CN111484891B - Emulsified anti-rust oil - Google Patents
Emulsified anti-rust oil Download PDFInfo
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- CN111484891B CN111484891B CN202010339786.5A CN202010339786A CN111484891B CN 111484891 B CN111484891 B CN 111484891B CN 202010339786 A CN202010339786 A CN 202010339786A CN 111484891 B CN111484891 B CN 111484891B
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- oil
- rust
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- rust oil
- triethanolamine
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
- C10M2203/1065—Naphthenic fractions used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
- C10M2205/163—Paraffin waxes; Petrolatum, e.g. slack wax used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
- C10M2215/222—Triazines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
- C10M2215/226—Morpholines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
Abstract
The invention discloses emulsified anti-rust oil which comprises the following components in percentage by mass: 5-20% of petroleum sodium sulfonate; 5-10% of triethanolamine; 5-20% of triethanolamine oleate soap; 5-15% of an emulsifier; 0.5-3% of potassium hydroxide; 1-3% of water; 1-3% of a bactericide; the balance being base oil. The emulsified anti-rust oil disclosed by the invention has the advantages that the components are organically matched, so that the anti-rust oil has good anti-rust performance, and is not layered and does not float oil after being placed for a long time; in addition, the raw materials adopted by the invention are easy to obtain, the dosage is less, and the use cost is lower.
Description
Technical Field
The invention relates to the technical field of anti-rust oil, and particularly relates to emulsified anti-rust oil.
Background
Currently, rust preventive products widely used in the field of metal processing include rust preventive oil, water-based rust preventive liquid, and emulsion type rust preventive oil. The anti-rust oil has the advantages of good anti-rust performance and long anti-rust period, and has the defects of using a large amount of petroleum solvent, generating a large amount of VOC (volatile organic compounds), polluting the environment and being harmful to the health of a human body; on the other hand, most of petroleum solvents have low flash points, are inflammable and have certain potential safety hazards. Compared with antirust oil, the water-based antirust liquid has the advantages of low cost, no flammability, safety and environmental protection by using water as a diluent, but has poor antirust performance and short antirust period. The emulsified anti-rust oil has the advantages of the two products, and has better anti-rust performance, lower cost, safety and environmental protection.
The existing emulsified anti-rust oil usually has the problems of short anti-rust period, easy layering after long-term standing and the like, so how to develop the emulsified anti-rust oil with long anti-rust period, low cost and good stability is a problem which needs to be solved urgently in the field.
Disclosure of Invention
The invention provides emulsified anti-rust oil for overcoming the defects in the prior art, which has the advantages of long anti-rust period, low cost and good stability.
In order to achieve the purpose, the invention adopts the following technical scheme:
the invention provides emulsified anti-rust oil which comprises the following components in percentage by mass:
further, the emulsified anti-rust oil comprises the following components in percentage by mass:
further, the bactericide is one or more of triazines, morpholines, oxazolines, isothiazolinones or pyridines.
Further, the base oil is one or more of paraffin base oil or naphthenic base oil.
By adopting the technical scheme, compared with the prior art, the invention has the following technical effects:
the emulsified anti-rust oil disclosed by the invention has the advantages that the components are organically matched, so that the anti-rust oil has good anti-rust performance, and is not layered and does not float oil after being placed for a long time; in addition, the raw materials adopted by the invention are easy to obtain, the dosage is less, and the use cost is lower.
Drawings
FIG. 1 is a state after a 5% dilution of an emulsified rust preventive oil according to the present invention is left for 1 month.
Detailed Description
The present invention will be described in detail and specifically with reference to the following examples to facilitate better understanding of the present invention, but the following examples do not limit the scope of the present invention.
Example 1
The embodiment provides emulsified anti-rust oil which comprises the following components in percentage by mass: 6 percent of petroleum sodium sulfonate; 5% of triethanolamine; triethanolamine oleate soap 10%; 6% of an emulsifier; 1% of potassium hydroxide; 1% of water; 1% of triazine bactericide; the balance being naphthenic base oil.
Example 2
The embodiment provides emulsified anti-rust oil which comprises the following components in percentage by mass: 15% of petroleum sodium sulfonate; 6 percent of triethanolamine; triethanolamine oleate soap 10%; 8% of an emulsifier; 2% of potassium hydroxide; 2% of water; 2% of triazine bactericide; the balance of paraffin-based base oil.
Example 3
The embodiment provides emulsified anti-rust oil which comprises the following components in percentage by mass: 18% of petroleum sodium sulfonate; 8% of triethanolamine; 12% of triethanolamine oleate soap; 10% of an emulsifier; 2% of potassium hydroxide; 2% of water; 2% of triazine bactericide; the balance being naphthenic base oil.
