CN111480657A - Stable composite chlorine dioxide solid lozenge and preparation method thereof - Google Patents
Stable composite chlorine dioxide solid lozenge and preparation method thereof Download PDFInfo
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- CN111480657A CN111480657A CN202010432704.1A CN202010432704A CN111480657A CN 111480657 A CN111480657 A CN 111480657A CN 202010432704 A CN202010432704 A CN 202010432704A CN 111480657 A CN111480657 A CN 111480657A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/02—Sulfur; Selenium; Tellurium; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/08—Alkali metal chlorides; Alkaline earth metal chlorides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/14—Boron; Compounds thereof
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Abstract
The invention discloses a stable composite chlorine dioxide solid lozenge and a preparation method thereof, wherein the stable composite chlorine dioxide solid lozenge comprises the following components in parts by weight: 6-7 parts of sodium chlorate, 9-10 parts of sodium chlorite, 30-31 parts of sodium dichloroisocyanurate, 32-33 parts of sodium bisulfate, 3-4 parts of sodium sulfate, 2-3 parts of boric acid, 15-16 parts of sodium chloride, 2-3 parts of sodium carboxymethylcellulose, 6-31 parts of oxidant, 34-36 parts of inorganic acid, 18-20 parts of diluent and 2-3 parts of adhesive. The invention relates to the technical field of chlorine dioxide solid agents, and particularly provides a stable compound chlorine dioxide solid lozenge which is portable in use, small in size, high in reaction speed, convenient to store, transport and use, free of operations such as preparation, metering and the like of a user, and environment-friendly in residues after use, and a preparation method thereof.
Description
Technical Field
The invention relates to the technical field of chlorine dioxide solid agents, in particular to a stable compound chlorine dioxide solid lozenge and a preparation method thereof.
Background
Chlorine dioxide has the functions of sterilization, bleaching, deodorization, disinfection and fresh keeping. The action mechanism is mainly oxidation, the electronic structure of the chlorine dioxide molecule is in an unsaturated state, the outer layer has 19 electrons, and the chlorine dioxide molecule has strong oxidation action force, and mainly attacks atomic groups (such as enzyme containing sulfydryl, sulfide and chloride) rich in electrons (or electron donors) to rob electrons forcibly, so that the electrons are changed into substances losing activity and changing properties, and the aim is achieved.
At present, the diversified development of the domestic chlorine dioxide product takes the mechanical equipment of a chlorine dioxide generator as a main product and takes a liquid solvent as a second time. The installation and the use of the chlorine dioxide generator mechanical equipment need professional training, reaction generating raw materials are added from time to time, reaction residues of the generated product equipment can be eliminated periodically, the reaction raw materials are not easy to store, and the like, so that the chlorine dioxide generator mechanical equipment is not required by a common user. And a few solid products exist, and most of the solid products are applied to the aquaculture and fishery. The pH value of water is strictly controlled by a breeding manufacturer, most products cannot be effectively and quickly dissolved in a short time under the limitation of the proportion condition of a formula, residues after dissociation cannot cause secondary pollution in the water, and the formula accounts for most of the proportion of an oxidant, so that the generation amount of chlorine dioxide is small, and a large amount of chlorine dioxide needs to be used.
Disclosure of Invention
Aiming at the situation, in order to overcome the defects of the prior art, the invention provides the stable compound chlorine dioxide solid pastille which is portable in use, small in volume, high in reaction speed, convenient to store, transport and use, free of operations such as preparation, metering and the like of a user and environment-friendly in residues after use, and the preparation method thereof.
The technical scheme adopted by the invention is as follows: a stable composite chlorine dioxide solid pastille comprises the following components in parts by weight: 6-7 parts of sodium chlorate, 9-10 parts of sodium chlorite, 30-31 parts of sodium dichloroisocyanurate, 32-33 parts of sodium bisulfate, 3-4 parts of sodium sulfate, 2-3 parts of boric acid, 15-16 parts of sodium chloride, 2-3 parts of sodium carboxymethylcellulose, 6-31 parts of oxidant, 34-36 parts of inorganic acid, 18-20 parts of diluent and 2-3 parts of adhesive.
