydimethylsiloxane.
Further, the volatile silicone oil is one or a combination of cyclopentadidimethyl siloxane and polydimethylsiloxane.
Furthermore, in the functional powder, the synthetic fluorophlogopite is more than or equal to 70 percent, the hydroxyapatite is less than or equal to 20 percent, and the zinc oxide is less than or equal to 10 percent by mass percent.
Furthermore, the film forming agent consists of polymethylsilsesquioxane and trimethylsiloxysilicate according to the weight ratio of 1:1.51: 10.
Further, the polydimethylsiloxane in the composition is a low viscosity polydimethylsiloxane in the range of 1-2 cst.
The trimethylsiloxy silicate is an oil-soluble film forming agent with strong hydrophobicity and strong adhesion to powder, has good water resistance and friction resistance when used in a product, can effectively reduce toner migration, but has hard film performance; the polymethylsilsesquioxane is an oil-soluble film forming agent with strong hydrophobicity and strong adhesion to powder, and has soft film performance. When the polymethylsilsesquioxane is compounded with trimethylsiloxysilicate, the film hardness of the trimethylsiloxysilicate film forming agent can be reduced, the brittleness of the trimethylsiloxysilicate film forming agent can be reduced, the friction resistance of the trimethylsiloxysilicate film forming agent can be improved, and the toner migration can be effectively reduced. When in application, the two film-forming agents are preferably dissolved in high-volatility silicone oil such as cyclopentadimethylsiloxane or low-viscosity polydimethylsiloxane, so that the film-forming speed can be increased in the coating process, and the effect of quick makeup is achieved.
PEG/PPG-18/18 polydimethylsiloxane, PEG/PPG-19/19 polydimethylsiloxane and PEG/PPG-20/20 polydimethylsiloxane are copolymers of polydimethylsiloxane and polyhydric alcohol, are W/O type emulsifiers with good dispersion effect on powder, are light and moist in skin feel and can improve the smearing feel of thick film-forming agents; when the emulsion is applied to foundation products, the sticky feeling of the film forming agent after film forming can be reduced, the sticky feeling of the skin after sebum secretion is reduced, and the comfortable and non-sticky use feeling is achieved.
The mixture of synthetic fluorophlogopite, hydroxyapatite and zinc oxide is functional powder with directional sebum absorption and flocculation solidified sebum, can improve the fitting property of foundation products, can directionally absorb and flocculate solidified sebum when being used on the surface of skin, does not adsorb moisturizing grease in cosmetics, and therefore has the skin feel of controlling oil and not drying.
The invention also aims to provide application of the composition with the make-up maintaining and oil controlling effect to preparation of cosmetics with the make-up maintaining and oil controlling effect.
The invention also aims to provide a cosmetic with a make-up maintaining and oil controlling effect, which comprises the composition with the make-up maintaining and oil controlling effect.
A cosmetic with a make-up maintaining and oil controlling effect comprises the following components in percentage by mass: 22-50% of the composition with the effects of maintaining makeup and controlling oil, 1.5-3.5% of emulsifier, 4.5-12% of emollient, 6-18% of colorant, 0-3% of sunscreen agent, 0.1-1.5% of filler, 1.5-4.5% of thickener, 0.3-0.6% of antioxidant, 0.02-0.2% of chelating agent, 0.3-1.5% of stabilizer, 2-10% of humectant, 0.07-0.5% of skin conditioner, 0.2-0.8% of preservative, 0-0.3% of aromatic and 22-35% of water.
