CN111511468B - 用于通过氧化酯化产生甲基丙烯酸甲酯的非均相催化剂 - Google Patents

用于通过氧化酯化产生甲基丙烯酸甲酯的非均相催化剂 Download PDF

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CN111511468B
CN111511468B CN201880083173.0A CN201880083173A CN111511468B CN 111511468 B CN111511468 B CN 111511468B CN 201880083173 A CN201880083173 A CN 201880083173A CN 111511468 B CN111511468 B CN 111511468B
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catalyst
noble metal
mol
titanium
support
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Chinese (zh)
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CN111511468A (zh
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C·D·弗里克
J·赫伦
K·W·林巴贺
W·S·李
V·J·苏斯曼
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Dow Global Technologies LLC
Rohm and Haas Co
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Dow Global Technologies LLC
Rohm and Haas Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B01J35/53—Spheres with a core-shell structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/035—Precipitation on carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201880083173.0A 2018-01-10 2018-12-13 用于通过氧化酯化产生甲基丙烯酸甲酯的非均相催化剂 Active CN111511468B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201862615502P 2018-01-10 2018-01-10
US62/615502 2018-01-10
PCT/US2018/065372 WO2019139719A1 (en) 2018-01-10 2018-12-13 Heterogeneous catalyst for the production of methyl methacrylate by oxidative esterification

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CN111511468A CN111511468A (zh) 2020-08-07
CN111511468B true CN111511468B (zh) 2023-07-11

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US (1) US11577225B2 (enExample)
EP (1) EP3737496A1 (enExample)
JP (2) JP2021510344A (enExample)
KR (1) KR102739478B1 (enExample)
CN (1) CN111511468B (enExample)
BR (1) BR112020011829B1 (enExample)
CA (1) CA3085928A1 (enExample)
MX (1) MX2020006629A (enExample)
SA (1) SA520412331B1 (enExample)
SG (1) SG11202005796UA (enExample)
WO (1) WO2019139719A1 (enExample)

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KR20210022620A (ko) 2018-06-28 2021-03-03 다우 글로벌 테크놀로지스 엘엘씨 불균일 촉매
KR102755859B1 (ko) * 2018-06-28 2025-01-15 다우 글로벌 테크놀로지스 엘엘씨 불균일 촉매
MX2022011304A (es) 2020-03-17 2022-11-16 Dow Global Technologies Llc Proceso y catalizador para esterificación oxidativa con catalizador de larga vida.

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CN1361761A (zh) * 1998-02-09 2002-07-31 三菱丽阳株式会社 制备甲基丙烯酸甲酯的方法
CN101835768A (zh) * 2007-10-24 2010-09-15 利安德化学技术有限公司 使用改进的催化剂组合物的直接环氧化方法
CN105189444A (zh) * 2013-04-19 2015-12-23 赢创罗姆有限公司 制备甲基丙烯酸甲酯的方法
CN105377805A (zh) * 2013-07-29 2016-03-02 罗门哈斯公司 经由氧化酯化方法制备丙烯酸甲酯

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JP4069242B2 (ja) * 2001-06-04 2008-04-02 株式会社日本触媒 金属粒子担持体及びカルボン酸エステルの製造方法
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JP2004181357A (ja) 2002-12-03 2004-07-02 Nippon Shokubai Co Ltd 金微粒子の剥離抑制方法
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CN1361761A (zh) * 1998-02-09 2002-07-31 三菱丽阳株式会社 制备甲基丙烯酸甲酯的方法
CN101835768A (zh) * 2007-10-24 2010-09-15 利安德化学技术有限公司 使用改进的催化剂组合物的直接环氧化方法
CN105189444A (zh) * 2013-04-19 2015-12-23 赢创罗姆有限公司 制备甲基丙烯酸甲酯的方法
CN105377805A (zh) * 2013-07-29 2016-03-02 罗门哈斯公司 经由氧化酯化方法制备丙烯酸甲酯

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Publication number Publication date
JP7804625B2 (ja) 2026-01-22
SA520412331B1 (ar) 2024-02-19
EP3737496A1 (en) 2020-11-18
KR20200105854A (ko) 2020-09-09
JP2021510344A (ja) 2021-04-22
BR112020011829A2 (pt) 2020-11-24
JP2023175730A (ja) 2023-12-12
MX2020006629A (es) 2020-09-22
US20200330959A1 (en) 2020-10-22
KR102739478B1 (ko) 2024-12-09
BR112020011829B1 (pt) 2023-05-09
CA3085928A1 (en) 2019-07-18
SG11202005796UA (en) 2020-07-29
US11577225B2 (en) 2023-02-14
WO2019139719A1 (en) 2019-07-18
CN111511468A (zh) 2020-08-07

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