Further, the stable composite chlorine dioxide solid pastille comprises the following components in parts by weight: 6.5 parts of sodium chlorate, 9.5 parts of sodium chlorite, 30.5 parts of sodium dichloroisocyanurate, 32.5 parts of sodium bisulfate, 3.5 parts of sodium sulfate, 2.5 parts of boric acid, 15.5 parts of sodium chloride, 2.5 parts of sodium carboxymethylcellulose, 18.5 parts of oxidant, 35 parts of inorganic acid, 19 parts of diluent and 2.5 parts of adhesive.
The invention also discloses a preparation method of the stable composite chlorine dioxide solid pastille, which comprises the following steps:
weighing the components according to the weight parts of the components, respectively grinding, screening and filtering the components, and then grinding for the second time;
step two, drying the components after grinding for 24 hours at the temperature of 75 ℃;
step three, firstly putting the dried sodium chlorate, sodium chlorite, sodium dichloroisocyanurate, sodium bisulfate, sodium sulfate, boric acid, sodium chloride and sodium carboxymethylcellulose into mixing equipment for mixing, then adding an oxidant, adding a diluent, inorganic acid and an adhesive after mixing uniformly, and mixing uniformly to obtain a mixture;
and step three, pressing the mixture into pastilles through a die and a pressing ingot under the environment that the temperature is 20 ℃ and the relative humidity is 30%.
Preferably, the lozenge is 1 gram in weight, i.e., a 100ppm aqueous solution of chlorine dioxide can be obtained by dissolving 1 lozenge in one liter of clear water, which is convenient for use.
The invention with the structure has the following beneficial effects: the stable composite chlorine dioxide solid lozenge prepared by the scheme is compounded with the product standard specified by the state, and solves the problems that the existing chlorine dioxide solid preparation is generally poor in release stability, complicated in time-consuming operation, poor in effect after long-time release and not suitable for occasions needing quick sterilization; the sterilization agent has the advantages of portability, small volume, high reaction speed, convenience in storage, transportation and use, no operation of preparation, metering and the like by a user, environment-friendly residues after use, small influence by temperature and ammonia, basically consistent sterilization effect at low temperature and high temperature, and high sterilization efficiency in a pH range of 2-10; can kill viruses, bacteria, protists, algae, fungi and various spores and thalli formed by the spores, can kill all bacterial propagules and a plurality of pathogenic bacteria under 0.1ppm, and can completely kill the bacterial propagules, hepatitis viruses, bacteriophage and bacterial spores under 50 ppm; it does not produce chlorination reaction with organic matter, carcinogenic, teratogenic, mutagenic and other toxic substances, and when it is less than 500ppm, its influence can be ignored, and when it is less than 100ppm, it has no any influence on human body.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments; all other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1, a stable composite chlorine dioxide solid lozenge comprises the following components in parts by weight: 6 parts of sodium chlorate, 9 parts of sodium chlorite, 30 parts of sodium dichloroisocyanurate, 32 parts of sodium bisulfate, 3 parts of sodium sulfate, 2 parts of boric acid, 15 parts of sodium chloride, 2 parts of sodium carboxymethylcellulose, 6 parts of oxidant, 34 parts of inorganic acid, 18 parts of diluent and 2 parts of adhesive.
A preparation method of a stable compound chlorine dioxide solid lozenge comprises the following steps:
weighing the components according to the weight parts of the components, respectively grinding, screening and filtering the components, and then grinding for the second time;
step two, drying the components after grinding for 24 hours at the temperature of 75 ℃;
step three, firstly putting the dried sodium chlorate, sodium chlorite, sodium dichloroisocyanurate, sodium bisulfate, sodium sulfate, boric acid, sodium chloride and sodium carboxymethylcellulose into mixing equipment for mixing, then adding an oxidant, adding a diluent, inorganic acid and an adhesive after mixing uniformly, and mixing uniformly to obtain a mixture;
and step three, pressing the mixture into pastilles through a die and a pressing ingot under the environment that the temperature is 20 ℃ and the relative humidity is 30%.