Example 4
The embodiment provides emulsified anti-rust oil which comprises the following components in percentage by mass: 15% of petroleum sodium sulfonate; 6 percent of triethanolamine; triethanolamine oleate soap 10%; 8% of an emulsifier; 2% of potassium hydroxide; 2% of water; 2% of morpholine bactericide; the rest is paraffin-based base oil.
Example 5
The embodiment provides emulsified anti-rust oil which comprises the following components in percentage by mass: 18% of petroleum sodium sulfonate; 8% of triethanolamine; 12% of triethanolamine oleate soap; 10% of an emulsifier; 2% of potassium hydroxide; 2% of water; 2% of oxazoline bactericide; the balance being naphthenic base oil.
Comparative example
The emulsified anti-rust oil prepared in the above examples 1 to 5 and the existing commercially available emulsified anti-rust oil are diluted with water according to the mass ratio of 1:19, and then water mist tests are respectively carried out according to the test standard of ASTM D1735, wherein the test results are shown in Table 1:
TABLE 1
| Detecting items | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Commercial emulsified antirust oil |
| Appearance of the product | Milky white color | Milky white color | Milky white color | Milky white color | Milky white color | Milky white color |
| Rust resistance (h) | 20 | 40 | 42 | 41 | 43 | 18 |
The embodiments of the present invention have been described in detail, but the embodiments are merely examples, and the present invention is not limited to the embodiments described above. Any equivalent modifications and substitutions for the present invention are within the scope of the present invention for those skilled in the art. Accordingly, equivalent changes and modifications made without departing from the spirit and scope of the present invention should be covered by the present invention.
Claims (1)
1. An emulsified anti-rust oil is characterized by comprising the following components in percentage by mass:
15-18% of petroleum sodium sulfonate;
6-8% of triethanolamine;
10-12% of triethanolamine oleate soap;
8-10% of an emulsifier;
2% of potassium hydroxide;
2% of water;
2% of a bactericide;
the balance of base oil;
the bactericide is one or more of triazines, morpholines, oxazolines, isothiazolinones or pyridines;
the base oil is one or more of paraffin base oil or naphthenic base oil.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010339786.5A CN111484891B (en) | 2020-04-26 | 2020-04-26 | Emulsified anti-rust oil |
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| CN202010339786.5A CN111484891B (en) | 2020-04-26 | 2020-04-26 | Emulsified anti-rust oil |
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| CN111484891A CN111484891A (en) | 2020-08-04 |
| CN111484891B true CN111484891B (en) | 2022-08-26 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018000433A1 (en) * | 2016-07-01 | 2018-01-04 | 深圳市恒兆智科技有限公司 | Anti-rust agent, metal workpiece and anti-rust treatment method |
| CN108018110A (en) * | 2016-10-28 | 2018-05-11 | 刘泽坤 | A kind of anticorrosive emulsified oil |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| DE2442844C3 (en) * | 1974-09-06 | 1979-08-02 | Zahnradfabrik Friedrichshafen Ag, 7990 Friedrichshafen | Corrosion-inhibiting aqueous solution for machined workpieces made of metals and plastics |
| CN101608310B (en) * | 2008-06-16 | 2011-03-02 | 南京科润工业介质有限公司 | Long-acting emulsion-type antirust fluid |
| CN105112132B (en) * | 2015-07-16 | 2016-05-18 | 路伯润滑油（苏州）有限公司 | A kind of anti-rust emulsion oil and preparation method thereof |
| CN105670738A (en) * | 2016-03-11 | 2016-06-15 | 东莞市纳晟润滑油科技有限公司 | Rust-proof emulsified type metal cutting fluid |
| CN109054973B (en) * | 2018-10-10 | 2021-08-13 | 华阳-恩赛有限公司 | Micro-emulsified cutting fluid, preparation method and application |
| CN110591796B (en) * | 2019-08-21 | 2022-04-12 | 北美防锈技术（上海）有限公司 | Environment-friendly emulsified antirust oil |
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2020
- 2020-04-26 CN CN202010339786.5A patent/CN111484891B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018000433A1 (en) * | 2016-07-01 | 2018-01-04 | 深圳市恒兆智科技有限公司 | Anti-rust agent, metal workpiece and anti-rust treatment method |
| CN108018110A (en) * | 2016-10-28 | 2018-05-11 | 刘泽坤 | A kind of anticorrosive emulsified oil |
Non-Patent Citations (3)
| Title |
|---|
| L-1防锈乳化油的研究与应用;朱焱等;《武汉理工大学学报(信息与管理工程版)》;20001231;第22卷(第06期);第97-100页 * |
| 液压支架用乳化油复合料的研制;孔令坡;《煤炭科学技术》;20130815;第41卷;第275-277页 * |
| 防锈乳化油的研制;王恩锋;《润滑油》;20041231;第19卷(第06期);第45-47页 * |
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