Further, the emulsifier is bis-PEG/PPG-14/14 polydimethylsiloxane// cyclopentadimethylsiloxane and/or polyglycerol-3 diisostearate, more preferably a combination of the two;
the emollient is selected from one or more of diphenyl polydimethylsiloxane, isostearic acid, cyclopentadimethylsiloxane, VP/hexadecene copolymer, pentaerythritol tetra (ethyl hexanoate), tribehenate, diisostearyl malate, triisostearin and polydimethylsiloxane, and the combination of diphenyl polydimethylsiloxane, isostearic acid, cyclopentadimethylsiloxane, VP/hexadecene copolymer, pentaerythritol tetra (ethyl hexanoate) and tribehenate is more preferable;
the colorant is selected from one or more of CI 77492// triethoxyoctylsilane, CI 77491// triethoxyoctylsilane, CI77499// triethoxyoctylsilane, and CI 77891// aluminum hydroxide// triethoxyoctylsilane, and the combination of the two is more preferable;
the sunscreen agent is titanium dioxide// aluminum hydroxide// stearic acid;
the filler is selected from one or more of vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer, methyl methacrylate cross-linked polymer and silica, and preferably the vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer;
the thickening agent is selected from one or more of cyclopentadimethylsiloxane// disteardimonium hectorite// propylene carbonate, disteardimonium hectorite, xanthan gum and cellulose gum, preferably the combination of cyclopentadimethylsiloxane// disteardimonium hectorite// propylene carbonate and xanthan gum;
the antioxidant is selected from one or more of tocopherol, butylated hydroxytoluene and p-hydroxyacetophenone, and preferably the combination of the tocopherol, the butylated hydroxytoluene and the p-hydroxyacetophenone;
the chelating agent is EDTA disodium;
the stabilizer is magnesium sulfate;
the humectant is selected from one or more of glycerol, butanediol and propylene glycol, and preferably butanediol;
the skin conditioner is selected from one or more of bisabolol, arginine and dipotassium glycyrrhizinate, preferably the combination of the three.
The invention has the following beneficial effects:
1. according to the composition with the makeup holding and oil control effects, polydimethylsiloxane, a polyol copolymer, a film forming agent, functional powder and volatile silicone oil are interacted in a reasonable proportion, and the two film forming agents are synergistic, so that the film formed by the composition is excellent in performance, the powder can be tightly locked, the composition has a strong water-resistant effect, and the migration resistance of a foundation product is effectively improved; the polydimethylsiloxane and the polyalcohol copolymer are used as the emulsifier, so that the powder is well dispersed, the adsorption effect of the powder on grease is favorably improved, the thick smearing feeling and the sticky feeling of the film forming agent are improved, and the light and comfortable use feeling is provided; the functional powder can adsorb and flocculate and solidify sebum to achieve a good oil control effect; the volatile silicone oil well dissolves the film forming agent and the emulsifying agent, is beneficial to spreading the film forming agent and the functional powder on the skin, accelerates the film forming speed and achieves the effects of quick makeup and good makeup holding. The four components are matched with each other to realize synergistic interaction, so that the anti-migration performance of the product is effectively improved, sebum is absorbed and flocculated and solidified, a good oil control effect is achieved, the influence of the sebum secreted by the skin on the makeup can be effectively reduced, and the skin can keep natural and lasting makeup.
2. When the polymethylsilsesquioxane and the trimethylsiloxysilicate are compounded in a certain proportion, the film hardness of the trimethylsiloxysilicate film forming agent can be reduced, the brittleness of the trimethylsiloxysilicate film forming agent can be reduced, the friction resistance of the trimethylsiloxysilicate film forming agent can be improved, the toner migration can be effectively reduced, and a better makeup-holding effect can be achieved.
3. The cosmetic containing the composition with the make-up maintaining and oil controlling effect has the advantages of moist and light smearing sense, quick film forming, quick make-up, fitting make-up effect, refreshing, no sticky sense, capability of directionally absorbing and flocculating and solidifying sebum, good oil controlling effect, no make-up removal, no darkness and capability of achieving the purpose of maintaining make-up for a long time.
Detailed Description
The technical solutions of the present invention are further described in detail with reference to specific embodiments, but the described embodiments are only a part of the embodiments of the present invention, rather than all embodiments, and any other changes, modifications, substitutions, combinations, and simplifications that do not depart from the spirit and principle of the present invention should be regarded as equivalent substitutions and are included in the scope of the present invention. For process parameters or conditions not specifically mentioned, it can be carried out with reference to conventional techniques. The raw materials used in the present invention may be obtained by home-made or purchased from commercial sources.
The functional powders in the examples and comparative examples were a mixture of synthetic fluorophlogopite, hydroxyapatite, and zinc oxide, and were purchased from Kzhou Gerui mining, Inc.
bis-PEG/PPG-14/14 Dimethicone// Cyclopentamethicone was purchased from New chemical trade development (hong Kong) Inc.; CI 77492// triethoxyoctylsilane, CI 77491// triethoxyoctylsilane, CI77499// triethoxyoctylsilane, Cyclopenta-dimethyl-siloxane// dimethyl ammonium distearate hectorite// propylene carbonate were all available from Domperane (Shanghai) chemical trade Co., Ltd; CI 77891// aluminum hydroxide// triethoxycaprylylsilane from Polyoceanization technology, Inc., Guangzhou; titanium dioxide// aluminum hydroxide// stearic acid was purchased from Shanghai Haotai Biotech, Inc.