Embodiment 2, a stable composite chlorine dioxide solid lozenge, comprising the following components in parts by weight: 6.5 parts of sodium chlorate, 9.5 parts of sodium chlorite, 30.5 parts of sodium dichloroisocyanurate, 32.5 parts of sodium bisulfate, 3.5 parts of sodium sulfate, 2.5 parts of boric acid, 15.5 parts of sodium chloride, 2.5 parts of sodium carboxymethylcellulose, 18.5 parts of oxidant, 35 parts of inorganic acid, 19 parts of diluent and 2.5 parts of adhesive.
A preparation method of a stable compound chlorine dioxide solid lozenge comprises the following steps:
weighing the components according to the weight parts of the components, respectively grinding, screening and filtering the components, and then grinding for the second time;
step two, drying the components after grinding for 24 hours at the temperature of 75 ℃;
step three, firstly putting the dried sodium chlorate, sodium chlorite, sodium dichloroisocyanurate, sodium bisulfate, sodium sulfate, boric acid, sodium chloride and sodium carboxymethylcellulose into mixing equipment for mixing, then adding an oxidant, adding a diluent, inorganic acid and an adhesive after mixing uniformly, and mixing uniformly to obtain a mixture;
and step three, pressing the mixture into pastilles through a die and a pressing ingot under the environment that the temperature is 20 ℃ and the relative humidity is 30%.
Example 3, a stable composite chlorine dioxide solid lozenge comprises the following components in parts by weight: 6-7 parts of sodium chlorate, 9-10 parts of sodium chlorite, 30-31 parts of sodium dichloroisocyanurate, 32-33 parts of sodium bisulfate, 3-4 parts of sodium sulfate, 2-3 parts of boric acid, 15-16 parts of sodium chloride, 2-3 parts of sodium carboxymethylcellulose, 6-31 parts of oxidant, 34-36 parts of inorganic acid, 18-20 parts of diluent and 2-3 parts of adhesive.
A preparation method of a stable compound chlorine dioxide solid lozenge comprises the following steps:
weighing the components according to the weight parts of the components, respectively grinding, screening and filtering the components, and then grinding for the second time;
step two, drying the components after grinding for 24 hours at the temperature of 75 ℃;
step three, firstly putting the dried sodium chlorate, sodium chlorite, sodium dichloroisocyanurate, sodium bisulfate, sodium sulfate, boric acid, sodium chloride and sodium carboxymethylcellulose into mixing equipment for mixing, then adding an oxidant, adding a diluent, inorganic acid and an adhesive after mixing uniformly, and mixing uniformly to obtain a mixture;
and step three, pressing the mixture into pastilles through a die and a pressing ingot under the environment that the temperature is 20 ℃ and the relative humidity is 30%.
It should be noted that, in this document, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (3)
1. A stable composite chlorine dioxide solid pastille is characterized by comprising the following components in parts by weight: 6-7 parts of sodium chlorate, 9-10 parts of sodium chlorite, 30-31 parts of sodium dichloroisocyanurate, 32-33 parts of sodium bisulfate, 3-4 parts of sodium sulfate, 2-3 parts of boric acid, 15-16 parts of sodium chloride, 2-3 parts of sodium carboxymethylcellulose, 6-31 parts of oxidant, 34-36 parts of inorganic acid, 18-20 parts of diluent and 2-3 parts of adhesive.
2. The stable composite chlorine dioxide solid lozenge according to claim 1, comprising the following components in parts by weight: 6.5 parts of sodium chlorate, 9.5 parts of sodium chlorite, 30.5 parts of sodium dichloroisocyanurate, 32.5 parts of sodium bisulfate, 3.5 parts of sodium sulfate, 2.5 parts of boric acid, 15.5 parts of sodium chloride, 2.5 parts of sodium carboxymethylcellulose, 18.5 parts of oxidant, 35 parts of inorganic acid, 19 parts of diluent and 2.5 parts of adhesive.
