CN111511468B - 用于通过氧化酯化产生甲基丙烯酸甲酯的非均相催化剂 - Google Patents

用于通过氧化酯化产生甲基丙烯酸甲酯的非均相催化剂 Download PDF

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CN111511468B
CN111511468B CN201880083173.0A CN201880083173A CN111511468B CN 111511468 B CN111511468 B CN 111511468B CN 201880083173 A CN201880083173 A CN 201880083173A CN 111511468 B CN111511468 B CN 111511468B
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catalyst
noble metal
mol
titanium
support
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CN111511468A (zh
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C·D·弗里克
J·赫伦
K·W·林巴贺
W·S·李
V·J·苏斯曼
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Dow Global Technologies LLC
Rohm and Haas Co
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Dow Global Technologies LLC
Rohm and Haas Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B01J35/53—Spheres with a core-shell structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/035—Precipitation on carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201880083173.0A 2018-01-10 2018-12-13 用于通过氧化酯化产生甲基丙烯酸甲酯的非均相催化剂 Active CN111511468B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201862615502P 2018-01-10 2018-01-10
US62/615502 2018-01-10
PCT/US2018/065372 WO2019139719A1 (en) 2018-01-10 2018-12-13 Heterogeneous catalyst for the production of methyl methacrylate by oxidative esterification

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CN111511468A CN111511468A (zh) 2020-08-07
CN111511468B true CN111511468B (zh) 2023-07-11

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US (1) US11577225B2 (https=)
EP (1) EP3737496A1 (https=)
JP (2) JP2021510344A (https=)
KR (1) KR102739478B1 (https=)
CN (1) CN111511468B (https=)
BR (1) BR112020011829B1 (https=)
CA (1) CA3085928A1 (https=)
MX (1) MX2020006629A (https=)
SA (1) SA520412331B1 (https=)
SG (1) SG11202005796UA (https=)
WO (1) WO2019139719A1 (https=)

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* Cited by examiner, † Cited by third party
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CN112165987B (zh) * 2018-06-28 2024-05-17 陶氏环球技术有限责任公司 非均相催化剂
JP2021528231A (ja) * 2018-06-28 2021-10-21 ダウ グローバル テクノロジーズ エルエルシー 不均一触媒
JP2023519126A (ja) * 2020-03-17 2023-05-10 ダウ グローバル テクノロジーズ エルエルシー 長寿命触媒による酸化的エステル化の方法及び触媒

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CN1361761A (zh) * 1998-02-09 2002-07-31 三菱丽阳株式会社 制备甲基丙烯酸甲酯的方法
CN101835768A (zh) * 2007-10-24 2010-09-15 利安德化学技术有限公司 使用改进的催化剂组合物的直接环氧化方法
CN105189444A (zh) * 2013-04-19 2015-12-23 赢创罗姆有限公司 制备甲基丙烯酸甲酯的方法
CN105377805A (zh) * 2013-07-29 2016-03-02 罗门哈斯公司 经由氧化酯化方法制备丙烯酸甲酯

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JP4069242B2 (ja) * 2001-06-04 2008-04-02 株式会社日本触媒 金属粒子担持体及びカルボン酸エステルの製造方法
JP2004181357A (ja) * 2002-12-03 2004-07-02 Nippon Shokubai Co Ltd 金微粒子の剥離抑制方法
JP2004181359A (ja) * 2002-12-03 2004-07-02 Nippon Shokubai Co Ltd カルボン酸エステル製造用触媒及びカルボン酸エステル製造方法
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JP2005013800A (ja) * 2003-06-24 2005-01-20 Mitsubishi Chemicals Corp 固体触媒及びこれを用いた酸化的付加生成物の製造方法
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CN1361761A (zh) * 1998-02-09 2002-07-31 三菱丽阳株式会社 制备甲基丙烯酸甲酯的方法
CN101835768A (zh) * 2007-10-24 2010-09-15 利安德化学技术有限公司 使用改进的催化剂组合物的直接环氧化方法
CN105189444A (zh) * 2013-04-19 2015-12-23 赢创罗姆有限公司 制备甲基丙烯酸甲酯的方法
CN105377805A (zh) * 2013-07-29 2016-03-02 罗门哈斯公司 经由氧化酯化方法制备丙烯酸甲酯

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Publication number Publication date
EP3737496A1 (en) 2020-11-18
JP7804625B2 (ja) 2026-01-22
US11577225B2 (en) 2023-02-14
US20200330959A1 (en) 2020-10-22
JP2023175730A (ja) 2023-12-12
SG11202005796UA (en) 2020-07-29
BR112020011829A2 (pt) 2020-11-24
CA3085928A1 (en) 2019-07-18
CN111511468A (zh) 2020-08-07
KR20200105854A (ko) 2020-09-09
SA520412331B1 (ar) 2024-02-19
JP2021510344A (ja) 2021-04-22
KR102739478B1 (ko) 2024-12-09
WO2019139719A1 (en) 2019-07-18
MX2020006629A (es) 2020-09-22
BR112020011829B1 (pt) 2023-05-09

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