Example 1
A composition with a make-up maintaining and oil controlling effect comprises the following components in parts by weight: 1.5 parts of PEG/PPG-18/18 polydimethylsiloxane, 1.2 parts of polymethylsilsesquioxane, 6 parts of trimethylsiloxysilicate, 3.5 parts of functional powder and 21 parts of polydimethylsiloxane (2 cst).
Example 2
A composition with a make-up maintaining and oil controlling effect comprises the following components in parts by weight: 2.5 parts of PEG/PPG-19/19 polydimethylsiloxane, 1 part of polymethylsilsesquioxane, 7 parts of trimethylsiloxysilicate, 6.5 parts of functional powder, 24 parts of cyclopentasiloxane and 9 parts of polydimethylsiloxane (1 cst).
Example 3
A composition with a make-up maintaining and oil controlling effect comprises the following components in parts by weight: 0.8 part of PEG/PPG-20/20 polydimethylsiloxane, 0.5 part of polymethylsilsesquioxane, 4.5 parts of trimethylsiloxysilicate, 2.2 parts of functional powder and 14 parts of cyclopentadimethylsiloxane.
Example 4
A composition with a make-up maintaining and oil controlling effect comprises the following components in parts by weight: 1 part of PEG/PPG-18/18 polydimethylsiloxane, 0.7 part of PEG/PPG-20/20 polydimethylsiloxane, 1.5 parts of polymethylsilsesquioxane, 3 parts of trimethylsiloxysilicate, 1 part of functional powder, 10 parts of cyclopentadimethylsiloxane and 10 parts of polydimethylsiloxane (1.5 cst).
Example 5
A composition with a make-up maintaining and oil controlling effect comprises the following components in parts by weight: 0.8 part of PEG/PPG-19/19 polydimethylsiloxane, 0.4 part of PEG/PPG-20/20 polydimethylsiloxane, 1 part of polymethylsilsesquioxane, 10 parts of trimethylsiloxysilicate, 8 parts of functional powder and 25 parts of cyclopentadimethylsiloxane.
Example 6
A composition with a make-up maintaining and oil controlling effect comprises the following components in parts by weight: 0.8 part of PEG/PPG-18/18 polydimethylsiloxane, 0.4 part of PEG/PPG-19/19 polydimethylsiloxane, 1 part of PEG/PPG-20/20 polydimethylsiloxane, 1.6 parts of polymethylsilsesquioxane, 2.4 parts of trimethylsiloxysilicate, 4.5 parts of functional powder, 11 parts of cyclopentadimethylsiloxane and 13 parts of polydimethylsiloxane (1 cst).
Example 7
A composition with a make-up maintaining and oil controlling effect comprises the following components in parts by weight: 1.5 parts of PEG/PPG-18/18 polydimethylsiloxane, 3.6 parts of polymethylsilsesquioxane, 3.6 parts of trimethylsiloxysilicate, 3.5 parts of functional powder and 21 parts of polydimethylsiloxane (2 cst).
Example 8
A composition with a make-up maintaining and oil controlling effect comprises the following components in parts by weight: 1.5 parts of PEG/PPG-18/18 polydimethylsiloxane, 0.6 part of polymethylsilsesquioxane, 6.6 parts of trimethylsiloxysilicate, 3.5 parts of functional powder and 21 parts of polydimethylsiloxane (2 cst).
Application examples 1 to 8
The application examples provide a group of cosmetics containing the composition with the makeup-sustaining and oil-controlling effect, the specific formula is shown in table 1, and the content of each component is calculated by wt%.