3. A preparation method of a stable compound chlorine dioxide solid lozenge is characterized by comprising the following steps:
weighing the components according to the weight parts of the components, respectively grinding, screening and filtering the components, and then grinding for the second time;
step two, drying the components after grinding for 24 hours at the temperature of 75 ℃;
step three, firstly putting the dried sodium chlorate, sodium chlorite, sodium dichloroisocyanurate, sodium bisulfate, sodium sulfate, boric acid, sodium chloride and sodium carboxymethylcellulose into mixing equipment for mixing, then adding an oxidant, adding a diluent, inorganic acid and an adhesive after mixing uniformly, and mixing uniformly to obtain a mixture;
and step three, pressing the mixture into pastilles through a die and a pressing ingot under the environment that the temperature is 20 ℃ and the relative humidity is 30%. .
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010432704.1A CN111480657A (en) | 2020-05-20 | 2020-05-20 | Stable composite chlorine dioxide solid lozenge and preparation method thereof |
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| CN202010432704.1A CN111480657A (en) | 2020-05-20 | 2020-05-20 | Stable composite chlorine dioxide solid lozenge and preparation method thereof |
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Citations (8)
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|---|---|---|---|---|
| CN1556046A (en) * | 2003-12-30 | 2004-12-22 | 成都柯邦药业有限公司 | Synergism type chlorine dioxide bactericide and its manufacturing method and use in aquatic culture |
| CN102283246A (en) * | 2011-05-30 | 2011-12-21 | 石家庄科大绿源科技发展有限公司 | Solid chlorine dioxide effervescent tablet and preparation method thereof |
| CN103493843A (en) * | 2013-09-10 | 2014-01-08 | 昆明双玖消毒药业有限公司 | Production formula for neutral chlorine dioxide powder (unitary package) |
| WO2014157484A1 (en) * | 2013-03-29 | 2014-10-02 | ダイソー株式会社 | Tablet for preparing solution of chlorine dioxide |
| CN104138390A (en) * | 2014-06-11 | 2014-11-12 | 龚佳郎 | Chlorine dioxide effervescent tablet for killing barbier bacteria and fungi and preparation method thereof |
| CN106719796A (en) * | 2016-11-19 | 2017-05-31 | 湖南云康共享生物环保有限公司 | A kind of air disinfection sanitizer |
| CN110150315A (en) * | 2019-05-17 | 2019-08-23 | 四川蓝洁绿源环保科技有限公司 | A kind of solid high-pure chlorinedioxide releasing agent |
| CN110292050A (en) * | 2019-04-30 | 2019-10-01 | 广州超威生物科技有限公司 | It is a kind of to adjust the method and chlorine dioxide slow-release gel that chlorine dioxide steadily discharges |
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2020
- 2020-05-20 CN CN202010432704.1A patent/CN111480657A/en active Pending
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| CN102283246A (en) * | 2011-05-30 | 2011-12-21 | 石家庄科大绿源科技发展有限公司 | Solid chlorine dioxide effervescent tablet and preparation method thereof |
| WO2014157484A1 (en) * | 2013-03-29 | 2014-10-02 | ダイソー株式会社 | Tablet for preparing solution of chlorine dioxide |
| CN103493843A (en) * | 2013-09-10 | 2014-01-08 | 昆明双玖消毒药业有限公司 | Production formula for neutral chlorine dioxide powder (unitary package) |
| CN104138390A (en) * | 2014-06-11 | 2014-11-12 | 龚佳郎 | Chlorine dioxide effervescent tablet for killing barbier bacteria and fungi and preparation method thereof |
| CN106719796A (en) * | 2016-11-19 | 2017-05-31 | 湖南云康共享生物环保有限公司 | A kind of air disinfection sanitizer |
| CN110292050A (en) * | 2019-04-30 | 2019-10-01 | 广州超威生物科技有限公司 | It is a kind of to adjust the method and chlorine dioxide slow-release gel that chlorine dioxide steadily discharges |
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