TABLE 1
The preparation method of the group of application examples is as follows:
preprocessing a phase D: firstly, mixing and stirring film-forming agents (polymethylsilsesquioxane and trimethylsiloxy silicate) by using cyclopentadimethylsiloxane and/or polydimethylsiloxane for uniform dissolution, and then adding the D-phase rest material for uniform dispersion for later use;
mixing the raw materials of the phase D and the phase A1 pretreated in the step I, and grinding the mixture to be fine and smooth for later use;
mixing and heating A3 phase raw materials to 68-72 ℃, and uniformly stirring and dissolving for later use;
mixing and heating the B3 phase raw materials to 68-72 ℃, and uniformly stirring and dissolving for later use;
fifthly, adding the A1+ D phase, the A2 phase and the A3 phase obtained in the step II into an emulsifying pot, stirring and heating to 50-55 ℃, homogenizing to be uniform, and preserving heat for later use;
sixthly, adding the B1 phase raw material into a water phase pot, heating to 85-90 ℃, adding the B2 phase which is stirred and dispersed uniformly in advance, homogenizing for 3-5min, stirring and preserving heat for 5-10min to be uniform, cooling to 60 ℃, adding the treated B3 phase, stirring uniformly, and preserving heat at 50-55 ℃ for standby;
seventhly, slowly pumping the raw materials in the water phase pot into an emulsifying pot under the stirring state, homogenizing uniformly, preserving heat under vacuum, stirring until no bubbles exist, and cooling;
cooling to 45 ℃, adding the phase C raw material into an emulsifying pot, stirring uniformly, cooling to 40 ℃, homogenizing for 4-5min until the phase C raw material reaches the standard consistency, cooling to 38 ℃, reporting the standard of the pot, and discharging after the phase C raw material is qualified.
Comparative application example 1
A cosmetic composition which is different from the cosmetic composition of application example 1 in that polymethylsilsesquioxane in the D phase is replaced with the same amount of trimethylsiloxysilicate and the other components and the content are not changed, and the preparation method is the same as that of the above application example.
Comparative application example 2
A cosmetic is different from the cosmetic in application example 1 in that polydimethylsiloxane (2cst) in the phase D is replaced by polydimethylsiloxane (6cst) in the same amount, other components and contents are not changed, and the preparation method is the same as that of the application example. Polydimethylsiloxane (6cst) is a nonvolatile, low viscosity dimethylsilicone fluid.
Comparative application example 3
A cosmetic is different from the cosmetic in the application example 6 in that PEG/PPG-18/18 polydimethylsiloxane, PEG/PPG-19/19 polydimethylsiloxane and PEG/PPG-20/20 polydimethylsiloxane in the phase D are replaced by the same amount of bis-PEG/PPG-14/14 polydimethylsiloxane, other components and contents are not changed, and the preparation method is the same as that of the application example.
Comparative application example 4
A cosmetic is different from the cosmetic in the application example 6 in that PEG/PPG-18/18 polydimethylsiloxane, PEG/PPG-19/19 polydimethylsiloxane and PEG/PPG-20/20 polydimethylsiloxane in the phase D are replaced by the same amount of polyglycerol-3 diisostearate, other components and contents are not changed, and the preparation method is the same as that of the application example.
And (3) testing the efficacy:
the cosmetics obtained in the above application examples and comparative application examples were subjected to the following tests:
1. oil control effect simulation test
Test samples: application examples 1-6 and comparative application examples 3-4
The test method comprises the following steps: respectively weighing 4g of the cosmetics of the application examples 1-6 and the comparative application examples 3-4, uniformly coating the cosmetics on a glass culture dish with the diameter of 60mm, placing the glass culture dish in a constant temperature box with the temperature of 30 ℃, standing for 48 hours, and then placing the glass culture dish at room temperature for 30 min; then, 40ul of oleic acid was dropped onto the middle position of the dish, and after standing for 30 minutes, the area of the oleic acid diffused was observed, and the diameter of the oil spot was measured. Three groups of samples were made and the average was taken. The smaller the diameter of the oil spot is, the stronger the oil control capability of the product is. The results are shown in Table 2.
TABLE 2 oil control Effect test results
| Test sample | Oil spot diameter (mm) |
| Application example 1 | 7.9 |
| Application example 2 | 7.4 |
| Application example 3 | 8.8 |
| Application example 4 | 9.5 |
| Application example 5 | 7.0 |
| Application example 6 | 8.3 |
| Comparative application example 3 | 13.6 |
| Comparative application example 4 | 15.0 |
The results in table 2 show that the cosmetic surface oil spot diameter obtained in the above application examples is significantly smaller than that of comparative application examples 3 and 4, which indicates that the copolymer of polydimethylsiloxane and polyol is used as an emulsifier, which can well disperse functional powder, and is helpful for improving the adsorption effect of the powder on oil and fat, thereby achieving better oil control effect, and PEG/PPG-18/18 polydimethylsiloxane, PEG/PPG-19/19 polydimethylsiloxane, PEG/PPG-20/20 polydimethylsiloxane are preferably used, which has better effect of dispersing functional powder.
2. Simulation test of make-up effect
Test samples: application examples 1 to 8 and comparative application examples 1 to 2
The test method comprises the following steps: 0.4g of the cosmetics of the above application examples 1 to 8 and comparative application examples 1 to 2 was weighed out, respectively, dropped on the forearm, smeared with a spoon having a smooth surface, left to stand for 10 minutes, and then dried naturally. The three areas were pressed with paper towels with the same force, and the weight gain (i.e. the transfer) of 3 paper towels was weighed with an analytical balance, and the results are averaged as shown in table 3. The smaller the increment, the smaller the migration, the greater the makeup retention of the product tested.
TABLE 3 migration test results
| Test sample | Transport volume/g | Total amount/g | Mobility/% |
| Application example 1 | 0.027 | 0.400 | 6.75 |
| Application example 2 | 0.019 | 0.400 | 4.75 |
| Application example 3 | 0.040 | 0.400 | 10.00 |
| Application example 4 | 0.038 | 0.400 | 9.50 |
| Application example 5 | 0.015 | 0.400 | 3.75 |
| Application example 6 | 0.036 | 0.400 | 9.00 |
| Application example 7 | 0.058 | 0.400 | 14.50 |
| Application example 8 | 0.055 | 0.400 | 13.75 |
| Comparative application example 1 | 0.104 | 0.400 | 26.00 |
| Comparative application example 2 | 0.081 | 0.400 | 20.25 |
From the results in table 3, the migration volume of the products of the application examples 1 to 8 is obviously lower than that of the products of the comparative application examples 1 to 2, which shows that the products of the application examples 1 to 8 have better makeup-holding effect than that of the products of the comparative application examples 1 to 2, and shows that the two film-forming agents of the polymethylsilsesquioxane and the trimethylsiloxysilicate in the composition of the invention are synergistic, so that the powder can be tightly locked, and the migration resistance of the product is improved; the volatile silicone oil can well dissolve the film forming agent and the emulsifying agent, is beneficial to spreading the film forming agent and the functional powder on the skin, and achieves good make-up effect.
The migration amount of the products of application examples 1-6 is lower than that of the products of application examples 7 and 8, which shows that when the polymethylsilsesquioxane and the trimethylsiloxysilicate are compounded in a certain proportion, the film hardness of the trimethylsiloxysilicate film forming agent can be reduced, the brittleness of the trimethylsiloxysilicate film forming agent can be reduced, the friction resistance of the trimethylsiloxysilicate film forming agent can be improved, the toner migration can be effectively reduced, and a better makeup-holding effect can be achieved.
3. Sensory evaluation
Test samples: cosmetic preparations of application examples 1, 6, 7 and 8 and comparative application examples 1 to 4
Subject: the total 80 people, age 22-48 years, meet the volunteer selection standard of the subject.
The test method comprises the following steps: subjects were evenly divided into 8 groups, and the cosmetics of application examples 1, 6, 7, 8 and comparative application examples 1 to 4 were applied to the face, respectively, and the persistence, spreadability, smoothness, skin-contacting property, comfort, and oil control effect of the samples were evaluated in order in a scoring manner (0 to 5 points, the higher the score, the better the representative effect), and the results were averaged as shown in table 4.
TABLE 4 sensory evaluation results
| Test sample | Durability | Spreadability | Degree of smoothness | Skin-sticking property | Comfort feeling | Oil control effect |
| Application example 1 | 4.6 | 4.5 | 4.6 | 4.8 | 4.7 | 4.4 |
| Application example 6 | 4.8 | 4.6 | 4.6 | 4.9 | 4.7 | 4.5 |
| Application example 7 | 4.1 | 4.3 | 4.4 | 4.3 | 4.5 | 4.0 |
| Application example 8 | 4.2 | 4.1 | 4.1 | 4.2 | 4.6 | 4.0 |
| Comparative application example 1 | 2.7 | 3.4 | 3.5 | 2.9 | 3.9 | 3.4 |
| Comparative application example 2 | 3.5 | 2.6 | 3.4 | 3.5 | 3.7 | 3.5 |
| Comparative application example 3 | 3.6 | 3.5 | 3.6 | 3.7 | 3.2 | 3.3 |
| Comparative application example 4 | 3.3 | 3.2 | 3.1 | 3.7 | 2.8 | 2.6 |
From the results in the table above, the results of the application examples are that the durability, spreadability, smoothness, skin-attaching property, comfort and oil control effect of the product are all better than the effects of the comparative application examples, which shows that the composition with the makeup-holding and oil-control effect of the invention utilizes the interaction of polydimethylsiloxane, polyol copolymer, film-forming agent, functional powder and volatile silicone oil in a reasonable proportion to realize synergistic interaction, effectively improves the anti-migration property of foundation products, absorbs and flocculates and solidifies sebum, has good oil-resistant and oil-control effects, can effectively reduce the influence of the sebum secreted by the skin on the makeup appearance, and enables the skin to keep natural and lasting makeup.
Claims (10)
1. The composition with the effect of keeping makeup and controlling oil is characterized by comprising the following components in parts by weight: 0.8-2.5 parts of polydimethylsiloxane-polyol copolymer, 4-11 parts of film-forming agent, 1-8 parts of functional powder and 14-33 parts of volatile silicone oil;
the functional powder is a mixture of synthetic fluorophlogopite, hydroxyapatite and zinc oxide;
the film forming agent is a combination of polymethylsilsesquioxane and trimethylsiloxysilicate.
2. The composition as claimed in claim 1, wherein the dimethicone-polyol copolymer is a combination of any one or more of PEG/PPG-18/18 dimethicone, PEG/PPG-19/19 dimethicone, and PEG/PPG-20/20 dimethicone.
3. The composition according to claim 1, wherein the volatile silicone oil is one or a combination of cyclopentadimethicone and dimethicone.
4. The composition of claim 1, wherein the functional powder comprises, by mass, at least 70% of synthetic fluorophlogopite, at most 20% of hydroxyapatite, and at most 10% of zinc oxide.
5. The composition according to claim 1, wherein the weight ratio of polymethylsilsesquioxane to trimethylsiloxysilicate is: 1:1.5-1:10.
6. The composition as claimed in claim 3, wherein the polydimethylsiloxane is a low viscosity polydimethylsiloxane in the range of 1-2 cst.
7. Use of the composition with a make-up maintaining and oil controlling effect according to any one of claims 1 to 6 for preparing a cosmetic with a make-up maintaining and oil controlling effect.
8. A cosmetic with a make-up maintaining and oil controlling effect, which comprises the composition with the make-up maintaining and oil controlling effect as claimed in any one of claims 1 to 6.
9. The cosmetic with the make-up and oil control effect according to claim 8, which is characterized by comprising the following components in percentage by mass: 22-50% of the composition of any one of claims 1-6, 1.5-3.5% of an emulsifier, 4.5-12% of an emollient, 6-18% of a colorant, 0-3% of a sunscreen agent, 0.1-1.5% of a filler, 1.5-4.5% of a thickener, 0.3-0.6% of an antioxidant, 0.02-0.2% of a chelating agent, 0.3-1.5% of a stabilizer, 2-10% of a humectant, 0.07-0.5% of a skin conditioner, 0.2-0.8% of a preservative, 0-0.3% of a fragrance, and 22-35% of water.
10. Cosmetic product according to claim 9, characterized in that the emulsifier is bis-PEG/PPG-14/14 dimethicone// cyclopentadimethicone and/or polyglyceryl-3 diisostearate;
the emollient is selected from one or more of diphenyl polydimethylsiloxane, isostearic acid, cyclopentadimethylsiloxane, VP/hexadecene copolymer, pentaerythritol tetra (ethyl hexanoate), behenyl behenate, diisostearyl malate, triisostearin and polydimethylsiloxane;
the colorant is selected from one or more of CI 77492// triethoxyoctylsilane, CI 77491// triethoxyoctylsilane, CI77499// triethoxyoctylsilane, and CI 77891// aluminum hydroxide// triethoxyoctylsilane;
the sunscreen agent is titanium dioxide// aluminum hydroxide// stearic acid;
the filler is selected from one of vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer, methyl methacrylate cross-linked polymer and silica;
the thickening agent is one or more of cyclopentadimethyl dimethyl siloxane// disteardimonium hectorite// propylene carbonate, disteardimonium hectorite, xanthan gum and cellulose gum;
the antioxidant is selected from one or more of tocopherol, butylated hydroxytoluene and p-hydroxyacetophenone;
the chelating agent is EDTA disodium;
the stabilizer is magnesium sulfate;
the humectant is one or more selected from glycerol, butanediol and propylene glycol.
The skin conditioner is selected from one or more of bisabolol, arginine and dipotassium glycyrrhizinate.
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